宽分子量分布、宽等规指数分布聚丙烯的制备及在高速BOPP中的应用

分析了非对称外给电子体及非对称加氢气的聚合方法对聚丙烯分子结构的影响,并用DSC和GPC等表征手段对聚丙烯结构进行分析。结果表明:非对称外给电子体技术制备的聚丙烯的等规指数分布较宽,具有低等规度的大分子和高等规度的小分子的特征,使聚丙烯等规序列分布均匀化,有利于提高薄膜挺度,并提高薄膜厚度均匀性,而非对称加氢技术制备的聚丙烯分子量分布较宽,保证了聚丙烯熔体高速拉伸的稳定性。非对称外给电子体和非对称加氢技术制备的聚丙烯具有高速拉膜稳定性好、成膜率高、无破膜,模头无烟雾和油性物质、不结焦,厚薄均匀、表面平整性好,挺度高、透明性好的优点,成功应用于高速、高挺度BOPP工业化生产。

聚丙烯等规序列长度分布对BOPP薄膜加工性能的影响

通过高温凝胶渗透色谱(GPC)、连续自成核退火分级技术(SSA)和升温淋洗分级技术(TREF)研究2种Unipol气相法工艺生产具有不同加工性能的聚丙烯树脂(PP1在BOPP薄膜加工过程发生破膜现象、而在同样条件下PP_2成膜性很好)链结构的差异性。结果表明:2种聚丙烯树脂分子量及分子量分布和等规度几乎是相同的,但等规序列长度分布存在明显的差异,PP_2长等规序列的级份含量比PP_1少,而较长的等规序列级份的含量比PP_1多,平均等规序列的长度比PP_1短,等规序列长度的分布比PP_1宽。

武山铜矿岩溶塌陷规律分析及防治

武山铜矿岩溶地面塌陷主要影响因素包括岩溶地下水水位降落漏斗范围扩展,覆盖层岩性、厚度、构造及岩溶的发育程度等。对武山铜矿南矿带岩溶塌陷进行稳定性分区:南矿带基本稳定区(Ⅰ区);南矿带南部岩溶塌陷不稳定区(Ⅱ区);南矿带南部岩溶塌陷未来不稳定区(Ⅲ区)。提出从时空上及规模上对岩溶塌趋势进行预测预报;做好地面防渗透工作;合理开采,减少沉降等防治岩溶塌陷的对策和建议,对于该地区避免造成居民的生命和财产损失有重要指导意义。

小兴安岭地区天然白桦林直径分布的研究

以伊春林区小兴安岭收集的200块天然白桦林样地资料,对天然白桦林林木直径静态分布规律进行研究的结果表明,本研究区的直径分布情况多数呈单峰山状分布曲线,少数呈反J型曲线,在已知林分直径分布信息的基础上,绘制了径阶株数分布直方图。在现代森林经营决策中通过对直方图的分析,能够了解和掌握全林分总的蓄积量和全林分的各个径阶的分布状态,从而达到获取到材积(或材种出材量)的分布情况。

Distributing Characteristics of the Charge on the Bomb Body with Capacitance Fuze

For establishing the equation of the capacitive target detection accurately, the distributing characteristics of the charges on the bomb body with capacitance fuze were explored. Continuous charges were analyzed dispersively. Based on the Coulomb's law, the dynamic equilibrium equations of the inducing charges on the bomb body were set up. For the four cases of d 0/L (the ratio between the electrode distance and the bomb length), the curves of the charge's distribution were given. It was concluded that: ① the charge density decreases steadily from the end near the frontal electrode to the bomb tail; ② the declining rate of the density is governed by d 0/L , the larger the value of d 0/L ,the higher the declining rate, and vice versa.

Fractal features of size distribution of Chinese intercity bus hubs

Size distribution characteristics of intercity bus hubs in China from 1997 to 2（104 were analyzed regarding highway passenger volume as a size index of intercity bus hubs. Yearly fractal dimensions of intercity bus hub sizes were exactly calculated by a novel model. Fractal dimensions of the 200 biggest intercity bus hubs from 2000 to 2004 were 1. 486 2 to 1. 511 8, and that is consistent with fractal dimensions of Chinese urban system sizes. It showed that the size distribution of intercity bus hubs had fractal structure. Fractal dimensions from 1997 to 2004 indicated that intercity bus hub size distribution grew from bi-fractal to single fractal. It is concluded that the intercity bus hub system is in evolutionary progress, and the Central Government should support large intercity bus hubs more to optimize system structure.

Cross Point Assignment Algorithm Under Consideration of Very Long Nets

A cross point assignment algorithm is proposed under consideration of very long nets (LCPA).It is to consider not only the cost of connection between cross points and pins and the exclusive cost among cross points on the boundary of a global routing cell,but also the cost of displacement among cross points of the same net.The experiment results show that the quality and speed in the following detailed routing are improved obviously,especially for very long nets.

Distributed Sampling Measurement Model in a Large-Scale High-Speed IP Networks

The distributed passive measurement is an important technology for networkbehavior research. To achieve a consistent measurement, the same packets should be sampled atdistributed measurement points. And in order to estimate the character of traffic statistics, thetraffic sample should be random in statistics. A distributed samplingmask measurement model isintroduced to tackle the difficulty of measuring the full trace of high-speed networks. The keypoint of the model is to choose some bits that are suitable to be sampling mask. In the paper, thebit entropy and bit flow entropy of IP packet headers in CERNET backbone are analyzed, and we findthat the 16 bits of identification field in IP packet header are fit to the matching field ofsampling mask. Measurement traffic also can be used to analyze the statistical character ofmeasurement sample and the randomicity of the model. At the same time the experiment resultsindicate that the model has a good sampling performance.

Leaching and Redistribution of Nutrients in Surface Layer of Red Soils in Southeast China

The leaching and redistribution of nutrients in the surface layer of 4 types of red soils in SoutheastChina were studied with a lysimeter experiment under field conditions. Results showed that the leachingconcentrated in the rainy season (from April to June). Generaily, the leaching of soil nutrients from thesurface layer of red soils was in the order of Ca > Mg > K > NO3-N. In fertilization treatment, the totalamount of soil nutrients leached out of the surface layer in a red soil derived from granite was the highest inall soils. The uptake by grass decreased the leaching of fertilizer ions in surface layer, particularly for NO3-N.Soil total N and exchangeable K, Ca and Mg in the surface layer decreased with leaching and grass uptakeduring the 2 years without new fertilization of urea, Ca(H2PO4)2, KCl, CaCO3 and MgCO3. Ca movedfrom the application layer (0~5 cm) of fertilizer and accumulated in the 10~30 cm depth in the soils studiedexcept that derived from Quaternary red clay. The deficiency of soil exchangeable K will become a seriousdegradation process facing the Southeast China.

Key factor analysis and model establishment of variation of rock face temperature in a deep open-pit mine

In recent years, with the increase of the depth of open-pit mining, the pollution level has been on the rise due to harmful gases and dust occurring in the process of mining. In order to accelerate the diffusion of these air pollutants, the distributed regularity of the rock face temperature which is directly related to the air ventilation in deep open-pit mines should be studied. Here, we establish the key factors influencing the rock face temperature in a deep open-pit mine. We also present an empirical model of the rock face temperature variation in the deep open-pit mine, of which the performance is interestingly high compared with that of the field test. This study lays a foundation to study the ventilation thermodynamic theory in the deep open-pit mine, which is of great importance for theoretical studies and engineering applications of solving air pollution problem in deep open-pit mines.

Plastic zone distribution laws and its types of surrounding rock in large-span roadway

In order to study the distribution laws and types of plastic zone of surrounding rock in large-span roadway, we analyzed the distribution laws with different spans and lateral pressures using FLAC3D numerical calcu- lation software. Based on the roadway support difficulty and distribution laws of the plastic zone of sur- rounding rock, we defined the large-span roadway and classified the types of large-span rectangular roadways. As a result, the distribution laws of the plastic zone on surrounding rock in a rectangular roadway with different spans and lateral pressures were obtained. The results show that the area of the plastic zone on surrounding rock increased with the increase of the spans and lateral pressures, and the plastic zone was symmetrical to the center line of roadway. At λ=0.5, 1.0, 1.5, and 2.0, the plastic zone presented ＂addle- shape＂ distribution, ＂ellipse＂ distribution, ＂thin and high＂ distribution and ＂inverse trapezium＂ distribu- tion, respectively. In addition, we classified the roadways into four types according to the different lateral pressures and spans, including small-span, moderate-span, large-span and extreme-large-span roadways.

Distribution of Sediment Chloroplastic Pigments in the Southern Yellow Sea,China

The distribution of sediment chloroplastic pigments (Chl-a, i.e. chlorophylla and Pha-a, i.e. phaeophorbide a) in the Southern Yellow Sea of China was studied. Samples werecollected from four cruises in January and June 2003, and January and June 2004. The results showthat the vertical distribution of Chl-a and Pha-a in the sediment layers 0-2cm, 2-5cm and 5-8cm,follows a stable ratio, 5:3:2. The average ratio of Pha-a to Chl-a in sediment is 2.83. Spearman2-tailed rank correlation analysis shows that Chl-a and Pha-a contents in each sediment layer have ahighly significant correlation. The average contents of Chl-a and Pha-a in the sediment of the0-8cm layer in the investigated area are 0.31-0.47 μg g^(-1) and 1.28-1.40 μg g^(-1) sediment (dryweight), respectively. The average Chl-a and Pha-a contents in sediment are higher in summer thanin winter. ANOVA analysis shows that there is a highly significant variation among the Chl-acontents (P = 0.002 【 0.01) of the four cruies, but this is not true for the case of Pha-a content(P = 0.766 】0.05). The average Chl-a and Pha-a contents in the 2 sediment layers (0-2cm and 2-5cm)have significant or highly significant correlations with organic matter (OM), median diameter(Md_φ), silt plus clay percentage in the January 2003 cruise. In the June 2003 cruise, the averageChl-a content in the 3 sediment layers (0-2cm, 2-5cm, and 5-8cm) has a significant correlation withmeiofauna biomass, and Pha-a content has highly significant correlations with water depth, bottomwater temperature, OM and Md_φ. The contents of Chl-a and Pha-a are lower than those in estuariesand intertidal areas, but close to those in the same area studied previously.

Temperature Stress Analysis of Prestressed Concrete Box Girder with Corrugated Steel Webs

To figure out the distribution of temperature gradient along the girder height of steel-concrete composite box girder, combined with the mechanical characteristics of prestressed concrete composed box girder with corrugated steel webs, the calculation formulas of cross-sectional temperature stress along the span in a simply-supported beam bridge with composite section were derived under the conditions of static equilibrium and deformation compatibility of the beam element. The methods of calculating the maximum temperature stress value were discussed when the connectors are assumed rigid or flexible. Theoretical and numerical results indicate that the method proposed shows better precision for the calculation of temperature self-stress in both the top and the bottom surfaces of the box girder. Moreover, the regularity of temperature stress distribution at different locations along the girder span is that the largest axial force of the top or the bottom plate of the box girder is located in the midspan and spreads decreasingly until zero at both supported ends, and that the greatest longitudinal shear density in steel-concrete interface appears at both supported ends and then reduces gradually to zero in the midspan.

Braided river and distribution patterns of sand bodies of Jurassic Badaowan formation in Block T13 of Junggar basin

In order to determine the planar and volume distribution of sand bodies of the Jurassic Badaowan formation in Block T13 of Junggar basin,we used analysis of field outcrop and 3D seismic data,which play an essential role in areas of sparse well coverage.We describe sedimentary facies characteristics,sand body planforms,width and connectivity patterns of sand bodies,and vertical associations and successions by acoustic impedance inversion technology and sedimentological theory.Results of our study show braided fluvial strata deposits in the Jurassic Badaowan formation.Each sand body is approximately lenticular in shape.The width of each sand body falls in the range 100～800 m,with most between 200 and 400 m.The sand bodies vary in thickness from 4 to 13 m,with most below 9 m.The width/thickness ratios lie in the range 20～55.The connectivity of braided fluvial channel sand bodies is controlled by changes of accommodation space.One fining-upward sedimentary cycle of base-level rise is recognized in Badaowan formation,representing an upward rise of base level.The connectivity of sand bodies was found to be greatest in the early stage of base-level rise,becoming progressively worse with increasing base-level rise.

Relationship Between Soil Properties and Different Fractions of Soil Hg

Correlation and path analysis methods were used to study the relationship between soil properties and the distribution of different soil Hg fractions with nine representative soils from Chongqing, China. Results showed that clay (< 2 m) could increase water-soluble Hg (r = 0.700*). Soil organic matter (OM) could enhance the increase of elemental Hg (r = 0.674*). The higher the base saturation percentage (BSP), the more the residual Hg (T = 0.684*). Organic Hg, the sum of acid-soluble organic Hg and alkali-soluble Hg, was positively affected by silt (2-20 μm) but negatively affected by pH, with the direct path coefficients amounting to 1.0487 and 0.5121, respectively. The positive effect of OM and negative effect of BSP on organic Hg were the most significant, with the direct path coefficients being 0.7614 and -0.8527, respectively. The indirect effect of clay (< 2 μm) via BSP (path coefficient = 0.4186) was the highest, showing that the real influencing factor in the effect of clay (< 2 μm) on acid-soluble organic Hg was BSP. Since the available Hg fraction, water-soluble Hg, was positively affected by soil clay content, and the quite immobile and not bioavailable residual Hg by soil BSP, suitable reduction of clay content and increase of BSP would be of much help to reduce the Hg availability and Hg activity in Hg-contaminated soils.

Gully Erosion Regionalization of Black Soil Area in Northeastern China

Gully erosion is the frequent and main form of soil erosion in the black soil area of the northeastern China, which is one of the most important commodity grain production bases in China. It is encroaching upon the fertile farmland there. Regionalization of gully erosion can reveal the spatial distribution and regularity of the development of gully erosion. Based on the eco-geographical regional background features of the black soil area, this study combined the regionalization with influencing factors of the development of gully erosion. GIS spatial analysis, geostatistical analysis, spatial statistics, reclassification, debris polygon processing and map algebra methods were employed. As a result, the black soil area was divided into 12 subregions. The field survey data on type, length, volume and other characteristics indicators of gully erosion were used to calibrate the results. Then the features of every subregion, such as where the gully erosion is, how serious it is, and why it happens and develops, were expounded. The result is not only an essential prerequisite for gully erosion surveys and monitoring, but also an important basis for gully erosion prevention.

Coal seam methane distribution and its significance in Pingdingshan mining area

A study aimed at the coal seam group E and F in Pingdingshan mining area has been completed. This study is on the relationship of the coal seam methane reserve to coal thickness, coal rank, coal seam depth, surrounding rock and geological structure and other factors. The study indicates that different geological factor plays different role in controlling the law of coal seam methane reserve. The coal seam methane rich area, which was formed because of various factors and comprehensive effect, is the coal and methane outburst prone area, and also the key area for coal bed methane recovery. Among all factors, coal seam depth and geological structure is more important factor in affecting coal seam methane content in Pingdingshan mining area.

Theory and test research on permeability of coal and rock body influenced by mining

Stress distribution rules and deformation and failure properties of coal and rockbodies influenced by mining were analyzed.Experimental research on permeability of coaland rock samples under different loading conditions was finished in the laboratory.In-situmeasurement of coal permeability influenced by actual mining was done as well.Theoryanalysis show that permeability varied with damage development of coal and rock understress,and the influence of fissure on permeability was greatest.Laboratory results showthat under different loading conditions permeability was different and it varied with stress,which indicated that permeability was directly related to the loading process.In-situ testsshowed that permeability is related to abutment stress to some degree.The above resultsmay be referenced to gas prevention and drainage.

Distribution laws of abutment pressure around fully mechanized top-coal caving face by in-situ measurement

In order to obtain the distribution rules of abutment pressure around the 1151 （3） fully mechanized top-coal caving （FMTC） face of Xieqiao Colliery, the KSE-II-1 type bore-hole stress gauges were installed in the tailentry and headentry to measure the mining-induced stress. The distribution rules of the front and side abutment pressure were demonstrated. The results show that distribution rules of stress are obviously different in the vicinity of the face and entries. The peak value of abutment pressure in the protective coal pillar and face are located commonly in front of the working face along the strike, and they are located at the stress-decreased zone near the face. There is no stress peak value in the lateral coal mass beside the headentry in front of the face on the strike, and the peak value of abutment pressure appears at the rear area of the face. There are stress peak values both in the protective coal pillar and in the lateral coal mass beside the headentry to the dip.

Designing an optimal stope layout for underground mining based on a heuristic algorithm

An optimal layout or three-dimensional spatial distribution of stopes guarantees the maximum profitability over life span of an underground mining operation.Thus,stope optimization is one of the key areas in underground mine planning practice.However,the computational complexity in developing an optimal stope layout has been a reason for limited availability of the algorithms offering solution to this problem.This article shares a new and efficient heuristic algorithm that considers a three-dimensional ore body model as an input,maximizes the economic value,and satisfies the physical mining and geotechnical constraints for generating an optimal stope layout.An implementation at a copper deposit demonstrates the applicability and robustness of the algorithm.A parallel processing based modification improving the performance of the original algorithm in terms of enormous computational time saving is also presented.