Distribution behavior of ketoprofen enantiomers was examined in methanol aqueous and organic solvent mixture containing tartaric esters. The influence of length of alkyl chain of tartaric esters, concentration of L-ta...Distribution behavior of ketoprofen enantiomers was examined in methanol aqueous and organic solvent mixture containing tartaric esters. The influence of length of alkyl chain of tartaric esters, concentration of L-tartaric esters and methanol aqueous, kind of organic solvent on partition ratio and separation factors was investigated. The results show that L-tartaric and D-tartaric esters have different chiral recognition abilities. S-ketoprofen is easily extracted by L-tartaric esters, and R-ketoprofen is easily extracted by D-tartaric esters. L-tartaric esters form more stable diastereomeric complexes with S-enantiomer than that with R-enantiomer. This distribution behavior is consistent with chiral recognition mechanism. With the increase of the concentration of tartaric ester from 0 to 0.3 mol/L, partition coefficient K and separation factor a increase. Also, the kind of organic solvent and the concentration of the methanol aqueous have significant influence on K and a.展开更多
In this paper, the (G′/G)-expansion method is extended to solve fractional partial differential equations in the sense of modified Riemann-Liouville derivative. Based on a nonlinear fractional complex transformation,...In this paper, the (G′/G)-expansion method is extended to solve fractional partial differential equations in the sense of modified Riemann-Liouville derivative. Based on a nonlinear fractional complex transformation, a certain fractional partial differential equation can be turned into another ordinary differential equation of integer order. For illustrating the validity of this method, we apply it to the space-time fractional generalized Hirota-Satsuma coupled KdV equations and the time-fractional fifth-order Sawada-Kotera equation. As a result, some new exact solutions for them are successfully established.展开更多
基金Project(20376085) supportecd by the National Natural Science Foundation of China
文摘Distribution behavior of ketoprofen enantiomers was examined in methanol aqueous and organic solvent mixture containing tartaric esters. The influence of length of alkyl chain of tartaric esters, concentration of L-tartaric esters and methanol aqueous, kind of organic solvent on partition ratio and separation factors was investigated. The results show that L-tartaric and D-tartaric esters have different chiral recognition abilities. S-ketoprofen is easily extracted by L-tartaric esters, and R-ketoprofen is easily extracted by D-tartaric esters. L-tartaric esters form more stable diastereomeric complexes with S-enantiomer than that with R-enantiomer. This distribution behavior is consistent with chiral recognition mechanism. With the increase of the concentration of tartaric ester from 0 to 0.3 mol/L, partition coefficient K and separation factor a increase. Also, the kind of organic solvent and the concentration of the methanol aqueous have significant influence on K and a.
文摘In this paper, the (G′/G)-expansion method is extended to solve fractional partial differential equations in the sense of modified Riemann-Liouville derivative. Based on a nonlinear fractional complex transformation, a certain fractional partial differential equation can be turned into another ordinary differential equation of integer order. For illustrating the validity of this method, we apply it to the space-time fractional generalized Hirota-Satsuma coupled KdV equations and the time-fractional fifth-order Sawada-Kotera equation. As a result, some new exact solutions for them are successfully established.
