ZrO2/PMMA nanocomposite particles are synthesized through an in-situ free radical emulsion polymerization based on the silane coupling agent （Z-6030） modified ZrO2 nanoparticles, and the morphology, size and its dis...ZrO2/PMMA nanocomposite particles are synthesized through an in-situ free radical emulsion polymerization based on the silane coupling agent （Z-6030） modified ZrO2 nanoparticles, and the morphology, size and its distribution of nanocomposite particles are investigated. Scanning electron microscopy （SEM） images demonstrate that the methyl methacrylate （MMA） feeding rate has a significant effect on the particle size and morphology. When the MMA feeding rate decreases from 0.42 ml-min-1 to 0.08 ml. min-1, large particles （about 200-550.nm） will not form, and the size distribution become narrow （36-54 nm）. The average nanocomposite particles size increases from 34 nm to 55 nm, as the MMA/ZrO2 nanoparticles mass ratio increased from 4 ： 1 to 16 ： 1. Regular spherical ZrO2/PMMA nanocomposite particles are synthesized when the emulsifier OP-10 concentration is 2 mg.m1-1. The nanocomposite particles could be mixed with VAc-VeoVa10 polymer matrix just by magnetic stirring to prepare the ZrOE/PMMA/VAc-VeoVal0 hybrid coatings. SEM and atomic force microscopy （AFM） photos reveal that the distribution of the ZrO2/PMMA nanocomposite particles in the VAc-VeoVal0 polymer matrix is homogenous and stable. Here, the grafted-PMMA polymer on ZrO2 nanoparticles plays as a bridge which effectively connects the ZrO2 nanoparticles and the VAc-VeoVal0 polymer matrix with improved comparability. In consequence, the hybrid coating with good dispersion stability is obtained.展开更多
Axial liquid dispersion was experimentally studied in liquid-solid and gas-liquid-solid magnetically stabilized beds using the ferromagnetic catalyst of SRNA-4 as the solid phase. The effects of operating factors and ...Axial liquid dispersion was experimentally studied in liquid-solid and gas-liquid-solid magnetically stabilized beds using the ferromagnetic catalyst of SRNA-4 as the solid phase. The effects of operating factors and fluid characters, such as superficial liquid velocity, superficial gas velocity, magnetic field intensity, liquid viscosity and surface tension, on axial dispersion coefficients of liquid were investigated. The dispersion coefficients increased with the increase of superficial liquid velocity and superficial gas velocity, and decreased with the increase of liquid viscosity, liquid surface tension and magnetic field intensity. A correlation equation of Peclet number was obtained for both liquid-solid and gas-liquid-solid magnetically stabilized bed.展开更多
A numerical method was developed to directly simulate the compressible, particle-laden turbulent jets.The fourth order compact finite difference schemes were used to discretize the space derivatives. The Lagrangian me...A numerical method was developed to directly simulate the compressible, particle-laden turbulent jets.The fourth order compact finite difference schemes were used to discretize the space derivatives. The Lagrangian method was adopted to simulate the particle motion based on one-way coupling. It is found that the turbulent intensity profiles attain self-similar status in the jet downstream regions. At the Stokes number of 1, particles are concentrated largely in the outer boundaries of the large-scale vortex structures with the most uneven distribution and the widest dispersion in the lateral direction. Particles at the much smaller Stokes numbers are distributed evenly in the flow field, and the lateral dispersion is also considerable. Distribution of particles at much larger Stokes numbers is more uniform and the lateral dispersion becomes small. In addition, the inflow conditions have different effects on the particle dispersion. The direct numerical simulation (DNS) results accord with the previous experiments and numerical studies.展开更多
In this paper methods of differential inequalities and Liapunov functionals for proving the global stability of constant equilibria of reaction-diffusion systems are given, and examples for showing how to use these me...In this paper methods of differential inequalities and Liapunov functionals for proving the global stability of constant equilibria of reaction-diffusion systems are given, and examples for showing how to use these methods are also given.展开更多
基金Supported by Production, Teaching & Research Combination Project for Universities in Guangdong Province(cgzhzd0904),Department of Education of Guangdong Province, China
文摘ZrO2/PMMA nanocomposite particles are synthesized through an in-situ free radical emulsion polymerization based on the silane coupling agent （Z-6030） modified ZrO2 nanoparticles, and the morphology, size and its distribution of nanocomposite particles are investigated. Scanning electron microscopy （SEM） images demonstrate that the methyl methacrylate （MMA） feeding rate has a significant effect on the particle size and morphology. When the MMA feeding rate decreases from 0.42 ml-min-1 to 0.08 ml. min-1, large particles （about 200-550.nm） will not form, and the size distribution become narrow （36-54 nm）. The average nanocomposite particles size increases from 34 nm to 55 nm, as the MMA/ZrO2 nanoparticles mass ratio increased from 4 ： 1 to 16 ： 1. Regular spherical ZrO2/PMMA nanocomposite particles are synthesized when the emulsifier OP-10 concentration is 2 mg.m1-1. The nanocomposite particles could be mixed with VAc-VeoVa10 polymer matrix just by magnetic stirring to prepare the ZrOE/PMMA/VAc-VeoVal0 hybrid coatings. SEM and atomic force microscopy （AFM） photos reveal that the distribution of the ZrO2/PMMA nanocomposite particles in the VAc-VeoVal0 polymer matrix is homogenous and stable. Here, the grafted-PMMA polymer on ZrO2 nanoparticles plays as a bridge which effectively connects the ZrO2 nanoparticles and the VAc-VeoVal0 polymer matrix with improved comparability. In consequence, the hybrid coating with good dispersion stability is obtained.
基金Supported by the National Natural Science Foundation of China （No.20206023） and SIN0PEC （No.X504029）.
文摘Axial liquid dispersion was experimentally studied in liquid-solid and gas-liquid-solid magnetically stabilized beds using the ferromagnetic catalyst of SRNA-4 as the solid phase. The effects of operating factors and fluid characters, such as superficial liquid velocity, superficial gas velocity, magnetic field intensity, liquid viscosity and surface tension, on axial dispersion coefficients of liquid were investigated. The dispersion coefficients increased with the increase of superficial liquid velocity and superficial gas velocity, and decreased with the increase of liquid viscosity, liquid surface tension and magnetic field intensity. A correlation equation of Peclet number was obtained for both liquid-solid and gas-liquid-solid magnetically stabilized bed.
基金Supported by the Natural Science Foundation of Zhejiang Province (No. 502047 and No. M503094)National Basic Research Program of China (No. 2003CB214500).
文摘A numerical method was developed to directly simulate the compressible, particle-laden turbulent jets.The fourth order compact finite difference schemes were used to discretize the space derivatives. The Lagrangian method was adopted to simulate the particle motion based on one-way coupling. It is found that the turbulent intensity profiles attain self-similar status in the jet downstream regions. At the Stokes number of 1, particles are concentrated largely in the outer boundaries of the large-scale vortex structures with the most uneven distribution and the widest dispersion in the lateral direction. Particles at the much smaller Stokes numbers are distributed evenly in the flow field, and the lateral dispersion is also considerable. Distribution of particles at much larger Stokes numbers is more uniform and the lateral dispersion becomes small. In addition, the inflow conditions have different effects on the particle dispersion. The direct numerical simulation (DNS) results accord with the previous experiments and numerical studies.
基金This research is supportedby the National Natural Science Foundation of China(No. 19971004 and19331043).
文摘In this paper methods of differential inequalities and Liapunov functionals for proving the global stability of constant equilibria of reaction-diffusion systems are given, and examples for showing how to use these methods are also given.
