A series of poly（acrylic acid） macromolecular chain transfer agents with different molecular weights were synthesized by reversible addition-fragmentation chain transfer （RAFT） poly- merization and characterized b...A series of poly（acrylic acid） macromolecular chain transfer agents with different molecular weights were synthesized by reversible addition-fragmentation chain transfer （RAFT） poly- merization and characterized by 1^H NMR and gel permeation chromatography. Multiresponsive core-shell nanogels were prepared by dispersion polymerization of N-isopropylacrylamide in water using these poly（potassium acrylate） macro-RAFT agents as the electrostcric stabilizer. The size of the nanogels decreases with the amount of the macro-RAFT agent, indicating that the surface area occupied by per polyelectrolyte group is a critical parameter for stabilizing the nanogels. The volume phase transition and the zeta potentials of the nanogels in aqueous solutions were studied by dynamic light scattering and zetasizer analyzer, respectively.展开更多
The accuracy of hard core attractive Yukawa (HCAY) potential and adhesivehard sphere (AH) potential in representing the structure factor of short range square well potentialand Asakura and Oosawa (AO) depletion potent...The accuracy of hard core attractive Yukawa (HCAY) potential and adhesivehard sphere (AH) potential in representing the structure factor of short range square well potentialand Asakura and Oosawa (AO) depletion potential is examined by comparing theoretical predictionswith the existing simulation data and the present numerical results from the non-linear optimizedrandom phase approximation closure for Ornstein—Zernike equation. For the case of square-well (SW)potential, it is shown that the structure factor of HCAY potential based on a recently proposedsemi-analytical expression for the radial distribution function can describe the structure factor ofSW potential with reduced well width λ ≤ 2 only if the reduced contact potential βε_(sw) ≤0.25, while the analytical expression for the structure factor of AH potential under Percus-Yevick(PY) approximation completely fails for the case of λ 】 1.2. For the case of AO depletionpotential, the domain of validity of both HCAY potential and AH potential is complementary. With theabove analysis and considering the solid-liquid transition of the AH potential with an adhesiveparameter τ below 1.31 cannot be predicted by modified weighted density approximation, the roleplayed by the HCAY potential about the mapping manipulation should not be ignored.展开更多
We analyze the dynamics of a bright soliton in atomic scattering length in an expulsive parabolic potential. Bose-Einstein condensates （BECs） with time-dependent Under a safe ravage of parameters in which the Gross...We analyze the dynamics of a bright soliton in atomic scattering length in an expulsive parabolic potential. Bose-Einstein condensates （BECs） with time-dependent Under a safe ravage of parameters in which the Gross-Pitaevskii （GP） equation is effective in one dimension, our results show that, the dynamics of the bright soliton can be classed into two phases, depending on the value of the scattering length. Meanwhile, there exists a critical value of the absolute value of the atomic scattering length, below which, the dynamics of the bright soliton is very regular. Those phenomena can be useful for developing concrete applications of the nonlinear matter waves. We also obtain the orbital equation of the bright soliton and get some interesting data which may be useful for the experimental observation of the bright soliton and the application of the atom laser with manipulated intensity.展开更多
文摘A series of poly（acrylic acid） macromolecular chain transfer agents with different molecular weights were synthesized by reversible addition-fragmentation chain transfer （RAFT） poly- merization and characterized by 1^H NMR and gel permeation chromatography. Multiresponsive core-shell nanogels were prepared by dispersion polymerization of N-isopropylacrylamide in water using these poly（potassium acrylate） macro-RAFT agents as the electrostcric stabilizer. The size of the nanogels decreases with the amount of the macro-RAFT agent, indicating that the surface area occupied by per polyelectrolyte group is a critical parameter for stabilizing the nanogels. The volume phase transition and the zeta potentials of the nanogels in aqueous solutions were studied by dynamic light scattering and zetasizer analyzer, respectively.
文摘The accuracy of hard core attractive Yukawa (HCAY) potential and adhesivehard sphere (AH) potential in representing the structure factor of short range square well potentialand Asakura and Oosawa (AO) depletion potential is examined by comparing theoretical predictionswith the existing simulation data and the present numerical results from the non-linear optimizedrandom phase approximation closure for Ornstein—Zernike equation. For the case of square-well (SW)potential, it is shown that the structure factor of HCAY potential based on a recently proposedsemi-analytical expression for the radial distribution function can describe the structure factor ofSW potential with reduced well width λ ≤ 2 only if the reduced contact potential βε_(sw) ≤0.25, while the analytical expression for the structure factor of AH potential under Percus-Yevick(PY) approximation completely fails for the case of λ 】 1.2. For the case of AO depletionpotential, the domain of validity of both HCAY potential and AH potential is complementary. With theabove analysis and considering the solid-liquid transition of the AH potential with an adhesiveparameter τ below 1.31 cannot be predicted by modified weighted density approximation, the roleplayed by the HCAY potential about the mapping manipulation should not be ignored.
基金Supported by National Natural Science Foundation of China under Grant Nos.90406017 and 60525417the NKBRSF of China under Grant No.2006CB921400
文摘We analyze the dynamics of a bright soliton in atomic scattering length in an expulsive parabolic potential. Bose-Einstein condensates （BECs） with time-dependent Under a safe ravage of parameters in which the Gross-Pitaevskii （GP） equation is effective in one dimension, our results show that, the dynamics of the bright soliton can be classed into two phases, depending on the value of the scattering length. Meanwhile, there exists a critical value of the absolute value of the atomic scattering length, below which, the dynamics of the bright soliton is very regular. Those phenomena can be useful for developing concrete applications of the nonlinear matter waves. We also obtain the orbital equation of the bright soliton and get some interesting data which may be useful for the experimental observation of the bright soliton and the application of the atom laser with manipulated intensity.
