赋能动力学色谱法快速海水提铀研究

作为重要的分离和分析手段,液相色谱法主要应用在分析化学领域,而在核素分离工作中报道十分罕见。本项目基于动力学色谱理论基础,研发出一种脉冲式进样-赋能动力学色谱柱,色谱柱的填料采用粒径为0.2 mm的惰性二氧化硅,柱长为5 m,色谱分离单元约3.06万个。通过改变色谱柱外界条件,分析铀酰离子在色谱柱内的运动情况;通过水浴加热、超声波和外加磁场对色谱柱进行赋能,以提高离子相互分离的效果;在不同进样流速和温度下,研究混合核素的分离情况,得到最佳分离条件及色谱柱的动力学特性。结果表明,样品流速为4.109 mL·min^(−1),色谱柱加热温度为50℃,此时铀酰离子和钠离子的分离因数为1.1854。以最佳分离条件进行海水提铀,得到铀和钠离子的分离因数为α=1.575,实现海水中铀和钠离子分离理论上需要20级。脉冲式进样-赋能动力学色谱柱能够高效快速地实现海水中铀的分离提取。文中采用的创新性方法,还可应用于其他核素的分离研究。

就业与家庭照顾间的平衡:基于性别与职业位置的比较

本文使用第三期妇女地位调查资料,对城镇家庭女性的工作和家庭平衡问题进行研究。女性的双重压力依然存在,家务劳动依然占据女性更多的时间;但在职业方面女性的时间付出几乎与男性相同。女性高层人才兼顾事业和家庭,是工作和家务时间付出最多的人。当代城镇夫妻共在职场,男性更可能因工作忙而顾不上家庭。对0-3岁孩子的抚育上,家庭支持网络应对单位制的解体,夫妻双系的父母帮助成为最主要的力量;部分高层人才依靠市场力量,雇佣家政工来帮助抚育,但受到经济条件的制约在一般从业者中这一比例并不高。

190kA大型预焙槽焦粒焙烧启动新技术

通过对大型预焙电解槽焦粒焙烧启动方法的深入研究 ,对焙烧时间、分流方法、分流时间、分流量等参数的分析研究 ,探索出一套焙烧启动技术 。

Numerical simulation of flow regions in red mud separation thickener's feedwell by analysis of residence-time distribution

The residence-time distribution （RTD） and the compartment model were applied to characterizing the flow regions in red mud separation thickener’s feedwells. Combined with the experimental work, validated mathematical model as well as three-dimensional computational fluid dynamics （CFD） model was established to analyze the flow regions of feedwells on an industrial scale. The concept of RTD, although a well-known method for the characterization of mixing behavior in conventional mixers and reactors, is still a novel measure for the characterization of mixing in feedwells. Numerical simulation results show that the inlet feed rate and the aspect ratio of feedwells are the most critical parameters which affect the RTD of feedwell. Further simulation experiments were then carried out. Under the optimal operation conditions, the volume fraction of dead zone can reduce by10.8% and an increasement of mixing flow volume fraction by 6.5% is also observed. There is an optimum feed inlet rate depending on the feedwell design. The CFD model in conjunction with the RTD analysis then can be used as an effective tool in the design, evaluation and optimization of thickener feedwell in the red mud separation.

校正改良早期预警评分法在急诊留观患者中的应用

探讨校正改良早期预警评分法在急诊留观患者中的应用。方法:选取2018年3月~2019年3月在我院急诊观察室留院观察的患者88例,随机分为试验组和对照组两组,每组44例。对照组实施常规病情评估及分流处理,试验组则采用校正改良早期预警评分法对患者进行病情评估,根据评分对患者进行合理的分流处理。观察并比较两组患者留观时间及对观察室的护理满意度。结果:试验组患者留院观察的时间显著短于对照组,差异有统计学意义(P<0.05);试验组患者对观察室的护理满意度显著高于对照组,差异有统计学意义(P<0.05)。结论:将校正改良早期预警评分法应用于急诊留观患者中,可更为准确地评估和监测急诊留观患者的病情,为留观患者的合理分流提供理论依据,使医疗资源得到合理利用,提高观察室护理满意度。

The Relationship Between Hysteresis and Liquid Flow Distribution in Trickle Beds

Experiments were conducted on a trickle bed with 0.283m ID to elucidate the relationship between hysteretic phenomena and liquid distribution. The hysteresis of pressure drop and the variance of radial liquid distribution were observed simultaneously. Residence time distribution (RTD), holdup and mean residence time (RT) of liquid phase were also found to demonstrate hysteresis of the same nature. RTD, liquid holdup and mean RT calculated with a simple model from the distribution of liquid flow rate show characteristics consistant with the experimental data, suggesting that the hyteretic phenomena originate from the multiplicity and nonuniformity of liquid flow distribution.

THERMAL EFFECTS OF BUILDING′S EXTERNAL SURFACES IN CITY——Characteristics of Heat Flux into and out of External Wall Surfaces

This study examined the thermal effects of building′s external wall surfaces, using observational data of spatial-temporal distribution of surface temperature, air temperature, and heat flux into and out of external surface. Results indicate that external wall surface temperature and nearby air temperature vary with the change of orientation, height and season. In general, the external wall surface temperature is lower near the ground, and is higher near the roof, than nearby air temperature. But north wall surface temperature is mostly lower than nearby air temperature at the same height; south wall surface temperature during the daytime in December, and west wall surface temperature all day in August, is respectively higher than nearby air temperature. The heat fluxes into and out of external wall surfaces show the differences that exist in the various orientations, heights and seasons. In December, south wall surface at the lower sites emits heat and north wall surface at the higher sites absorbs heat. In April, all external wall surfaces, emit heat near the ground and absorb heat near the roof. In August, west wall surface all day emits heat, and other wall surfaces just show the commensurate behavior with that in April.

Analysis of Turbulence Structure in the Stirred Tank with a Deep Hollow Blade Disc Turbine by Time-resolved PIV

The turbulence structure in the stirred tank with a deep hollow blade(semi-ellispe) disc turbine(HEDT) was investigated by using time-resolved particle image velocimetry(TRPIV) and traditional PIV.In the stirred tank,the turbulence generated by blade passage includes the periodic components and the random turbulent ones.Traditional PIV with angle-resolved measurement and TRPIV with wavelet analysis were both used to obtain the random turbulent kinetic energy as a comparison.The wavelet analysis method was successfully used in this work to separate the random turbulent kinetic energy.The distributions of the periodic kinetic energy and the random turbulent kinetic energy were obtained.In the impeller region,the averaged random turbulent kinetic energy was about 2.6 times of the averaged periodic one.The kinetic energies at different wavelet scales from a6 to d1 were also calculated and compared.TRPIV was used to record the sequence of instantaneous velocity in the impeller stream.The evolution of the impeller stream was observed clearly and the sequence of the vorticity field was also obtained for the identification of vortices.The slope of the energy spectrum was approximately-5/3 in high frequency representing the existence of inertial subrange and some isotropic properties in stirred tank.From the power spectral density(PSD) ,one peak existed evidently,which was located at f0(blade passage frequency) generated by the blade passage.

Is percutaneous endoscopic gastrostomy tube placement safe in patients with ventriculoperitoneal shunts?

AIM:To investigate whether percutaneous endoscopic gastrostomy (PEG) tube placement is safe in patients with ventriculoperitoneal (VP) shunts.METHODS: This was a retrospective study of all patients undergoing PEG insertion at our institution between June 1999 and June 2006. Post-PEG complications were compared between two groups according to the presence or absence of VP shunts. VP shunt infection rates, the interval between PEG placement and VP shunt catheter insertion, and long-term follow-up were also investigated.RESULTS: Fifty-five patients qualified for the study. Seven patients (12.7%) had pre-existing VP shunts. All patients received prophylactic antibiotics. The complication rate did not differ between VP shunt patients undergoing PEG (PEG/VP group) and non-VP shunt patients undergoing PEG (control group) [1 (14.3%) vs 6 (12.5%), P=1.000]. All patients in the PEG/VP group had undergone VP shunt insertion prior to PEG placement. The mean interval between VP shunt insertion and PEG placement was 308.7 d (range, 65-831 d). The mean follow-up duration in the PEG/VP group was 6.4 mo (range, 1-15 mo). There were no VP shunt infections, although one patient in the PEG/VP group developed a minor peristomal infection during follow-up.CONCLUSION: Complications following PEG placement in patients with VP shunts were infrequent in this study.

Velocity Component Comparison between CFD and EFD in Taylor Vortex Flow

Since the classical investigation of the Taylor vortex by G. I. Taylor in 1923, many researchers have studied the Taylor vortex as one of the most important vortex types in flow. In this study, the inner cylinder is rotating, while the outer cylinder, which is concentric with the inner cylinder, is stationary. In addition, the measurement of the velocity distribution is carried out by the PIV （Particle Image Velocimetry） method. The radius of the inner cylinder is 20 mm, and that of the outer cylinder is 30 mm. In this study, Re = 650-1,200 is assumed. In the upper part of the apparatus, movable ends are fixed to the upper and lower sides of the cylinder to change the aspect ratio. The aspect ratio is defined as the ratio of cylinder height to gap distance. A servo motor to rotate the inner cylinder, a servo-motor control device, a servo amplifier for rotation speed control, and a YAG laser light source are installed in the apparatus. For the visualization of Taylor vortex flow, aluminum powder composed of scale like fine particles is used. As tracer particles used in the PIV method, fluorescent particles with a size of 48 Ixm were used. The governing equations are Navier-Stokes equations with cylindrical coordinates （r, θ, z） and the equations of continuity. Each physical value is nondimensionalized using the angular velocity of the inner cylinder as the representative velocity, and the radius difference between the inner and outer cylinders as the representative length. Discretization of the governing equations is based on the MAC method. The results of EFD and CFD （computational fluid dynamics） are compared. The mode bifurcation is observed, and the flow structure is investigated.

Oil–water two-phase flow pattern analysis with ERT based measurement and multivariate maximum Lyapunov exponent

Oil–water two-phase flow patterns in a horizontal pipe are analyzed with a 16-electrode electrical resistance tomography(ERT) system. The measurement data of the ERT are treated as a multivariate time-series, thus the information extracted from each electrode represents the local phase distribution and fraction change at that location. The multivariate maximum Lyapunov exponent(MMLE) is extracted from the 16-dimension time-series to demonstrate the change of flow pattern versus the superficial velocity ratio of oil to water. The correlation dimension of the multivariate time-series is further introduced to jointly characterize and finally separate the flow patterns with MMLE. The change of flow patterns with superficial oil velocity at different water superficial velocities is studied with MMLE and correlation dimension, respectively, and the flow pattern transition can also be characterized with these two features. The proposed MMLE and correlation dimension map could effectively separate the flow patterns, thus is an effective tool for flow pattern identification and transition analysis.

Meteorological Data Generation for the Numerical Simulation of Stratified Flow in the Joumine Reservoir, Tunisia

Dynamic numerical simulation of water conditions is useful for reservoir management. In remote semi-arid areas, however, meteorological and hydrological time-series data needed for computation are not frequently measured and must be obtained using other information. This paper presents a case study of data generation for the computation of thermal conditions in the Joumine Reservoir, Tunisia. Data from the Wind Finder web site and daily sunshine duration at the nearest weather stations were utilized to generate cloud cover and solar radiation data based on meteorological correlations obtained in Japan, which is located at the same latitude as Tunisia. A time series of inflow water temperature was estimated from air temperature using a numerical filter expressed as a linear second-order differential equation. A numerical simulation using a vertical 2-D （two-dimensional） turbulent flow model for a stratified water body with generated data successfully reproduced seasonal thermal conditions in the reservoir, which were monitored using a thermistor chain.

Growth of Semi-Insulating GaN Using N2 as Nucleation Layer Carrier Gas Combining with an Optimized Annealing Time

Semi-insulating （SI） GaN is grown using N2 as the nucleation layer （NL） carrier gas combined with an optimized annealing time by metalorganic chemical vapour deposition. Influence of using 1-12 and N2 as the NL carrier gas is investigated in our experiment. It is found that the sheet resistance of unintentionally doped GaN can be increased from 10^4 Ω/sq to 10^10 Ω/sq by changing the NL carrier gas from 1-12 to N2 while keeping the other growth parameters to be constant, however crystal quality and roughness of the tilm are degraded unambiguously. This situation can be improved by optimizing the NL annealing time. The high resistance of GaN grown on NL using N2 as the carrier gas is due to higher density of threading dislocations caused by the higher density of nucleation islands and small statistic diameter grain compared to the one using 1-12 as carrier gas. Annealing the NL for an optimized annealing time can decrease the density of threading dislocation and improve the tilm roughness and interface of AlGaN/GaN without degrading the sheet resistance of as-grown GaN signiticantly. High-quality SI GaN is grown after optimizing the annealing time, and AlGaN/GaN high electron mobility transistors are also prepared.

The Resident Time Distribution of Injected Dispersed Drops in Stirred Extraction Columns

A resident time model is proposed to evaluate the performance of agitated extraction columns. In this model, the resident time of dispersed drops is simulated with the discrete phase modeling, where the continuous phase and the dispersed phase （drops） are described by the single-phase Navier-Stokes （turbulence） model and Lagrangian model, respectively. The interaction of dispersed phase and continuous phase is neglected for the low concentration of drop in the cases studied. The statistical parameters of drops （the average resident time and standard deviation） under different operation conditions are computed for four columns. The relation of the above statistical parameters with the performance of columns is discussed and the criterions for an optimal compartment are outlined. Our results indicate that the resident time model is useful to evaluate the performance and optimize the design of extraction columns.

Data Distribution Mechanism over Opportunistic Networks with Limited Epidemic

Most of data distribution mechanism in Opportunistic Networks is derived by Epidemic data distribution,and Epidemic data distribution means that when each node meets another node,it may copy its own messages and transfer to another node.On the one hand,the copies improve the forwarding rate,and reduce the transmission delay.However,on the other hand,energy consumption increases and network survival time is reduced because the copies consume transmission resource.Therefore,copy number should be under control.In this paper,we first introduce the existing routing strategy based on Epidemic briefly,and present the Epidemic routing protocol analysis model and copy control mechanism based on the limited Epidemic in Opportunistic Networks.Then based on the limited copies scheme(LCS),we propose an energy balance scheme(EBS),the results show that EBS can improve the network survival time.

Multi-Time Scale Analysis of Runoff at the Yangtze Estuary Based on the Morlet Wavelet Transform Method

Runoff series of the Yangtze River presents an intricate variation tendency under the reinforced influence of human activities.The Morlet Wavelet Transform method has been applied to analyze the annual runoff data from 1950 to 2011 at the Yangtze River Estuary.It can clearly reveal the multi-time scales structure,break point,change and distribution of periodic variation in the different time scales of the runoff series.The main conclusions are that:1) Repeated periodic oscillations accompanied by an extremely large fluctuation are presented in the runoff series with an obvious difference between wet and dry years,and the major periods of the time series are about 3,8,16 and 23 years respectively.Among them,the presented maximum periodic oscillation is 23 years scale.2) In the 23-year time scale,the wet periods are 1950-1958,1969-1980 and 1992-2003,and the dry periods are 1959-1968,1981-1991 and 2004-2011.3) It can be predicted from the view of long time scales that the low annual runoff will likely occur in the near future.

Process Optimization of Vacuum Fried Rice-Straw Mushroom （Volvariella Volvacea） Stem Chip Making

The study was aimed to obtain the optimum conditions for vacuum frying and predicting the moisture lost during rice straw mushrooms stem chip production. The raw materials were obtained from the local farmer around the campus. A completely randomized factorial experimental design and Duncan＇s multiple range tests were used to achieve the objectives. Three temperatures, i.e. 80, 90 and 100 ℃ and five frying time, i.e. 3, 6, 9, and 15 minutes with a 2 mm slice thickness were studied to determine the optimum condition and predict the moisture decrease. Results showed that the vacuum frying time in general affects the chips color and oil uptake significantly （p 〈 0.01） and correlated with the moisture decrease. The chips moisture content decline significantly after vacuum frying at 90 ℃ and 100 ℃ for 3 minutes. While for the 80 ℃ vacuum frying, the significant decrease of moisture occurred due to the increase of vacuum frying time from 3 to 6 minutes （p 〈 0.01）. The optimum conditions for a 2 mm slice thickness chips making are vacuum frying at 100 ℃ for 3 minutes. The chips moisture lost followed generally a two-stage of falling rate pattern during vacuum frying, and each could be well predicted by an exponential equation （R2 = 0.99）.

Multifractal Characteristics of Intermittent Turbulence in the Urban Canopy Layer

The multifractality of energy and thermal dissipation of fully developed intermittent turbulence is investigated in the urban canopy layer under unstable conditions by the singularity spectrum for the fractal dimensions of sets of singularities characterizing multifractals. In order to obtain high-order moment properties of smallscale turbulent dissipation in the inertial range, an ultrasonic anemometer with a high sampling frequency of 100 Hz was used. The authors found that the turbulent signal could be singular everywhere. Moreover, the singular exponents of energy and thermal dissipation rates are most frequently encountered at around 0.2, which is significantly smaller than the singular exponents for a wind tunnel at a moderate Reynolds number. The evidence indicates a higher intermittency of turbulence in the urban canopy layer at a high Reynolds number, which is demonstrated by the data with high temporal resolution. Furthermore, the temperature field is more intermittent than the velocity field. In addition, a large amount of samples could be used for verification of the results.

Minimum Amount of Slop Cut in Batch Distillation

The pulse-control operation technique which alternates between total reflux operation and total efflux operation in batch distillation was studied along with the minimum amount of slop cut. Total reflux time was confirmed by dynamic simulation, and total efflux time was adopted by statistic method. For the mixture of hexane and cyclohexane and the traditional constant reflux ratio operation strategy, the amount of slop cut is 1.8-2.1 times of the minimum amount of slop cut; whereas for the pulse-control operation strategy, it is 1. 2 -1.4 times of the minimum amount of slop cut. So compared with the traditional constant reflux ratio operation, the pulse-control operation can decrease the amount of slop cut and operation time, and meanwhile, enhance separation efficiency and yield.