分流沉积的井下进液器及其在措施管柱中的应用

单流阀作为分层注水、分层调驱、防污染等管柱底阀时,往往存在上部固相颗粒无处沉积并卡死阀球的现象,造成措施管柱失效。为此,研制了具有侧向进液、分流沉积通道、单向球弹簧扶正等机构的分流沉积井下进液器,该进液器具有侧管进液、分流通道沉砂、阀球不易砂卡等功能,与措施管柱组合,能够起到卡封管柱的侧向进液、分层注入管柱的反洗井、分层调驱和防污染管柱的固相颗粒沉入下部尾管的作用,提高了措施管柱的可靠性,增强了措施管柱在出砂、斜井条件下的适应性。

辽河滩海仙鹤地区东三段水下分流河道沉积体的地震多参数识别

地震、测井、录井及岩心资料综合分析结果表明,辽河滩海仙鹤地区东三段发育三角洲水下分流河道沉积,在岩心资料上为砂砾岩或含砾砂岩,在测井曲线上为高幅值钟形曲线,在地震剖面上为强振幅透镜状反射。利用三维地震资料,采用相干体处理技术和种子点雕刻技术揭示了辽河滩海仙鹤地区东三段三角洲水下分流河道沉积体的空间分布,水下分流河道沉积体呈条带状分布于HN8井—XH4井一线,L300测线以西分流河道砂体呈近S—N向,L300测线以东转变为SW—NE向。

淮南煤田第四含煤段砂体的演化特征及对煤层厚度的控制

讨论了淮南煤田第四含煤段砂体的演化特征及其对 13- 1煤层厚度的影响。研究表明 ,煤层底板砂体展布型式变化较大 ,继承性较差 ,反映出网状三角洲平原上分流河道发育特点 ;顶板分流河道沉积作用以垂向加积作用为主 ,岩体演化具有较好的继承性 ;在靠近煤层发育的时期内 ,底板砂岩和煤层空间分布呈现互为消长的关系 ,而在顶板砂体发育的早期 。

陕北绥靖油田延安组延9油组油气成藏控制因素

综合分析了鄂尔多斯盆地绥靖油田延安组延9油组油气成藏的油源条件、沉积储层特征,并应用印模法对前侏罗纪古地貌进行了恢复,探讨了古地貌对延9油组的控制。研究结果表明延9油组烃源岩为延长组长7期泥岩;研究区发育的三角洲平原分流河道砂体为其主要储集层,且物性较好;由于受古地貌构造高部位控制,研究目的层形成鼻隆状构造油气藏,成藏模式属它源-双向排烃-多期次生成藏或古生新储-双向排烃-多期次生成藏。下一步石油勘探重点应在高地、山脊等古地貌构造高点部位与分流河道叠合区。

Nutrient Losses in Soils on Loess Plateau

The soil nutrient losses due to excessive soil loss on Loess Plateau were studied by means of runoff plotsand systematical determination of soil nutrients both in sediments and runoff.The results show that theamounts of nutrient losses depended on the amounts of erosion sediments. Along with sediment, 11-197 kgnitrogen/hectare and 9-174 kg phosphorus/hectare were lost, accounting for 92.46-99.47 percent of the totalamount of nitrogen loss and 99.85-99.99 percent of the total amount of phosphorns loss respectively. Thenutrient losses, very small in runoff, were mainly attributed to erosion of a few rainstorms during a year. Thenutrient level in sediment was mostly higher than that in the original soil. Planting grass evidently reducedthe losses of soil nutrients. The N level was lower in runoff than in rainfall so that the N loss from runoffconld be made up by rainfall. Fertilizer application to crops raised the nutrient level in runoff.

Braided river and distribution patterns of sand bodies of Jurassic Badaowan formation in Block T13 of Junggar basin

In order to determine the planar and volume distribution of sand bodies of the Jurassic Badaowan formation in Block T13 of Junggar basin,we used analysis of field outcrop and 3D seismic data,which play an essential role in areas of sparse well coverage.We describe sedimentary facies characteristics,sand body planforms,width and connectivity patterns of sand bodies,and vertical associations and successions by acoustic impedance inversion technology and sedimentological theory.Results of our study show braided fluvial strata deposits in the Jurassic Badaowan formation.Each sand body is approximately lenticular in shape.The width of each sand body falls in the range 100～800 m,with most between 200 and 400 m.The sand bodies vary in thickness from 4 to 13 m,with most below 9 m.The width/thickness ratios lie in the range 20～55.The connectivity of braided fluvial channel sand bodies is controlled by changes of accommodation space.One fining-upward sedimentary cycle of base-level rise is recognized in Badaowan formation,representing an upward rise of base level.The connectivity of sand bodies was found to be greatest in the early stage of base-level rise,becoming progressively worse with increasing base-level rise.

Spatial distribution,sources and ecological risk assessment of heavy metals in Shenjia River watershed of the Three Gorges Reservoir Area

Surface soil/sediment samples were collected from the Water-Level Fluctuation Zone(WLFZ), cultivated land and forest land at 50 different grid points from Shenjia watershed, the Three Gorges Reservoir area in August 2013. The spatial distribution, sources and ecological risk assessment for Arsenic(As), Cadmium(Cd),Chromium(Cr), Copper(Cu), Nickel(Ni), Lead(Pb)and Zinc(Zn) were analyzed in this study. The results showed all tested metals had similar distribution patterns except Ni and Cr, with areas of high concentrations distributed in the southwest(WLFZ and watershed outlet) of the study area. Ni and Cr,which were highly positively correlated and present in high concentrations, were primarily distributed in the south and middle zones of the study area. Lower concentration areas of all metals were uniformly distributed west of the high-elevation zones and forest land. Factor analysis(FA) and factor analysismultiple linear regression(FA-MLR) showed that the major sources of Cd were fertilizer and traffic sources,which together accounted for 87% of Cd. As, Zn and Cu levels were primarily supplied by industrial and domestic sources, accounting for 76% of As, 75% of Cu and 67% of Zn. Surface soils/sediments of the study watershed contaminated by Cd represent a high ecological risk, whereas other metals represent low ecological risks. The potential ecological risk index(PERI) analysis indicated that it had a low(widerange) ecological risk and a moderate(small-range)ecological risk primarily distributed in the outlet of the study watershed. Fertilizers and traffic are the primary sources of Cd pollution, which should be more closely controlled for the purposes of water quality and ecological conservation.

Hydrodynamic processes and depositional styles of glacierassociated deposits in the Moxi basin, Southwest China

This study aims to understand the particle size distribution and depositional styles of glacierassociated deposits in the Moxi basin in southwest China. Based on field surveys, 28 samples from glacier-associated deposits(including glacial till,fluvioglacial, debris flow, river and lake deposits)were collected and tested in the laboratory. The results showed that the glacier-associated deposits can be differentiated based on particle gradation,particle size distribution and accumulated percentages. We evaluated the evolution of a former dammed lake in the Moxi basin based on glacierassociated deposits. The results of this study also indicated that the Moxi Platform was not formed by a single depositional process but is composed of both fluvioglacial and debris flow deposits. This research shows that the depositional style analysis is useful in identifying different glacier-associated deposits in high mountain regions. Moreover, the evaluation of the differences in particle sizes of the glacierassociated deposits is useful in reconstructing geohazard events in periglacial regions, and this information can help in identifying and reducing the potential risks associated with geo-hazards.

Numerical Analysis of Adaptation-to-capacity Length for Fluvial Sediment Transport

Over the last several decades,various sediment transport capacity formulations have been used by geomorphologists and engineers to calculate fluvial morphological changes.However,it remains poorly understood if the adaptation to capacity could be fulfilled instantly in response to differing inflow discharges and sediment supplies,and thus if the calculation of morphological changes in rivers based on the assumed capacity status is fully justified.Here we present a numerical investigation on this issue.The distance required for sediment transport to adapt to capacity(i.e.,adaptation-to-capacity length) of both bed load and suspended sediment transport is computationally studied using a coupled shallow water hydrodynamic model,in line with varied inlet sediment concentrations.It is found that the adaptation-to-capacity length generally decreases as the Rouse number increases,irrespective of whether the inlet sediment concentration increases or reduces.For cases with vanishing inlet sediment concentration a unified relationship is found between the adaptation-to-capacity length and the Rouse number.Quantitatively,the adaptation-to-capacity length of bed load sediment is limited to tens of times of the flow depth,whilst that of suspended sediment increases substantially with decreasing Rouse number and can be up to hundreds of times of the flow depth.The present finding concurs that bed load sediment transport can adapt to capacity much more rapidly than suspended sediment transport,and it facilitates a quantitative criterion on which the applicability of bed load or suspended sediment transport capacity for natural rivers can be readily assessed.

Multi-Physics Modeling of Solid Oxide Fuel Cell Fueled by Methane and Analysis of Carbon Deposition

Internal reformation of low steam methane fuel is important for the high efficiency and low cost operation of solid oxide fuel cell. Understanding and overcoming carbon deposition is crucial for the technology development. Here a multi-physics model is established for the relevant experimental cells. Balance of electrochemical potentials for the electrochemical reactions, generic rate expression for the methane steam reforming, dusty gas model in a form of Fick＇s model for anode gas transport are used in the model. Excellent agreement between the theoretical and experimental current-voltage relations is obtained, demonstrating the validity of the proposed theoretical model. The steam reaction order in low steam methane reforming reaction is found to be 1. Detailed information about the distributions of physical quantities is obtained by the numerical simulation. Carbon deposition is analyzed in detail and the mechanism for the coking inhibition by operating current is illustrated clearly. Two expressions of carbon activity are analyzed and found to be correct qualitatively, but not quantitatively. The role of anode diffusion layer on reducing the current threshold for carbon removal is also explained. It is noted that the current threshold reduction may be explained quantitatively with the carbon activity models that are only qualitatively correct.

Synthesis of VIB Group Metals Silicides Dispersed Powders by Electrolysis of Halide-Oxide Melts

Study of electrochemical behavior of chromium （molybdenum, tungsten） and silicon containing melts allowed defining conditions for synthesis of silicides of chromium, molybdenum and tungsten in the form of fine powders by electrolysis of halide-oxide melts. Sequence of stages of electrosynthesis of silicides of molybdenum and tungsten was found as follows： deposition of more electroposifve metal （molybdenum or tungsten）, deposition of the second component （silicon） on the surface of metal deposited previously, and reaction diffusion of silicon into the deep of the metal-salt ＂pear＂ with the formation of silicide phases of different compositions up to the higher silicides. In contrast, during the electrodeposition of chromium silicides, one of the components （chromium） is deposited not in elemental form, but in oxide form, and the other （silicon） acts as a reducing agent for this oxide to form binary compounds. Duration of the synthesis first stage （deposition of refractory metal or of its oxide） depends on the refractory metal compound content in the system and on the cathode current density. Synthesis of silicides is possible due to retention of powders of molybdenum （tungsten） or chromium oxide at the cathode without scaling. Optimal values of concentrations ratio, current density, temperature, and duration of electrosynthesis were found. Phase composition of products were obtained, as well as their chemical and thermal stability, were studied.

Response of the distributary channel of the Huanghe River estuary to water and sediment discharge regulation in 2007

The water and sediment discharge regulation （WSDR） project, which has been performed since 2002 before flood season every year, is of great significance to the river management in China. Until 2007, six experiments have been fulfilled to evaluate the effect of the project on the natural environment. To fill the gap of investigations, a study on flood and suspended sediment transportation and channel changing along the distributary channel of the Huanghe （Yellow） River was conducted during the WSDR project period in 2007. The lower channel was scoured rapidly and the channel became unobstructed gradually several days after the flood peak water was discharged from the Xiaolangdi Reservoir. Within four days after the flood peak at 3 000 m3/s entered the distributary, the channel in the river mouth area was eroded quickly. Both the mean values of area and depth of the main channel were tripled, and the maximum flood carrying capacity increased to 5 500 m3/s or more. Then, the river channel was silted anew in a very short time after completion of the WSDR. Favored by the WSDR project, the fiver status in April 2008 became better than that of the year before. The adjustment ranges of main channel parameters were about 30%, 10%, and 10% at sections C2, Q4, and Q7, respectively. The process of rapid erosion-deposition was more active 15 km away in the channel from the fiver mouth due to the marine influence. It is reasonable for discharging sediment at concentration peak from Xiaolangdi Reservoir at the end of the flood peak. As a result, the sediment peak reached the river mouth about two days later than that of the water current. In addition, the WSDR project has improved the development of the estuarine wetland. Wetland vegetation planted along the river banks restrained the water flow as a strainer and improved the main channel stability. It is suggested to draw water at mean rate of 150 m3/s from the Huanghe River during flood periods, because at the rate the water in the wetland would be stored and replenished in balance. Moreover, we believe that cropland on the river shoal of the lower Huanghe River should be replaced by wetland. These activities should achieve the Huanghe River management strategy of ＂To concentrate flow to scour sediment, stabilize the main channel, and regulate water and sediment＂.

Distribution of fatty acids in the alpine grassland soils of the Qinghai-Tibetan Plateau

As an important biomarker, fatty acids(FAs) have been extensively used to trace the origin of organic matter in sediments and soils. However, studies of the distribution and abundance of FAs in alpine grassland soils are still rare, especially on the Qinghai-Tibetan Plateau(QTP), the highest plateau in the world, which contributes sediments to many large rivers in Asia. This study investigates the composition, distribution and source of FAs with increasing soil depths from 17 typical alpine grassland sites in the QTP. The most abundant FAs included the ubiquitous C16 FA and even-numbered long-chain FAs(C20–C30), indicating mixed inputs from microbial and higher plant sources. Source apportionment showed that higher plants were the dominant contributor of FAs(approximately 40%) in QTP soils. The abundance of FAs decreased with soil depth, with the highest value(1.08±0.09 mg/g C) at a 0–10 cm depth and the lowest value(0.46±0.12 mg/g C) at a 50–70 cm depth, due to much lower plant inputs into the deeper horizons. The total concentration of FAs was negatively correlated to the mean annual temperature(MAT; P<0.05) and soil p H(P<0.01), suggesting that the preservation of FAs was favored in low-MAT and low-p H soils on the QTP. The abundance of fresh C source FAs increased significantly with the mean annual precipitation(MAP; P<0.05), indicating that high MAP facilitates the accumulation of fresh FAs in QTP soils. Other environmental parameters, such as the soil mineral content(aluminum and iron oxide), microbial community composition as well as litter quality and quantity, may also exert a strong control on the preservation of FAs in QTP soils and warrant further research to better understand the mechanisms responsible for the preservation of FAs in QTP soils.

Synergistic effect of atomic layer deposition-assisted cocatalyst and crystal facet engineering in SnS2 nanosheet for solar water oxidation

The severe bulk recombination and sluggish oxygen evolution reaction(OER)dynamics of photoanodes severely restrict the application of photoelectrochemical(PEC)devices.To solve these two problems,crystallographic facet orientation and cocatalyst emergence with a high-quality photoanode/cocatalyst interface were realized through an air annealing-assisted strategy to treat atomic layer deposition(ALD)-modified SnSnanosheet arrays.Based on experimental observations and theoretical calculations,the reduced(001)crystal facet of SnSdecreases the recombination of photogenerated carriers in the bulk and improves the carrier separation of the photoanode.Moreover,the unexpectedly formed ZnTiOSfilm decreases the overpotential of the surface OER,reduces interface recombination,and extends the carrier lifetime.These synergistic effects lead to significantly enhanced PEC performance,with a high photocurrent density of 1.97 mA cm^(-2)at 1.23 V vs.reversible hydrogen electrode(RHE)and a low onset potential of 0.21 V vs.RHE,which are superior to reported mostly SnS-based photoanodes.