The sex pheromone blend of a China strain of the black cutworm moth Agrotis ypsilon (Rottemberg) (Lepidoptera: Noctuidae) was investigated. Chemical analysis of pheromone gland extracts of 3-day-old females showe...The sex pheromone blend of a China strain of the black cutworm moth Agrotis ypsilon (Rottemberg) (Lepidoptera: Noctuidae) was investigated. Chemical analysis of pheromone gland extracts of 3-day-old females showed that individual isolated glands contained only very small amounts of pheromone. The high-resolution gas chromatography combined with mass spectrometry (GC-MS) analysis showed the presence of Cis-7-dodecenyl acetate (Z7-12:Ac, A), Cis-9-tetradecenyl acetate (Z9-14:Ac, B), Cis- 11-hexadecenyl acetate (Z 11 - 16 :Ac, C), Cis-8-dodecenyl acetate (Z8-12:Ac, E) and Cis-5-decenyl acetate (Z5-10:Ac, D) in biologically active pheromone gland extracts. An extract of one gland from a day 3 female gave the following values for the gland components: 0.245±0.098ng for Z7-12:Ac, 0.080±0.031ng for Z9-14:Ac, 0.089±0.033ng for Z11-16:Ac, 0.085±0.031ng for Z5-10:Ac, 0.105±0.065ng for Z8-12:Ac per female. The percentages of Z7-12:Ac, Z9-14:Ac, Z11-16:Ac, Z5-10:Ac and ZS-12:Ac in pheromone gland extracts from individual females were (meaniSE) 40.451±13.66, 13.176±5.279, 14.943±5.142, 14.392±6.10 and 17.225±9.792 respectively, and the percentages of Z7-12:Ac, Z9-14:Ac and Z11-16:Ac were 58.75±9.429, 18.91±7.539 and 22.34±7.209. Field trials indicated that each single component of sex pheromone was non-effective and captured no males. The lures baited with duality compound of AB (3 : 1) had a certain attraction to males, the mean captured number was 2.6. The attraction ability of the lures baited with ternary compound of ABC (3 : 1 :1) to males added significantly, the mean captured number per trap was 7.40, which was 2.8 times of duality compound of AB (3 : 1). The contents of sex pheromone could obviously affect its capture ability to males, the mean captured number was the highest at the dosage of 200 μg.展开更多
Taking B District in A City as an example, quality classification of basic farmland was evaluated based on farmland gradation. It can be concluded from the analysis that utilization grade of basic farmland in current ...Taking B District in A City as an example, quality classification of basic farmland was evaluated based on farmland gradation. It can be concluded from the analysis that utilization grade of basic farmland in current round was 16.82 without consideration of farmland gradation updating, and the grade enhanced by 0.08, still lower by 0.11 than that in last round, when the updating was taken into account. Finally, the reasons for problems occurred in the round were analyzed as follows: less consideration of protection on basic farmland in orientation of urban development; neglecting of basic farmland quality in Overall Plan of Land Utilization; non-classification of excellent lands after land consolidation; untimely updating of farmland gradation. In addition, the countermeasures were proposed correpondingly, including strengthening of basic farmland quality in the Plan, classification of excellent lands after consolidation, timely updating and inclusion of farmland gradation into "one map" project.展开更多
The condensates from the Yacheng Gas Field, Ying-Qiong Basins, have unusual chemical characteristics, with distribution dominated by terpanes and steranes derived from higher-plants. Pr/Ph ratios (6-11) are very high....The condensates from the Yacheng Gas Field, Ying-Qiong Basins, have unusual chemical characteristics, with distribution dominated by terpanes and steranes derived from higher-plants. Pr/Ph ratios (6-11) are very high. Drimane, cadinanes and homocadinanes exist in high concentration. Anomalously abundant 18α(H)-oleanane and remarkably abundant bicadinanes are present in Yacheng condensates, while 17α(H)-hopanes are in extremely low concentration. Taraxastane and significantly abundant 17α(H)-diahopanes occur in the condensates. In addition, a number of C 29 and C 30 unknown pentacyclic triterpanes were monitored in the condensates, some of which are abundant. The unknown compounds may be terrestrial biomarkers or their occurrence may suggest a sub-oxic (dyacrobic) clay-rich depositional environment. C 29 homologues are relatively predominant in regular and rearranged steranes. The concentration of diasteranes is markedly higher than that of regular steranes. The characteristics of Yacheng condensates are indicative of terrestrial source input. Based on condensate-condensate and condensate-rock correlations, combined with results of studies on sedimentary facies. Yacheng condensates may be sourced from Yacheng and Lingshui Formations in the Qiongdongnan Basin. The maturity of Yacheng condensate is relatively high, at late oil window stage (corresponding to 0.9%-1.3% R 0), based on sterane and terpane maturity parameters.展开更多
In order to get a clear picture of distribution characteristics of mulching plastic film residue in cotton fields in the Yellow River Delta and make scientific pollution prevention and control strategies, an investiga...In order to get a clear picture of distribution characteristics of mulching plastic film residue in cotton fields in the Yellow River Delta and make scientific pollution prevention and control strategies, an investigation was conducted in Dongying City. Five typical cotton fields were chosen, and then the number, distri- bution density and area of residual film were measured. The results showed that the residual film was 18. 84-53. 53 kg/hm^2 in cotton fields for more than 20 years, and the differences between fields were larger. The residual density was 225-340 thousand per hectare. There were great differences among residual pieces. The proportion of residual pieces over 25 cm^2 was 94. 1%, that between 100 cm^2 and 500 cm^2 was more than 50. 0%, and that bigger than 500 cm^2 was about 21. 0%. In the Yellow River Delta cotton region, large, thin and difficult to recovery were the main characteristics of mulching plastic film residue, and it had the possibility of mi- grating to deep soil. Thus, the ecological risk of mulching plastic film residue was higher. Key words The Yellow River Delta; Cotton field; Residue of mulching plastic film; Distribution characteristic展开更多
The Jurassic is an important period of global coal formation, including the development of several large coalfields in central Asia and northern China. Individual seams within these peatlands represent sustained perio...The Jurassic is an important period of global coal formation, including the development of several large coalfields in central Asia and northern China. Individual seams within these peatlands represent sustained periods of terrestrial carbon accumulation and a key environmental indicator attributed to this record is the rate of carbon accumulation. Determining the rate of carbon accumulation requires a measure of time contained within the coal and this study aimed at determining the rate via the identification of Milankovitch orbital cycles using spectral analysis. Spectral analyses of geophysical data from two thick coal seams, No. 43(35.9 m) and No. 3(13.2 m), of the Middle Jurassic of the southern Junggar coalfield were conducted to identify significant signals of variations in ash content. The results showed that the variations in ash content of the coal showed spatial cycles at 0.2, 0.7 and 1.1 m^(-1), which were interpreted to represent 123 ka(eccentricity), 37.1 ka(obliquity), and 21.2 ka(precession) orbital periodicities, respectively. Using this timeframe, the depositional time of the No. 43 and No. 3 coal seams were calculated to be 876–970 and 322–357 ka, respectively. In combination with an understanding of carbon loss during coalification, the carbon accumulation rates of these Middle Jurassic peatlands were calculated to be 58.6–64.9 and60.3–66.8 g C m^(-2) a^(-1) for the No. 43 and No. 3 coal seams, respectively. Given that the net primary productivity(NPP) was 4.3 times the value of the carbon accumulation in a mid-latitude region of 40°–45°N, an NPP of 251.8–279.1 and259.1–287.1 g C m^(-2) a^(-1) was calculated for the No. 43 and No. 3 coal seams, respectively. In the context of the same paleolatitude(40°–45°N) and peat type, the NPP values of the Middle Jurassic strata in the study area were higher than those of the peatlands of the Holocene and Permian, and were similar to the NPP values of Early Cretaceous peatlands. Considering the NPP of a peatland is predominantly controlled by atmospheric CO_2 and O_2 levels and temperature, the lower content of CO_2 and an excessive O_2 level in the temporal atmosphere would lead to a decrease in peatland NPP. Therefore, it is inferred that the CO_2 level during the Middle Jurassic was higher than that of the icehouse Permian and Holocene periods, and it was similar to the CO_2 level of the greenhouse Cretaceous period. The results are consistent with the global CO_2 variation curve of Berner. In conclusion, Milankovitch orbital cycles calculated from geophysical logs can be used to infer the NPP of temporal peatlands during different geological periods, based on which the deep-time paleoclimates can be analyzed.展开更多
Branched glycerol dialkyl glycerol tetraethers(brGDGTs),likely produced by bacteria in soil and peat,are widely distributed,easily detected,newly adopted biomarker compounds.In this study,brGDGTs were used to explore ...Branched glycerol dialkyl glycerol tetraethers(brGDGTs),likely produced by bacteria in soil and peat,are widely distributed,easily detected,newly adopted biomarker compounds.In this study,brGDGTs were used to explore the relationship between the absolute abundance of brGDGTs and the distribution of oil and gas fields in the Duoshiqiao area of the Jiyang depression.The results showed that the concentrations at the Xiakou fault and in the oil and gas fields were obviously higher than those in the contrast areas.The clear relationship among the concentration of brGDGTs,the distribution of oil and gas fields,and the acidolysis hydrocarbon(ethane)indicates that the concentration effectively responds to hydrocarbon seeps from the oil and gas field below.brGDGTs may become some of the most important indicators in surface geochemical prospecting for oil and gas.展开更多
Little is known about the stable carbon isotopes of methane (CH4) emitted (δ13CH4elnitted) from permanently flooded rice fields and double rice-cropping fields. The CH4 emission and corresponding (δ13CH4emitted...Little is known about the stable carbon isotopes of methane (CH4) emitted (δ13CH4elnitted) from permanently flooded rice fields and double rice-cropping fields. The CH4 emission and corresponding (δ13CH4emitted under various field managements (mulching, water regime, tillage, and nitrogen (N) fertilization) were simultaneously measured in three typical Chinese rice fields, a permanently flooded rice field in Ziyang City, Sichuan Province, Southwest China, a double-rice cropping field in Yingtan City, Jiangxi Province, Southeast China, and a rice-wheat rotation field in Jurong City, Jiangsu Province, East China, from 2010 to 2012. Results showed different seasonal variations of δ13CH4emitted among the three fields during the rice-growing season. The values of (δ13CH4emitted were negatively correlated with corresponding CH4 emissions in seasonal variation and mean, indicating the importance of CH4 production, oxidation, and transport associated with isotopic fractionation effects to the δ13CH4emitted. Seasonal variations of δ13CH4emltted were slightly impacted by mulching cultivation, tillage, and N application, but highly controlled by drainage. Meanwhile, tillage, N application, and especially mulching cultivation had important effects on seasonal mean CH4 emissions and corresponding δ13CH4emitted with low emissions accompanied by high values of δ13CH4emitted. Seasonal mean values of (δ13CH4emitted from the three fields were similar, mostly ranging from -60‰ to -50‰ which are well in agreement with previously published data. These demonstrated that seasonal variations of (δ13CH4emitted mainly depended on the changes in CH4 emission from rice fields and further indicated the important effects of methanogenic pathways, CH4 oxidation, and CH4 transport associated with isotope fractionation effects influenced by field managements on δ13CH4emitted.展开更多
基金Science and Technology Fund of Guizhou Province (2006-2048)
文摘The sex pheromone blend of a China strain of the black cutworm moth Agrotis ypsilon (Rottemberg) (Lepidoptera: Noctuidae) was investigated. Chemical analysis of pheromone gland extracts of 3-day-old females showed that individual isolated glands contained only very small amounts of pheromone. The high-resolution gas chromatography combined with mass spectrometry (GC-MS) analysis showed the presence of Cis-7-dodecenyl acetate (Z7-12:Ac, A), Cis-9-tetradecenyl acetate (Z9-14:Ac, B), Cis- 11-hexadecenyl acetate (Z 11 - 16 :Ac, C), Cis-8-dodecenyl acetate (Z8-12:Ac, E) and Cis-5-decenyl acetate (Z5-10:Ac, D) in biologically active pheromone gland extracts. An extract of one gland from a day 3 female gave the following values for the gland components: 0.245±0.098ng for Z7-12:Ac, 0.080±0.031ng for Z9-14:Ac, 0.089±0.033ng for Z11-16:Ac, 0.085±0.031ng for Z5-10:Ac, 0.105±0.065ng for Z8-12:Ac per female. The percentages of Z7-12:Ac, Z9-14:Ac, Z11-16:Ac, Z5-10:Ac and ZS-12:Ac in pheromone gland extracts from individual females were (meaniSE) 40.451±13.66, 13.176±5.279, 14.943±5.142, 14.392±6.10 and 17.225±9.792 respectively, and the percentages of Z7-12:Ac, Z9-14:Ac and Z11-16:Ac were 58.75±9.429, 18.91±7.539 and 22.34±7.209. Field trials indicated that each single component of sex pheromone was non-effective and captured no males. The lures baited with duality compound of AB (3 : 1) had a certain attraction to males, the mean captured number was 2.6. The attraction ability of the lures baited with ternary compound of ABC (3 : 1 :1) to males added significantly, the mean captured number per trap was 7.40, which was 2.8 times of duality compound of AB (3 : 1). The contents of sex pheromone could obviously affect its capture ability to males, the mean captured number was the highest at the dosage of 200 μg.
文摘Taking B District in A City as an example, quality classification of basic farmland was evaluated based on farmland gradation. It can be concluded from the analysis that utilization grade of basic farmland in current round was 16.82 without consideration of farmland gradation updating, and the grade enhanced by 0.08, still lower by 0.11 than that in last round, when the updating was taken into account. Finally, the reasons for problems occurred in the round were analyzed as follows: less consideration of protection on basic farmland in orientation of urban development; neglecting of basic farmland quality in Overall Plan of Land Utilization; non-classification of excellent lands after land consolidation; untimely updating of farmland gradation. In addition, the countermeasures were proposed correpondingly, including strengthening of basic farmland quality in the Plan, classification of excellent lands after consolidation, timely updating and inclusion of farmland gradation into "one map" project.
文摘The condensates from the Yacheng Gas Field, Ying-Qiong Basins, have unusual chemical characteristics, with distribution dominated by terpanes and steranes derived from higher-plants. Pr/Ph ratios (6-11) are very high. Drimane, cadinanes and homocadinanes exist in high concentration. Anomalously abundant 18α(H)-oleanane and remarkably abundant bicadinanes are present in Yacheng condensates, while 17α(H)-hopanes are in extremely low concentration. Taraxastane and significantly abundant 17α(H)-diahopanes occur in the condensates. In addition, a number of C 29 and C 30 unknown pentacyclic triterpanes were monitored in the condensates, some of which are abundant. The unknown compounds may be terrestrial biomarkers or their occurrence may suggest a sub-oxic (dyacrobic) clay-rich depositional environment. C 29 homologues are relatively predominant in regular and rearranged steranes. The concentration of diasteranes is markedly higher than that of regular steranes. The characteristics of Yacheng condensates are indicative of terrestrial source input. Based on condensate-condensate and condensate-rock correlations, combined with results of studies on sedimentary facies. Yacheng condensates may be sourced from Yacheng and Lingshui Formations in the Qiongdongnan Basin. The maturity of Yacheng condensate is relatively high, at late oil window stage (corresponding to 0.9%-1.3% R 0), based on sterane and terpane maturity parameters.
基金Supported by Cotton Innovation Team of Modern Agriculture Technology System of Shandong Province(SDAIT-07)Special Fund for Independent Innovation Achievement Transformation(2013ZHZX2A0402)~~
文摘In order to get a clear picture of distribution characteristics of mulching plastic film residue in cotton fields in the Yellow River Delta and make scientific pollution prevention and control strategies, an investigation was conducted in Dongying City. Five typical cotton fields were chosen, and then the number, distri- bution density and area of residual film were measured. The results showed that the residual film was 18. 84-53. 53 kg/hm^2 in cotton fields for more than 20 years, and the differences between fields were larger. The residual density was 225-340 thousand per hectare. There were great differences among residual pieces. The proportion of residual pieces over 25 cm^2 was 94. 1%, that between 100 cm^2 and 500 cm^2 was more than 50. 0%, and that bigger than 500 cm^2 was about 21. 0%. In the Yellow River Delta cotton region, large, thin and difficult to recovery were the main characteristics of mulching plastic film residue, and it had the possibility of mi- grating to deep soil. Thus, the ecological risk of mulching plastic film residue was higher. Key words The Yellow River Delta; Cotton field; Residue of mulching plastic film; Distribution characteristic
基金supported by the National Natural Science Foundation of China (Grant No. 41572090)the China Geological Survey Project (Grant No. DD20160204-YQ17W01)
文摘The Jurassic is an important period of global coal formation, including the development of several large coalfields in central Asia and northern China. Individual seams within these peatlands represent sustained periods of terrestrial carbon accumulation and a key environmental indicator attributed to this record is the rate of carbon accumulation. Determining the rate of carbon accumulation requires a measure of time contained within the coal and this study aimed at determining the rate via the identification of Milankovitch orbital cycles using spectral analysis. Spectral analyses of geophysical data from two thick coal seams, No. 43(35.9 m) and No. 3(13.2 m), of the Middle Jurassic of the southern Junggar coalfield were conducted to identify significant signals of variations in ash content. The results showed that the variations in ash content of the coal showed spatial cycles at 0.2, 0.7 and 1.1 m^(-1), which were interpreted to represent 123 ka(eccentricity), 37.1 ka(obliquity), and 21.2 ka(precession) orbital periodicities, respectively. Using this timeframe, the depositional time of the No. 43 and No. 3 coal seams were calculated to be 876–970 and 322–357 ka, respectively. In combination with an understanding of carbon loss during coalification, the carbon accumulation rates of these Middle Jurassic peatlands were calculated to be 58.6–64.9 and60.3–66.8 g C m^(-2) a^(-1) for the No. 43 and No. 3 coal seams, respectively. Given that the net primary productivity(NPP) was 4.3 times the value of the carbon accumulation in a mid-latitude region of 40°–45°N, an NPP of 251.8–279.1 and259.1–287.1 g C m^(-2) a^(-1) was calculated for the No. 43 and No. 3 coal seams, respectively. In the context of the same paleolatitude(40°–45°N) and peat type, the NPP values of the Middle Jurassic strata in the study area were higher than those of the peatlands of the Holocene and Permian, and were similar to the NPP values of Early Cretaceous peatlands. Considering the NPP of a peatland is predominantly controlled by atmospheric CO_2 and O_2 levels and temperature, the lower content of CO_2 and an excessive O_2 level in the temporal atmosphere would lead to a decrease in peatland NPP. Therefore, it is inferred that the CO_2 level during the Middle Jurassic was higher than that of the icehouse Permian and Holocene periods, and it was similar to the CO_2 level of the greenhouse Cretaceous period. The results are consistent with the global CO_2 variation curve of Berner. In conclusion, Milankovitch orbital cycles calculated from geophysical logs can be used to infer the NPP of temporal peatlands during different geological periods, based on which the deep-time paleoclimates can be analyzed.
基金supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. KZCXZ-YW-JC103)contribution no.1866 from Guangzhou Institute of Geochemistry, Chinese Academy of Sciences
文摘Branched glycerol dialkyl glycerol tetraethers(brGDGTs),likely produced by bacteria in soil and peat,are widely distributed,easily detected,newly adopted biomarker compounds.In this study,brGDGTs were used to explore the relationship between the absolute abundance of brGDGTs and the distribution of oil and gas fields in the Duoshiqiao area of the Jiyang depression.The results showed that the concentrations at the Xiakou fault and in the oil and gas fields were obviously higher than those in the contrast areas.The clear relationship among the concentration of brGDGTs,the distribution of oil and gas fields,and the acidolysis hydrocarbon(ethane)indicates that the concentration effectively responds to hydrocarbon seeps from the oil and gas field below.brGDGTs may become some of the most important indicators in surface geochemical prospecting for oil and gas.
基金financially supported by the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB15020103)the National Key Technology Research and Development Program of China(No.2013BAD11B02)+2 种基金the National Natural Sciences Foundation of China(Nos.41571232 and 41271259)the State Key Laboratory of Soil and Sustainable Agriculture(No.Y412010003)the Knowledge Innovation Program of Institute of Soil Science,Chinese Academy of Sciences(No.ISSASIP1654)
文摘Little is known about the stable carbon isotopes of methane (CH4) emitted (δ13CH4elnitted) from permanently flooded rice fields and double rice-cropping fields. The CH4 emission and corresponding (δ13CH4emitted under various field managements (mulching, water regime, tillage, and nitrogen (N) fertilization) were simultaneously measured in three typical Chinese rice fields, a permanently flooded rice field in Ziyang City, Sichuan Province, Southwest China, a double-rice cropping field in Yingtan City, Jiangxi Province, Southeast China, and a rice-wheat rotation field in Jurong City, Jiangsu Province, East China, from 2010 to 2012. Results showed different seasonal variations of δ13CH4emitted among the three fields during the rice-growing season. The values of (δ13CH4emitted were negatively correlated with corresponding CH4 emissions in seasonal variation and mean, indicating the importance of CH4 production, oxidation, and transport associated with isotopic fractionation effects to the δ13CH4emitted. Seasonal variations of δ13CH4emltted were slightly impacted by mulching cultivation, tillage, and N application, but highly controlled by drainage. Meanwhile, tillage, N application, and especially mulching cultivation had important effects on seasonal mean CH4 emissions and corresponding δ13CH4emitted with low emissions accompanied by high values of δ13CH4emitted. Seasonal mean values of (δ13CH4emitted from the three fields were similar, mostly ranging from -60‰ to -50‰ which are well in agreement with previously published data. These demonstrated that seasonal variations of (δ13CH4emitted mainly depended on the changes in CH4 emission from rice fields and further indicated the important effects of methanogenic pathways, CH4 oxidation, and CH4 transport associated with isotope fractionation effects influenced by field managements on δ13CH4emitted.