Covalent organic frameworks(COFs)are promising materials for converting solar energy into green hydrogen.However,limited charge separation and transport in COFs impede their application in the photocatalytic hydrogen ...Covalent organic frameworks(COFs)are promising materials for converting solar energy into green hydrogen.However,limited charge separation and transport in COFs impede their application in the photocatalytic hydrogen evolution reaction(HER).In this study,the intrinsically tunable internal bond electric field(IBEF)at the imine bonds of COFs was manipulated to cooperate with the internal molecular electric field(IMEF)induced by the donor-acceptor(D-A)structure for an efficient HER.The aligned orientation of IBEF and IMEF resulted in a remarkable H_(2) evolution rate of 57.3 mmol·g^(-1)·h^(-1)on TNCA,which was approximately 520 times higher than that of TCNA(0.11 mmol·g^(-1)·h^(-1))with the opposing electric field orientation.The superposition of the dual electric fields enables the IBEF to function as an accelerating field for electron transfer,kinetically facilitat-ing the migration of photogenerated electrons from D to A.Furthermore,theoretical calculations indicate that the inhomogeneous charge distribution at the C and N atoms in TNCA not only pro-vides a strong driving force for carrier transfer but also effectively hinders the return of free elec-trons to the valence band,improving the utilization of photoelectrons.This strategy of fabricating dual electric fields in COFs offers a novel approach to designing photocatalysts for clean energy synthesis.展开更多
We calculate the multicomponent responses of surface-hole transient electromagnetic method. The methods and models are unsuitable as geoelectric models of conductive surrounding rocks because they are based on regular...We calculate the multicomponent responses of surface-hole transient electromagnetic method. The methods and models are unsuitable as geoelectric models of conductive surrounding rocks because they are based on regular local targets. We also propose a calculation and analysis scheme based on numerical simulations of the subsurface transient electromagnetic fields. In the modeling of the electromagnetic fields, the forward modeling simulations are performed by using the finite-difference time-domain method and the discrete image method, which combines the Gaver–Stehfest inverse Laplace transform with the Prony method to solve the initial electromagnetic fields. The precision in the iterative computations is ensured by using the transmission boundary conditions. For the response analysis, we customize geoelectric models consisting of near-borehole targets and conductive wall rocks and implement forward modeling simulations. The observed electric fields are converted into induced electromotive force responses using multicomponent observation devices. By comparing the transient electric fields and multicomponent responses under different conditions, we suggest that the multicomponent-induced electromotive force responses are related to the horizontal and vertical gradient variations of the transient electric field at different times. The characteristics of the response are determined by the varying the subsurface transient electromagnetic fields, i.e., diffusion, attenuation and distortion, under different conditions as well as the electromagnetic fields at the observation positions. The calculation and analysis scheme of the response consider the surrounding rocks and the anomalous field of the local targets. It therefore can account for the geological data better than conventional transient field response analysis of local targets.展开更多
A novel analytical model for the thin film silicon on insulator (TFSOI) reduced surface field (RESURF) devices has been proposed.Based on the 2-D Poisson equation solution,the analytical expressions for the surface po...A novel analytical model for the thin film silicon on insulator (TFSOI) reduced surface field (RESURF) devices has been proposed.Based on the 2-D Poisson equation solution,the analytical expressions for the surface potential and field distributions are derived.From this analysis,the optimum design condition for the maximum breakdown voltage is obtained.The dependence of the maximum breakdown voltage on the drift region length is examined and the relationship between the critical doping concentration and the front- and back- interface oxide layer thickness is discussed.The numerical simulation performed by the advanced semiconductor simulation tool,DESSIS-ISE,has been shown to support the analytical results.展开更多
Based on the first-principles computational method and elastic scattering Green's function theory, we have investigated the effect of gate electric field on electronic transport properties of a series of single organ...Based on the first-principles computational method and elastic scattering Green's function theory, we have investigated the effect of gate electric field on electronic transport properties of a series of single organic molecular junctions theoretically. The numerical results show that the molecular junctions that have redox centers and relatively large dipole moments parallel gate direction can respond to the gate electric field remarkably. The current-voltage properties of 2,5-dimethyl-thiophene-dithiol present N-channel-metal-oxide-semiconductorlike characteristics. Its distinct current-voltage properties can be understood from the evo- lution of eigenvalues, coupling energies, and atomic charges with gate electric field.展开更多
To improve the electrorheological effect of electrorheological fluid (ERF), a new type of the electrosensitive particle material, polynaphthalene quinone was prepared, whose molecules contain blended atoms of nitrogen...To improve the electrorheological effect of electrorheological fluid (ERF), a new type of the electrosensitive particle material, polynaphthalene quinone was prepared, whose molecules contain blended atoms of nitrogen, oxygen, sulphur and big π bond conjugate system. In both DC and AC electric fields, the ERF material showed a distinct ER effect. Especially, in the alternating electric field, the shear stress of this material versus AC voltage has a better quadratic relation than that of the other materials. The experimental data showed that organic semiconductor polymers with big π bond conjugate system are a new type of electrosensitive particle materials which are worth well developing.展开更多
In order to study the thermoelectric efficiency of microwave heating and reproduction of asphalt pavements and the uniformity of reproduction temperature distribution, a waveguide excitation cavity is designed and app...In order to study the thermoelectric efficiency of microwave heating and reproduction of asphalt pavements and the uniformity of reproduction temperature distribution, a waveguide excitation cavity is designed and applied to the structural design of a microwave heater. The structural sizes of the incentive cavities are determined based on the waveguide transmission line theory. Using IE3D software, electromagnetic simulations are respectively carried out in four different situations, including the distances between the magnetron probes (antennas) and a short-circuit board, different horn electric lengths and aperture sizes, different dielectric properties of the asphalt mixture, and the distances between the asphalt surface and the mouth cavity. The results show that, when the distance between the magnetron probe and the short-circuit board is 32.5 ram, it is the best installation site; reduction of aerial length is the main factor in improving the heating uniformity. When the aggregate is limestone, the best heating effect can be produced. Maximum radiation efficiency can be realized by adjusting the space between the heater radiation port and the asphalt pavement. The experimental results of asphalt mixture heating in four different situations have a substantial agreement with the simulation results, which confirms that the developed microwave heater can achieve better impedance matching, thus improving the quality and efficiency of heating regeneration.展开更多
An analytical model of the surface field distribution and breakdown voltage of the reduced surface field lateral double diffusion MOS transistor is proposed.Based on the 2-D Poisson's equation solution,the derived...An analytical model of the surface field distribution and breakdown voltage of the reduced surface field lateral double diffusion MOS transistor is proposed.Based on the 2-D Poisson's equation solution,the derived model gives the closed form solutions of the surface potential and electrical field distributions as a function of the structure parameters and drain bias.A criterion for obtaining the optimal trade-off between the breakdown voltage and on-resistance is also presented to serve to quantify the maximum breakdown voltage and optimal relations of all design parameters.Analytical results are shown in good agreement with the numerical analysis obtained by the semiconductor device simulator MEDICI and previous reported experimental data.展开更多
WT8.BZ]A new quasi 2-dimensional analytical approach to predicting the ring voltage,edge peak fields and optimal spacing of the planar junction with a single floating field limiting ring structure has been proposed,ba...WT8.BZ]A new quasi 2-dimensional analytical approach to predicting the ring voltage,edge peak fields and optimal spacing of the planar junction with a single floating field limiting ring structure has been proposed,based on the cylindrical symmetric solution and the critical field concept.The effects of the spacing and reverse voltage on the ring junction voltage and edge peak field profiles have been analyzed.The optimal spacing and the maximum breakdown voltage of the structure have also been obtained.The analytical results are in excellent agreement with that obtained from the 2-D device simulator,MEDICI and the reported result,which proves the presented model valid.展开更多
An 1∶8 frequency divider is designed and realized in a 0 35μm standard CMOS technology.The chip consists of three stages of 1∶2 divider cells,which are constructed with source couple logic (SCL) flip flops.By rev...An 1∶8 frequency divider is designed and realized in a 0 35μm standard CMOS technology.The chip consists of three stages of 1∶2 divider cells,which are constructed with source couple logic (SCL) flip flops.By revising the traditional topology of SCL flip flop,a divider with better performances is got.The results of measurement show that the whole chip achieves the frequency division at more than 8 5GHz.Each 1∶2 divider consumes about 11mW from a 3 3V supply.The divider can be used in RF and optic fiber transceivers and other high speed systems.展开更多
The damper is capable of providing a continuously variable dampering force/torque in response to a magnetic field. It consists of an upside cap and an underside cap with a rotor located between them, the magneto-rheol...The damper is capable of providing a continuously variable dampering force/torque in response to a magnetic field. It consists of an upside cap and an underside cap with a rotor located between them, the magneto-rheological (MR) fluid is filled into the gaps between the rotor and the caps. When the viscosity of the MR fluid increases under the influence of the magnetic field, the movement of the rotor will be resisted. The output torque is made up of the torque caused by the magnetic field, the torque caused by the plastic viscosity of the MR fluid, and the torque caused by the coulomb friction. The viscous torque can be calculated by a simple method and the frictional torque can be obtained by experiments. The torque dependent on the magnetic field is obtained by electromagnetic finite dement analysis. Experiments are done on the damper prototype and the validity of the design is verified.展开更多
Ionization is the fundamental process in interaction of atoms/molecules with femtosecond strong laser fields. Comparing to atoms, molecules exhibit peculiar behaviors in strong-field ionization because of their divers...Ionization is the fundamental process in interaction of atoms/molecules with femtosecond strong laser fields. Comparing to atoms, molecules exhibit peculiar behaviors in strong-field ionization because of their diverse geometric structures, molecular electronic orbitals as well as extra nuclear degrees of freedom. In this study, we investigate strong field single and double ionization of carbon monoxide (CO) and carbon dioxide (CO2) in linearly polarized 50-fs, 800-nm laser fields with peak intensity in the range of 2×10 13 W/cm2 to 2×10 14 W/cm2 using time-of-flight mass spectrometer. By comparing the ionization yields with that of the companion atom krypton (Kr), which has similar ionization potential to the molecules, we investigate the effect of molecular electronic orbitals on the strong-field ionization. The results show that comparing to Kr, no significant suppression is observed in single ionization of both molecules and in non-sequential double ionization (NSDI) of CO, while the NSDI probability of CO2 is strongly suppressed. Based on our results and previous studies on homonuclear diatomic molecules (N2 and O2), the mechanism of different suppression effect is discussed. It is indicated that the different structure of the highest occupied molecular orbitals of CO and CO2 leads to distinct behaviors in two-center interference by the electronic wave-packet and angular distributions of the ionized electrons, resulting in different suppression effect in strong-field ionization.展开更多
Numerical simulation of the electrical field distribution helps in-depth understanding of the mechanisms behind the responses and the benefits of the high voltage pulse comminution. The COMSOL Multiphysics package was...Numerical simulation of the electrical field distribution helps in-depth understanding of the mechanisms behind the responses and the benefits of the high voltage pulse comminution. The COMSOL Multiphysics package was used to numerically simulate the effect of ore compositions in this study. Regarding phosphate ore particles shape and composition, the effects of mineral composition, particle size, particle shape and electrodes distance were investigated on the electrical field intensity and distribution. The results show that the induced electrical field is significantly dependent on the electrical properties of minerals,the feed particle size and the location of conductive minerals in ores. The angle of material contact surface with the discharge electrode is also an important factor in the intensity of electrical field. Moreover,it is found that the specific liberation effect at the disintegration of phosphate ore by electrical pulses is due to the locality of the electrical field at the interface of mineral components of the phosphate ore aggregates with different permittivities. However, the intensity of the electrical field increases with sharpening the contact angle. Besides, the electrical discharge in the samples is converted to the electrohydraulic discharge across the surrounding water by changing the distance between the discharge electrode and sample surface.展开更多
A model of magnetic stimulation is presented for analysis of the spatial distributions of the electric field induced by magnetic coils.Dimensionless analysis is introduced and makes the factors influencing the magnitu...A model of magnetic stimulation is presented for analysis of the spatial distributions of the electric field induced by magnetic coils.Dimensionless analysis is introduced and makes the factors influencing the magnitude of electric field into two parts:c (represents the stimulation conditions),and E 0 (reflects the geometry of coil).By 3 D simulation of the induced electric field of two kinds of coils,the effect of magnetic stimulation can be demonstrated and the factors influencing stimulating focality and depth are identified.The principles for determining the electric field magnitude,focality and magnetic stimulation depth when designing a reasonable coil and stimulator and achieving ideal stimulating effect are discussed.展开更多
Objective Early researches found that different heartbeat perceivers have different heartbeat evoked potential (HEP)waves.Two tasks were considered in our experiments to get more details about the differences betwee...Objective Early researches found that different heartbeat perceivers have different heartbeat evoked potential (HEP)waves.Two tasks were considered in our experiments to get more details about the differences between good and poor heartbeat perceivers at attention and resting state.Methods Thirty channels of electroencephalogram(EEG)were recorded in 22 subjects,who had been subdivided into good and poor heartbeat perceivers by mental tracking task. Principal component analysis(PCA)was applied to remove cardiac field artifact(CFA)from the HEP.Results(1)The good heart-beat perceivers showed difference between attention and resting state in the windows from 250 ms to 450 ms after R wave at C3 location and from 100 ms to 300 ms after R wave at C4 location;(2)The difference waveforms between good and poor heartbeat perceivers was a positive waveform at FZ from 220 ms to 340 ms after R wave,which was more significant in attention state.Conclusion Attention state had more effect on the HEPs of good heartbeat perceivers than that of poor heartbeat perceivers;and perception ability influenced HEPs more strongly in the attention state than in the resting state.展开更多
Considering the droplet coalescence, the motion of a group of dispersed droplets in W/O emulsion in a DC electric field is simulated. The simulation demonstrates the evolutions of droplet number, size as well as its d...Considering the droplet coalescence, the motion of a group of dispersed droplets in W/O emulsion in a DC electric field is simulated. The simulation demonstrates the evolutions of droplet number, size as well as its distribution,local concentration distribution and droplet size-velocity relation with the applied time of electric field. The simulated average droplet size is roughly consistent with the experimental value. The simulated variation of droplet number with time under several applied voltages shows that increasing voltage is more effective for raising the rate of droplet coalescence than extending exerting time. However, with the further raise of applied voltage, the improvement in droplet coalescence rate becomes less significant. The evolution of simulated droplet size–velocity relationship with time shows that the inter-droplet electric repulsion force is very strong due to larger electric charge on the droplet under higher applied voltage, so that the magnitude and the direction of droplet velocity become more random, which looks helpful to droplet coalescence.展开更多
The distribution of electric field for the alignment and attachment of carbon nanotubes (CNTs) was simulated. To be attached at the desired place, the aligned and attracted CNTs should be stayed in the desired area ca...The distribution of electric field for the alignment and attachment of carbon nanotubes (CNTs) was simulated. To be attached at the desired place, the aligned and attracted CNTs should be stayed in the desired area called the stable region or the quasi-stable region for an instant where the change of electric field is minimized. Since the conical electrode has the very narrow sized quasi-stable region, few CNTs can be attached. The rectangular electrodes have a wide stable region, so lots of CNTs can be attached. The results indicate that the round electrode which has a proper sized quasi-stable region is more effective for aligning and attaching a single CNT than the conical or rectangular shaped electrodes.展开更多
Constructing bismuth oxyhalide solid solutions with a single homogeneous phase have intrigued the research community;however,a deeper understanding of the intrinsic origin for improved bulk-charge separation is still ...Constructing bismuth oxyhalide solid solutions with a single homogeneous phase have intrigued the research community;however,a deeper understanding of the intrinsic origin for improved bulk-charge separation is still unclear.Herein,a series of Bi_(24)O_(31)Cl_(x)Br_(10-x) solid solutions with the same structural characteristics were synthesized by crystal structure regulation.Combining density functional theory calculation,Kelvin probe force microscopy,and zeta potential testing results,an enhanced internal electric field(IEF)intensity between[Bi_(24)O_(31)]and[X]layers was achieved by changing halogen types and ratios.This greatly facilitated bulk-charge separation and transfer efficiency,which is significant for the degradation of phenolic organic pollutants.Owing to the enhanced IEF intensity,the charge carrier density of Bi_(24)O_(31)Cl_(4)Br_(6) was 33.1 and 4.7 times stronger than that of Bi_(24)O_(31)Cl_(10) and Bi_(24)O_(31)Br_(10),respectively.Therefore,Bi24O31Cl4Br6 had an optimal photoactivity for the degradation of bisphenol A,which was 6.21 and 2.71 times higher than those of Bi_(24)O_(31)Cl_(10) and Bi_(24)O_(31)Br_(10),respectively.Thus,this study revealed the intrinsic mechanism of the solid solution strategy for photocatalytic performance enhancement with respect to an IEF.展开更多
文摘Covalent organic frameworks(COFs)are promising materials for converting solar energy into green hydrogen.However,limited charge separation and transport in COFs impede their application in the photocatalytic hydrogen evolution reaction(HER).In this study,the intrinsically tunable internal bond electric field(IBEF)at the imine bonds of COFs was manipulated to cooperate with the internal molecular electric field(IMEF)induced by the donor-acceptor(D-A)structure for an efficient HER.The aligned orientation of IBEF and IMEF resulted in a remarkable H_(2) evolution rate of 57.3 mmol·g^(-1)·h^(-1)on TNCA,which was approximately 520 times higher than that of TCNA(0.11 mmol·g^(-1)·h^(-1))with the opposing electric field orientation.The superposition of the dual electric fields enables the IBEF to function as an accelerating field for electron transfer,kinetically facilitat-ing the migration of photogenerated electrons from D to A.Furthermore,theoretical calculations indicate that the inhomogeneous charge distribution at the C and N atoms in TNCA not only pro-vides a strong driving force for carrier transfer but also effectively hinders the return of free elec-trons to the valence band,improving the utilization of photoelectrons.This strategy of fabricating dual electric fields in COFs offers a novel approach to designing photocatalysts for clean energy synthesis.
基金supported by the Young Scientists Fund of the National Natural Science Foundation of China(No.41304082)the China Postdoctoral Science Foundation(No.2016M590731)+2 种基金the Young Scientists Fund of the Natural Science Foundation of Hebei Province(No.D2014403011)the Program for Young Excellent Talents of Higher Education Institutions of Hebei Province(No.BJ2016046)the Geological survey project of China Geological Survey(No.1212011121197)
文摘We calculate the multicomponent responses of surface-hole transient electromagnetic method. The methods and models are unsuitable as geoelectric models of conductive surrounding rocks because they are based on regular local targets. We also propose a calculation and analysis scheme based on numerical simulations of the subsurface transient electromagnetic fields. In the modeling of the electromagnetic fields, the forward modeling simulations are performed by using the finite-difference time-domain method and the discrete image method, which combines the Gaver–Stehfest inverse Laplace transform with the Prony method to solve the initial electromagnetic fields. The precision in the iterative computations is ensured by using the transmission boundary conditions. For the response analysis, we customize geoelectric models consisting of near-borehole targets and conductive wall rocks and implement forward modeling simulations. The observed electric fields are converted into induced electromotive force responses using multicomponent observation devices. By comparing the transient electric fields and multicomponent responses under different conditions, we suggest that the multicomponent-induced electromotive force responses are related to the horizontal and vertical gradient variations of the transient electric field at different times. The characteristics of the response are determined by the varying the subsurface transient electromagnetic fields, i.e., diffusion, attenuation and distortion, under different conditions as well as the electromagnetic fields at the observation positions. The calculation and analysis scheme of the response consider the surrounding rocks and the anomalous field of the local targets. It therefore can account for the geological data better than conventional transient field response analysis of local targets.
文摘A novel analytical model for the thin film silicon on insulator (TFSOI) reduced surface field (RESURF) devices has been proposed.Based on the 2-D Poisson equation solution,the analytical expressions for the surface potential and field distributions are derived.From this analysis,the optimum design condition for the maximum breakdown voltage is obtained.The dependence of the maximum breakdown voltage on the drift region length is examined and the relationship between the critical doping concentration and the front- and back- interface oxide layer thickness is discussed.The numerical simulation performed by the advanced semiconductor simulation tool,DESSIS-ISE,has been shown to support the analytical results.
基金This work was supported by the National Natural Science Foundation of China (No.10804064 and No.10974121).
文摘Based on the first-principles computational method and elastic scattering Green's function theory, we have investigated the effect of gate electric field on electronic transport properties of a series of single organic molecular junctions theoretically. The numerical results show that the molecular junctions that have redox centers and relatively large dipole moments parallel gate direction can respond to the gate electric field remarkably. The current-voltage properties of 2,5-dimethyl-thiophene-dithiol present N-channel-metal-oxide-semiconductorlike characteristics. Its distinct current-voltage properties can be understood from the evo- lution of eigenvalues, coupling energies, and atomic charges with gate electric field.
文摘To improve the electrorheological effect of electrorheological fluid (ERF), a new type of the electrosensitive particle material, polynaphthalene quinone was prepared, whose molecules contain blended atoms of nitrogen, oxygen, sulphur and big π bond conjugate system. In both DC and AC electric fields, the ERF material showed a distinct ER effect. Especially, in the alternating electric field, the shear stress of this material versus AC voltage has a better quadratic relation than that of the other materials. The experimental data showed that organic semiconductor polymers with big π bond conjugate system are a new type of electrosensitive particle materials which are worth well developing.
基金The Sci-Tech Achievements Transformation Program of Colleges and Universities in Jiangsu Province(No.JH09-13)the Research Fund of Nanjing Institute of Technology(No.YKJ201005)
文摘In order to study the thermoelectric efficiency of microwave heating and reproduction of asphalt pavements and the uniformity of reproduction temperature distribution, a waveguide excitation cavity is designed and applied to the structural design of a microwave heater. The structural sizes of the incentive cavities are determined based on the waveguide transmission line theory. Using IE3D software, electromagnetic simulations are respectively carried out in four different situations, including the distances between the magnetron probes (antennas) and a short-circuit board, different horn electric lengths and aperture sizes, different dielectric properties of the asphalt mixture, and the distances between the asphalt surface and the mouth cavity. The results show that, when the distance between the magnetron probe and the short-circuit board is 32.5 ram, it is the best installation site; reduction of aerial length is the main factor in improving the heating uniformity. When the aggregate is limestone, the best heating effect can be produced. Maximum radiation efficiency can be realized by adjusting the space between the heater radiation port and the asphalt pavement. The experimental results of asphalt mixture heating in four different situations have a substantial agreement with the simulation results, which confirms that the developed microwave heater can achieve better impedance matching, thus improving the quality and efficiency of heating regeneration.
文摘An analytical model of the surface field distribution and breakdown voltage of the reduced surface field lateral double diffusion MOS transistor is proposed.Based on the 2-D Poisson's equation solution,the derived model gives the closed form solutions of the surface potential and electrical field distributions as a function of the structure parameters and drain bias.A criterion for obtaining the optimal trade-off between the breakdown voltage and on-resistance is also presented to serve to quantify the maximum breakdown voltage and optimal relations of all design parameters.Analytical results are shown in good agreement with the numerical analysis obtained by the semiconductor device simulator MEDICI and previous reported experimental data.
文摘WT8.BZ]A new quasi 2-dimensional analytical approach to predicting the ring voltage,edge peak fields and optimal spacing of the planar junction with a single floating field limiting ring structure has been proposed,based on the cylindrical symmetric solution and the critical field concept.The effects of the spacing and reverse voltage on the ring junction voltage and edge peak field profiles have been analyzed.The optimal spacing and the maximum breakdown voltage of the structure have also been obtained.The analytical results are in excellent agreement with that obtained from the 2-D device simulator,MEDICI and the reported result,which proves the presented model valid.
文摘An 1∶8 frequency divider is designed and realized in a 0 35μm standard CMOS technology.The chip consists of three stages of 1∶2 divider cells,which are constructed with source couple logic (SCL) flip flops.By revising the traditional topology of SCL flip flop,a divider with better performances is got.The results of measurement show that the whole chip achieves the frequency division at more than 8 5GHz.Each 1∶2 divider consumes about 11mW from a 3 3V supply.The divider can be used in RF and optic fiber transceivers and other high speed systems.
基金The National Basic Research Program of China(973Program) (No2002CB312102)the National Natural ScienceFoundation of China (No60675047)
文摘The damper is capable of providing a continuously variable dampering force/torque in response to a magnetic field. It consists of an upside cap and an underside cap with a rotor located between them, the magneto-rheological (MR) fluid is filled into the gaps between the rotor and the caps. When the viscosity of the MR fluid increases under the influence of the magnetic field, the movement of the rotor will be resisted. The output torque is made up of the torque caused by the magnetic field, the torque caused by the plastic viscosity of the MR fluid, and the torque caused by the coulomb friction. The viscous torque can be calculated by a simple method and the frictional torque can be obtained by experiments. The torque dependent on the magnetic field is obtained by electromagnetic finite dement analysis. Experiments are done on the damper prototype and the validity of the design is verified.
文摘Ionization is the fundamental process in interaction of atoms/molecules with femtosecond strong laser fields. Comparing to atoms, molecules exhibit peculiar behaviors in strong-field ionization because of their diverse geometric structures, molecular electronic orbitals as well as extra nuclear degrees of freedom. In this study, we investigate strong field single and double ionization of carbon monoxide (CO) and carbon dioxide (CO2) in linearly polarized 50-fs, 800-nm laser fields with peak intensity in the range of 2×10 13 W/cm2 to 2×10 14 W/cm2 using time-of-flight mass spectrometer. By comparing the ionization yields with that of the companion atom krypton (Kr), which has similar ionization potential to the molecules, we investigate the effect of molecular electronic orbitals on the strong-field ionization. The results show that comparing to Kr, no significant suppression is observed in single ionization of both molecules and in non-sequential double ionization (NSDI) of CO, while the NSDI probability of CO2 is strongly suppressed. Based on our results and previous studies on homonuclear diatomic molecules (N2 and O2), the mechanism of different suppression effect is discussed. It is indicated that the different structure of the highest occupied molecular orbitals of CO and CO2 leads to distinct behaviors in two-center interference by the electronic wave-packet and angular distributions of the ionized electrons, resulting in different suppression effect in strong-field ionization.
文摘Numerical simulation of the electrical field distribution helps in-depth understanding of the mechanisms behind the responses and the benefits of the high voltage pulse comminution. The COMSOL Multiphysics package was used to numerically simulate the effect of ore compositions in this study. Regarding phosphate ore particles shape and composition, the effects of mineral composition, particle size, particle shape and electrodes distance were investigated on the electrical field intensity and distribution. The results show that the induced electrical field is significantly dependent on the electrical properties of minerals,the feed particle size and the location of conductive minerals in ores. The angle of material contact surface with the discharge electrode is also an important factor in the intensity of electrical field. Moreover,it is found that the specific liberation effect at the disintegration of phosphate ore by electrical pulses is due to the locality of the electrical field at the interface of mineral components of the phosphate ore aggregates with different permittivities. However, the intensity of the electrical field increases with sharpening the contact angle. Besides, the electrical discharge in the samples is converted to the electrohydraulic discharge across the surrounding water by changing the distance between the discharge electrode and sample surface.
文摘A model of magnetic stimulation is presented for analysis of the spatial distributions of the electric field induced by magnetic coils.Dimensionless analysis is introduced and makes the factors influencing the magnitude of electric field into two parts:c (represents the stimulation conditions),and E 0 (reflects the geometry of coil).By 3 D simulation of the induced electric field of two kinds of coils,the effect of magnetic stimulation can be demonstrated and the factors influencing stimulating focality and depth are identified.The principles for determining the electric field magnitude,focality and magnetic stimulation depth when designing a reasonable coil and stimulator and achieving ideal stimulating effect are discussed.
基金the National Natural Science Foundation of China(No.30400105);the National Basic Research Development Program(973)(No. 2003CB716106);the National Science Fund for Distinguished Young Scholars of China(No.30525030).
文摘Objective Early researches found that different heartbeat perceivers have different heartbeat evoked potential (HEP)waves.Two tasks were considered in our experiments to get more details about the differences between good and poor heartbeat perceivers at attention and resting state.Methods Thirty channels of electroencephalogram(EEG)were recorded in 22 subjects,who had been subdivided into good and poor heartbeat perceivers by mental tracking task. Principal component analysis(PCA)was applied to remove cardiac field artifact(CFA)from the HEP.Results(1)The good heart-beat perceivers showed difference between attention and resting state in the windows from 250 ms to 450 ms after R wave at C3 location and from 100 ms to 300 ms after R wave at C4 location;(2)The difference waveforms between good and poor heartbeat perceivers was a positive waveform at FZ from 220 ms to 340 ms after R wave,which was more significant in attention state.Conclusion Attention state had more effect on the HEPs of good heartbeat perceivers than that of poor heartbeat perceivers;and perception ability influenced HEPs more strongly in the attention state than in the resting state.
基金Supported by the Special Research Project of Fujian Province(JK2012027)the Natural Science Foundation of Fujian Province(2014J01201)
文摘Considering the droplet coalescence, the motion of a group of dispersed droplets in W/O emulsion in a DC electric field is simulated. The simulation demonstrates the evolutions of droplet number, size as well as its distribution,local concentration distribution and droplet size-velocity relation with the applied time of electric field. The simulated average droplet size is roughly consistent with the experimental value. The simulated variation of droplet number with time under several applied voltages shows that increasing voltage is more effective for raising the rate of droplet coalescence than extending exerting time. However, with the further raise of applied voltage, the improvement in droplet coalescence rate becomes less significant. The evolution of simulated droplet size–velocity relationship with time shows that the inter-droplet electric repulsion force is very strong due to larger electric charge on the droplet under higher applied voltage, so that the magnitude and the direction of droplet velocity become more random, which looks helpful to droplet coalescence.
基金Project supported by the Pusan National University Research GrantProject(2010-0008-276) supported by NCRC (National Core Research Center) through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology
文摘The distribution of electric field for the alignment and attachment of carbon nanotubes (CNTs) was simulated. To be attached at the desired place, the aligned and attracted CNTs should be stayed in the desired area called the stable region or the quasi-stable region for an instant where the change of electric field is minimized. Since the conical electrode has the very narrow sized quasi-stable region, few CNTs can be attached. The rectangular electrodes have a wide stable region, so lots of CNTs can be attached. The results indicate that the round electrode which has a proper sized quasi-stable region is more effective for aligning and attaching a single CNT than the conical or rectangular shaped electrodes.
文摘Constructing bismuth oxyhalide solid solutions with a single homogeneous phase have intrigued the research community;however,a deeper understanding of the intrinsic origin for improved bulk-charge separation is still unclear.Herein,a series of Bi_(24)O_(31)Cl_(x)Br_(10-x) solid solutions with the same structural characteristics were synthesized by crystal structure regulation.Combining density functional theory calculation,Kelvin probe force microscopy,and zeta potential testing results,an enhanced internal electric field(IEF)intensity between[Bi_(24)O_(31)]and[X]layers was achieved by changing halogen types and ratios.This greatly facilitated bulk-charge separation and transfer efficiency,which is significant for the degradation of phenolic organic pollutants.Owing to the enhanced IEF intensity,the charge carrier density of Bi_(24)O_(31)Cl_(4)Br_(6) was 33.1 and 4.7 times stronger than that of Bi_(24)O_(31)Cl_(10) and Bi_(24)O_(31)Br_(10),respectively.Therefore,Bi24O31Cl4Br6 had an optimal photoactivity for the degradation of bisphenol A,which was 6.21 and 2.71 times higher than those of Bi_(24)O_(31)Cl_(10) and Bi_(24)O_(31)Br_(10),respectively.Thus,this study revealed the intrinsic mechanism of the solid solution strategy for photocatalytic performance enhancement with respect to an IEF.