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乙基叔丁基醚的催化反应与渗透蒸发膜分离耦合法的合成 被引量:24
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作者 杨伯伦 姚瑞卿 杨三八 《石油化工》 EI CAS CSCD 北大核心 1999年第2期77-81,共5页
以乙醇(EtOH)及叔丁醇(TBA)为原料,用催化反应与渗透蒸发膜分离耦合的方法,以强酸性阳离子交换树脂Amberlyst15为催化剂,合成了乙基叔丁基醚(ETBE)。研究考察了水-醇体系中水的渗透速率及膜的选择性,... 以乙醇(EtOH)及叔丁醇(TBA)为原料,用催化反应与渗透蒸发膜分离耦合的方法,以强酸性阳离子交换树脂Amberlyst15为催化剂,合成了乙基叔丁基醚(ETBE)。研究考察了水-醇体系中水的渗透速率及膜的选择性,讨论了渗透蒸发膜分离耦合与否对其反应结果的影响。在考虑了试验条件下TBA分解为水与异丁烯(IB)而引起的体积减少、水的吸附对催化剂活性的阻害效应以及水的渗透通量等因素的基础上,得出了一数学模型。试验结果与模型计算值比较一致。 展开更多
关键词 乙基叔丁基醚 催化 渗透蒸发 蒸发膜 分离耦合法
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电解分离.电感耦合等离子体发射光谱法测定TP2纯铜中的铜元素和磷元素
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作者 卢耀之 蔡纯 《科技与管理(武汉)》 2013年第3期38-40,共3页
本文采用恒电流电解,电解后溶液用IcP法测得残留铜量予以补正的方法测定铜元素含量,电解后的溶液测定余量铜及磷元素含量,建立了电解分离一电感耦合等离子体发射光谱法测定TP2纯铜中的铜元素和磷元素。目前我国采用GB/T5121-2008重... 本文采用恒电流电解,电解后溶液用IcP法测得残留铜量予以补正的方法测定铜元素含量,电解后的溶液测定余量铜及磷元素含量,建立了电解分离一电感耦合等离子体发射光谱法测定TP2纯铜中的铜元素和磷元素。目前我国采用GB/T5121-2008重量法测定铜含量,原子吸收火焰法或者磷钼钒光度法测定磷含量,通过这两种方法测定磷含量较麻烦,不易操作。 展开更多
关键词 电解分离——电感耦合等离子体发射光谱 TP2纯铜 铜磷
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新型高级氧化技术处理硫化染料废水的研究进展 被引量:9
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作者 聂发辉 刘荣荣 +1 位作者 张慧敏 刘占孟 《化工环保》 CAS CSCD 北大核心 2015年第5期492-497,共6页
综述了各种用于硫化染料废水的新型高级氧化技术,包括电化学氧化法、E-peroxone氧化法、类Fenton试剂氧化法、光催化氧化法、光催化与膜分离耦合法和光催化燃料电池法。分析了各种高级氧化技术的主要影响因素,并指出各种方法的优势与不... 综述了各种用于硫化染料废水的新型高级氧化技术,包括电化学氧化法、E-peroxone氧化法、类Fenton试剂氧化法、光催化氧化法、光催化与膜分离耦合法和光催化燃料电池法。分析了各种高级氧化技术的主要影响因素,并指出各种方法的优势与不足,对高级氧化技术的发展方向提出了展望,为今后硫化染料废水的综合治理提供了技术指导。 展开更多
关键词 电化学氧化 E-peroxone氧化 类Fenton试剂氧化 光催化氧化 光催化与膜分离耦合法 光催化燃料电池 硫化染料废水
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Continuum and Discrete Element Coupling Approach to Analyzing Seismic Responses of a Slope Covered by Deposits 被引量:7
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作者 ZHANG Hua LU Yang 《Journal of Mountain Science》 SCIE CSCD 2010年第3期264-275,共12页
Numerical analyses of earthquake effects on the deformation, stability, and load transfer of a slope covered by deposits are traditionally based on the assumption that the slope is a continuum. It would be problem... Numerical analyses of earthquake effects on the deformation, stability, and load transfer of a slope covered by deposits are traditionally based on the assumption that the slope is a continuum. It would be problematic, however, to extend these approaches to the simulation of the slide, collapse and disintegration of the deposits under seismic loading. Contrary to this, a discrete element method (DEM) provides a means to consider large displacement and rotation of the non-continuum. To take the advantages of both methods of continuum and non- continuum analyses, seismic responses of a slope covered by deposits are studied by coupling a twodimensional (a-D) finite difference method and a 2-D DEM, with the bedrock being modelled by the finite difference grids and the deposits being represented by disks. A smooth transition across the boundaries of the continuous/discontinuous domains is obtained by imposing the compatibility condition and equilibrium condition along their interfaces. In the course of computation, the same time-step value is chosen for both continuous and discontinuous domains. The free-field boundaries are adopted for lateral grids of bedrock domain to eliminate the radiation damping effect. When the static equilibrium under gravity load is obtained, dynamic calculation begins under excitation of the seismic wave input from the continuum model bottom. In this way, responses to the earthquake of a slope covered by deposits are analyzed dynamically. Combined with field monitoring data, deformation and stability of the slope are discussed. The effects of the relevant parameters of spectrum characteristic, duration, andpeak acceleration of seismic waves are further investigated and explained from the simulations. 展开更多
关键词 SLOPE DEPOSIT CONTINUUM discreteelement method dynamic coupling rock/soilinterface
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Land Use Effects on the Distribution and Speciation of Heavy Metals and Arsenic in Coastal Soils on Chongming Island in the Yangtze River Estuary, China 被引量:13
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作者 ZHENG Rong ZHAO Jiale +3 位作者 ZHOU Xiu MA Chao WANG Li GAO Xiaojiang 《Pedosphere》 SCIE CAS CSCD 2016年第1期74-84,共11页
The reclamation of tidal fiats has been one of the important approaches to replenish the arable lands in the coastal areas; pollution status of reclaimed soils has received wide attention recently, especially for the ... The reclamation of tidal fiats has been one of the important approaches to replenish the arable lands in the coastal areas; pollution status of reclaimed soils has received wide attention recently, especially for the study of heavy metals due to the relative high pollutant concentrations in wetlands. To understand the impact of land use change on heavy metal and arsenic (As) geochemistry by the reclamation of wetlands for agriculture, surface soils and soil profiles were collected from the agricultural land reclaimed in the 1990s and the intertidal flat wetland at Dongtan on Chongming Island in the Yangtze River Estuary, China. The soil samples were analyzed for total concentrations and chemical speciation of chromium (Cr), zinc (Zn), copper (Cu), lead (Pb), nickel (Ni), cadmium (Cd) and As using inductively coupled plasma mass spectrometry (ICP-MS). Results showed that soil properties (salinity, total organic carbon and grain-size distribution) and the concentrations of heavy metals and As in the soils differed under the different land use types. The conversion of wetland to forest had caused obvious losses of all the measured heavy metals. In paddy field and dryland with frequent cultivation, the concentrations of Cr, Zn, Cu, Ni and As were higher when compared to forest land which was disturbed rarely by human activities. Speciation analysis showed that Cr, Zn, Cu, Ni and As were predominated by the immobile residual fraction, while Pb and Cd showed relatively higher mobility. In general, metal (except Ni) and As mobility decreased in the following order: wetland 〉 dryland 〉 paddy field 〉 forest land, which suggested that the reclaimed soils had lower metal and As mobility than the intertidal fiat wetland. The results of this study contribute to a better understanding of the effects of land use on heavy metals and As in the reclaimed soils of the study area and other similar coastal areas. 展开更多
关键词 chemical fraction DRYLAND forest land intertidal flat paddy field reclaimed soils WETLAND
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Dual-core photonic crystal fiber polarization splitter based on lead silicate glass
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作者 孙宇伟 白育堃 马秀荣 《Optoelectronics Letters》 EI 2015年第3期170-173,共4页
A dual-core photonic crystal fiber(PCF)polarization splitter based on lead silicate glass is proposed.The characteristics of the polarization splitter are analyzed using full-vector finite element method.Compared with... A dual-core photonic crystal fiber(PCF)polarization splitter based on lead silicate glass is proposed.The characteristics of the polarization splitter are analyzed using full-vector finite element method.Compared with the silica glass PCF polarization splitter with the same structure,it is shown that the new material polarizer can realize splitting with less coupling loss and higher extinction ratio.When the wavelength is 1 550 nm and the PCF length in the beam splitter is 688μm,the coupling loss is only 0.001 9 d B,and the extinction ratio for the input core is-64.1 d B. 展开更多
关键词 Crystal whiskers Finite element method GLASS Light extinction Nonlinear optics Optical instruments Photonic crystals POLARIZATION SILICATES
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