A combination of high-field asymmetric waveform ion mobility spectrometry （FAIMS） with mass spectrometer （MS） was analyzed. FAIMS separates ions from the volatile organic compounds in the gas-phase as an ion-filte...A combination of high-field asymmetric waveform ion mobility spectrometry （FAIMS） with mass spectrometer （MS） was analyzed. FAIMS separates ions from the volatile organic compounds in the gas-phase as an ion-filter for MS. The sample ions were created at ambient pressure by ion source, which was equipped with a 10.6 eV UV discharge lamp （A=116.5 nm）. The drift tube of FAIMS is composed of two parallel planar electrodes and the dimension is 10 mm×8 mm×0.5 mm. FAIMS was investigated when driven by the high-filed rectangular asymmetric waveform with the peak-to-peak voltage of 1.36 kV at the frequency of 1 MHz and the duty cycle of 30%. The acetone, the butanone, and their mixture were adopted to characterize the FAIMS-MS. The mass spectra obtained from MS illustrate that there are ion-molecular reactions between the ions and the sample neutral molecular. And the proton transfer behavior in the mixture of the acetone and the butanone is also observed. With the compensation voltage tuned from -30 V to 10 V with a step size of 0.1 V, the ion pre-separation before MS is realized.展开更多
A simple harmonic motion is proposed to make the membrane move in a simpleharmonic way so as to enhance the membrane filtration, and minimize the membrane fouling andconcentration polarization. The velocity distributi...A simple harmonic motion is proposed to make the membrane move in a simpleharmonic way so as to enhance the membrane filtration, and minimize the membrane fouling andconcentration polarization. The velocity distribution and pressure distribution are deduced from theNavier-Stokes equation on the basis of a laminar flow when the membrane rotates at the speed of Asin(αt). And then the shear stress, shear force, moment of force on the membrane surface and powerconsumed by viscous force are calculated. The velocity distribution demonstrates that the phase ofmembrane velocity does not synchronize with that of shear stress. The simple harmonic motion canresult in self-cleaning, optimize energy utilization, provide the velocity field with instability,and make the feed fluid fluctuation. It also results in higher shear stress on the membrane surfacethan the constant motion when they consume the same quantitative energy.展开更多
Based on the analysis of high-speed video images, the detachment behavior of dust cake from the ceramic candle filter surface during pulse cleaning process is investigated. The influences of the dust cake loading,the ...Based on the analysis of high-speed video images, the detachment behavior of dust cake from the ceramic candle filter surface during pulse cleaning process is investigated. The influences of the dust cake loading,the reservoir pressure, and the filtration velocity on the cleaning effectiveness are analyzed. Experimental results show that there exists an optimum dust cake thickness for pulse-cleaning process. For thin dust cake, the patchy cleaning exists and the cleaning efficiency is low; if the dust cake is too thick, the pressure drop across the dust cake becomes higher and a higher reservoir pressure may be needed. At the same time there also exists an optimum reservoir pressure for a given filtration condition.展开更多
The Yangzi Petrochemical Company has successfully imple-mented the test commissioning of a 45 t/h pressure filter (base on dry feed material) installed in the PTA unit with its pressure filter technique commanding a l...The Yangzi Petrochemical Company has successfully imple-mented the test commissioning of a 45 t/h pressure filter (base on dry feed material) installed in the PTA unit with its pressure filter technique commanding a leading展开更多
This paper presents an investigation of a new method of purifying cryogenic liquid using sintered metallic wire-mesh filter, which has the advantages of high purifying efficiency and preferred strength at absolutely l...This paper presents an investigation of a new method of purifying cryogenic liquid using sintered metallic wire-mesh filter, which has the advantages of high purifying efficiency and preferred strength at absolutely low temperature. Experiments are conducted to purify solid CO2 particles from liquid nitrogen. Temperature and pressure in the upstream and downstream of the filter, and the flow rate of carbon dioxide （CO2） gas and liquid nitrogen are measured, with the gas content of filtrate analyzed using a CO2 concentration detector. It is illustrated that after filtration, the purity of liquid nitrogen （volume fraction） is higher than 99.99%, which means that the volume fraction of CO2 is less than 0.01%. Effects of operation parameters on the performance of the filter, such as pressure drop Ap and filtration efficiency E are analyzed quantitatively. The present conclusions will provide a guideline to the optimumal design and operation of sintered metallic wire-mesh filter in cryogenic application.展开更多
文摘A combination of high-field asymmetric waveform ion mobility spectrometry （FAIMS） with mass spectrometer （MS） was analyzed. FAIMS separates ions from the volatile organic compounds in the gas-phase as an ion-filter for MS. The sample ions were created at ambient pressure by ion source, which was equipped with a 10.6 eV UV discharge lamp （A=116.5 nm）. The drift tube of FAIMS is composed of two parallel planar electrodes and the dimension is 10 mm×8 mm×0.5 mm. FAIMS was investigated when driven by the high-filed rectangular asymmetric waveform with the peak-to-peak voltage of 1.36 kV at the frequency of 1 MHz and the duty cycle of 30%. The acetone, the butanone, and their mixture were adopted to characterize the FAIMS-MS. The mass spectra obtained from MS illustrate that there are ion-molecular reactions between the ions and the sample neutral molecular. And the proton transfer behavior in the mixture of the acetone and the butanone is also observed. With the compensation voltage tuned from -30 V to 10 V with a step size of 0.1 V, the ion pre-separation before MS is realized.
文摘A simple harmonic motion is proposed to make the membrane move in a simpleharmonic way so as to enhance the membrane filtration, and minimize the membrane fouling andconcentration polarization. The velocity distribution and pressure distribution are deduced from theNavier-Stokes equation on the basis of a laminar flow when the membrane rotates at the speed of Asin(αt). And then the shear stress, shear force, moment of force on the membrane surface and powerconsumed by viscous force are calculated. The velocity distribution demonstrates that the phase ofmembrane velocity does not synchronize with that of shear stress. The simple harmonic motion canresult in self-cleaning, optimize energy utilization, provide the velocity field with instability,and make the feed fluid fluctuation. It also results in higher shear stress on the membrane surfacethan the constant motion when they consume the same quantitative energy.
基金Supported by the National Natural Science Foundation of China (No. 50376042)Doctoral Program Foundation of Institute of Higher Education of China (20040425007).
文摘Based on the analysis of high-speed video images, the detachment behavior of dust cake from the ceramic candle filter surface during pulse cleaning process is investigated. The influences of the dust cake loading,the reservoir pressure, and the filtration velocity on the cleaning effectiveness are analyzed. Experimental results show that there exists an optimum dust cake thickness for pulse-cleaning process. For thin dust cake, the patchy cleaning exists and the cleaning efficiency is low; if the dust cake is too thick, the pressure drop across the dust cake becomes higher and a higher reservoir pressure may be needed. At the same time there also exists an optimum reservoir pressure for a given filtration condition.
文摘The Yangzi Petrochemical Company has successfully imple-mented the test commissioning of a 45 t/h pressure filter (base on dry feed material) installed in the PTA unit with its pressure filter technique commanding a leading
基金the National Natural Science Foundation of China(No.50476022)the Ministries and Commissions of Science and Technology of Shanghai Government(No.03DZ 14014)
文摘This paper presents an investigation of a new method of purifying cryogenic liquid using sintered metallic wire-mesh filter, which has the advantages of high purifying efficiency and preferred strength at absolutely low temperature. Experiments are conducted to purify solid CO2 particles from liquid nitrogen. Temperature and pressure in the upstream and downstream of the filter, and the flow rate of carbon dioxide （CO2） gas and liquid nitrogen are measured, with the gas content of filtrate analyzed using a CO2 concentration detector. It is illustrated that after filtration, the purity of liquid nitrogen （volume fraction） is higher than 99.99%, which means that the volume fraction of CO2 is less than 0.01%. Effects of operation parameters on the performance of the filter, such as pressure drop Ap and filtration efficiency E are analyzed quantitatively. The present conclusions will provide a guideline to the optimumal design and operation of sintered metallic wire-mesh filter in cryogenic application.
