基于CORS的分米级GNSS差分定位云服务研究

面向GNSS大众应用领域海量高精度位置服务需求,提出了一种基于CORS的分米级差分定位云服务建设方法,采用虚拟格网用户生成改正数的形式,通过设计解算服务器与业务服务器分离的云服务模式,解决了传统CORS服务中基准站数据安全风险大、用户并发访问数量受限的问题,并以API和SDK形式面向用户和开发者提供应用服务,降低了高精度位置服务专业技术门槛。同时,依托本文研究成果,基于湖南省位置服务平台(HNCORS),设计并实现了基于CORS的分米级GNSS差分定位云服务架构,并以丢包率、外符合精度、高并发访问为指标进行测试。结果表明,本文设计的云服务架构具有较好的精度、稳定性和可靠性,在高精度位置服务应用中具有较好的应用前景,也可为其他省级CORS网的高精度位置服务云平台建设提供技术参考。

亚分米级GPS基线解算新算法

当双差模糊度固定解的可靠性下降时,三差基线解成为当前情况下的最优选择,但通常情况下三差基线解精度只能达到分米级,难以满足高精度的要求.通过对三差测量值进行误差分析,给出三差观测量信噪比模型,结合实际观测数据分析,指出噪声对三差观测量影响很大.借鉴均值漂移理论出了精度为亚分米级的基线解算的新算法,给出了适用于单频三差基线解算的均值漂移模型,所述算法的精度可以达到10 cm,即亚分米级.

面向北斗单历元分米级定位的ARAIM保护水平计算方法

精密定位的质量控制和完好性评估是实时全球卫星导航系统(GNSS)导航应用不可或缺的环节,尤其是在GNSS易受损害的城市峡谷等场景下,这种需求更加迫切.广域精密单点定位(PPP)瞬时分米级定位,利用GNSS三频信号形成的两个宽巷观测值可以实现单点单历元分米级定位.然而,在城市复杂环境中,反射信号、严重多路径以及其他信号干扰对定位造成的影响无法准确评估与识别,限制了PPP瞬时分米级单点定位的应用.完好性概念中的高级接收机自主完好性监测(ARAIM)可以计算用户定位误差最小置信区间的上限保护水平(PL)以评估定位有效性,可经过一定改进用于PPP瞬时定位的质量控制.针对当前ARAIM中计算PL的误差模型难以适应高精度定位需求的问题,提出了一种改进的ARAIM PL算法,称其为BARAIM(Back Advanced Receiver Autonomous Integrity Monitoring).使用PPP三频组合观测值残差对ARAIM权与误差模型进行修正以计算PL.基于不同复杂程度的环境下采集的车载数据对算法进行了验证,对PL的改进情况以及导航的可用性提升情况进行评估.结果表明:在不同环境下,基于改进的B-ARAIM算法得到的PL,相比传统方法得到的PL更符合城市定位的需要,将PL降低了30%~70%.此方法有助于将ARAIM算法应用在高精度GNSS定位领域.

单WiFi室内分米级定位技术探讨

无线WiFi是现在互联网世界的基础,一切互联网技术都是在这个平台上使用的。近几年,互联网的使用很大程度上都是依赖无线网WiFi,其中的WiFi室内定位技术已经成为人们讨论最多的话题,很多人都在这方面做了研究。目前,WiFi大多数智能是在室内定位已知的先验条件下实现的,但在实际中,不能部署多个AP依然是最大问题。

顾及广播星历误差分离吸收的分米级星载GPS实时定轨新方法

受广播星历轨道误差与卫星钟误差以及伪距观测噪声等因素的制约,传统的星载GPS伪距实时定轨方法位置精度通常只能达到1.0m左右,速度精度为1.0mm/s左右。本文提出了一种新的高精度星载GPS实时定轨方法,该方法基于广播星历误差的缓变特性,同时使用伪距与相位作为观测值,通过在卡尔曼滤波模型中设置相应参数对广播星历误差进行分离吸收,从而实现分米级精度的实时定轨。采用自主研制的实时定轨软件SATPODS对不同轨道高度的CHAMP（320km）、GRACE-A（460km）与SAC-C（700km）卫星连续31d的实测数据模拟在轨实时处理,结果表明,新方法可以实现30-40cm的位置精度以及0.3-0.5mm/s的速度精度,相比于传统的伪距实时定轨方法,精度可提高50%以上。

分米波毫秒级太阳射电爆发的几个形态

介绍使用１０ｍ天线上２１ｃｍ波段ｍｓ级连续快速记录系统，观测到分米波太阳射电快速活动的几种形态、特征、尖峰辐射及其共生现象。

基于机载InSAR干涉相位的高层建筑重构

通过分米级高分辨SAR能够提取城市更细致的细节信息,特别是结合InSAR技术,能够获取个体建筑的三维信息和其他信息。国内城区中分布着大量的高层建筑,因此在大城市和城镇中心的城市规划中,获取高层建筑的三维信息非常重要。该文首先分析高层建筑在分米级InSAR中的投影分布特性;在此基础上,依据干涉相位图中的高层建筑特性,通过建筑检测、墙体提取和三维参数估计的逐层处理方法,实现基于InSAR干涉缠绕相位的城市场景高层建筑的三维信息重建。并采用机载N-SAR系统录取的城市实测数据验证了该方法的可行性。

Self-assembly of hierarchical ZnSnO_3-SnO_2 nanoflakes and their gas sensing properties

A new type of hierarchical ZnSnO3-SnO2 flower-shaped nanostructure composed of thin nanoflakes as secondary units is successfully prepared through a simple hydrothermal process. The polyhedral ZnSnO3 core acts as a sacrificed template for the growth of hierarchical SnO2 nanoflakes, and the average thickness of SnO2 nanoflakes is around 25 nm. The time-dependent morphology evolution of ZnSnO3-SnO2 samples was investigated, and a possible formation mechanism of these hierarchical structures is discussed. The gas sensor based on these novel ZnSnO3-SnO2 nanostructures exhibits high response and quick response- recovery traits to ethanol （C2H5OH）. It is found that ZnSnO3-SnO2 nanoflakes have a response of 27.8 to 50×10-6 C2H5OH at the optimal operating temperature of 270 °C, and the response and recovery time are within 1.0 and 1.8 s, respectively.

Nanosized and hierarchical zeolites: A short review

Zeolites are crystalline aluminosilicates with three‐dimensional microporous structures. They have been used as ion‐exchangers, catalysts, and adsorbents in various fields such as oil refining, petro‐chemistry, agriculture, and water and wastewater treatment. Their wide use is because of their many beneficial properties, such as framework and compositional flexibilities, physical and hydro‐thermal stabilities, non‐toxicity, high surface areas, exchangeable cations, and good cost‐benefit ratios. Although many zeolite applications depend on their microporous structures, this can cause diffusional constraints for bulky reactant and product molecules. There have been many efforts to overcome the intrinsic limitations of conventional zeolites by preparing nanosized and hierarchi‐cally structured zeolites. As a result of these efforts, several strategies have been established and the use of new zeolitic materials in various catalytic and adsorptive reactions has been investigated. Longer lifetimes, high catalytic performances, and postponed coking and catalyst deactivation can be achieved using hierarchical and nanosized zeolites. The aim of this review is to provide an over‐view of the enhanced properties of hierarchical and nanosized zeolites, and recent development methods for their synthesis. The advantages and disadvantages of each route are discussed, and the catalytic applications of nanozeolites and zeolites with secondary porosity, and a comparison with conventional zeolites, are briefly presented.

Hierarchical TiO2 nanorods with a highly active surface for photocatalytic CO_(2) reduction

Photocatalytic carbon dioxide reduction reaction(CO_(2)RR)has been considered as one of most effective ways to solve the current energy crisis and environmental problems.However,the practical application of photocatalytic CO_(2)RR is largely hindered by lock of efficient catalyst.Here,hierarchical titanium dioxide(TiO_(2))nanostructures with a highly active{001}surface were successfully synthesized by a facile approach from metal Ti powders.The obtained hierarchical TiO_(2)nanostructures were composed of TiO_(2)nanorods,which have a diameter about 5–10 nm and a length of several micrometers.It is found that these nanorods have exposed{001}facets.On the other hand,these hierarchical TiO_(2)nanostructures have a good light-harvesting efficiency with the help of TiO_(2)nanorods component and large specific surface area.Therefore,these hierarchical TiO_(2)nanostructures exhibit a much better activity for photocatalytic CO_(2)reduction than that of commercial TiO_(2)(P25).This high activity can be attributed to the synergistic effects of active surface,efficient charge transfer along nanorods and good light harvesting in the nanorod-hierarchical nanostructures.

High-performance Pt catalysts supported on hierarchical nitrogen-doped carbon nanocages for methanol electrooxidation

Hierarchical nitrogen-doped carbon nanocages （hNCNC） with large specific surface areas were used as a catalyst support to immobilize Pt nanoparticles by a microwave-assisted polyol method. The Pt/hNCNC catalyst with 20 wt% loading has a homogeneous dispersion of Pt nanoparticles with the average size of 3.3 nm, which is smaller than 4.3 and 4.9 nm for the control catalysts with the same loading supported on hierarchical carbon nanocages （hCNC） and commercial Vulcan XC-72, respec- tively. Accordingly, Pt/hNCNC has a larger electrochemical surface area than Pt/hCNC and Pt/XC-72. The Pt/hNCNC catalyst exhibited excellent electrocatalytic activity and stability for methanol oxidation, which was better than the control catalysts. This was attributed to the en- hanced interaction between Pt and hNCNC due to nitrogen participation in the anchoring function. By making use of the unique advantages of the hNCNC support, a heavy Pt loading up to 60 wt% was prepared without serious agglomeration, which gave a high peak-current density per unit mass of catalyst of 95.6 mA/mg for achieving a high power density. These results showed the potential of the Pt/hNCNC catalyst for methanol oxidation and of the new hNCNC support for wide applications.

Correlation between H-ZSM-5 crystal size and catalytic performance in the methanol-to-aromatics reaction

The porosity of H‐ZSM‐5zeolite is known to facilitate the diffusion of molecules in the methanol‐to‐aromatics(MTA)reaction.The activity and selectivity of the H‐ZSM‐5catalyst in the MTAreaction has been studied as a function of crystal size.ZSM‐5zeolites with different crystal sizeswere successfully synthesized by conventional hydrothermal methods.Tailoring ZSM‐5particle sizewas easily controlled by changes to the sol‐gel composition,and in particular,the deionized waterto tetrapropylammonium hydroxide ratio,and crystallization time.The structure of the H‐ZSM‐5zeolites were characterized by X‐ray diffraction and the morphology of the zeolite particles wasdetermined by scanning electron microscopy.N2adsorption‐desorption measurements establishedchanges to the textural properties,and compositional properties were characterized by X‐ray fluorescencespectroscopy.Acidity measurements of the catalysts were measured by pyridine‐adsorbedFourier transform infrared spectroscopy and the temperature‐programmed desorption of ammonia.After subjecting the catalysts to the MTA reaction,the total amount of coke formed on the spentdeactivated catalysts was determined by thermal gravimetric analysis.The results show that theSiO2/Al2O3molar ratios and acidic properties of the H‐ZSM‐5samples are similar,however,thenano‐sized hierarchical ZSM‐5zeolite with an additional level of auxiliary pores possesses a higher

Photocatalytic Activity of Hierarchical Flower-Like TiO_(2) Superstructures with Dominant {001} Facets

The fabrication of well defined hierarchical structures of anatase TiO_(2) with a high percentage of reactive facets is of great importance and challenging.Hierarchically flower-like TiO_(2) superstructures(HFTS)self-assembled from anatase TiO_(2) nanosheets with exposed{001}facets(up to 87%)were synthesized by a simple alcohothermal strategy in a HF-H_(2)O-C_(2)H_(5)OH mixed solution using titanate nanotubes as precursor.The samples were characterized by X-ray diffraction,scanning electron microscopy,transmission electron microscopy,and N2 adsorption-desorption isotherms.The photocatalytic activity was evaluated by the photocatalytic oxidation decomposition of acetone in air and methyl orange in aqueous solution under UV illumination.The photocatalytic activity of HFTS was much higher than that of commercial Degussa P25 and tabular-shaped anatase TiO_(2) obtained using pure water as the synthesis medium.The enhancement in photocatalytic activity was related to several factors,including the hierarchically porous structure,exposed{001}facets,and increased light harvesting ability.The HFTS was also of interest for use in solar cells,photocatalytic H_(2) production,optoelectronic devices,sensors,and catalysis.

Solid state synthesis of nano-mineral particles

Many researchers in academia and industries are interested in reducing particle sizes from few submicrometers to nano-meter levels.These nano-particles find application in several areas including ceramics,paints,cosmetics,microelectronics,sensors,textiles and biomedical,etc.This article reviews the present state of the art for solid state synthesis of mineral nano-particles by wet milling,including their operating variables such as ball size,solid mass fraction and suspension stability.This article concludes and recommends with a critical discussion of nano-particles synthesis and a few common strategies to overcome stability issues.

Preparation of Nano-sized Silica-alumina Support by Supersolubilizing Self-assembly Technique

Nano-sized silica-alumina particles were in-situ synthesized in supersolubilizing reverse micellae.Both the most probable pore diameters and the particle sizes were distributed in nano-scale SiO2-Al2O3 particulates.The influence of SiO2/Al2O3 mass ratio and the surfactant content on the particle size and morphology,pore structure,and acidity was characterized by the low temperature nitrogen adsorption/desorption (BET),SEM,TEM and NH3-TPD methods.The test results indicated that the most probable pore diameter of SiO2-Al2O3 nanoparticles was around 10 nm,the specific surface area was about 223-286 m2 /g,the pore volumes were about 0.48-0.63 cm 3 /g,and the particle sizes of porous SiO2-Al2O3 calcined at 550 ℃ were distributed always in the range between 10 nm to 50 nm.The calcined SiO2-Al2O3 nano-powders showed their acidity being stronger than the porous γ-Al2O3 support.

Investigation of nanometer-scale films using low angle Xray reflectivity analysis in IPOE

The X-ray low angle reflectivity measurement is used to investigate single and bilayer films to determine the parameters of nanometer-scale structures,three effectual methods are presented by using X-ray reflectivity analysis to provide an accurate estimation of the nanometer film structures. The parameters of tungsten (W) single layer, such as the material density, interface roughness and deposition rate, were obtained easily and speedily. The base metal layer was introduced to measure the profiles of single low Z material film. A 0.3 nm chromium (Cr) film was also studied by low angle reflectivity analysis.

Scanning Raman Picoscopy: Angstrom-Resolved Tip-Enhanced Raman Spectromicroscopy

In this review,we present a brief overview on the recent advances in Angstr6m-resolved tip-enhanced Raman spectromicroscopy.We first introduce the theoretical understanding of the confinement of light at the atomistic scale,and explain how the Raman scattering from a single molecule happens under the“illumination”of such an atomically confined light.Then we describe the latest developments on Angstr6m-resolved tipenhanced Raman spectromicroscopy,particularly on a new methodology called“scanning Raman picoscopy”for visually cons true ting the chemical st ruc ture of a single molecule in real space.Finally,we give a perspective of this technique in various applications where iden ti fying the chemical st ruc tu res of mat erials at the chemical bond level is required.

PPP-B2b常数偏差实时改正后的多频单历元定位

针对PPP-B2b钟差产品存在纳秒级钟差常数偏差,且此常数偏差对PPP-B2b单历元定位存在较大影响的问题,该文通过分析PPP-B2b钟差及轨道精度确定了PPP-B2b常数偏差的存在,提出了一种利用卫星UDP产品构造北斗四频AFIF高精度观测值实时估计PPP-B2b常数偏差的算法,并进一步分析了估计值对于PPP-B2b单历元定位能力的提升。本文验证了卫星各弧段内不同测站所估计的常数偏差值的一致性,彼此之间差异约0.15ns,使用常数偏差估计值改正后,在E、N、U方向上的单历元定位可分别实现0.1802、0.1355和0.5207m的定位精度。上述实验结果表明,使用上述算法估计的常数偏差值相对于不加改正可大幅度提升PPP-B2b单历元定位精度,定位能力与精密星历精度相仿,实现了PPP-B2b实时单历元分米级定位。

Ni(OH)_2 nanoflakes supported on 3D hierarchically nanoporous gold/Ni foam as superior electrodes for supercapacitors

The increasing demand for portable electronic devices and hybrid electric vehicles stimulates the develop- ment of supercapacitors as an advanced energy storage system. Here, we demonstrate a binder-free nickel hydroxide@nano- porous gold/Ni foam （Ni（OH）2@NPG/Ni foam） electrode for high-performance supercapacitors, which is prepared by a facile three-step fabrication route including electrodeposition of Au-Sn alloy on Ni foam, chemical dealloying of Sn and electrodepostion of Ni（OH）2 on NPG/Ni foam. Such Ni（OH）2@NPG/Ni foam electrode is composed of a thin layer of conformable Ni（OH）2 nanoflakes supported on three-di- mensional （3D） hierarchically porous NPG/Ni foam substrate. The resulting Ni（OH）2@NPG/Ni foam electrode can offer highways for both electron transfer and ion transport and lead to an excellent electrochemical performance with an ultrahigh specific capacitance of 3,380 F g-1 at a current density of 2 A g-1. Even when the current density was increased to 50 A g-1, it still retained a high capacitance of 1,927 F g-1. The promising performance of the Ni（OH）2@NPG/Ni foam elec- trode is mainly ascribed to the 3D hierarchical porosity and the highly conductive network on the NPG/Ni foam composite current collector, as well as the conformal electrodeposition of Ni（OH）2 active material on the NPG/Ni foam, which induces the formation of interconnected porosity both on the top surface and on the inner surface of the electrode. This in- spiring electrochemical performance would make the as-de- signed electrode material become one of the most promising candidates for future electrochemical energy storage systems.

Contactless probing of the intrinsic carrier transport single-walled carbon nanotubes

Intrinsic carrier transport properties of single-walled carbon nanotubes have been probed by two parallel methods on the same individual tubes： The contactless dielectric force microscopy （DFM） technique and the conventional field-effect transistor （FET） method. The dielectric responses of SWNTs are strongly correlated with electronic transport of the corresponding FETs. The DC bias voltage in DFM plays a role analogous to the gate voltage in FET. A microscopic model based on the general continuity equation and numerical simulation is built to reveal the link between intrinsic properties such as carrier concentration and mobility and the macroscopic observable, i.e. dielectric responses, in DFM experiments. Local transport barriers in nanotubes, which influence the device transport behaviors, are also detected with nanometer scale resolution.