The pyrolysis characteristics of Shendong Shangwan coal and its macerals concentrate were investigated using thermogravimetry (TG) coupled with mass spectrometry (MS). The evolved gases were analyzed online by MS ...The pyrolysis characteristics of Shendong Shangwan coal and its macerals concentrate were investigated using thermogravimetry (TG) coupled with mass spectrometry (MS). The evolved gases were analyzed online by MS spectroscopy. The results of TG/DTG (derivative thermogravimetry) show ths vitrinite concentrate has greater weight loss rate and higher volatile yield than the other two samples. More light hydrocarbons C1-C5 are released from the vitfinite concentrate than from the Shendong Shangwan coal and inertinite concentrated in the process of pyrolysis. Three samples have similar shape curves of evolved gases of C2~C5 with different intensities. When the pyrolysis temperature was lower than 418℃, the amount of C6H6 evolved in the process of pyrolysis of inertinite concentrated was higher than that of raw coal and vitrinite concentrate. As the temperature rising, the production rate of C6H6 increased. Below 672℃, C6H6 evolution rate of vitrinite concentrate was far greater than the other two samples; the main evolution temperature range of C7H8 was 400℃ to 700℃ for the three samples. The amount of HE and H20 released first increased and then decreased with the temperature increase while more H2 released for pyrolysis of inertinite concentrated and more H20 released for the pyrolysis of vitrinite concentrate.展开更多
The viscosity-time curve of a single-component polyurethane(PU)was examined to determine the mixing and compacting temperatures of its mixture and investigate the curing and mechanical properties of single-component P...The viscosity-time curve of a single-component polyurethane(PU)was examined to determine the mixing and compacting temperatures of its mixture and investigate the curing and mechanical properties of single-component PU porous elastic mixture(PPEM).The curing properties of the single-component PU and PPEM were studied with Fourier transform infrared spectroscopy(FTIR)and Marshall test.The mechanical properties of PPEM were explored via the following tests:rutting test,3-point bending test,soaked Marshall stability test,freeze-thaw splitting test,and Cantabro test.The effects of a water bath on the stability of aggregate-PU/asphalt mortar-aggregate systems were evaluated through a pull-out test and a shear test.The results show that the recommended mixing temperatures of toluene diisocyanate and methylene diphenyl diisocyanate range from 75 to 80℃and from 64 to 68℃,respectively.Room temperature(25℃)can be adopted as the compacting temperature of PPEM.PPEM can be fully cured in 4 d.Nevertheless,the water sprinkle method can obviously shorten the full curing time of PPEM.PPEM exhibites good resistance to rutting,brittle cracking,and raveling.The adhesive and shear strength of aggregate-PU/asphalt mortar-aggregate systems are negatively related to water bath duration.展开更多
Pedestrian's road-crossing model is the key part of micro-simulation for mixed traffic at signalized intersection.To reproduce the crossing behavior of pedestrians,the microscopic behaviors of the pedestrians pass...Pedestrian's road-crossing model is the key part of micro-simulation for mixed traffic at signalized intersection.To reproduce the crossing behavior of pedestrians,the microscopic behaviors of the pedestrians passing through the crosswalk at signalized intersection were analyzed.A pedestrian's decision making model based on gap acceptance theory was proposed.Based on the field data at three typical intersections in Beijing,China,the critical gaps and lags of pedestrians were calibrated.In addition,considering pedestrian's required space,a modification of the social force model that consists of a self-deceleration mechanism prevents a simulated pedestrian from continuously pushing over other pedestrians,making the simulation more realistic.After the simple change,the modified social force model is able to reproduce the fundamental diagram of pedestrian flows for densities less than 3.5 m-2 as reported in the literature.展开更多
The dynamical behavior in the cortical brain network of macaque is studied by modeling each cortical area with a subnetwork of interacting excitable neurons. We characterize the system by studying how to perform the t...The dynamical behavior in the cortical brain network of macaque is studied by modeling each cortical area with a subnetwork of interacting excitable neurons. We characterize the system by studying how to perform the transition, which is now topology-dependent, from the active state to that with no activity. This could be a naive model for the wakening and sleeping of a brain-like system, i.e., a multi-component system with two different dynamical behavior.展开更多
Investigated the effect of an addition of CaF2 on the crystallization of a glass-ceramic with abrasion resistance. X-ray diffraction, differential thermal analysis and scanning electron microscopy were used to determi...Investigated the effect of an addition of CaF2 on the crystallization of a glass-ceramic with abrasion resistance. X-ray diffraction, differential thermal analysis and scanning electron microscopy were used to determine the effect. The results showed that a suitable addition of CaF2 promoted crystallization by forming an interme- diate crystalline phase. CaF2 can decrease the temperature and active energy of the base-glass for crystallization. When 4 mass-% of CaF2-fraction is added in the glass, the crystallization temperature and active energy is 936 ℃and 172.75 kJ/mol respectively. When CaF2 is increased to 6 mass-%, the temperature and active energy decrease to 890 ℃ and 88.81 kJ/mol. CaF2 is an efficient nucleating agent for the glass-ceramics with abrasion resistant, the optimal content of CaF2 is about 6 mass-%.展开更多
One can distinguish three levels in the integrative unity of knowledge and norms (assessments), which is termed bioethics. The first level is theoretical. It is connected with the facts and truths. The second level ...One can distinguish three levels in the integrative unity of knowledge and norms (assessments), which is termed bioethics. The first level is theoretical. It is connected with the facts and truths. The second level deals with establishing of certain standards and rules of conduct, with the monitoring of their implementation and the assessment of the results of implementation/violation of norms. The third level is associated with individual behavior, formed on the basis of relevant knowledge (or lack of it, as is evident from the table), and the rules governing its application. Theoretical Bioethics is an integral part of Philosophy---the practical Bioethics is directly related to Law and applied Bioethics deals with the personal standards of specific behavior in concrete situations. Social need for regulatory control of any activity with living entities has led to rapid development of practical Bioethics, while its philosophical content developed more slowly. This creates a conflict of norms and values, hampering the adoption of individual decisions now in the field of applied Bioethics. Deontologization of Bioethics can lead to the fact that it will lose its philosophical content and become a specific area of Law. This, in turn, leads to the dehumanization of Bioethics. It is therefore necessary to conduct a methodological analysis of the relationship of Philosophy, Bioethics and Law, the results of which will focus the researchers on the synchronization of the axiological, praxeological and ethical components of scientific research in order to preserve the intellectual integrity of Bioethics.展开更多
The structural evolution of the chars from pyrolysis of biomass components (cellulose, hemicellulose and lignin) in a xenon lamp radiation reactor was investigated. The elemental composition analysis showed that the...The structural evolution of the chars from pyrolysis of biomass components (cellulose, hemicellulose and lignin) in a xenon lamp radiation reactor was investigated. The elemental composition analysis showed that the C content increased at the expense of H and O contents during the chars formation. The values of AH/C/ZSO/c for the formation of cellulose and hemicellulose chars were close to 2, indicating that dehydration was the dominant reaction. Meanwhile, the value was more than 3 for lignin char formation, suggesting that the occurrence of demethoxylation was prevalent. FTIR and XRD analyses further disclosed that the cellulose pyrolysis needed to break down the stable crystal structure prior to the severe depolymerization. As for hemicellulose and lignin pyrolysis, the weak branches and linkages decomposed firstly, followed by the major decomposition. After the devolatilization at the main pyrolysis stage, the three components encountered a slow carbonization process to form condensed aromatic chars. The SEM results showed that the three components underwent different devolatilization behaviors, which induced various surface mornhologies of the chars.展开更多
Since its installation on the International Space Station(ISS)in mid-May 2011,the Alpha Magnetic Spectrometer(AMS)has spent over two years on orbit,fully operational,collecting an enormous amount of data including the...Since its installation on the International Space Station(ISS)in mid-May 2011,the Alpha Magnetic Spectrometer(AMS)has spent over two years on orbit,fully operational,collecting an enormous amount of data including the temperatures from the on-board 1118 sensors for thermal control.A large database is continuously updated and analyzed to understand the thermal behavior of the experiment in the space environment and its interaction with the ISS.This paper specifies the design,building,analysis and testing of the thermal control system and its various components for an overview of the AMS thermal control system and its space environment.Also given are some examples of analysis and correlation of the space environmental and ISS parameters with the thermal behaviors of various AMS components.展开更多
The active transmission of information from sender to receiver is a fundamental component of communication, and is therefore a primary facet in evolutionary models of sexual selection. Research in several systems has ...The active transmission of information from sender to receiver is a fundamental component of communication, and is therefore a primary facet in evolutionary models of sexual selection. Research in several systems has underlined the importance of multiple sensory modalities in courtship signals. However, we still tend to think of individuals as having a relatively static signal in consecutive communicative events. While this may be true for certain traits such as body size or coloration, behaviorally modulated signals can quickly violate this assumption. In this work, we explore how intraspecific variation may be an important component of interspecific signal divergence using cichlid fishes from Lake Malawi. Behavioral analyses were made using six species of Malawian cichlids from two divergent genera. While interspecific differences were found between congeners based on species-level analyses of both acoustic and audiovisual signals, intraspecific variation was of a similar magnitude. Specifically, individual fishes were found to possess highly plastic signal repertoires. This finding was ubiquitous across all species and resuited in a great deal of overlap between heterospecific individuals, despite statistically distinct species means. These results demonstrate that some aspects of courtship in Malawian cichlids are more plastic than previously proposed, and that studies must account for signal variability within individuals. We propose here that behavioral variability in signaling is important in determining the communication landscape on which signals are perceived. We review potential complexity deriving from multimodal signaling, discuss the sources for such lability, and suggest ways in which this issue may be approached experimentally .展开更多
Heteracalixaromatics are an emerging generation of macrocyclic host molecules in supramolecular chemistry. As a typical example of heteracalixaromatics, oxacalix[2]arene[2]triazine adopts a shape-persistent 1,3-altern...Heteracalixaromatics are an emerging generation of macrocyclic host molecules in supramolecular chemistry. As a typical example of heteracalixaromatics, oxacalix[2]arene[2]triazine adopts a shape-persistent 1,3-alternate conformation and can be easily functionalized. Taking it as a platform, a series of oxacalix[2]arene[2]triazine-based amphiphiles bearing long alkyl chains were synthesized through post-macrocyclization functionalization or 3+1 fragment coupling protocols. The self-assembly behavior of these arnphiphiles in a mixture of tetrahydrofuran (THF) and water was investigated. Dynamic light scattering (DLS) measurements revealed that the size of the self-assembled aggregates is dependent on the structure of the amphiphiles. The long alkyl chain substituents and/or interrnolecular hydrogen bonds were found to promote the self-assembly.展开更多
To understand complex state behavior, a detailed study of strategic behavior is needed. To get rid of what is out-of-date and take in fresh perspectives, we need to eliminate the current methodological bottleneck and ...To understand complex state behavior, a detailed study of strategic behavior is needed. To get rid of what is out-of-date and take in fresh perspectives, we need to eliminate the current methodological bottleneck and take full advantage of multivariate research methods to explore the complex interactions among variables and develop a basic analytical framework. First, strategic behavior should be divided into four stages, i.e., strategic assessment, strategic decision-making, strategic mobilization and strategic implementation, then the factors affecting each stage should be clarified and their interactions grasped. A preliminary framework for understanding state strategic behavior will help to promote the in-depth development of this field of research.展开更多
A self-assembled 1-dodecanethiol film assisted with the preferential adhesion of polydopamine was prepared on the non-etching 304 stainless steel surfaces by a simple dip-coating method.The formation and surface struc...A self-assembled 1-dodecanethiol film assisted with the preferential adhesion of polydopamine was prepared on the non-etching 304 stainless steel surfaces by a simple dip-coating method.The formation and surface structure of the film were characterized by water contact angle measurement,atomic force microscopy(AFM),and X-ray photoelectron spectroscopy(XPS).The corrosion behavior of the complex films was evaluated by Tafel polarization curve and electrochemical impedance spectroscopy(EIS).The excellent corrosion resistance property could be attributed to the compact hybrid film structure and superior seawater stability for modified 304 stainless steel surface.展开更多
By applying non-equilibrium Green's functions (NEGF) in combination with the density functional theory (DFT), we investigate the electronic transport properties of molecular junctions constructed by OPE derivative...By applying non-equilibrium Green's functions (NEGF) in combination with the density functional theory (DFT), we investigate the electronic transport properties of molecular junctions constructed by OPE derivatives with different side groups combined C60 molecules. The results show that the side groups play an important role in the properties of electron transport. Negative differential resistance (NDR) is observed in such devices. Especially for the molecule with electron-donating group ( OCH3), two NDR appear at different bias voltage regions. And the mechanism is proposed for the NDR behavior, owing to the shift of the molecular orbitals caused by the change in molecule charge.展开更多
文摘The pyrolysis characteristics of Shendong Shangwan coal and its macerals concentrate were investigated using thermogravimetry (TG) coupled with mass spectrometry (MS). The evolved gases were analyzed online by MS spectroscopy. The results of TG/DTG (derivative thermogravimetry) show ths vitrinite concentrate has greater weight loss rate and higher volatile yield than the other two samples. More light hydrocarbons C1-C5 are released from the vitfinite concentrate than from the Shendong Shangwan coal and inertinite concentrated in the process of pyrolysis. Three samples have similar shape curves of evolved gases of C2~C5 with different intensities. When the pyrolysis temperature was lower than 418℃, the amount of C6H6 evolved in the process of pyrolysis of inertinite concentrated was higher than that of raw coal and vitrinite concentrate. As the temperature rising, the production rate of C6H6 increased. Below 672℃, C6H6 evolution rate of vitrinite concentrate was far greater than the other two samples; the main evolution temperature range of C7H8 was 400℃ to 700℃ for the three samples. The amount of HE and H20 released first increased and then decreased with the temperature increase while more H2 released for pyrolysis of inertinite concentrated and more H20 released for the pyrolysis of vitrinite concentrate.
基金The Fundamental Research Funds for the Central Research Institute (No. 2020-9054)。
文摘The viscosity-time curve of a single-component polyurethane(PU)was examined to determine the mixing and compacting temperatures of its mixture and investigate the curing and mechanical properties of single-component PU porous elastic mixture(PPEM).The curing properties of the single-component PU and PPEM were studied with Fourier transform infrared spectroscopy(FTIR)and Marshall test.The mechanical properties of PPEM were explored via the following tests:rutting test,3-point bending test,soaked Marshall stability test,freeze-thaw splitting test,and Cantabro test.The effects of a water bath on the stability of aggregate-PU/asphalt mortar-aggregate systems were evaluated through a pull-out test and a shear test.The results show that the recommended mixing temperatures of toluene diisocyanate and methylene diphenyl diisocyanate range from 75 to 80℃and from 64 to 68℃,respectively.Room temperature(25℃)can be adopted as the compacting temperature of PPEM.PPEM can be fully cured in 4 d.Nevertheless,the water sprinkle method can obviously shorten the full curing time of PPEM.PPEM exhibites good resistance to rutting,brittle cracking,and raveling.The adhesive and shear strength of aggregate-PU/asphalt mortar-aggregate systems are negatively related to water bath duration.
基金Project(70972041)supported by the National Natural Science Foundation of ChinaProject(20100009110010)supported by the PhD Programs Foundation of Ministry of Education of ChinaProject(2011YJS246)supported by Fundamental Research Funds for the Central Universities of China
文摘Pedestrian's road-crossing model is the key part of micro-simulation for mixed traffic at signalized intersection.To reproduce the crossing behavior of pedestrians,the microscopic behaviors of the pedestrians passing through the crosswalk at signalized intersection were analyzed.A pedestrian's decision making model based on gap acceptance theory was proposed.Based on the field data at three typical intersections in Beijing,China,the critical gaps and lags of pedestrians were calibrated.In addition,considering pedestrian's required space,a modification of the social force model that consists of a self-deceleration mechanism prevents a simulated pedestrian from continuously pushing over other pedestrians,making the simulation more realistic.After the simple change,the modified social force model is able to reproduce the fundamental diagram of pedestrian flows for densities less than 3.5 m-2 as reported in the literature.
基金supported by National Natural Science Foundation of China under Grant No. 10675060
文摘The dynamical behavior in the cortical brain network of macaque is studied by modeling each cortical area with a subnetwork of interacting excitable neurons. We characterize the system by studying how to perform the transition, which is now topology-dependent, from the active state to that with no activity. This could be a naive model for the wakening and sleeping of a brain-like system, i.e., a multi-component system with two different dynamical behavior.
基金Supported by National Natural Science Foundation of China and Shanghai Baosteel Group Corporation(50174024)
文摘Investigated the effect of an addition of CaF2 on the crystallization of a glass-ceramic with abrasion resistance. X-ray diffraction, differential thermal analysis and scanning electron microscopy were used to determine the effect. The results showed that a suitable addition of CaF2 promoted crystallization by forming an interme- diate crystalline phase. CaF2 can decrease the temperature and active energy of the base-glass for crystallization. When 4 mass-% of CaF2-fraction is added in the glass, the crystallization temperature and active energy is 936 ℃and 172.75 kJ/mol respectively. When CaF2 is increased to 6 mass-%, the temperature and active energy decrease to 890 ℃ and 88.81 kJ/mol. CaF2 is an efficient nucleating agent for the glass-ceramics with abrasion resistant, the optimal content of CaF2 is about 6 mass-%.
文摘One can distinguish three levels in the integrative unity of knowledge and norms (assessments), which is termed bioethics. The first level is theoretical. It is connected with the facts and truths. The second level deals with establishing of certain standards and rules of conduct, with the monitoring of their implementation and the assessment of the results of implementation/violation of norms. The third level is associated with individual behavior, formed on the basis of relevant knowledge (or lack of it, as is evident from the table), and the rules governing its application. Theoretical Bioethics is an integral part of Philosophy---the practical Bioethics is directly related to Law and applied Bioethics deals with the personal standards of specific behavior in concrete situations. Social need for regulatory control of any activity with living entities has led to rapid development of practical Bioethics, while its philosophical content developed more slowly. This creates a conflict of norms and values, hampering the adoption of individual decisions now in the field of applied Bioethics. Deontologization of Bioethics can lead to the fact that it will lose its philosophical content and become a specific area of Law. This, in turn, leads to the dehumanization of Bioethics. It is therefore necessary to conduct a methodological analysis of the relationship of Philosophy, Bioethics and Law, the results of which will focus the researchers on the synchronization of the axiological, praxeological and ethical components of scientific research in order to preserve the intellectual integrity of Bioethics.
基金Supported by the National Natural Science Foundation of China(51276166)the National Basic Research Program of China(2013CB228101)the National Science and Technology Supporting Plan Through Contract(2015BAD15B06)
文摘The structural evolution of the chars from pyrolysis of biomass components (cellulose, hemicellulose and lignin) in a xenon lamp radiation reactor was investigated. The elemental composition analysis showed that the C content increased at the expense of H and O contents during the chars formation. The values of AH/C/ZSO/c for the formation of cellulose and hemicellulose chars were close to 2, indicating that dehydration was the dominant reaction. Meanwhile, the value was more than 3 for lignin char formation, suggesting that the occurrence of demethoxylation was prevalent. FTIR and XRD analyses further disclosed that the cellulose pyrolysis needed to break down the stable crystal structure prior to the severe depolymerization. As for hemicellulose and lignin pyrolysis, the weak branches and linkages decomposed firstly, followed by the major decomposition. After the devolatilization at the main pyrolysis stage, the three components encountered a slow carbonization process to form condensed aromatic chars. The SEM results showed that the three components underwent different devolatilization behaviors, which induced various surface mornhologies of the chars.
文摘Since its installation on the International Space Station(ISS)in mid-May 2011,the Alpha Magnetic Spectrometer(AMS)has spent over two years on orbit,fully operational,collecting an enormous amount of data including the temperatures from the on-board 1118 sensors for thermal control.A large database is continuously updated and analyzed to understand the thermal behavior of the experiment in the space environment and its interaction with the ISS.This paper specifies the design,building,analysis and testing of the thermal control system and its various components for an overview of the AMS thermal control system and its space environment.Also given are some examples of analysis and correlation of the space environmental and ISS parameters with the thermal behaviors of various AMS components.
文摘The active transmission of information from sender to receiver is a fundamental component of communication, and is therefore a primary facet in evolutionary models of sexual selection. Research in several systems has underlined the importance of multiple sensory modalities in courtship signals. However, we still tend to think of individuals as having a relatively static signal in consecutive communicative events. While this may be true for certain traits such as body size or coloration, behaviorally modulated signals can quickly violate this assumption. In this work, we explore how intraspecific variation may be an important component of interspecific signal divergence using cichlid fishes from Lake Malawi. Behavioral analyses were made using six species of Malawian cichlids from two divergent genera. While interspecific differences were found between congeners based on species-level analyses of both acoustic and audiovisual signals, intraspecific variation was of a similar magnitude. Specifically, individual fishes were found to possess highly plastic signal repertoires. This finding was ubiquitous across all species and resuited in a great deal of overlap between heterospecific individuals, despite statistically distinct species means. These results demonstrate that some aspects of courtship in Malawian cichlids are more plastic than previously proposed, and that studies must account for signal variability within individuals. We propose here that behavioral variability in signaling is important in determining the communication landscape on which signals are perceived. We review potential complexity deriving from multimodal signaling, discuss the sources for such lability, and suggest ways in which this issue may be approached experimentally .
基金supported by the National Natural Science Foundation of China(21272239,91427301,21521002)Ministry of Science and Technology(2013CB834504)
文摘Heteracalixaromatics are an emerging generation of macrocyclic host molecules in supramolecular chemistry. As a typical example of heteracalixaromatics, oxacalix[2]arene[2]triazine adopts a shape-persistent 1,3-alternate conformation and can be easily functionalized. Taking it as a platform, a series of oxacalix[2]arene[2]triazine-based amphiphiles bearing long alkyl chains were synthesized through post-macrocyclization functionalization or 3+1 fragment coupling protocols. The self-assembly behavior of these arnphiphiles in a mixture of tetrahydrofuran (THF) and water was investigated. Dynamic light scattering (DLS) measurements revealed that the size of the self-assembled aggregates is dependent on the structure of the amphiphiles. The long alkyl chain substituents and/or interrnolecular hydrogen bonds were found to promote the self-assembly.
基金support from the National Social Science Foundation Project "Research on the Analytical Framework and Instruments of International Strategic Studies"(No.:12BZZ053)the Ministry of Education Key Institute of the Humanities and Social Sciences(Center of American Studies,Fudan University) Major Project "Strategic Behavior in History:A Comparison between the U.S.and Other Countries"(No.:11JJD810017)
文摘To understand complex state behavior, a detailed study of strategic behavior is needed. To get rid of what is out-of-date and take in fresh perspectives, we need to eliminate the current methodological bottleneck and take full advantage of multivariate research methods to explore the complex interactions among variables and develop a basic analytical framework. First, strategic behavior should be divided into four stages, i.e., strategic assessment, strategic decision-making, strategic mobilization and strategic implementation, then the factors affecting each stage should be clarified and their interactions grasped. A preliminary framework for understanding state strategic behavior will help to promote the in-depth development of this field of research.
基金supported by the National Natural Science Foundation of China (Grant No. 51072188)the Natural Science Foundation of Shandong Province (Grant No. Y2008B46)
文摘A self-assembled 1-dodecanethiol film assisted with the preferential adhesion of polydopamine was prepared on the non-etching 304 stainless steel surfaces by a simple dip-coating method.The formation and surface structure of the film were characterized by water contact angle measurement,atomic force microscopy(AFM),and X-ray photoelectron spectroscopy(XPS).The corrosion behavior of the complex films was evaluated by Tafel polarization curve and electrochemical impedance spectroscopy(EIS).The excellent corrosion resistance property could be attributed to the compact hybrid film structure and superior seawater stability for modified 304 stainless steel surface.
基金supported by the Independent Innovative Natural Science Foundation of Shandong University (Grant No. 2009TS097)the Natural Science Foundation of Shandong Province of China (Grant Nos. ZR2009-AL004 and ZR2010AM037)
文摘By applying non-equilibrium Green's functions (NEGF) in combination with the density functional theory (DFT), we investigate the electronic transport properties of molecular junctions constructed by OPE derivatives with different side groups combined C60 molecules. The results show that the side groups play an important role in the properties of electron transport. Negative differential resistance (NDR) is observed in such devices. Especially for the molecule with electron-donating group ( OCH3), two NDR appear at different bias voltage regions. And the mechanism is proposed for the NDR behavior, owing to the shift of the molecular orbitals caused by the change in molecule charge.