The process of thermal degradation of sulphonated polyetherketoneketone (SPEKK) was studied by the thermogravimetry (TG) and differential thermal gravinetric analysis (DTG).There were two weight loss steps in TG for S...The process of thermal degradation of sulphonated polyetherketoneketone (SPEKK) was studied by the thermogravimetry (TG) and differential thermal gravinetric analysis (DTG).There were two weight loss steps in TG for SPEKK.The first one was the -SO 3H aparts from the main chain of SPEKK,the activation energy was found to be 67.44kJ/mol.The second,was the polymer main chain degradated of which the activation energy was about 210.4kJ/mol.The thermal degradation of SPEKK was in agreement with the models of random initation.展开更多
随着科技的发展,我国的交通运输水平已处于世界前列,特别是轨道车辆的发展,为我国人员流通、物资运输和经济的发展作出重大贡献。轨道交通列车运行过程中,车辆内部运行控制信号及电力的输送保障至关重要。在轨道交通列车上使用的薄壁控...随着科技的发展,我国的交通运输水平已处于世界前列,特别是轨道车辆的发展,为我国人员流通、物资运输和经济的发展作出重大贡献。轨道交通列车运行过程中,车辆内部运行控制信号及电力的输送保障至关重要。在轨道交通列车上使用的薄壁控制电缆的外层护套绝缘材料种类中,有一种为乙烯-醋酸乙烯共聚物(EVA),该材料在酸性、潮湿等恶劣条件下易发生黄变、开裂、鼓包等现象,从而影响电缆的剩余寿命,使得电缆出现传输异常,影响列车正常运行,严重时可能出现短路发生火灾造成重大事故及人员伤亡。为对轨道车辆用乙烯-醋酸乙烯共聚物(EVA)电缆的剩余寿命进行快速评估,文章采用热重分析法(TGA)研究了不同老化程度的EVA绝缘材料的热分解特性,计算出了其对应的热分解活化能。在此基础上,参照ASTM E 1877-00:2021标准中的方法建立了EVA绝缘材料的热寿命方程。研究结果表明:热分解特性能够用来评估轨道车辆用EVA电缆的实际老化情况,结合建立的热寿命方程能完成电缆使用状况的快速评估,与传统评估方法相比,该方法操作更加简单。展开更多
文摘The process of thermal degradation of sulphonated polyetherketoneketone (SPEKK) was studied by the thermogravimetry (TG) and differential thermal gravinetric analysis (DTG).There were two weight loss steps in TG for SPEKK.The first one was the -SO 3H aparts from the main chain of SPEKK,the activation energy was found to be 67.44kJ/mol.The second,was the polymer main chain degradated of which the activation energy was about 210.4kJ/mol.The thermal degradation of SPEKK was in agreement with the models of random initation.
文摘随着科技的发展,我国的交通运输水平已处于世界前列,特别是轨道车辆的发展,为我国人员流通、物资运输和经济的发展作出重大贡献。轨道交通列车运行过程中,车辆内部运行控制信号及电力的输送保障至关重要。在轨道交通列车上使用的薄壁控制电缆的外层护套绝缘材料种类中,有一种为乙烯-醋酸乙烯共聚物(EVA),该材料在酸性、潮湿等恶劣条件下易发生黄变、开裂、鼓包等现象,从而影响电缆的剩余寿命,使得电缆出现传输异常,影响列车正常运行,严重时可能出现短路发生火灾造成重大事故及人员伤亡。为对轨道车辆用乙烯-醋酸乙烯共聚物(EVA)电缆的剩余寿命进行快速评估,文章采用热重分析法(TGA)研究了不同老化程度的EVA绝缘材料的热分解特性,计算出了其对应的热分解活化能。在此基础上,参照ASTM E 1877-00:2021标准中的方法建立了EVA绝缘材料的热寿命方程。研究结果表明:热分解特性能够用来评估轨道车辆用EVA电缆的实际老化情况,结合建立的热寿命方程能完成电缆使用状况的快速评估,与传统评估方法相比,该方法操作更加简单。
