针对五轴石材切板机床的圆形锯片安装中心相对于机床控制点存在偏置以及锯片本身尺寸导致过切的问题,对切削点相对于控制点的空间位姿关系进行了分析,对加工图元为直线时的各种工况进行了详尽研究,提出了一种基于美国3S开放式系统(Servo...针对五轴石材切板机床的圆形锯片安装中心相对于机床控制点存在偏置以及锯片本身尺寸导致过切的问题,对切削点相对于控制点的空间位姿关系进行了分析,对加工图元为直线时的各种工况进行了详尽研究,提出了一种基于美国3S开放式系统(Servo Works S-140M)的偏置补偿算法,建立了刀位轨迹与数控轨迹之间的联系。通过系统仿真功能验证了该算法的正确性,并通过实际加工进行了测试。研究结果表明,所加工出的零件能满足加工工艺和精度要求,提高了加工效率和加工精度,降低了生产成本。展开更多
Anthracene-based cylindrical macrotricyclic polyether (1) containing two dibenzo-30-crown-10 cavities has been proved to be an efficient host for the templated complexation with N,N'-dipropyl-1,4,5,8-naphthalenete...Anthracene-based cylindrical macrotricyclic polyether (1) containing two dibenzo-30-crown-10 cavities has been proved to be an efficient host for the templated complexation with N,N'-dipropyl-1,4,5,8-naphthalenetetracarboxylic diimide in the presence of lithium ions in both solution and solid state. Host 1 could also form 1:1 complex with the bispyridinium salt with two β-hydroxyethyl groups in solution and in the solid state. Moreover, it was also found that the switchable complexation processes between the macrotricyclic host and two different kinds of guests could be chemically controlled by the addition and removal of lithium ions.展开更多
The ultrathin polyelectrolyte molecular deposition films and polyelectrolyte composite nanoparticles molecular deposition films were prepared using layer-by-layer molecular deposition method and in situ growth method....The ultrathin polyelectrolyte molecular deposition films and polyelectrolyte composite nanoparticles molecular deposition films were prepared using layer-by-layer molecular deposition method and in situ growth method.A micro-tribometer has been developed to measure the shear response of those ultrathin molecular deposition films.By using a smooth steel sphere in a ball-on-flat configuration,the shear force was determined for molecular deposition films on glass substrate for different layers.The results indicate that the shear behaviors of molecular deposition film were mainly determined with the contact area and film layers.Moreover,the composite molecular deposition film with nanoparticles has better shear behaviors than the polyelectrolyte molecular deposition film.The shear force of polyelectrolyte molecular deposition film is more dependent on the speed than that of composite nanoparticle molecular deposition film.展开更多
文摘针对五轴石材切板机床的圆形锯片安装中心相对于机床控制点存在偏置以及锯片本身尺寸导致过切的问题,对切削点相对于控制点的空间位姿关系进行了分析,对加工图元为直线时的各种工况进行了详尽研究,提出了一种基于美国3S开放式系统(Servo Works S-140M)的偏置补偿算法,建立了刀位轨迹与数控轨迹之间的联系。通过系统仿真功能验证了该算法的正确性,并通过实际加工进行了测试。研究结果表明,所加工出的零件能满足加工工艺和精度要求,提高了加工效率和加工精度,降低了生产成本。
基金supported by the National Natural Science Foundation of China (91127009, 20972162)the National Basic Research Program of China (2011CB932501)
文摘Anthracene-based cylindrical macrotricyclic polyether (1) containing two dibenzo-30-crown-10 cavities has been proved to be an efficient host for the templated complexation with N,N'-dipropyl-1,4,5,8-naphthalenetetracarboxylic diimide in the presence of lithium ions in both solution and solid state. Host 1 could also form 1:1 complex with the bispyridinium salt with two β-hydroxyethyl groups in solution and in the solid state. Moreover, it was also found that the switchable complexation processes between the macrotricyclic host and two different kinds of guests could be chemically controlled by the addition and removal of lithium ions.
基金supported by the National Natural Science Foundation of China (Grant No. 50975288)the National Basic Research Program of China ("973" Program) (Grant No. 2007CB607604)
文摘The ultrathin polyelectrolyte molecular deposition films and polyelectrolyte composite nanoparticles molecular deposition films were prepared using layer-by-layer molecular deposition method and in situ growth method.A micro-tribometer has been developed to measure the shear response of those ultrathin molecular deposition films.By using a smooth steel sphere in a ball-on-flat configuration,the shear force was determined for molecular deposition films on glass substrate for different layers.The results indicate that the shear behaviors of molecular deposition film were mainly determined with the contact area and film layers.Moreover,the composite molecular deposition film with nanoparticles has better shear behaviors than the polyelectrolyte molecular deposition film.The shear force of polyelectrolyte molecular deposition film is more dependent on the speed than that of composite nanoparticle molecular deposition film.
