Aluminum （AI）, Vanadium （V）, Chromium （Cr）, Manganese （Mn）, Iron （Fe）, Strontium （Sr）, Molybdenum （Mo）, Silver （Ag）, Cadmium （Cd）, Tin （Sn）, Caesium （Cs）, Barium （Ba）, Lead （Pb）, Bismuth （Bi...Aluminum （AI）, Vanadium （V）, Chromium （Cr）, Manganese （Mn）, Iron （Fe）, Strontium （Sr）, Molybdenum （Mo）, Silver （Ag）, Cadmium （Cd）, Tin （Sn）, Caesium （Cs）, Barium （Ba）, Lead （Pb）, Bismuth （Bi） and Uranium （U） concentrations were investigated in water samples from fifteen sampling locations in Naviundu river basin, Luano and Ruashi rivers and Luwowoshi spring in Lubumbashi city during February, March and April 2016. Chemical analyses of the samples were carried out using Inductively Coupled Plasma-Mass Spectrometer. Water pH was determined using a pH-meter and mean pH values ranged from 4.2 to 5.8. The highest mean levels of Al （5,961.954 μg·L^-1）, Pb （472.287 μg·L^-1）, V （21.014 μg·L^-1）, Cr （8.185μg·L^-1）, U （4.163μg·L^-1） and Bi （0.012 μg·L^-1） were recorded in Chemaf （Chemicals of Africa） hydrometallurgical plant effluent, those of Mn （29,714.593 μg·L^-1）, Sr （374.377μg·L^-1）, Cd （11.358μg·L^-1） and Cs （0.107μg·L^-1） in Naviundu river at Cimenkat （Katanga＇s Cement Factory） exit, those of Fe （14,258.9 μg·L^-1） and Ba （307.641μg·L^-1） in Luano river and those of Ag （2.669 μg·L^-1）, Mo （0.559 μg·L^-1） and Sn （0.325 μg·L^-1） were respectively noted in Foire channel, Naviundu river under bridge on Kasenga road and Kalulako river. The concentrations of Cd in Naviundu river at Cimenkat exit （11.358 μg·L^-1）, Chemaf bydrometallurgical plant effluent （9.697μg·L^-1）, Naviundu river under bridge on De Plaines Avenue （6.95 μg·L^-1） and Kalulako river （3.229 μg·L^-1）, Pb concentrations in Chemaf hydrometallurgical plant effluent （472.287 μg·L^-1） as well as the AI, Fe and Mn concentrations recorded in most waters in this study exceeded the WHO （World Health Organization） maximum permissible limits for drinking water. The metal contamination of waters of the studied rivers, channel and spring might be partially attributed to natural processes, unplanned urbanization and poor waste management, and mostly to abandoned and ongoing mining and ore processing activities in Lubumbashi city.展开更多
Arsenic （As）, Barium （Ba）, Cadmium （Cd）, Cobalt （Co）, Chromium （Cr）, Copper （Cu）, Iron （Fe）, Manganese （Mn）, Lead （Pb） and Zinc （Zn） concentrations were investigated in sediments collected from six...Arsenic （As）, Barium （Ba）, Cadmium （Cd）, Cobalt （Co）, Chromium （Cr）, Copper （Cu）, Iron （Fe）, Manganese （Mn）, Lead （Pb） and Zinc （Zn） concentrations were investigated in sediments collected from sixteen sampling sites in the Lubumbashi river basin and five sites in Kafubu, Kimilolo and Kinkalabwamba rivers during February, March and April 2016. Analyses of the samples were carried out using a portable X-RFS （X-Ray Fluorescence Spectrometer）. Water pH and OM （Organic Matter） content of the sediments were also determined. Trace metal toxicity risk to aquatic organisms was assessed using SQGs （Sediment Quality Guidelines）---TELs （Threshold Effect Levels） and PELs （Probable Effect Levels）---for freshwater sediments. Mean values ofpH and OM ranged from 4.2 to 7.8 and from 1.27% to 6.22%, respectively. The highest mean levels of trace metals in sediments were 5,438 mg·kg-1·dw and 902.5 mg·kg-1·dw for Cu and Co, respectively in Lubumbashi river 1.45 kilometer downward the Lubumbashi Slag heap, 1,534.5 mg·kg-1·dw and 342 mg·kg-1·dwdw for Zn and Pb, respectively at the confluence of Lubumbashi and Kafubu rivers, 108,900 mg·kg-1·dw, 547 mg·kg-1·dw and 174.5 mg·kg-1·dw for Fe, Ba and Cr, respectively in Kinkalabwamba river, 531 mg·kg-1·dw and 22 mg-kgl＇dw for Mn and Cd, respectively in Kimilolo river, and 37 mg·kg-1·dw for As at the confluence of Tshondo and Lubumbashi rivers. The mean concentrations of As, Cd, Cr, Cu, Pb and Zn in the sediments exceeded the corresponding SQGs＇ PELvalues and could have adverse effects on aquatic organisms of those rivers. Trace metal contamination of the studied sediments might he partially attributed to natural processes, unplanned urbanization and poor waste management and mostly to abandoned and ongoing mining and ore processing activities in Lubumbashi city.展开更多
Concentrations of fifteen trace metals including Aluminum （Al）, Vanadium （V）, Chromium （Cr）, Manganese （Mn）, Iron （Fe）, Strontium （Sr）, Molybdenum （Mo）, Silver （Ag）, Cadmium （Cd）, Tin （Sn）, Caesium...Concentrations of fifteen trace metals including Aluminum （Al）, Vanadium （V）, Chromium （Cr）, Manganese （Mn）, Iron （Fe）, Strontium （Sr）, Molybdenum （Mo）, Silver （Ag）, Cadmium （Cd）, Tin （Sn）, Caesium （Cs）, Barium （Ba）, Lead （Pb）, Bismuth （Bi） and Uranium （U） were investigated in water samples collected from sixteen sampling locations in the Lubumbashi river basin and five locations in Kafubu, Kimilolo and Kinkalabwamba rivers during February, March and April 2016. Chemical analyses of the samples were carried out using ICP-MS （Inductively Coupled Plasma-Mass Spectrometer）. Water pH was determined using a pH-meter and pH values ranged from 4.2 to 7.8. The highest mean trace metal levels of water were 5,515.816 ）μg·L^-1, 166.925μg·L^-1, 3.898μg·L^-1 and 1.879μg·L^-1 for Al, Ba, Cr and U, respectively in Kashobwe river, 2,419.522 μg·L^-1 and 17.994 μg·L^-1 for Fe and Cd, respectively in Kafubu river at its confluence with Lubumbashi rivers, 1,408.136μg·L^-1 for Mn in Kafubu river 1.36 kilometer downward its confluence with Naviundu river, 222.406 μg·L^-1 and 0.092 μg·L^-1 for Sr and Cs, respectively in Kamalondo river 60 meters from the GCM-Lubumbashi （General of Quarries and Mines-Lubumbashi） smelter, 140.294μg·L^-1, 12.063 μg·L^-1 and 0.008μg·L^-1 for Pb, V and Bi, respectively in Munua river, 3.544 μg·L^-1 for Ag in Kabulameshi river, 1.49 μg·L^-1 for Mo in Kafubu river and 0.081μg·L^-1 for Sn in Tshondo river. The mean concentrations of Al, Cd, Fe, Mn and Pb in water of many rivers and the channel exceeded the maximum admissible limits of the WHO （World Health Organization）, USEPA （United States Environmental Protection Agency） and EU （European Union） drinking-water standards. Trace metal contamination of water of the studied rivers, channel and springs might be partially attributed to natural processes, unplanned urbanization, poor waste management and mostly to abandoned and ongoing mining and ore processing activities in Lubumbashi city.展开更多
文摘Aluminum （AI）, Vanadium （V）, Chromium （Cr）, Manganese （Mn）, Iron （Fe）, Strontium （Sr）, Molybdenum （Mo）, Silver （Ag）, Cadmium （Cd）, Tin （Sn）, Caesium （Cs）, Barium （Ba）, Lead （Pb）, Bismuth （Bi） and Uranium （U） concentrations were investigated in water samples from fifteen sampling locations in Naviundu river basin, Luano and Ruashi rivers and Luwowoshi spring in Lubumbashi city during February, March and April 2016. Chemical analyses of the samples were carried out using Inductively Coupled Plasma-Mass Spectrometer. Water pH was determined using a pH-meter and mean pH values ranged from 4.2 to 5.8. The highest mean levels of Al （5,961.954 μg·L^-1）, Pb （472.287 μg·L^-1）, V （21.014 μg·L^-1）, Cr （8.185μg·L^-1）, U （4.163μg·L^-1） and Bi （0.012 μg·L^-1） were recorded in Chemaf （Chemicals of Africa） hydrometallurgical plant effluent, those of Mn （29,714.593 μg·L^-1）, Sr （374.377μg·L^-1）, Cd （11.358μg·L^-1） and Cs （0.107μg·L^-1） in Naviundu river at Cimenkat （Katanga＇s Cement Factory） exit, those of Fe （14,258.9 μg·L^-1） and Ba （307.641μg·L^-1） in Luano river and those of Ag （2.669 μg·L^-1）, Mo （0.559 μg·L^-1） and Sn （0.325 μg·L^-1） were respectively noted in Foire channel, Naviundu river under bridge on Kasenga road and Kalulako river. The concentrations of Cd in Naviundu river at Cimenkat exit （11.358 μg·L^-1）, Chemaf bydrometallurgical plant effluent （9.697μg·L^-1）, Naviundu river under bridge on De Plaines Avenue （6.95 μg·L^-1） and Kalulako river （3.229 μg·L^-1）, Pb concentrations in Chemaf hydrometallurgical plant effluent （472.287 μg·L^-1） as well as the AI, Fe and Mn concentrations recorded in most waters in this study exceeded the WHO （World Health Organization） maximum permissible limits for drinking water. The metal contamination of waters of the studied rivers, channel and spring might be partially attributed to natural processes, unplanned urbanization and poor waste management, and mostly to abandoned and ongoing mining and ore processing activities in Lubumbashi city.
文摘Arsenic （As）, Barium （Ba）, Cadmium （Cd）, Cobalt （Co）, Chromium （Cr）, Copper （Cu）, Iron （Fe）, Manganese （Mn）, Lead （Pb） and Zinc （Zn） concentrations were investigated in sediments collected from sixteen sampling sites in the Lubumbashi river basin and five sites in Kafubu, Kimilolo and Kinkalabwamba rivers during February, March and April 2016. Analyses of the samples were carried out using a portable X-RFS （X-Ray Fluorescence Spectrometer）. Water pH and OM （Organic Matter） content of the sediments were also determined. Trace metal toxicity risk to aquatic organisms was assessed using SQGs （Sediment Quality Guidelines）---TELs （Threshold Effect Levels） and PELs （Probable Effect Levels）---for freshwater sediments. Mean values ofpH and OM ranged from 4.2 to 7.8 and from 1.27% to 6.22%, respectively. The highest mean levels of trace metals in sediments were 5,438 mg·kg-1·dw and 902.5 mg·kg-1·dw for Cu and Co, respectively in Lubumbashi river 1.45 kilometer downward the Lubumbashi Slag heap, 1,534.5 mg·kg-1·dw and 342 mg·kg-1·dwdw for Zn and Pb, respectively at the confluence of Lubumbashi and Kafubu rivers, 108,900 mg·kg-1·dw, 547 mg·kg-1·dw and 174.5 mg·kg-1·dw for Fe, Ba and Cr, respectively in Kinkalabwamba river, 531 mg·kg-1·dw and 22 mg-kgl＇dw for Mn and Cd, respectively in Kimilolo river, and 37 mg·kg-1·dw for As at the confluence of Tshondo and Lubumbashi rivers. The mean concentrations of As, Cd, Cr, Cu, Pb and Zn in the sediments exceeded the corresponding SQGs＇ PELvalues and could have adverse effects on aquatic organisms of those rivers. Trace metal contamination of the studied sediments might he partially attributed to natural processes, unplanned urbanization and poor waste management and mostly to abandoned and ongoing mining and ore processing activities in Lubumbashi city.
文摘Concentrations of fifteen trace metals including Aluminum （Al）, Vanadium （V）, Chromium （Cr）, Manganese （Mn）, Iron （Fe）, Strontium （Sr）, Molybdenum （Mo）, Silver （Ag）, Cadmium （Cd）, Tin （Sn）, Caesium （Cs）, Barium （Ba）, Lead （Pb）, Bismuth （Bi） and Uranium （U） were investigated in water samples collected from sixteen sampling locations in the Lubumbashi river basin and five locations in Kafubu, Kimilolo and Kinkalabwamba rivers during February, March and April 2016. Chemical analyses of the samples were carried out using ICP-MS （Inductively Coupled Plasma-Mass Spectrometer）. Water pH was determined using a pH-meter and pH values ranged from 4.2 to 7.8. The highest mean trace metal levels of water were 5,515.816 ）μg·L^-1, 166.925μg·L^-1, 3.898μg·L^-1 and 1.879μg·L^-1 for Al, Ba, Cr and U, respectively in Kashobwe river, 2,419.522 μg·L^-1 and 17.994 μg·L^-1 for Fe and Cd, respectively in Kafubu river at its confluence with Lubumbashi rivers, 1,408.136μg·L^-1 for Mn in Kafubu river 1.36 kilometer downward its confluence with Naviundu river, 222.406 μg·L^-1 and 0.092 μg·L^-1 for Sr and Cs, respectively in Kamalondo river 60 meters from the GCM-Lubumbashi （General of Quarries and Mines-Lubumbashi） smelter, 140.294μg·L^-1, 12.063 μg·L^-1 and 0.008μg·L^-1 for Pb, V and Bi, respectively in Munua river, 3.544 μg·L^-1 for Ag in Kabulameshi river, 1.49 μg·L^-1 for Mo in Kafubu river and 0.081μg·L^-1 for Sn in Tshondo river. The mean concentrations of Al, Cd, Fe, Mn and Pb in water of many rivers and the channel exceeded the maximum admissible limits of the WHO （World Health Organization）, USEPA （United States Environmental Protection Agency） and EU （European Union） drinking-water standards. Trace metal contamination of water of the studied rivers, channel and springs might be partially attributed to natural processes, unplanned urbanization, poor waste management and mostly to abandoned and ongoing mining and ore processing activities in Lubumbashi city.
