A support vector machine with guadratic polynomial kernel function based nonlinear model multi-step-ahead optimizing predictive controller was presented. A support vector machine based predictive model was established...A support vector machine with guadratic polynomial kernel function based nonlinear model multi-step-ahead optimizing predictive controller was presented. A support vector machine based predictive model was established by black-box identification. And a quadratic objective function with receding horizon was selected to obtain the controller output. By solving a nonlinear optimization problem with equality constraint of model output and boundary constraint of controller output using Nelder-Mead simplex direct search method, a sub-optimal control law was achieved in feature space. The effect of the controller was demonstrated on a recognized benchmark problem and a continuous-stirred tank reactor. The simulation results show that the multi-step-ahead predictive controller can be well applied to nonlinear system, with better performance in following reference trajectory and disturbance-rejection.展开更多
In order to find a feasible way to control excavator’s arm and realize autonomous excavation, the dynamic model for the boom of excavator’s arm which was regarded as a planar manipulator with three degrees of freedo...In order to find a feasible way to control excavator’s arm and realize autonomous excavation, the dynamic model for the boom of excavator’s arm which was regarded as a planar manipulator with three degrees of freedom was constructed with Lagrange equation. The excavator was retrofitted with electrohydraulic proportional valves, associated sensors (three inclinometers) and a computer control system (the motion controller of EPEC). The full nonlinear mathematic model of electrohydraulic proportional system was achieved. A discontinuous projection based on an adaptive robust controller to approximate the nonlinear gain coefficient of the valve was presented to deal with the nonlinearity of the whole system, the error was dealt with by robust feedback and an adaptive robust controller was designed. The experiment results of the boom motion control show that, using the controller, good performance for tracking can be achieved, and the peak tracking error of boom angles is less than 4°.展开更多
An experimental method is introduced in this paper to build the dynamics of AMSS (the active magnetic suspension system), which doesn’t depend on system’s physical parameters. The rotor can be reliably suspended und...An experimental method is introduced in this paper to build the dynamics of AMSS (the active magnetic suspension system), which doesn’t depend on system’s physical parameters. The rotor can be reliably suspended under the unit feedback control system designed with the primary dynamic model obtained. Online identification in frequency domain is processed to give the precise model. Comparisons show that the experimental method is much closer to the precise model than the theoretic method based on magnetic circuit law. So this experimental method is a good choice to build the primary dynamic model of AMSS.展开更多
A numerical model is presented to investigate the performance of homogeneous charge compression ignition(HCCI) engines fueled with ethanol. Two approaches are studied. On one hand, two-step reaction mechanisms with Ar...A numerical model is presented to investigate the performance of homogeneous charge compression ignition(HCCI) engines fueled with ethanol. Two approaches are studied. On one hand, two-step reaction mechanisms with Arrhenius reaction rates are implemented in combustion chemistry modeling. On the other hand, a reduced mechanism containing important reactions of ethanol involving heat release rate and reaction rates compatible with experimental data is employed. Since controls of combustion phenomenon and ignition timing are the main issues of these engines, the effects of inlet temperature and equivalence ratio as the controlling factors on the operating parameters such as ignition timing, burn duration, in-cylinder temperature and pressure of HCCI engines are explored. The results show that the maximum predicted pressures for thermodynamic model are about 71.3×10~5 Pa and 79.79×10~5 Pa, and for chemical kinetic model, they are about 71.48×10~5 Pa and 78.123×10~5 Pa, fairly comparable with corresponding experimental values of 72×10~5 Pa and 78.7×10~5 Pa. It is observed that increasing the initial temperature advances the ignition timing, decreases the burn duration and increases the peak temperature and pressure. Moreover, the maximum temperature and pressure are associated with richer mixtures.展开更多
Objective: To provide a kinetic model(s) and reveal the mechanism of thymoquinone and Poloxin blocking an emerging anti-cancer target, human Polo-like kinase 1 (hPlkl) Polo-box domain (PBD). Methods: The bindi...Objective: To provide a kinetic model(s) and reveal the mechanism of thymoquinone and Poloxin blocking an emerging anti-cancer target, human Polo-like kinase 1 (hPlkl) Polo-box domain (PBD). Methods: The binding kinetics was determined by using a fluorescence polarization based assay. The putative mechanism was examined with a competition test. Results: Thymoquinone follows a one-step binding with an association rate constant (k1) of 6.635× 10^3 L.mol^-1 min^-1.Poloxin fit a two-step binding with a dissociation constant (Ki) of 118 μmol/L for the intermediate complex and its isomerization rate (k4) of 0.131 5 minJ to form an irreversible adduct. No significant dissociation was observed for either ligand up to 13 h. The inhibitors responded insignificantly to the presence of Michael donors as hPIkl-PBD competitors. Conclusion: Thymoquinone and Poloxin are slow-tight ligands to the hPlkl-PBD with kinetic models distinct from each other. Michael addition as the mechanism is excluded.展开更多
Nonlinear dynamic inversion(NDI)has been applied to the control law design of quad-rotors mainly thanks to its good robustness and simplicity of parameter tuning.However,the weakness of relying on accurate model great...Nonlinear dynamic inversion(NDI)has been applied to the control law design of quad-rotors mainly thanks to its good robustness and simplicity of parameter tuning.However,the weakness of relying on accurate model greatly restrains its application on quad-rotors,especially nano quad-rotors(NQRs).NQRs are easy to be influenced by uncertainties such as model uncertainties(mainly from complicated aerodynamic interferences,strong coupling in roll-pitch-yaw channels and inaccurate aerodynamic prediction of rotors)and external uncertainties(mainly from winds or gusts),particularly persistent ones.Therefore,developing accurate model for altitude and attitude control of NQRs is difficult.To solve this problem,in this paper,an improved nonlinear dynamic inversion(INDI)method is developed,which can reject the above-mentioned uncertainties by estimating them and then counteracting in real time using linear extended state observer(LESO).Comparison with the traditional NDI(TNDI)method was carried out numerically,and the results show that,in coping with persistent uncertainties,the INDI-based method presents significant superiority.展开更多
The kinetics of casein tryptic hydrolysis to prepare activepeptides was investigated. Taking into account the reaction mechanismincluding single substrate hydrolysis, irreversible enzymeinactivation, and substrate inh...The kinetics of casein tryptic hydrolysis to prepare activepeptides was investigated. Taking into account the reaction mechanismincluding single substrate hydrolysis, irreversible enzymeinactivation, and substrate inhibition, a set of exponentialequations was established to characterize the enzymatic hydrolysiscurves. The verification was carried out by a series of experimentalresults and indicated that the average regressive error was less than5/100. According to the proposed kinetic model, the kinetic constantsand thermodynamic constants of the reaction system were alsocalculated.展开更多
The flow past a primary cylinder with one tandem control rod and one staggered control rod is simulated in this paper through solving the Navier-Stokes equations. Two examples are simulated to validate the model, and ...The flow past a primary cylinder with one tandem control rod and one staggered control rod is simulated in this paper through solving the Navier-Stokes equations. Two examples are simulated to validate the model, and the results matched well with those of previous researches. The Reynolds number based on the diameter of the primary cylinder is 500. The diameter ratio between the control rod and the primary cylinder (d/D) is 0.25. It was found that the effect of the combination of one upstream tandem control rod and one staggered control rod on the hydrodynamics of the primary cylinder is a linear superposition of the effect of a corresponding single control rod, and the effect of the upstream tandem control rod is dominant at larger spacing ratios such as G/D=2. For the combination of a downstream tandem control rod and a staggered control rod, the effect of the control rods is different from that of the corresponding single control rod in the region of 0.2〈G/D〈0.5 & 30°〈a〈120° and 0.9〈G/D〈1.4 & 30°〈a〈50°, where the additional effect is obvious. In this case, the effect of the downstream tandem control rod is dominant at small spacing ratios (such as G/D=0.1). At moderate spacing ratios such as G/D=0.4, the effects of the tandem control rod and the staggered control rod are comparable in both cases.展开更多
When mining metal mines with steep structure planes by the caving method,there is a mechanical model in which the horizontal stress on the rock mass is simplified as a column before surface subsidence.The model is use...When mining metal mines with steep structure planes by the caving method,there is a mechanical model in which the horizontal stress on the rock mass is simplified as a column before surface subsidence.The model is used to deduce critical support load and limiting column length for a given horizontal stress and support pressure.Considering the impact of the column effect,a method is proposed to determine the movement of the ground and caving area in a mine.After surface subsidence,the horizontal stress on a surrounding rock mass can be simplified to a cantilever beam mechanical model.Expressions for its bending fracture length are deduced,and a method is given to determine its stability.On this basis,an explanation for the large ground movement and subsidence scope was given.A case study shows that the damage effect of column and cantilever beam is significant for ground movement in metal-ore mine,and an appropriate correction value should be applied when designing for its angle of ground movements.展开更多
A dynamic thermal transfer model of a proton exchange membrane fuel cell (PEMFC) stack is developed based on energy conservation in order to reach better temperature control of PEMFC stack. Considering its uncertain p...A dynamic thermal transfer model of a proton exchange membrane fuel cell (PEMFC) stack is developed based on energy conservation in order to reach better temperature control of PEMFC stack. Considering its uncertain parameters and disturbance, we propose a robust adaptive controller based on backstepping algorithm of Lyaponov function. Numerical simulations indicate the validity of the proposed controller.展开更多
Performic acid (PFA) is an oxidant used in chemical processing, synthesis and bleaching. The macro kinetic models of synthesis, hydrolysis and decomposition of PFA were investigated via formic acid-autocatalyzed rea...Performic acid (PFA) is an oxidant used in chemical processing, synthesis and bleaching. The macro kinetic models of synthesis, hydrolysis and decomposition of PFA were investigated via formic acid-autocatalyzed reaction. It was found that the intrinsic activation energies of PFA synthesis and hydrolysis were 75.2 kJ·mol^-1 and 40.4 kJ·mol^-1 respectively. The observed activation energy of PFA decomposition was 95.4 kJ·mol^-1. The experi-mental results indicated that the decomposition of PFA was liable to occur even at the ambient temperature. Both the spontaneous decomposition and the radical-introduced decomposition contributed to the decomposition of PFA.展开更多
Adsorption process is acknowledged as an effective option for phenolic wastewater treatment. In this work, the activated carbon (AC) samples after thermal modification were prepared by using muffle furnace. The phen...Adsorption process is acknowledged as an effective option for phenolic wastewater treatment. In this work, the activated carbon (AC) samples after thermal modification were prepared by using muffle furnace. The phenol ad- sorption kinetics and equilibrium measurements were carried out under static conditions at temperature ranging from 25 to 55 ~C. The test results show that the thermal modification can enhance phenol adsorption on AC samples. The porous structure and surface chemistry analyses indicate that the decay in pore morphology and decrease of total oxygen-containing functional groups are found for the thermal modified AC samples. Thus, it can be further inferred that the decrease of total oxygen-containing functional groups on the modified AC sam- ples is the main reason for the enhanced phenol adsorption capacity. For both the raw sample and the optimum modified AC sample at 900 ~C, the pseudo-second order kinetics and Langmuir models are found to fit the exper- imental data very well. The maximum phenol adsorption capacity of the optimum modified AC sample can reach 144,93 mg.g ~ which is higher than that of the raw sample, i.e. 119.53 mg.g 1. Adsorption thermodynamics analysis confirms that the phenol adsorption on the optimum modified AC sample is an exothermic process and mainly via physical adsorption.展开更多
Wheeled mobile robot is one of the well-known nonholonomic systems. A two-wheeled sell-balance robot is taken as the research objective. This paper carried out a detailed force analysis of the robot and established a ...Wheeled mobile robot is one of the well-known nonholonomic systems. A two-wheeled sell-balance robot is taken as the research objective. This paper carried out a detailed force analysis of the robot and established a non-linear dynamics model. An adaptive tracking controller for the kinematic model of a nonhotonomic mobile robot with unknown parameters is also proposed. Using control Lyapunov function (CLF), the controller's global asymptotic stability has been proven. The adaptive trajectory tracking controller decreases the disturbance in the course of tracking control and enhances the real-time control characteristics. The simulation result indicated that the wheeled mobile robot tracking can be effectively controlled.展开更多
The leaching kinetics of Sb and Fe from antimony-bearing complex sulfides ore was investigated in HCl solution by oxidation?leaching with ozone.The effects of temperature,HCl concentration,stirring speed and particle ...The leaching kinetics of Sb and Fe from antimony-bearing complex sulfides ore was investigated in HCl solution by oxidation?leaching with ozone.The effects of temperature,HCl concentration,stirring speed and particle size on the process were explored.It is found that the recoveries of Sb and Fe reach86.1%and28.8%,respectively,when the reaction conditions are4.0mol/L HCl,900r/min stirring speed at85°C with<0.074mm particle size after50min leaching.XRD analysis indicates that no new solid product forms in the leaching residue and the leaching process can be described by shrinking core model.The leaching of Sb corresponds to diffusion-controlled model at low temperature(15?45°C)and mixed-controlled model at high temperature(45?85°C),and the apparent activation energies are6.91and17.93kJ/mol,respectively.The leaching of Fe corresponds to diffusion-controlled model,and the apparent activation energy is1.99kJ/mol.Three semi-empirical rate equations are obtained to describe the leaching process.展开更多
The research on spatial epidemic models is a topic of considerable recent interest. In another hand, the advances in computer technology have stimulated the development of stochastic models. Metapopulation models are ...The research on spatial epidemic models is a topic of considerable recent interest. In another hand, the advances in computer technology have stimulated the development of stochastic models. Metapopulation models are spatial designs that involve movements of individuals between distinct subpopulations. The purpose of the present work has been to develop stochastic models in order to study the transmission dynamics and control of infectious diseases in metapopulations. The authors studied Susceptible-Infected-Susceptible (SIS) and Susceptible-lnfected-Recovered (SIR) epidemic schemes, using the Gillespie algorithm, Computational numerical simulations were carried in order to explore the models. The results obtained show how the dynamics of transmission and the application of control measures within each subpopulation may affect all subpopulations of the system. They also show how the distribution of control measures among subpopulations affects the efficacy of these strategies. The dynamics of the stochastic models developed in the current study follow the trends observed in the classic deterministic designs. Also, the present models exhibit fluctuating behavior. This work highlights the importance of the spatial distribution of the population in spread and control of infectious diseases. In addition, it shows how chance could play an important role in these scenarios.展开更多
The given investigation presents the results of estimating the water circulation in the water area of the Bering Sea and the Sea of Okhotsks, considering the influence of various types of the atmospheric processes. To...The given investigation presents the results of estimating the water circulation in the water area of the Bering Sea and the Sea of Okhotsks, considering the influence of various types of the atmospheric processes. To solve the given problem it is used a hydrodynamic model calculating the integral functions of the flow from the surface to the bottom. By results of calculations, the maps of the integral water circulation were built for the following types of atmospheric circulation: "north-western" and "okhotsk-aleutian". In accordance with the performed calculations for the water area being studied, the hydrodynamic structures are distinguished both non-depending and depending on the type of the atmospheric circulation. The non-depending structures are characterized by the cyclonic activity in the Bering Sea and the Sea of Okhotsk in whole. Hydrodynamic structures depending on types of the atmospheric circulation have their peculiarities in the spatial-temporal distribution.展开更多
The simple dynamic model is often adopted to deal with control questions in research on semi-active suspension. The model has more theoretic meanings than authentic ones because of difference between practical and phy...The simple dynamic model is often adopted to deal with control questions in research on semi-active suspension. The model has more theoretic meanings than authentic ones because of difference between practical and physical models. The virtual prototype has remarkable advantages in its application simulation processes. It is not only faster and more veracious, but also of better visualization of the simulation results.展开更多
Recent observations support an emerging paradigm that climate variability dominates nutrient enrichment in costal eco-systems, which can explain seasonal and inter-annual variability of phytoplankton community composi...Recent observations support an emerging paradigm that climate variability dominates nutrient enrichment in costal eco-systems, which can explain seasonal and inter-annual variability of phytoplankton community composition, biomass (Chl-a), and primary production (PP). In this paper, we combined observation and modeling to investigate the regulation of phytoplankton dynamics in Chesapeake Bay. The year we chose is 1996 that has high river runoff and is usually called a 'wet year'. A 3-D physical-biogeochemical model based on ROMS was developed to simulate the seasonal cycle and the regional distributions of phytoplankton biomass and primary production in Chesapeake Bay. Based on the model results, NO3 presents a strong contrast to the river nitrate load during spring and the highest concentration in the bay reaches around 80 mmol Nm-3 . Compared with the normal year, phytoplankton bloom in spring of 1996 appears in lower latitudes with a higher concentration. Quantitative comparison between the modeled and observed seasonal averaged dissolved inorganic nitrogen concentrations shows that the model produces reliable results. The correlation coefficient r2 for all quantities exceeds 0.95, and the skill parameter for the four seasons is all above 0.95.展开更多
Based on an improved three-dimensional wheel-rail contact trace algorithm and a new model of wheel-rail contact force, wheel-rail derailment dynamical model is established on China Railways High-speed(CRH) vehicle a...Based on an improved three-dimensional wheel-rail contact trace algorithm and a new model of wheel-rail contact force, wheel-rail derailment dynamical model is established on China Railways High-speed(CRH) vehicle and developed in MATLAB software, which is called dynamical derailment system for CRH (DDSCRH). Analyzed on dynamical derailment process of high speed vehicle by DDSCRH, the critical position on chmb wheel and influence factors on lateral force for derailment are obtained. Finally, high-speed vehicle dynamical simulation is verified on DDSCRH by comparing with the existing results of the line test.展开更多
文摘A support vector machine with guadratic polynomial kernel function based nonlinear model multi-step-ahead optimizing predictive controller was presented. A support vector machine based predictive model was established by black-box identification. And a quadratic objective function with receding horizon was selected to obtain the controller output. By solving a nonlinear optimization problem with equality constraint of model output and boundary constraint of controller output using Nelder-Mead simplex direct search method, a sub-optimal control law was achieved in feature space. The effect of the controller was demonstrated on a recognized benchmark problem and a continuous-stirred tank reactor. The simulation results show that the multi-step-ahead predictive controller can be well applied to nonlinear system, with better performance in following reference trajectory and disturbance-rejection.
基金Project(2003AA430200) supported by the National Hi-Tech Research and Development Program(863) of China
文摘In order to find a feasible way to control excavator’s arm and realize autonomous excavation, the dynamic model for the boom of excavator’s arm which was regarded as a planar manipulator with three degrees of freedom was constructed with Lagrange equation. The excavator was retrofitted with electrohydraulic proportional valves, associated sensors (three inclinometers) and a computer control system (the motion controller of EPEC). The full nonlinear mathematic model of electrohydraulic proportional system was achieved. A discontinuous projection based on an adaptive robust controller to approximate the nonlinear gain coefficient of the valve was presented to deal with the nonlinearity of the whole system, the error was dealt with by robust feedback and an adaptive robust controller was designed. The experiment results of the boom motion control show that, using the controller, good performance for tracking can be achieved, and the peak tracking error of boom angles is less than 4°.
基金Supported by the National Nature Foundation of China (No.59975073)
文摘An experimental method is introduced in this paper to build the dynamics of AMSS (the active magnetic suspension system), which doesn’t depend on system’s physical parameters. The rotor can be reliably suspended under the unit feedback control system designed with the primary dynamic model obtained. Online identification in frequency domain is processed to give the precise model. Comparisons show that the experimental method is much closer to the precise model than the theoretic method based on magnetic circuit law. So this experimental method is a good choice to build the primary dynamic model of AMSS.
文摘A numerical model is presented to investigate the performance of homogeneous charge compression ignition(HCCI) engines fueled with ethanol. Two approaches are studied. On one hand, two-step reaction mechanisms with Arrhenius reaction rates are implemented in combustion chemistry modeling. On the other hand, a reduced mechanism containing important reactions of ethanol involving heat release rate and reaction rates compatible with experimental data is employed. Since controls of combustion phenomenon and ignition timing are the main issues of these engines, the effects of inlet temperature and equivalence ratio as the controlling factors on the operating parameters such as ignition timing, burn duration, in-cylinder temperature and pressure of HCCI engines are explored. The results show that the maximum predicted pressures for thermodynamic model are about 71.3×10~5 Pa and 79.79×10~5 Pa, and for chemical kinetic model, they are about 71.48×10~5 Pa and 78.123×10~5 Pa, fairly comparable with corresponding experimental values of 72×10~5 Pa and 78.7×10~5 Pa. It is observed that increasing the initial temperature advances the ignition timing, decreases the burn duration and increases the peak temperature and pressure. Moreover, the maximum temperature and pressure are associated with richer mixtures.
基金a co-sponsored graduate research project by China Pharmaceutical University and Shanghai Medicilon Inc
文摘Objective: To provide a kinetic model(s) and reveal the mechanism of thymoquinone and Poloxin blocking an emerging anti-cancer target, human Polo-like kinase 1 (hPlkl) Polo-box domain (PBD). Methods: The binding kinetics was determined by using a fluorescence polarization based assay. The putative mechanism was examined with a competition test. Results: Thymoquinone follows a one-step binding with an association rate constant (k1) of 6.635× 10^3 L.mol^-1 min^-1.Poloxin fit a two-step binding with a dissociation constant (Ki) of 118 μmol/L for the intermediate complex and its isomerization rate (k4) of 0.131 5 minJ to form an irreversible adduct. No significant dissociation was observed for either ligand up to 13 h. The inhibitors responded insignificantly to the presence of Michael donors as hPIkl-PBD competitors. Conclusion: Thymoquinone and Poloxin are slow-tight ligands to the hPlkl-PBD with kinetic models distinct from each other. Michael addition as the mechanism is excluded.
基金supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the Advanced Research Project of Army Equipment Development(No.301020803)
文摘Nonlinear dynamic inversion(NDI)has been applied to the control law design of quad-rotors mainly thanks to its good robustness and simplicity of parameter tuning.However,the weakness of relying on accurate model greatly restrains its application on quad-rotors,especially nano quad-rotors(NQRs).NQRs are easy to be influenced by uncertainties such as model uncertainties(mainly from complicated aerodynamic interferences,strong coupling in roll-pitch-yaw channels and inaccurate aerodynamic prediction of rotors)and external uncertainties(mainly from winds or gusts),particularly persistent ones.Therefore,developing accurate model for altitude and attitude control of NQRs is difficult.To solve this problem,in this paper,an improved nonlinear dynamic inversion(INDI)method is developed,which can reject the above-mentioned uncertainties by estimating them and then counteracting in real time using linear extended state observer(LESO).Comparison with the traditional NDI(TNDI)method was carried out numerically,and the results show that,in coping with persistent uncertainties,the INDI-based method presents significant superiority.
基金Supported by National Natural Science Foundation of China (No. 20276052) and Tianjin Science & Technology Commission (No. 023105411).
文摘The kinetics of casein tryptic hydrolysis to prepare activepeptides was investigated. Taking into account the reaction mechanismincluding single substrate hydrolysis, irreversible enzymeinactivation, and substrate inhibition, a set of exponentialequations was established to characterize the enzymatic hydrolysiscurves. The verification was carried out by a series of experimentalresults and indicated that the average regressive error was less than5/100. According to the proposed kinetic model, the kinetic constantsand thermodynamic constants of the reaction system were alsocalculated.
基金the support from the National Natural Science Foundation of China(Nos.11372188,and 51490674)the National Basic Research Program of China(973 Program)(No.2015CB251203)
文摘The flow past a primary cylinder with one tandem control rod and one staggered control rod is simulated in this paper through solving the Navier-Stokes equations. Two examples are simulated to validate the model, and the results matched well with those of previous researches. The Reynolds number based on the diameter of the primary cylinder is 500. The diameter ratio between the control rod and the primary cylinder (d/D) is 0.25. It was found that the effect of the combination of one upstream tandem control rod and one staggered control rod on the hydrodynamics of the primary cylinder is a linear superposition of the effect of a corresponding single control rod, and the effect of the upstream tandem control rod is dominant at larger spacing ratios such as G/D=2. For the combination of a downstream tandem control rod and a staggered control rod, the effect of the control rods is different from that of the corresponding single control rod in the region of 0.2〈G/D〈0.5 & 30°〈a〈120° and 0.9〈G/D〈1.4 & 30°〈a〈50°, where the additional effect is obvious. In this case, the effect of the downstream tandem control rod is dominant at small spacing ratios (such as G/D=0.1). At moderate spacing ratios such as G/D=0.4, the effects of the tandem control rod and the staggered control rod are comparable in both cases.
基金Project(51274188)supported by the National Natural Science Foundation of China
文摘When mining metal mines with steep structure planes by the caving method,there is a mechanical model in which the horizontal stress on the rock mass is simplified as a column before surface subsidence.The model is used to deduce critical support load and limiting column length for a given horizontal stress and support pressure.Considering the impact of the column effect,a method is proposed to determine the movement of the ground and caving area in a mine.After surface subsidence,the horizontal stress on a surrounding rock mass can be simplified to a cantilever beam mechanical model.Expressions for its bending fracture length are deduced,and a method is given to determine its stability.On this basis,an explanation for the large ground movement and subsidence scope was given.A case study shows that the damage effect of column and cantilever beam is significant for ground movement in metal-ore mine,and an appropriate correction value should be applied when designing for its angle of ground movements.
文摘A dynamic thermal transfer model of a proton exchange membrane fuel cell (PEMFC) stack is developed based on energy conservation in order to reach better temperature control of PEMFC stack. Considering its uncertain parameters and disturbance, we propose a robust adaptive controller based on backstepping algorithm of Lyaponov function. Numerical simulations indicate the validity of the proposed controller.
基金Supported by the International Cooperation Project of the Ministry of Science and Technology of China (2010DFB40170)the National Basic Research Program of China (973 Program) (2011CB707406)
文摘Performic acid (PFA) is an oxidant used in chemical processing, synthesis and bleaching. The macro kinetic models of synthesis, hydrolysis and decomposition of PFA were investigated via formic acid-autocatalyzed reaction. It was found that the intrinsic activation energies of PFA synthesis and hydrolysis were 75.2 kJ·mol^-1 and 40.4 kJ·mol^-1 respectively. The observed activation energy of PFA decomposition was 95.4 kJ·mol^-1. The experi-mental results indicated that the decomposition of PFA was liable to occur even at the ambient temperature. Both the spontaneous decomposition and the radical-introduced decomposition contributed to the decomposition of PFA.
基金Supported by the National Natural Science Foundation of China(41302132)Training Programmes of Innovation and Entrepreneurship for Undergraduates of Yunnan Province(Grant No.201510674042)the Introduced Talents Foundation of Kunming University of Science and Technology(KKSY201205160)
文摘Adsorption process is acknowledged as an effective option for phenolic wastewater treatment. In this work, the activated carbon (AC) samples after thermal modification were prepared by using muffle furnace. The phenol ad- sorption kinetics and equilibrium measurements were carried out under static conditions at temperature ranging from 25 to 55 ~C. The test results show that the thermal modification can enhance phenol adsorption on AC samples. The porous structure and surface chemistry analyses indicate that the decay in pore morphology and decrease of total oxygen-containing functional groups are found for the thermal modified AC samples. Thus, it can be further inferred that the decrease of total oxygen-containing functional groups on the modified AC sam- ples is the main reason for the enhanced phenol adsorption capacity. For both the raw sample and the optimum modified AC sample at 900 ~C, the pseudo-second order kinetics and Langmuir models are found to fit the exper- imental data very well. The maximum phenol adsorption capacity of the optimum modified AC sample can reach 144,93 mg.g ~ which is higher than that of the raw sample, i.e. 119.53 mg.g 1. Adsorption thermodynamics analysis confirms that the phenol adsorption on the optimum modified AC sample is an exothermic process and mainly via physical adsorption.
基金Supported by the National High Technology Research and Development Programme of China (No. 2006AA04Z245)the Program for Changjiang Scholars and Innovative Research Team in University ( No. IRT0423)the Fund for Foreign Scholars in University Research and Teaching Programs (No. B07018)
文摘Wheeled mobile robot is one of the well-known nonholonomic systems. A two-wheeled sell-balance robot is taken as the research objective. This paper carried out a detailed force analysis of the robot and established a non-linear dynamics model. An adaptive tracking controller for the kinematic model of a nonhotonomic mobile robot with unknown parameters is also proposed. Using control Lyapunov function (CLF), the controller's global asymptotic stability has been proven. The adaptive trajectory tracking controller decreases the disturbance in the course of tracking control and enhances the real-time control characteristics. The simulation result indicated that the wheeled mobile robot tracking can be effectively controlled.
基金Project (51474257) supported by the National Natural Science Foundation of ChinaProject (2015zzts037) supported by the Postgraduate Research and Innovation Projects of Hunan Province,ChinaProject (2015JC3005) supported by the Key Technology Research and Development Program of Hunan Province,China
文摘The leaching kinetics of Sb and Fe from antimony-bearing complex sulfides ore was investigated in HCl solution by oxidation?leaching with ozone.The effects of temperature,HCl concentration,stirring speed and particle size on the process were explored.It is found that the recoveries of Sb and Fe reach86.1%and28.8%,respectively,when the reaction conditions are4.0mol/L HCl,900r/min stirring speed at85°C with<0.074mm particle size after50min leaching.XRD analysis indicates that no new solid product forms in the leaching residue and the leaching process can be described by shrinking core model.The leaching of Sb corresponds to diffusion-controlled model at low temperature(15?45°C)and mixed-controlled model at high temperature(45?85°C),and the apparent activation energies are6.91and17.93kJ/mol,respectively.The leaching of Fe corresponds to diffusion-controlled model,and the apparent activation energy is1.99kJ/mol.Three semi-empirical rate equations are obtained to describe the leaching process.
文摘The research on spatial epidemic models is a topic of considerable recent interest. In another hand, the advances in computer technology have stimulated the development of stochastic models. Metapopulation models are spatial designs that involve movements of individuals between distinct subpopulations. The purpose of the present work has been to develop stochastic models in order to study the transmission dynamics and control of infectious diseases in metapopulations. The authors studied Susceptible-Infected-Susceptible (SIS) and Susceptible-lnfected-Recovered (SIR) epidemic schemes, using the Gillespie algorithm, Computational numerical simulations were carried in order to explore the models. The results obtained show how the dynamics of transmission and the application of control measures within each subpopulation may affect all subpopulations of the system. They also show how the distribution of control measures among subpopulations affects the efficacy of these strategies. The dynamics of the stochastic models developed in the current study follow the trends observed in the classic deterministic designs. Also, the present models exhibit fluctuating behavior. This work highlights the importance of the spatial distribution of the population in spread and control of infectious diseases. In addition, it shows how chance could play an important role in these scenarios.
文摘The given investigation presents the results of estimating the water circulation in the water area of the Bering Sea and the Sea of Okhotsks, considering the influence of various types of the atmospheric processes. To solve the given problem it is used a hydrodynamic model calculating the integral functions of the flow from the surface to the bottom. By results of calculations, the maps of the integral water circulation were built for the following types of atmospheric circulation: "north-western" and "okhotsk-aleutian". In accordance with the performed calculations for the water area being studied, the hydrodynamic structures are distinguished both non-depending and depending on the type of the atmospheric circulation. The non-depending structures are characterized by the cyclonic activity in the Bering Sea and the Sea of Okhotsk in whole. Hydrodynamic structures depending on types of the atmospheric circulation have their peculiarities in the spatial-temporal distribution.
文摘The simple dynamic model is often adopted to deal with control questions in research on semi-active suspension. The model has more theoretic meanings than authentic ones because of difference between practical and physical models. The virtual prototype has remarkable advantages in its application simulation processes. It is not only faster and more veracious, but also of better visualization of the simulation results.
基金supported by the National Science Foundation project of M. Li (OCE-082543)
文摘Recent observations support an emerging paradigm that climate variability dominates nutrient enrichment in costal eco-systems, which can explain seasonal and inter-annual variability of phytoplankton community composition, biomass (Chl-a), and primary production (PP). In this paper, we combined observation and modeling to investigate the regulation of phytoplankton dynamics in Chesapeake Bay. The year we chose is 1996 that has high river runoff and is usually called a 'wet year'. A 3-D physical-biogeochemical model based on ROMS was developed to simulate the seasonal cycle and the regional distributions of phytoplankton biomass and primary production in Chesapeake Bay. Based on the model results, NO3 presents a strong contrast to the river nitrate load during spring and the highest concentration in the bay reaches around 80 mmol Nm-3 . Compared with the normal year, phytoplankton bloom in spring of 1996 appears in lower latitudes with a higher concentration. Quantitative comparison between the modeled and observed seasonal averaged dissolved inorganic nitrogen concentrations shows that the model produces reliable results. The correlation coefficient r2 for all quantities exceeds 0.95, and the skill parameter for the four seasons is all above 0.95.
文摘Based on an improved three-dimensional wheel-rail contact trace algorithm and a new model of wheel-rail contact force, wheel-rail derailment dynamical model is established on China Railways High-speed(CRH) vehicle and developed in MATLAB software, which is called dynamical derailment system for CRH (DDSCRH). Analyzed on dynamical derailment process of high speed vehicle by DDSCRH, the critical position on chmb wheel and influence factors on lateral force for derailment are obtained. Finally, high-speed vehicle dynamical simulation is verified on DDSCRH by comparing with the existing results of the line test.