Concrete structures in main coal cleaning plants have been rebuilt and reinforced in the coal mines of the Shanghai Datun Energy Sources Co. Ltd., the first colliery of the Pingdingshan Coal Co. Ltd. and the Sanhejian...Concrete structures in main coal cleaning plants have been rebuilt and reinforced in the coal mines of the Shanghai Datun Energy Sources Co. Ltd., the first colliery of the Pingdingshan Coal Co. Ltd. and the Sanhejian mine of the Xuzhou Mining Group Co. Ltd. In these projects, the operating environment and reliability of concrete structures in the main plants of the three companies were investigated and the safety of the structures inspected. Qualitative and quantitative analyses were made on the special natural, technological and mechanical environments around the structures. On the basis of these analyses, we discuss the long-term, combined actions of the harsh natural (corrosive gases, liquids and solids) and mechanical environments on concrete structures and further investigated the damage and deteriorating mechanisms and curing techniques of concrete structures in the main coal cleaning plants. Our study can provide a theoretical basis for ensuring the reliability of concrete structures in main coal cleaning plants.展开更多
The advantages and disadvantages of organic antioxidant and inorganic salt on suppressing coal oxidation were analyzed on the basis of the theory that coal oxidation mechanisms can be attributed to the free radical ch...The advantages and disadvantages of organic antioxidant and inorganic salt on suppressing coal oxidation were analyzed on the basis of the theory that coal oxidation mechanisms can be attributed to the free radical chain-type reaction mechanism. The inhibition curves on suppressing coal oxidation of the different type and different concentration of organic antioxidant and inorganic salt were given through experimental study and data processing. Then some conclusions can be gained from the experimental study combining with theoretical analysis. First the inhibition mechanism of the organic antioxidant and inorganic salt is different. The former is that the chemical action is the dominant position. It can be called as the chain termination theory because the free radical is captured during coal oxidation. And the later is that the physical effect is the dominant position. It can be called as the decreasing-temperature theory because the liquid membrane which was formed by the inorganic salt can make coal body be the state of wetness and prevent oxygen from coal surface. Second the inhibition effect of the organic antioxidant is higher than the inorganic salt in the later period. But it is lower in the early period.展开更多
Inhibition mechanism between sodium (NaaAlF6) and sulfur on coke reactivity was investigated by simulating petroleum coke with low-impurity pitch coke and by impurity doping. The mechanism was discussed by scanning ...Inhibition mechanism between sodium (NaaAlF6) and sulfur on coke reactivity was investigated by simulating petroleum coke with low-impurity pitch coke and by impurity doping. The mechanism was discussed by scanning electron microscopy, energy-dispersive spectrometry, and X-ray powder diffraction. Results show that Na effectively inhibited S catalysis during carbon-air/CO2 reactions, and S inhibited the catalysis of Na during carbon- air reaction to a certain extent. A stable structure with a Na-to-S atomic ratio of 1.4 and a cyclic reaction system of "Na2SO3→ Na2S→Na2CO3→ Na2SO3" were likely the keys to producing this mutual inhibition.展开更多
Reliability and wear resistance of cutting picks play a significant role in coal mine exploitation with coal shearers.Tool bit separation,blade breaking,severe erosion of the cutting body and fatigue fractures are the...Reliability and wear resistance of cutting picks play a significant role in coal mine exploitation with coal shearers.Tool bit separation,blade breaking,severe erosion of the cutting body and fatigue fractures are the main reasons for failure of cutting picks.We carried out carburization on a 30CrMnMo alloy to synthesize a new cutting pick material with improved mechanical properties and high wear resistance.The results indicated that carburization can effectively strengthen the surface of the 30CrMnMo alloy by forming a thick carburized layer and thus significantly improve the surface hardness and wear resistance.In addition,the excellent toughness of 30CrMnMo alloy as a substrate of cutting picks can prevent brittle ruptures and fatigue fractures under high impact stress conditions.The significant decrease in both frictional coefficient and rate of erosion of this carburized 30CrMnMo alloy suggests that this alloy is a potential material for cutting picks of coal shearers after rational carburization.展开更多
The aim of this study is to express the receptor-binding domain of Bacillus anthracis protective antigen in E.coli . Signal sequence of the outer membrane protein A (OmpA) of E.coli was attached to the 5′ end of the ...The aim of this study is to express the receptor-binding domain of Bacillus anthracis protective antigen in E.coli . Signal sequence of the outer membrane protein A (OmpA) of E.coli was attached to the 5′ end of the gene encoding protective antigen receptor-binding domain (the 4 th domain of PA, PAD4). The plasmid carrying the fusion gene was then transformed into E.coli and induced to express recombinant PAD4 by IPTG. The recombinant protein was purified by chromatography and then identified by N-terminal sequencing and Western blot. The recombinant protein, about 10% of the total bacterial protein in volume, was secreted to the periplasmic space of the cell. After a purification procedure including ion-exchange chromatography and gel filtration, about 10 mg of homogenous recombinant PAD4 was obtained from 1 L culture. Data from N-terminal sequencing suggested that the amino acid sequence of recombinant PAD4 was identical with its natural counterpart. And the result of Western blot showed the recombinant protein could bind with anti-PA serum from rabbit. High level secreted expression of PAD4 was obtained in E.coli . The results reported here are parts of a continuing research to evaluate PAD4 as a potential drug for anthrax therapy or a candidate of new vaccine.展开更多
In this study, we provided more theoretical method for estimation of dissolution amount and applied this method to enhanced coalbed methane recovery (ECBMR) simulator. Dissolution amount was measured by method of di...In this study, we provided more theoretical method for estimation of dissolution amount and applied this method to enhanced coalbed methane recovery (ECBMR) simulator. Dissolution amount was measured by method of differential heat of adsorption. Akabira coal, a Japanese bituminous coal, was used for the experiment. The results showed that CO2 was stored in coal by both adsorption and dissolution. Using this result the methane production was calculated by ECBMR-simulator, enhanced coalbed methane recovery simulator, the University of Tokyo (ECOMERS-UT). Total stored CO2 was separated into adsorption component and dissolution component. Only the former component contributes to the competitive adsorption. Coalbed methane (CBM) production simulation considering the dissolution showed later and smaller peak production and prolonged methane production before the breakthrough than the conventional competitive adsorption.展开更多
Due to the different sources of charcoals, there are significant differences in their properties. In order to study the catalytic effect of different charcoals to nitrobenzene (NB), we selected nine charcoal-sources t...Due to the different sources of charcoals, there are significant differences in their properties. In order to study the catalytic effect of different charcoals to nitrobenzene (NB), we selected nine charcoal-sources to prepare nine charcoals with different properties. The experiments showed that NB could be rapidly reduced by sulfides in the presence of all charcoals. The surface area normalized reduction rate constants of NB increased with H/C and (O+N)/C ratio of charcoals increasing. The difference of catalytic effect for nine charcoals was mainly due to their different species and content of surface functional groups and original organic matter. Based on the theoretical calculation and experimental results, the reaction mechanism of NB catalyzed by charcoal in sulfides solution was analyzed. Some active surface functional groups and original organic matter of charcoals were regarded as the active sites and played an important role in catalyzing the reduction of NB by accelerating the transfer of electrons from sulfides to NB.展开更多
The Upper Carboniferous in northern Xinjiang, China was formed in a post-collisional depression and collapsed structural setting. Within the Upper Carboniferous, volcanic rocks and source rocks alternate over a wide r...The Upper Carboniferous in northern Xinjiang, China was formed in a post-collisional depression and collapsed structural setting. Within the Upper Carboniferous, volcanic rocks and source rocks alternate over a wide region. At the end of the Carboniferous, these layers were uplifted by plate collisions and subsequently weathered and leached. Volcanic weathering and leaching led to the establishment of weathered crusts that can be divided into five layers. Corrosion and crumble zones in these layers form favorable reservoirs. Volcanic weathering crust formed in sub-aerially exposed paleogeomorphic areas; the five relatively continuous layers are generally preserved in paleogeomorphic lowland and slope regions, but the upper soil layer is usually absent in structurally higher parts of the rock record. The thickness of the weathered layer has a positive nonlinear ex- ponential relationship to the duration of weathering and leaching, and the dynamic equilibrium time of weathered crust is about 36.3 Ma. The thickest weathered layer (~450 m) is located in fracture zones. Weathered crusts are possible from a range of volcanic rocks with different lithologies, given sufficient time for weathering and leaching. The combination of volcanic weathered crust and source rocks results in three types of hydrocarbon accumulation models: (1) sequences of volcanic weathered crust interbedded with source rocks, (2) a quasi-layered weathered volcanic core located above source rocks, and (3) volcanic rocks associated with pectinate unconformities adjacent to source rocks. Each of these three types has the potential to form a giant stratigraphic reservoir of volcanic weathered crust. This knowledge has changed the traditional exploration model of searching for favorable lithologic and lithofacies zones in volcanic rocks, and has changed the viewpoint that the Carboniferous does not have the genetic potential to be the basement of the basin in northern Xinjiang. The concepts developed here are of great scientific significance and application for focusing oil and gas exploration on volcanic weathered crust. As such, the Paleozoic volcanic weathered crust in the midwestern part of China may possibly contain large-scale stratigraphic reservoirs and thus could be a new oil and gas exploration target in the future.展开更多
基金Project BK2008128 supported by the Natural Science Foundation of Jiangsu Province
文摘Concrete structures in main coal cleaning plants have been rebuilt and reinforced in the coal mines of the Shanghai Datun Energy Sources Co. Ltd., the first colliery of the Pingdingshan Coal Co. Ltd. and the Sanhejian mine of the Xuzhou Mining Group Co. Ltd. In these projects, the operating environment and reliability of concrete structures in the main plants of the three companies were investigated and the safety of the structures inspected. Qualitative and quantitative analyses were made on the special natural, technological and mechanical environments around the structures. On the basis of these analyses, we discuss the long-term, combined actions of the harsh natural (corrosive gases, liquids and solids) and mechanical environments on concrete structures and further investigated the damage and deteriorating mechanisms and curing techniques of concrete structures in the main coal cleaning plants. Our study can provide a theoretical basis for ensuring the reliability of concrete structures in main coal cleaning plants.
文摘The advantages and disadvantages of organic antioxidant and inorganic salt on suppressing coal oxidation were analyzed on the basis of the theory that coal oxidation mechanisms can be attributed to the free radical chain-type reaction mechanism. The inhibition curves on suppressing coal oxidation of the different type and different concentration of organic antioxidant and inorganic salt were given through experimental study and data processing. Then some conclusions can be gained from the experimental study combining with theoretical analysis. First the inhibition mechanism of the organic antioxidant and inorganic salt is different. The former is that the chemical action is the dominant position. It can be called as the chain termination theory because the free radical is captured during coal oxidation. And the later is that the physical effect is the dominant position. It can be called as the decreasing-temperature theory because the liquid membrane which was formed by the inorganic salt can make coal body be the state of wetness and prevent oxygen from coal surface. Second the inhibition effect of the organic antioxidant is higher than the inorganic salt in the later period. But it is lower in the early period.
基金Projects(51374253,51574289)supported by the National Natural Science Foundation of China
文摘Inhibition mechanism between sodium (NaaAlF6) and sulfur on coke reactivity was investigated by simulating petroleum coke with low-impurity pitch coke and by impurity doping. The mechanism was discussed by scanning electron microscopy, energy-dispersive spectrometry, and X-ray powder diffraction. Results show that Na effectively inhibited S catalysis during carbon-air/CO2 reactions, and S inhibited the catalysis of Na during carbon- air reaction to a certain extent. A stable structure with a Na-to-S atomic ratio of 1.4 and a cyclic reaction system of "Na2SO3→ Na2S→Na2CO3→ Na2SO3" were likely the keys to producing this mutual inhibition.
基金the Youth Foundation of China University of Mining & Technology (No.2009A056)the Tribology Science Fund from State Key Laboratory of Tribology at Tsinghua University (No.SKLTKF08A01)+1 种基金the National Natural Science Foundation of China (Nos.50905180 and 51005234)the National Science and Technology Pillar Program in the Eleventh Five-Year Plan Period (No.2008BAB36B02)
文摘Reliability and wear resistance of cutting picks play a significant role in coal mine exploitation with coal shearers.Tool bit separation,blade breaking,severe erosion of the cutting body and fatigue fractures are the main reasons for failure of cutting picks.We carried out carburization on a 30CrMnMo alloy to synthesize a new cutting pick material with improved mechanical properties and high wear resistance.The results indicated that carburization can effectively strengthen the surface of the 30CrMnMo alloy by forming a thick carburized layer and thus significantly improve the surface hardness and wear resistance.In addition,the excellent toughness of 30CrMnMo alloy as a substrate of cutting picks can prevent brittle ruptures and fatigue fractures under high impact stress conditions.The significant decrease in both frictional coefficient and rate of erosion of this carburized 30CrMnMo alloy suggests that this alloy is a potential material for cutting picks of coal shearers after rational carburization.
文摘The aim of this study is to express the receptor-binding domain of Bacillus anthracis protective antigen in E.coli . Signal sequence of the outer membrane protein A (OmpA) of E.coli was attached to the 5′ end of the gene encoding protective antigen receptor-binding domain (the 4 th domain of PA, PAD4). The plasmid carrying the fusion gene was then transformed into E.coli and induced to express recombinant PAD4 by IPTG. The recombinant protein was purified by chromatography and then identified by N-terminal sequencing and Western blot. The recombinant protein, about 10% of the total bacterial protein in volume, was secreted to the periplasmic space of the cell. After a purification procedure including ion-exchange chromatography and gel filtration, about 10 mg of homogenous recombinant PAD4 was obtained from 1 L culture. Data from N-terminal sequencing suggested that the amino acid sequence of recombinant PAD4 was identical with its natural counterpart. And the result of Western blot showed the recombinant protein could bind with anti-PA serum from rabbit. High level secreted expression of PAD4 was obtained in E.coli . The results reported here are parts of a continuing research to evaluate PAD4 as a potential drug for anthrax therapy or a candidate of new vaccine.
文摘In this study, we provided more theoretical method for estimation of dissolution amount and applied this method to enhanced coalbed methane recovery (ECBMR) simulator. Dissolution amount was measured by method of differential heat of adsorption. Akabira coal, a Japanese bituminous coal, was used for the experiment. The results showed that CO2 was stored in coal by both adsorption and dissolution. Using this result the methane production was calculated by ECBMR-simulator, enhanced coalbed methane recovery simulator, the University of Tokyo (ECOMERS-UT). Total stored CO2 was separated into adsorption component and dissolution component. Only the former component contributes to the competitive adsorption. Coalbed methane (CBM) production simulation considering the dissolution showed later and smaller peak production and prolonged methane production before the breakthrough than the conventional competitive adsorption.
基金supported by the Major State Basic Research Development Program (2009CB421605)National Natural Science Foundation of China (20977009)National Water Pollution and Management Technology Project of China (2009ZX07209-008)
文摘Due to the different sources of charcoals, there are significant differences in their properties. In order to study the catalytic effect of different charcoals to nitrobenzene (NB), we selected nine charcoal-sources to prepare nine charcoals with different properties. The experiments showed that NB could be rapidly reduced by sulfides in the presence of all charcoals. The surface area normalized reduction rate constants of NB increased with H/C and (O+N)/C ratio of charcoals increasing. The difference of catalytic effect for nine charcoals was mainly due to their different species and content of surface functional groups and original organic matter. Based on the theoretical calculation and experimental results, the reaction mechanism of NB catalyzed by charcoal in sulfides solution was analyzed. Some active surface functional groups and original organic matter of charcoals were regarded as the active sites and played an important role in catalyzing the reduction of NB by accelerating the transfer of electrons from sulfides to NB.
基金supported by National S&T Major Project (Grant No. 2008ZX05001)Major Brainstorm Project of CNPC-provided Financial Aid (Grant No. 06-01A-01-01)
文摘The Upper Carboniferous in northern Xinjiang, China was formed in a post-collisional depression and collapsed structural setting. Within the Upper Carboniferous, volcanic rocks and source rocks alternate over a wide region. At the end of the Carboniferous, these layers were uplifted by plate collisions and subsequently weathered and leached. Volcanic weathering and leaching led to the establishment of weathered crusts that can be divided into five layers. Corrosion and crumble zones in these layers form favorable reservoirs. Volcanic weathering crust formed in sub-aerially exposed paleogeomorphic areas; the five relatively continuous layers are generally preserved in paleogeomorphic lowland and slope regions, but the upper soil layer is usually absent in structurally higher parts of the rock record. The thickness of the weathered layer has a positive nonlinear ex- ponential relationship to the duration of weathering and leaching, and the dynamic equilibrium time of weathered crust is about 36.3 Ma. The thickest weathered layer (~450 m) is located in fracture zones. Weathered crusts are possible from a range of volcanic rocks with different lithologies, given sufficient time for weathering and leaching. The combination of volcanic weathered crust and source rocks results in three types of hydrocarbon accumulation models: (1) sequences of volcanic weathered crust interbedded with source rocks, (2) a quasi-layered weathered volcanic core located above source rocks, and (3) volcanic rocks associated with pectinate unconformities adjacent to source rocks. Each of these three types has the potential to form a giant stratigraphic reservoir of volcanic weathered crust. This knowledge has changed the traditional exploration model of searching for favorable lithologic and lithofacies zones in volcanic rocks, and has changed the viewpoint that the Carboniferous does not have the genetic potential to be the basement of the basin in northern Xinjiang. The concepts developed here are of great scientific significance and application for focusing oil and gas exploration on volcanic weathered crust. As such, the Paleozoic volcanic weathered crust in the midwestern part of China may possibly contain large-scale stratigraphic reservoirs and thus could be a new oil and gas exploration target in the future.