According to the principles of simultaneous equilibrium and mass equilibrium, a series of thermodynamic equilibrium equations in Ni（II）-Co（II）-C2O4^2--NH3-NH4^＋-H2O system at ambient temperature were deduced. The...According to the principles of simultaneous equilibrium and mass equilibrium, a series of thermodynamic equilibrium equations in Ni（II）-Co（II）-C2O4^2--NH3-NH4^＋-H2O system at ambient temperature were deduced. The diagrams of logarithm ion concentrations versus pH values at different solution compositions were drawn. The results show that Ni^2＋ and Co^2＋ can completely precipitate at pH less than 5.0 and the predefined Ni/Co ratios can be well kept in the precursor. The precursor morphology is granular aggregation. However, rod aggregation precursor is obtained in the pH range of 5.0-8.0, and fibre-shape precursor is got at pH value higher than 8.0. The Ni/Co ratios in the above two precursors are not reproduced as that in the feed due to the formhtion of multi-coordinated Ni（NH3）n^2＋ and Co（NH3）n^2＋ （n=1-6）. Modification of precipitation medium is favorable for the precursors to keep the predefined Ni/Co ratios of the feed in the pH range of 2.0-8.6. Meanwhile, the precursors with fibrous morphology can be obtained.展开更多
In view of the relative positioning problem between non-regular quadrilateral grids and regular rectangle grid nodes in the wave front construction method, concrete realization problems with four grid positioning meth...In view of the relative positioning problem between non-regular quadrilateral grids and regular rectangle grid nodes in the wave front construction method, concrete realization problems with four grid positioning methods （vector cross product judgment, angle sum, intersection-point, and signs comparison algorithms） in wave front construction which are commonly used in computer graphics are compared and analyzed in this paper. Based on the stability analysis of the location method, the calculation examples show that the vector cross product judgment method is faster and more accurate than other methods in the realization of the relative positioning between non-regular quadrilateral grids and regular rectangle grid nodes in wave front construction. It provides precise grid point attribute values for the next steps of migration and demigration.展开更多
基金Project (20090162120080) supported by Research Fund for the Doctoral Program of Higher Education of China Project (20070410989) supported by China Postdoctoral Science Foundation+1 种基金 Project (2010FJ3012) supported by the Program of Science and Technology of Hunan Province, China Project (09JJ4028) supported by Natural Science Foundation of Hunan Province, China
文摘According to the principles of simultaneous equilibrium and mass equilibrium, a series of thermodynamic equilibrium equations in Ni（II）-Co（II）-C2O4^2--NH3-NH4^＋-H2O system at ambient temperature were deduced. The diagrams of logarithm ion concentrations versus pH values at different solution compositions were drawn. The results show that Ni^2＋ and Co^2＋ can completely precipitate at pH less than 5.0 and the predefined Ni/Co ratios can be well kept in the precursor. The precursor morphology is granular aggregation. However, rod aggregation precursor is obtained in the pH range of 5.0-8.0, and fibre-shape precursor is got at pH value higher than 8.0. The Ni/Co ratios in the above two precursors are not reproduced as that in the feed due to the formhtion of multi-coordinated Ni（NH3）n^2＋ and Co（NH3）n^2＋ （n=1-6）. Modification of precipitation medium is favorable for the precursors to keep the predefined Ni/Co ratios of the feed in the pH range of 2.0-8.6. Meanwhile, the precursors with fibrous morphology can be obtained.
基金This research work is supported by the Projects of National Science Foundation of China （Grant No, 40574052 and 40437018） and National Basic Research Program of China （973 Program） （Grant No. 2007CB209603）.Acknowledgements We wish to thank Researcher Xu Tao for his advice and comment. We also thank Mrs. Wang Kun for her help in the process of translation.
文摘In view of the relative positioning problem between non-regular quadrilateral grids and regular rectangle grid nodes in the wave front construction method, concrete realization problems with four grid positioning methods （vector cross product judgment, angle sum, intersection-point, and signs comparison algorithms） in wave front construction which are commonly used in computer graphics are compared and analyzed in this paper. Based on the stability analysis of the location method, the calculation examples show that the vector cross product judgment method is faster and more accurate than other methods in the realization of the relative positioning between non-regular quadrilateral grids and regular rectangle grid nodes in wave front construction. It provides precise grid point attribute values for the next steps of migration and demigration.
