司家营条带状含铁建造(Banded iron formation,BIF)型铁矿床是冀东地区规模最大的铁矿床,前人对其进行了大量的年代学、岩石学和元素地球化学工作,但目前尚未对其进行Fe同位素研究。笔者等通过Fe同位素和主微量、稀土元素相结合的方法...司家营条带状含铁建造(Banded iron formation,BIF)型铁矿床是冀东地区规模最大的铁矿床,前人对其进行了大量的年代学、岩石学和元素地球化学工作,但目前尚未对其进行Fe同位素研究。笔者等通过Fe同位素和主微量、稀土元素相结合的方法对司家营BIF的成矿物质来源和形成背景提出了有效制约,同时对司家营BIF的锆石U-Pb年龄数据进行补充。锆石U-Pb年代学显示,司家营BIF形成于2537~2531 Ma。地球化学数据显示司家营BIF矿石主要由TFe_(2)O_(3)和SiO_(2)组成,具有较低的Al_(2)O_(3)和TiO_(2)含量,富集Fe重同位素(δ^(56)Fe=0.341‰~0.525‰);稀土元素配分模式呈现轻稀土亏损、重稀土富集的特征,具有明显的Eu、Y、La正异常,Y/Ho值较高(Y/Ho=34.96~45.84)。这些特征表明司家营BIF是基本无碎屑物质参与的化学沉积岩,稀土元素来源于高温热液和海水的混合溶液,铁质来源于海相热液流体。司家营BIF缺乏真正的Ce负异常和Fe同位素组成均为正值指示其形成于缺氧环境。综合对比世界上其他地区太古宙BIF的Fe同位素特征,笔者等认为新太古代时期地球海洋含氧量逐步上升,此时海洋总体属于缺氧环境,但部分地区氧气含量较高。展开更多
Graphites which occur in the Early Precambrian banded iron formation (BIF)(3.1×10^9 yr, Algoma type) at Gongchangling, Anshan, China can be divided into two genetie types on the basis of their modes of occurrence...Graphites which occur in the Early Precambrian banded iron formation (BIF)(3.1×10^9 yr, Algoma type) at Gongchangling, Anshan, China can be divided into two genetie types on the basis of their modes of occurrence: biogenic and inorganic; the former occurs in garnet-mica-quartz schist and the latter in rich magnetite ore. The garnet-mica-quartz schist is located at the bottom of the formation. Its original rock is a volcanic tuff-bearing clayey siltstone. Graphite disseminates fairly uniformly in the schist. Chemical analysis of 20 samples of graphite yields an average content of 0.29±0.22%. The average δ^13C value of 4 samples is -26.6±0.6‰ (PDB). Rich magnetite ore bodies occur in the form of lens and layer within the banded magnetite quartzite, and wall-rock alteration is also noticed. Graphite-bearing rich magnetite ore is composed of magnetite, maghemite and minor graphite. Late chlorite and siderite are recognized locally. Disseminated graphite is generally distributed in scaly aggregates interstitial to the grains of magnetite, occasionally found within the grains of magnetite. It is non-uniformly distributed in the horizon of shoot, mainly in the core of the shoot. No graphite is found in the outer part of the shoot, poor ore in the same horizon, wallrock near the shoot and altered rock, indicating that graphite has a great bearing on the shoot. Chemical analysis of 15 samples gives an average graphite content of 0.89±0.51%. The average δ^23C value of 18 samples is-4.7±2.1‰(PDB). This kind of graphite seems to have been formed by the following reaction:6 FeCO3=2 Fe3O4+5 CO2+C in the primary sedimentary siderite under condition of amphibole-facies regional metamorphism.展开更多
文摘司家营条带状含铁建造(Banded iron formation,BIF)型铁矿床是冀东地区规模最大的铁矿床,前人对其进行了大量的年代学、岩石学和元素地球化学工作,但目前尚未对其进行Fe同位素研究。笔者等通过Fe同位素和主微量、稀土元素相结合的方法对司家营BIF的成矿物质来源和形成背景提出了有效制约,同时对司家营BIF的锆石U-Pb年龄数据进行补充。锆石U-Pb年代学显示,司家营BIF形成于2537~2531 Ma。地球化学数据显示司家营BIF矿石主要由TFe_(2)O_(3)和SiO_(2)组成,具有较低的Al_(2)O_(3)和TiO_(2)含量,富集Fe重同位素(δ^(56)Fe=0.341‰~0.525‰);稀土元素配分模式呈现轻稀土亏损、重稀土富集的特征,具有明显的Eu、Y、La正异常,Y/Ho值较高(Y/Ho=34.96~45.84)。这些特征表明司家营BIF是基本无碎屑物质参与的化学沉积岩,稀土元素来源于高温热液和海水的混合溶液,铁质来源于海相热液流体。司家营BIF缺乏真正的Ce负异常和Fe同位素组成均为正值指示其形成于缺氧环境。综合对比世界上其他地区太古宙BIF的Fe同位素特征,笔者等认为新太古代时期地球海洋含氧量逐步上升,此时海洋总体属于缺氧环境,但部分地区氧气含量较高。
文摘Graphites which occur in the Early Precambrian banded iron formation (BIF)(3.1×10^9 yr, Algoma type) at Gongchangling, Anshan, China can be divided into two genetie types on the basis of their modes of occurrence: biogenic and inorganic; the former occurs in garnet-mica-quartz schist and the latter in rich magnetite ore. The garnet-mica-quartz schist is located at the bottom of the formation. Its original rock is a volcanic tuff-bearing clayey siltstone. Graphite disseminates fairly uniformly in the schist. Chemical analysis of 20 samples of graphite yields an average content of 0.29±0.22%. The average δ^13C value of 4 samples is -26.6±0.6‰ (PDB). Rich magnetite ore bodies occur in the form of lens and layer within the banded magnetite quartzite, and wall-rock alteration is also noticed. Graphite-bearing rich magnetite ore is composed of magnetite, maghemite and minor graphite. Late chlorite and siderite are recognized locally. Disseminated graphite is generally distributed in scaly aggregates interstitial to the grains of magnetite, occasionally found within the grains of magnetite. It is non-uniformly distributed in the horizon of shoot, mainly in the core of the shoot. No graphite is found in the outer part of the shoot, poor ore in the same horizon, wallrock near the shoot and altered rock, indicating that graphite has a great bearing on the shoot. Chemical analysis of 15 samples gives an average graphite content of 0.89±0.51%. The average δ^23C value of 18 samples is-4.7±2.1‰(PDB). This kind of graphite seems to have been formed by the following reaction:6 FeCO3=2 Fe3O4+5 CO2+C in the primary sedimentary siderite under condition of amphibole-facies regional metamorphism.
