Although rare earth elements(REEs)in magmatic zircons have been widely used to identify the type and compositional evolution of host rocks,REE distribution patterns during the chemical alteration of zircons need clari...Although rare earth elements(REEs)in magmatic zircons have been widely used to identify the type and compositional evolution of host rocks,REE distribution patterns during the chemical alteration of zircons need clarification.We investigated REE characteristics in zircons with different degrees of chemical weathering through systematic observation of a granodiorite-weathering profile in southeast China.Despite the relatively stable provenance of the studied profile(zircon U–Pb ages are95.2±4.8 Ma),the zircon REEs exhibited systematic differences in abundance and fractionation patterns from the bedrock to upper layers,e.g.∑PREE,(LREE/HREE)_(CN),and Ce/Ce*.This evidence suggests chemical alteration of zircons during intensive chemical weathering and an expected influence on REE variability in the weathered products due to the presence of REE-bearing minerals.展开更多
基金supported by National Natural Science Foundation of China(No.41506058)Open Financial Grant from Qingdao National Laboratory for Marine Science and Technology(No.QNLM2016ORP0211)State Key Laboratory of Marine Geology,Tongji University(No.MG20170402)
文摘Although rare earth elements(REEs)in magmatic zircons have been widely used to identify the type and compositional evolution of host rocks,REE distribution patterns during the chemical alteration of zircons need clarification.We investigated REE characteristics in zircons with different degrees of chemical weathering through systematic observation of a granodiorite-weathering profile in southeast China.Despite the relatively stable provenance of the studied profile(zircon U–Pb ages are95.2±4.8 Ma),the zircon REEs exhibited systematic differences in abundance and fractionation patterns from the bedrock to upper layers,e.g.∑PREE,(LREE/HREE)_(CN),and Ce/Ce*.This evidence suggests chemical alteration of zircons during intensive chemical weathering and an expected influence on REE variability in the weathered products due to the presence of REE-bearing minerals.
