The by products from the dehydration of exo 2 camphanol in the camphor manufacture by hydration process contains two unknown components: A in 14% and B in 15%. The sample mixture containing 90% A and B with different ...The by products from the dehydration of exo 2 camphanol in the camphor manufacture by hydration process contains two unknown components: A in 14% and B in 15%. The sample mixture containing 90% A and B with different mass ratio(ca. 1∶1, 1∶2 and 1∶4) were collected by further fine fractional distillation with 60 plate number for spectroscopic characterization. The combined spectral results of GC, MS and 13 C NMR of the samples revealed that A is exo 2,2,3 trimethylbicyclo[2,2,1]heptane(exo isocamphane) and B is endo 2,2,3 trimethylbicyclo[2,2,1]heptane(endo isocomphane).展开更多
As a kind of low-cost and readily available industrial byproduct, ethylene tar （ET） was for the first time utilized for the preparation of heat-resistant condensed polynuclear aromatic resin （COPNAR）. The basic pr...As a kind of low-cost and readily available industrial byproduct, ethylene tar （ET） was for the first time utilized for the preparation of heat-resistant condensed polynuclear aromatic resin （COPNAR）. The basic properties of ET and the resulted COPNAR were characterized by FT-IR, IH-NMR, TGA and elemental analysis. The test results showed that ET with high aromatic content （〉50%） was suitable for the synthesis of COPNAR with superior heat resistance. The average molecular structure of ET was obtained by means of the improved Brown-Ladner method, and the reaction mechanism was considered as an acid-catalyzed positive ion-typed polymerization. Our findings have provided a new route to develop ET into technology-added heat-resistant resins.展开更多
Transesterification is the most common production process for biodiesel. From this reaction, a glycerin phase is produced that is impure, thus lowering market value. However, because it is rich in carbon, it is an alt...Transesterification is the most common production process for biodiesel. From this reaction, a glycerin phase is produced that is impure, thus lowering market value. However, because it is rich in carbon, it is an alternative for generating bioproducts with a higher added value through bioconversion by microorganisms. The aim of this study was to screen parameters, such as pH （4, 5, 6, 7 and 8） and the initial glycerol concentration at 30 ± ℃ with agitation at 150 rpm for bioemulsifier and lipid synthesis in a submerged medium by Yarrowia lipolytica IMUFRJ 50678 from crude glycerin. The best conditions for bioemulsifier production were 30 ± ℃ at pH： 6 with 50 g/L of initial substrate, which produced 2.7 g/L of lipids, from which the optimum 300.5 mg/L of triglycerides was produced over 48 h of microorganism growth.展开更多
文摘The by products from the dehydration of exo 2 camphanol in the camphor manufacture by hydration process contains two unknown components: A in 14% and B in 15%. The sample mixture containing 90% A and B with different mass ratio(ca. 1∶1, 1∶2 and 1∶4) were collected by further fine fractional distillation with 60 plate number for spectroscopic characterization. The combined spectral results of GC, MS and 13 C NMR of the samples revealed that A is exo 2,2,3 trimethylbicyclo[2,2,1]heptane(exo isocamphane) and B is endo 2,2,3 trimethylbicyclo[2,2,1]heptane(endo isocomphane).
基金supported by the Program for New Century Excellent Talents in University, China Ministry of Education, 2009 (No. NCET-10-0768)the National Natural Science Foundation of China (Nos. 20876176 and 51172285)the Natural Science Foundation of Shandong Province (ZR2011EL031, ZR2011EL030)
文摘As a kind of low-cost and readily available industrial byproduct, ethylene tar （ET） was for the first time utilized for the preparation of heat-resistant condensed polynuclear aromatic resin （COPNAR）. The basic properties of ET and the resulted COPNAR were characterized by FT-IR, IH-NMR, TGA and elemental analysis. The test results showed that ET with high aromatic content （〉50%） was suitable for the synthesis of COPNAR with superior heat resistance. The average molecular structure of ET was obtained by means of the improved Brown-Ladner method, and the reaction mechanism was considered as an acid-catalyzed positive ion-typed polymerization. Our findings have provided a new route to develop ET into technology-added heat-resistant resins.
文摘Transesterification is the most common production process for biodiesel. From this reaction, a glycerin phase is produced that is impure, thus lowering market value. However, because it is rich in carbon, it is an alternative for generating bioproducts with a higher added value through bioconversion by microorganisms. The aim of this study was to screen parameters, such as pH （4, 5, 6, 7 and 8） and the initial glycerol concentration at 30 ± ℃ with agitation at 150 rpm for bioemulsifier and lipid synthesis in a submerged medium by Yarrowia lipolytica IMUFRJ 50678 from crude glycerin. The best conditions for bioemulsifier production were 30 ± ℃ at pH： 6 with 50 g/L of initial substrate, which produced 2.7 g/L of lipids, from which the optimum 300.5 mg/L of triglycerides was produced over 48 h of microorganism growth.
