We study the time evolution of two two-state systems (two qubits) initially in the pure entangled states or the maximally entangled mixed states interacting with the individual environmental noise. It is shown that ...We study the time evolution of two two-state systems (two qubits) initially in the pure entangled states or the maximally entangled mixed states interacting with the individual environmental noise. It is shown that due to environment noise, all quantum entangled states are very fragile and become a classical mixed state in a short-time limit. But the environment can affect entanglement in very different ways. The type of decoherence process for certain entangled states belongs to amplitude damping, while the others belong to dephasing decoherenee.展开更多
The development of non‐precious metal catalysts that facilitate the oxygen evolution reaction(OER)is important for the widespread application of hydrogen production by water splitting.Various perovskite oxides have b...The development of non‐precious metal catalysts that facilitate the oxygen evolution reaction(OER)is important for the widespread application of hydrogen production by water splitting.Various perovskite oxides have been employed as active OER catalysts,however,the underlying mechanism that occurs at the catalyst‐electrolyte interface is still not well understood,prohibiting the design and preparation of advanced OER catalysts.Here,we report a systematic investigation into the effect of proton dynamics on the catalyst‐electrolyte interfaces of four perovskite catalysts:La_(0.5)Sr_(0.5)CoO_(3‐δ)(LSCO),LaCoO_(3),LaFeO_(3),and LaNiO_(3).The pH‐dependent OER activities,H/D kinetic isotope effect,and surface functionalization with phosphate anion groups were investigated to elucidate the role of proton dynamics in the rate‐limiting steps of the OER.For oxides with small charge‐transfer energies,such as LSCO and LaNiO_(3),non‐concerted proton‐coupled electron transfer steps are involved in the OER,and the activity is strongly controlled by the proton dynamics on the catalyst surface.The results demonstrate the important role of interfacial proton transfer in the OER mechanism,and suggest that proton dynamics at the interface should carefully be considered in the design of future high‐performance catalysts.展开更多
A fully coupled 6-degree-of-freedom nonlinear dynamic model is presented to analyze the dynamic response of a semi-submersible platform which is equipped with the dynamic positioning(DP) system. In the control force d...A fully coupled 6-degree-of-freedom nonlinear dynamic model is presented to analyze the dynamic response of a semi-submersible platform which is equipped with the dynamic positioning(DP) system. In the control force design, a dynamic model of reference linear drift frequency in the horizontal plane is introduced. The dynamic surface control(DSC) is used to design a control strategy for the DP. Compared with the traditional back-stepping methods, the dynamic surface control combined with radial basis function(RBF) neural networks(NNs) can avoid differentiating intermediate variables repeatedly in every design step due to the introduction of a first order filter. Low frequency motions obtained from total motions by a low pass filter are chosen to be the inputs for the RBF NNs which are used to approximate the low frequency wave force. Considering the propellers' wear and tear, the effect of filtering frequencies for the control force is discussed. Based on power consumptions and positioning requirements, the NN centers are determined. Moreover, the RBF NNs used to approximate the total wave force are built to monitor the disturbances. With the DP assistance, the results of fully coupled dynamic response simulations are given to illustrate the effectiveness of the proposed control strategy.展开更多
The synchronous tracking control problem of a hydraulic parallel manipulator with six degrees of freedom (DOF) is complicated since the inclusion of hydraulic elements increases the order of the system.To solve this p...The synchronous tracking control problem of a hydraulic parallel manipulator with six degrees of freedom (DOF) is complicated since the inclusion of hydraulic elements increases the order of the system.To solve this problem,cascade control method with an inner/outer-loop control structure is used,which masks the hydraulic dynamics with the inner-loop so that the designed controller takes into account of both the mechanical dynamics and the hydraulic dynamics of the manipulator.Furthermore,a cross-coupling control approach is introduced to the synchronous tracking control of the manipulator.The position synchronization error is developed by considering motion synchronization between each actuator joint and its adjacent ones based on the synchronous goal.Then,with the feedback of both position error and synchronization error,the tracking is proven to guarantee that both the position errors and synchronization errors asymptotically converge to zero.Moreover,the effectiveness of the proposed approach is verified by the experimental results performed with a 6-DOF hydraulic parallel manipulator.展开更多
We investigate the entanglement dynamics of a quantum system consisting of three superconducting charge qubits (SCQs) interacting with a microwave field. For separable and entangled states of the SCQs, the evolution...We investigate the entanglement dynamics of a quantum system consisting of three superconducting charge qubits (SCQs) interacting with a microwave field. For separable and entangled states of the SCQs, the evolutions are studied under various photon numbers of cavity field. The results show that the amplitude and period of the bipartite entanglement square concurrences can be controlled by the choice of initial states of SCQs and photon number of cavity field, respectively. This simple model of a quantum register allows us to understand the dynamic process of the quantum storage of information carried by charge qubit.展开更多
A hybrid quantum architecture was proposed to engineer a localization-delocalization phase transition of light in a two-dimension square lattices of superconducting coplanar waveguide resonators,which are interconnect...A hybrid quantum architecture was proposed to engineer a localization-delocalization phase transition of light in a two-dimension square lattices of superconducting coplanar waveguide resonators,which are interconnected by current-biased Josephson junction phase qubits.We find that the competition between the on-site repulsion and the nonlocal photonic hopping leads to the Mott insulator-superfluid transition.By using the mean-field approach and the quantum master equation,the phase boundary between these two different phases could be obtained when the dissipative effects of superconducting resonators and phase qubit are considered.The good tunability of the effective on-site repulsion and photon-hopping strengths enable quantum simulation on condensed matter physics and many-body models using such a superconducting resonator lattice system.The experimental feasibility is discussed using the currently available technology in the circuit QED.展开更多
基金supported by the National Natural Science Foundation of China under Grant No. 10374007
文摘We study the time evolution of two two-state systems (two qubits) initially in the pure entangled states or the maximally entangled mixed states interacting with the individual environmental noise. It is shown that due to environment noise, all quantum entangled states are very fragile and become a classical mixed state in a short-time limit. But the environment can affect entanglement in very different ways. The type of decoherence process for certain entangled states belongs to amplitude damping, while the others belong to dephasing decoherenee.
文摘The development of non‐precious metal catalysts that facilitate the oxygen evolution reaction(OER)is important for the widespread application of hydrogen production by water splitting.Various perovskite oxides have been employed as active OER catalysts,however,the underlying mechanism that occurs at the catalyst‐electrolyte interface is still not well understood,prohibiting the design and preparation of advanced OER catalysts.Here,we report a systematic investigation into the effect of proton dynamics on the catalyst‐electrolyte interfaces of four perovskite catalysts:La_(0.5)Sr_(0.5)CoO_(3‐δ)(LSCO),LaCoO_(3),LaFeO_(3),and LaNiO_(3).The pH‐dependent OER activities,H/D kinetic isotope effect,and surface functionalization with phosphate anion groups were investigated to elucidate the role of proton dynamics in the rate‐limiting steps of the OER.For oxides with small charge‐transfer energies,such as LSCO and LaNiO_(3),non‐concerted proton‐coupled electron transfer steps are involved in the OER,and the activity is strongly controlled by the proton dynamics on the catalyst surface.The results demonstrate the important role of interfacial proton transfer in the OER mechanism,and suggest that proton dynamics at the interface should carefully be considered in the design of future high‐performance catalysts.
基金funded by the National Basic Research Program of China (Grant Nos. 2011CB013702 and 2011CB013703)the Science Fund for Creative Research Groups of the National Natural Science Foundation of China (Grant No. 50921001)
文摘A fully coupled 6-degree-of-freedom nonlinear dynamic model is presented to analyze the dynamic response of a semi-submersible platform which is equipped with the dynamic positioning(DP) system. In the control force design, a dynamic model of reference linear drift frequency in the horizontal plane is introduced. The dynamic surface control(DSC) is used to design a control strategy for the DP. Compared with the traditional back-stepping methods, the dynamic surface control combined with radial basis function(RBF) neural networks(NNs) can avoid differentiating intermediate variables repeatedly in every design step due to the introduction of a first order filter. Low frequency motions obtained from total motions by a low pass filter are chosen to be the inputs for the RBF NNs which are used to approximate the low frequency wave force. Considering the propellers' wear and tear, the effect of filtering frequencies for the control force is discussed. Based on power consumptions and positioning requirements, the NN centers are determined. Moreover, the RBF NNs used to approximate the total wave force are built to monitor the disturbances. With the DP assistance, the results of fully coupled dynamic response simulations are given to illustrate the effectiveness of the proposed control strategy.
基金Project(50375139) supported by the National Natural Science Foundation of ChinaProject(NCET-04-0545) supported by the New Century Excellent Talent Plan of the Ministry of Education of China
文摘The synchronous tracking control problem of a hydraulic parallel manipulator with six degrees of freedom (DOF) is complicated since the inclusion of hydraulic elements increases the order of the system.To solve this problem,cascade control method with an inner/outer-loop control structure is used,which masks the hydraulic dynamics with the inner-loop so that the designed controller takes into account of both the mechanical dynamics and the hydraulic dynamics of the manipulator.Furthermore,a cross-coupling control approach is introduced to the synchronous tracking control of the manipulator.The position synchronization error is developed by considering motion synchronization between each actuator joint and its adjacent ones based on the synchronous goal.Then,with the feedback of both position error and synchronization error,the tracking is proven to guarantee that both the position errors and synchronization errors asymptotically converge to zero.Moreover,the effectiveness of the proposed approach is verified by the experimental results performed with a 6-DOF hydraulic parallel manipulator.
基金Supported by State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics of Chinese Academy of Sciences under Grant No.T152908Hunan Provincial Natural Science Foundation of China under Grant No.10JJ6010+1 种基金the Key Project Foundation of Hunan Provincial Education Department,China under Grant No.10A095Science Research Foundation of Jishou University of China under Grant No.10JDY034
文摘We investigate the entanglement dynamics of a quantum system consisting of three superconducting charge qubits (SCQs) interacting with a microwave field. For separable and entangled states of the SCQs, the evolutions are studied under various photon numbers of cavity field. The results show that the amplitude and period of the bipartite entanglement square concurrences can be controlled by the choice of initial states of SCQs and photon number of cavity field, respectively. This simple model of a quantum register allows us to understand the dynamic process of the quantum storage of information carried by charge qubit.
基金supported by the National Science Foundation of China(Grant Nos.11372122,10874122 and 11074070)the Program for Excellent Talents at the University of Guangdong Province(Guangdong Teacher Letter[1010]No.79)
文摘A hybrid quantum architecture was proposed to engineer a localization-delocalization phase transition of light in a two-dimension square lattices of superconducting coplanar waveguide resonators,which are interconnected by current-biased Josephson junction phase qubits.We find that the competition between the on-site repulsion and the nonlocal photonic hopping leads to the Mott insulator-superfluid transition.By using the mean-field approach and the quantum master equation,the phase boundary between these two different phases could be obtained when the dissipative effects of superconducting resonators and phase qubit are considered.The good tunability of the effective on-site repulsion and photon-hopping strengths enable quantum simulation on condensed matter physics and many-body models using such a superconducting resonator lattice system.The experimental feasibility is discussed using the currently available technology in the circuit QED.