Levulinic acid is considered as a promising green platform chemical derived from biomass.The kinetics of levulinic acid accumulation in the hydrolysis process of wheat straw was investigated in the study.Using dilute ...Levulinic acid is considered as a promising green platform chemical derived from biomass.The kinetics of levulinic acid accumulation in the hydrolysis process of wheat straw was investigated in the study.Using dilute sulfuric acid as a catalyst,the kinetic experiments were performed in a temperature range of 190-230°C and an acid concentration range of 1%-5% (by mass) .A simple model of first-order series reactions was developed,which provided a satisfactory interpretation of the experimental results.The kinetics of main intermediates including sugar and 5-hydroxymethylfurfural(5-HMF) were also established.The kinetic parameters provided useful information for understanding the hydrolysis process.展开更多
Based on the fact that the house dust usually falls on the ground, the floor level slit exhaust ventilation system including inlet located at the ceiling and outlet of slit exhaust installed at comer between wall and ...Based on the fact that the house dust usually falls on the ground, the floor level slit exhaust ventilation system including inlet located at the ceiling and outlet of slit exhaust installed at comer between wall and floor was considered. Experiments and simulations were performed to investigate the flow and diffusion fields that are affected by this floor level slit exhaust ventilation system. The characteristics of airflow with experiments and computation fluid dynamics （CFD） are generally similar except airflow at the location of impinging flow and the location right below the inlet. Riboflavin particles were used as the house dust. For the spatial distribution of riboflavin particles in the ventilation system before operation, due to the influence of gravity, different sizes of particles show smooth decay curve. After floor level slit exhaust ventilation system is operated, the decay rate of the particles becomes faster than that after the ventilation system is powered on, and the particles with diameter of 0.5-3.0 μm in the experimental data and calculated values show good agreement.展开更多
基金Supported by the National Key Technology R&D Program of China (2007BAD66B04)
文摘Levulinic acid is considered as a promising green platform chemical derived from biomass.The kinetics of levulinic acid accumulation in the hydrolysis process of wheat straw was investigated in the study.Using dilute sulfuric acid as a catalyst,the kinetic experiments were performed in a temperature range of 190-230°C and an acid concentration range of 1%-5% (by mass) .A simple model of first-order series reactions was developed,which provided a satisfactory interpretation of the experimental results.The kinetics of main intermediates including sugar and 5-hydroxymethylfurfural(5-HMF) were also established.The kinetic parameters provided useful information for understanding the hydrolysis process.
基金Project supported by Ministry of Land, Infrastructure, Transport and Tourism of Japan Project(DUT10RC(3)103) supported by the Fundamental Research Funds for the Central Universities in China+2 种基金 Project(20111027) supported by the Liaoning Provincial Scientific Research Foundation, China Key Project (2012BAJ02B05) supported by the Twelfth Five-Year National Technology Program of China Project supported by Dalian Municipal Construction Technology Program, China
文摘Based on the fact that the house dust usually falls on the ground, the floor level slit exhaust ventilation system including inlet located at the ceiling and outlet of slit exhaust installed at comer between wall and floor was considered. Experiments and simulations were performed to investigate the flow and diffusion fields that are affected by this floor level slit exhaust ventilation system. The characteristics of airflow with experiments and computation fluid dynamics （CFD） are generally similar except airflow at the location of impinging flow and the location right below the inlet. Riboflavin particles were used as the house dust. For the spatial distribution of riboflavin particles in the ventilation system before operation, due to the influence of gravity, different sizes of particles show smooth decay curve. After floor level slit exhaust ventilation system is operated, the decay rate of the particles becomes faster than that after the ventilation system is powered on, and the particles with diameter of 0.5-3.0 μm in the experimental data and calculated values show good agreement.
