To extract the cable forces due to dead load in cable-stayed bridges from the monitoring data,the effects of various factors are eliminated step by step by different statistical methods.The information of cable tensio...To extract the cable forces due to dead load in cable-stayed bridges from the monitoring data,the effects of various factors are eliminated step by step by different statistical methods.The information of cable tension sensors recorded by the health monitoring system of Nanjing No.3 Yangtze River Bridge is taken as an example. Temperature effects are eliminated by linear fitting analysis;a 5-level wavelet de-noising method is applied to eliminate the noise signal by the wavelet basis function of DB8.The rest cable force data is tested by the method of extreme-value type-Ⅲ distribution, and the fitted location parameter is selected as the cable force due to dead load.The results show that the cable force has a linear relationship with temperature. Sometimes, the temperature effect is significant.Noise effect accounts for a small percentage,and the vehicle loads effect has twice the temperature effect on the traffic volume in 2007. The calculation results of other stay cables verify the reliability and validity of the proposed method.展开更多
Microstructures of creep-aged 2524 (A1-4.3Cu-1.5Mg) aged at 170 ℃ with various stresses (0, 173 and 250 MPa) were studied on a creep machine. Ageing hardness curves under various stresses were plotted and the cor...Microstructures of creep-aged 2524 (A1-4.3Cu-1.5Mg) aged at 170 ℃ with various stresses (0, 173 and 250 MPa) were studied on a creep machine. Ageing hardness curves under various stresses were plotted and the corresponding microstructures were characterized by transmission electron microscopy (TEM). The results show that the value of peak hardness is increased, while the time to reach the peak hardness is reduced under an external stress. Meanwhile, the length of S(Al2CuMg) phase is shorter and the number density of S phases is larger in the creep-aged alloy. The predominant contribution to the peak hardness can be ascribed to the GPB zones with an elastic stress.展开更多
Molecular dynamics (MD) simulations of monocrystalline copper (100) surface during nanomachining process were performed based on a new 3D simulation model. The material removal mechanism and system temperature dis...Molecular dynamics (MD) simulations of monocrystalline copper (100) surface during nanomachining process were performed based on a new 3D simulation model. The material removal mechanism and system temperature distribution were discussed. The simulation results indicate that the system temperature distribution presents a roughly concentric shape, a steep temperature gradient is observed in diamond cutting tool, and the highest temperature is located in chip. Centrosymmetry parameter method was used to monitor defect structures. Dislocations and vacancies are the two principal types of defect structures. Residual defect structures impose a major change on the workpiece physical properties and machined surface quality. The defect structures in workpiece are temperature dependent. As the temperature increases, the dislocations are mainly mediated from the workpiece surface, while the others are dissociated into point defects. The relatively high cutting speed used in nanomachining results in less defect structures, beneficial to obtain highly machined surface quality.展开更多
The degradation characteristics of both wide and narrow devices under V _g= V _d/2 stress mode is investigated.The width-enhanced device degradation can be seen with devices narrowing.The main degradation mechanism is...The degradation characteristics of both wide and narrow devices under V _g= V _d/2 stress mode is investigated.The width-enhanced device degradation can be seen with devices narrowing.The main degradation mechanism is interface state generation for pMOSFETs with different channel width.The cause of the width-enhanced device degradation is attributed to the combination of width-enhanced threshold voltage and series resistance.展开更多
To investigate the effects of thickness and grain size on mechanical and deformation properties of C5210 phosphor bronze thin sheets, samples with different grain sizes were obtained through annealing heat treatment a...To investigate the effects of thickness and grain size on mechanical and deformation properties of C5210 phosphor bronze thin sheets, samples with different grain sizes were obtained through annealing heat treatment at different temperatures; and then tensile tests of samples with different thicknesses and grain sizes were conducted at room temperature. The results show that yield strength increases with decreasing thickness from 800 to 50 μm, but work hardening exponent and total elongation decrease, and a modified model was proposed to describe the relation between yield strength and thickness; yield strength decreases as the grain size increases, but work hardening exponent shows an increasing trend, total elongation increases to a peak and then decreases. Fracture morphology of tensile specimens was observed by SEM, which indicates that all tensile specimens are ductile fracture. The dimple intensity increases as the specimen thickness increases but reduces with the specimen grain size increasing.展开更多
In the process of deep projects excavation,deep rock often experiences a full stress process from high stress to unloading and then to impact disturbance failure.To study the dynamic characteristics of three-dimension...In the process of deep projects excavation,deep rock often experiences a full stress process from high stress to unloading and then to impact disturbance failure.To study the dynamic characteristics of three-dimensional high stressed red sandstone subjected to unloading and impact loads,impact compression tests were conducted on red sandstone under confining pressure unloading conditions using a modified split Hopkinson pressure bar.Impact disturbance tests of uniaxial pre-stressed rock were also conducted(without considering confining pressure unloading effect).The results demonstrate that the impact compression strength of red sandstone shows an obvious strain rate effect.With an approximately equal strain rate,the dynamic strength of red sandstone under confining unloading conditions is less than that in the uniaxial pre-stressed impact compression test.Confining pressure unloading produces a strength-weakening effect,and the dynamic strength weakening factor(DSWF)is also defined.The results also indicate that the strain rate of the rock and the incident energy change in a logarithmic relation.With similar incident energies,unloading results in a higher strain rate in pre-stressed rock.According to the experimental analysis,unloading does not affect the failure mode,but reduces the dynamic strength of pre-stressed rock.The influence of confining pressure unloading on the shear strength parameters(cohesion and friction angle)is discussed.Under the same external energy impact compression,prestressed rock subjected to unloading is more likely to be destroyed.Thus,the effect of unloading on the rock mechanical characteristics should be considered in deep rock project excavation design.展开更多
First-principles based calculations were carried out to explore the possible mechanisms of stress/strain aging in Al alloys. Potential effects of temperature and external stress/strain were evaluated on the solvus bou...First-principles based calculations were carried out to explore the possible mechanisms of stress/strain aging in Al alloys. Potential effects of temperature and external stress/strain were evaluated on the solvus boundary of Al3Se in Al-Sc alloy, and the interface energy of Al/θ" in Al-Cu alloys. Results show that applying tensile strain/stress during conventional aging can significantly decrease the solubility entropy, by red-shifting the phonon DOS at high states. The resulted solvus boundary would shift up on the phase diagram, suggesting a reduced solubility limit and an increased maximum possible precipitation volume of AlaSc in Al-Sc alloy. Moreover, the applied strain/stress has different impacts on the formation energies of different orientated Al/θ" interfaces in Al-Cu alloys, which can be further exaggerated by the Poisson effect, and eventually affect the preferential precipitation orientation in Al-Cu alloy. Both mechanisms are expected to play important roles during stress/strain aging.展开更多
Crystal plasticity theory was used to simulate upsetting tests of different dimensions and grain size micro copper cylinders in this study on the fluctuant flow stress scale effect. Results showed that with the decrea...Crystal plasticity theory was used to simulate upsetting tests of different dimensions and grain size micro copper cylinders in this study on the fluctuant flow stress scale effect. Results showed that with the decrease of billet grain quantity, flow stress fluctuation is not always increased, but there is a maximum. Through this study, the fluctuant flow stress scale effect can be understood deeper, and relevant necessary information was obtained for further prediction and control of this scale effect and to design the microforming process and die.展开更多
Considering both the compaction effect of pile surrounding soil and the stress diffusion effect of pile end soil,this paper theoretically investigates the torsional vibration characteristics of tapered pile.Utilizing ...Considering both the compaction effect of pile surrounding soil and the stress diffusion effect of pile end soil,this paper theoretically investigates the torsional vibration characteristics of tapered pile.Utilizing the complex stiffness transfer model to simulate compaction effect and tapered fictitious soil pile model to simulate stress diffusion,the analytical solution for the torsional impedance at tapered pile top is obtained by virtue of Laplace transform technique and impedance transfer method.Based on the present solution,a parametric study is conducted to investigate the rationality of the present solution and the influence of soil and pile properties on the torsional vibration characteristics of tapered pile embedded in layered soil.The results show that,both the compaction effect and stress diffusion effect have significant influence on the torsional vibration characteristics of tapered pile,and these two factors should be considered during the dynamic design of pile foundation.展开更多
Crack is found to be a major distress that affects the performance of the epoxy asphalt pavement.An extended finite element method was proposed for investigating the fracture properties of the epoxy asphalt mixture.Fi...Crack is found to be a major distress that affects the performance of the epoxy asphalt pavement.An extended finite element method was proposed for investigating the fracture properties of the epoxy asphalt mixture.Firstly,the single-edge notched beam test was used to analyze the temperature effect and calculate the material parameters.Then,the mechanical responses were studied using numerical analysis.It is concluded that 5℃ can be selected as the critical temperature that affects the fracture properties,and numerical simulations indicate that crack propagation is found to significantly affect the stress state of the epoxy asphalt mixture.The maximum principal stress at the crack surface exhibits different trends at various temperatures.Numerical solution of stress intensity factor can well meet the theoretical solution,especially when the temperature is lower than 5℃.展开更多
The effect of temperature on the properties of boron adsorption-desorption in brown-red soil, yellowbrown soil and calcareous alluvial soil of Hubei Province was investigated with the mobile displacement technique. Th...The effect of temperature on the properties of boron adsorption-desorption in brown-red soil, yellowbrown soil and calcareous alluvial soil of Hubei Province was investigated with the mobile displacement technique. The experimental data of B adsorption-desorption amounts and reaction t line at 25 and 40℃ were fitted by the zero-order, first-order and parabolic diffusion kinetic equations. The adsorption process was in conformity with the parabolic diffusion law at both the temperatures, and the values of rate constant of the parabolic diffusion equation in B adsorption were 0.138, 0.124 and 0.105 mg kg-1 min-1/2 at 25℃, and 0.147, 0.146 and 0.135 mg kg-1 min-1/2 at 40℃ for the brown-red soil, yellow-brown soil, and calcareous alluvial soil, respectively. The relationship between amount of B desorption and reaction time could be well described by the first-order kinetic equation, and the corresponding values of rate constant were 0.0422, 0.0563 and 0.0384 min-1 at 25℃, and 0.0408, 0.042 3 and 0.0401 min-1 at 40℃ for the brown-red soil, the yellow-brown soil and the calcareous alluvial soil, respectively. Therefore, the desorption process of B might be related to the amount of B adsorbed in soil. The higher the temperature, the lower the amount of B adsorption for the same soil in the same reaction time. The values of the apparent activation energy of B adsorption in the three soils calculated with the rate constants of parabolic diffusion equation were 3.27, 8.44 and 12.99 kJ mol-1, respectively, based on the experimental data of B adsorption amounts and reaction time at 25 and 40℃.展开更多
This study aimed to elucidate the strength weakening effect of high static pre-stressed rocks subjected to low-frequency disturbances under uniaxial compression.Based on the uniaxial compressive strength(UCS)of granit...This study aimed to elucidate the strength weakening effect of high static pre-stressed rocks subjected to low-frequency disturbances under uniaxial compression.Based on the uniaxial compressive strength(UCS)of granite under static loading,70%,80%,and 90%of UCS were selected as the initial high static pre-stress(σ_(p)),and then the pre-stressed rock specimens were disturbed by sinusoidal stress with amplitudes of 30%,20%,and 10%of UCS under low-frequency frequencies(f)of 1,2,5,and 10 Hz,respectively.The results show that the rockburst failure of pre-stressed granite is caused by low-frequency disturbance,and the failure strength is much lower than UCS.When theσp or f is constant,the specimen strength gradually decreases as the f or σ_(p) increases.The experimental study illustrates the influence mechanism of the strength weakening effect of high static pre-stress rocks under low-frequency dynamic disturbance,that is,high static pre-stress is the premise and leading factor of rock strength weakening,while low-frequency dynamic disturbance induces rock failure and affects the strength weakening degree.展开更多
We report the investigation on the low-temperature oxidation of cyclohexane in a jet-stirred reactor over 500-742 K. Synchrotron vacuum ultraviolet photoionization mass spectrometry (SVUV-PIMS) was used for identify...We report the investigation on the low-temperature oxidation of cyclohexane in a jet-stirred reactor over 500-742 K. Synchrotron vacuum ultraviolet photoionization mass spectrometry (SVUV-PIMS) was used for identifying and quantifying the oxidation species. Major products, cyclic olefins, and oxygenated products including reactive hydroperoxides and high oxygen compounds were detected. Compared with n-alkanes, a narrow low-temperature window (-80 K) was observed in the low-temperature oxidation of cyclohexane. Besides, a kinetic model for cyclohexane oxidation was developed based on the CNRS model [Combust. Flame 160, 2319 (2013)], which can better capture the experimental results than previous models. Based on the modeling analysis, the 1,5-H shift dominates the crucial isomerization steps of the first and second O2 addition products in the low-temperature chain branching process of cyclohexane. The negative temperature coefficient behavior of cyclohexane oxidation results from the reduced chain branching due to the competition from chain inhibition and propagation reactions, i.e. the reaction between cyclohexyl radical and O2 and the de- composition of cyclohexylperoxy radical, both producing cyclohexene and HO2 radical, as well as the decomposition of cyclohexylhydroperoxy radical producing hex-5-en-l-al and OH radical.展开更多
Scale effect is one of the important aspects in the macro mechanical parame- ters’ research of rock mass, from a new point of view, by means of lab and field rock me- chanics test, establishment of E^Vp relation, cla...Scale effect is one of the important aspects in the macro mechanical parame- ters’ research of rock mass, from a new point of view, by means of lab and field rock me- chanics test, establishment of E^Vp relation, classification of engineering rock mass, nu- merical simulation test and back analysis based on surrounding rock’s displacement monitoring results of Shuibuya Project’s underground power station, rock mass deforma- tion module’s size effect of surrounding rock of Shuibuya Project’s undegroud power sta- tion was studied. It’s shown that rock mass deformation module’s scale effect of sur- rounding rock of Shuibuya Project’s undeground power station is obvious, the rock mass deformation module to tranquilization is 20% of intact rock’s. Finally the relation between rock mass deformation modules and the scale of research was established.展开更多
The semi-classical black hole tunneling radiation (Parikh-Wilczek tunneling proposal) is calculated undera minimal length uncertainty analysis.It is shown that,the generalized second law of thermodynamics may bound th...The semi-classical black hole tunneling radiation (Parikh-Wilczek tunneling proposal) is calculated undera minimal length uncertainty analysis.It is shown that,the generalized second law of thermodynamics may bound thetunneling probability radiation of a Reissner-Nordstrom black hole radiation.展开更多
In order to study the stability of friction and contact of the rotating tribological pair system,considering the influence of the changeable factors on the stability,the system dynamics analysis model based on the Lag...In order to study the stability of friction and contact of the rotating tribological pair system,considering the influence of the changeable factors on the stability,the system dynamics analysis model based on the Lagrange equation is firstly established.The surface contact stiffness model is determined on the basis of the fractal theory.The model of the friction torque with velocities is created by using the Stribeck friction effect.The Lyapunov indirect method is employed to explore the eigenvalue problem of the system state equation.The effects of the applied load,the fractal dimension,the fractal scaling coefficient and the Stribeck coefficient on the system stability are investigated in detail.The numerical simulation results demonstrate that the tribological pair system is prone to causing system instability at low speed,and the system instability boundary value decreases when the Stribeck coefficient decreases.The fractal dimension and the fractal scaling coefficient impact the system stability slightly when fractal dimensions are large,and the system instability can be reduced by properly increasing the surface smoothness.Moreover,the system instability evidently increases with the increase in the applied load and the Stribeck coefficient.These achievements can provide a reference and theoretical support for the analysis of the dynamic performance of the tribological pair system.展开更多
The commonly used Mohr-Coulomb(M-C) failure condition has a limitation that it overestimates the tensile strength of cohesive soils. To overcome this limitation, the tensile strength cut-off was applied where the pred...The commonly used Mohr-Coulomb(M-C) failure condition has a limitation that it overestimates the tensile strength of cohesive soils. To overcome this limitation, the tensile strength cut-off was applied where the predicted tensile strength is reduced or eliminated. This work then presented a kinematical approach to evaluate the active earth pressure on subgrade retaining walls in cohesive backfills with saturated seepage effects. An effective rotational failure mechanism was constructed assuming an associative flow rule. The impact of seepage forces, whose distribution is described by a closed-form solution, was incorporated into the analysis. The thrust of active earth pressure was derived from the energy conservation equation, and an optimization program was then coded to obtain the most critical solution. Several sets of charts were produced to perform a parameter analysis. The results show that taking soil cohesion into account has a distinct beneficial influence on the stability of retaining walls, while seepage forces have an adverse effect. The active earth pressure increases when tensile strength cut-off is considered, and this increment is more noticeable under larger cohesion.展开更多
基金The National Natural Science Foundation of China(No.51208096)the Major Scientific and Technological Special Project of Jiangsu Provincial Communications Department(No.2014Y02)
文摘To extract the cable forces due to dead load in cable-stayed bridges from the monitoring data,the effects of various factors are eliminated step by step by different statistical methods.The information of cable tension sensors recorded by the health monitoring system of Nanjing No.3 Yangtze River Bridge is taken as an example. Temperature effects are eliminated by linear fitting analysis;a 5-level wavelet de-noising method is applied to eliminate the noise signal by the wavelet basis function of DB8.The rest cable force data is tested by the method of extreme-value type-Ⅲ distribution, and the fitted location parameter is selected as the cable force due to dead load.The results show that the cable force has a linear relationship with temperature. Sometimes, the temperature effect is significant.Noise effect accounts for a small percentage,and the vehicle loads effect has twice the temperature effect on the traffic volume in 2007. The calculation results of other stay cables verify the reliability and validity of the proposed method.
基金Project (2009BAG12A07-B02) supported by the National Science & Technology Pillar Program during the 11th Five-Year Plan Period,ChinaProject supported by Innovative Research Team in University of Liaoning Province,ChinaProject (51001022) supported by the National Natural Science Foundation of China
文摘Microstructures of creep-aged 2524 (A1-4.3Cu-1.5Mg) aged at 170 ℃ with various stresses (0, 173 and 250 MPa) were studied on a creep machine. Ageing hardness curves under various stresses were plotted and the corresponding microstructures were characterized by transmission electron microscopy (TEM). The results show that the value of peak hardness is increased, while the time to reach the peak hardness is reduced under an external stress. Meanwhile, the length of S(Al2CuMg) phase is shorter and the number density of S phases is larger in the creep-aged alloy. The predominant contribution to the peak hardness can be ascribed to the GPB zones with an elastic stress.
基金Project (50925521) supported by the National Natural Science Fund for Distinguished Young Scholars of China
文摘Molecular dynamics (MD) simulations of monocrystalline copper (100) surface during nanomachining process were performed based on a new 3D simulation model. The material removal mechanism and system temperature distribution were discussed. The simulation results indicate that the system temperature distribution presents a roughly concentric shape, a steep temperature gradient is observed in diamond cutting tool, and the highest temperature is located in chip. Centrosymmetry parameter method was used to monitor defect structures. Dislocations and vacancies are the two principal types of defect structures. Residual defect structures impose a major change on the workpiece physical properties and machined surface quality. The defect structures in workpiece are temperature dependent. As the temperature increases, the dislocations are mainly mediated from the workpiece surface, while the others are dissociated into point defects. The relatively high cutting speed used in nanomachining results in less defect structures, beneficial to obtain highly machined surface quality.
文摘The degradation characteristics of both wide and narrow devices under V _g= V _d/2 stress mode is investigated.The width-enhanced device degradation can be seen with devices narrowing.The main degradation mechanism is interface state generation for pMOSFETs with different channel width.The cause of the width-enhanced device degradation is attributed to the combination of width-enhanced threshold voltage and series resistance.
文摘To investigate the effects of thickness and grain size on mechanical and deformation properties of C5210 phosphor bronze thin sheets, samples with different grain sizes were obtained through annealing heat treatment at different temperatures; and then tensile tests of samples with different thicknesses and grain sizes were conducted at room temperature. The results show that yield strength increases with decreasing thickness from 800 to 50 μm, but work hardening exponent and total elongation decrease, and a modified model was proposed to describe the relation between yield strength and thickness; yield strength decreases as the grain size increases, but work hardening exponent shows an increasing trend, total elongation increases to a peak and then decreases. Fracture morphology of tensile specimens was observed by SEM, which indicates that all tensile specimens are ductile fracture. The dimple intensity increases as the specimen thickness increases but reduces with the specimen grain size increasing.
基金Projects(42077244,41877272)supported by the National Natural Science Foundation of ChinaProject(2020-05)supported by the Open Research Fund of Guangdong Provincial Key Laboratory of Deep Earth Sciences and Geothermal Energy Exploitation and Utilization,China。
文摘In the process of deep projects excavation,deep rock often experiences a full stress process from high stress to unloading and then to impact disturbance failure.To study the dynamic characteristics of three-dimensional high stressed red sandstone subjected to unloading and impact loads,impact compression tests were conducted on red sandstone under confining pressure unloading conditions using a modified split Hopkinson pressure bar.Impact disturbance tests of uniaxial pre-stressed rock were also conducted(without considering confining pressure unloading effect).The results demonstrate that the impact compression strength of red sandstone shows an obvious strain rate effect.With an approximately equal strain rate,the dynamic strength of red sandstone under confining unloading conditions is less than that in the uniaxial pre-stressed impact compression test.Confining pressure unloading produces a strength-weakening effect,and the dynamic strength weakening factor(DSWF)is also defined.The results also indicate that the strain rate of the rock and the incident energy change in a logarithmic relation.With similar incident energies,unloading results in a higher strain rate in pre-stressed rock.According to the experimental analysis,unloading does not affect the failure mode,but reduces the dynamic strength of pre-stressed rock.The influence of confining pressure unloading on the shear strength parameters(cohesion and friction angle)is discussed.Under the same external energy impact compression,prestressed rock subjected to unloading is more likely to be destroyed.Thus,the effect of unloading on the rock mechanical characteristics should be considered in deep rock project excavation design.
基金Project(51171211)supported by the National Natural Science Foundation of ChinaProject(2014CB644001-2)supported by the National Basic Research Program of China
文摘First-principles based calculations were carried out to explore the possible mechanisms of stress/strain aging in Al alloys. Potential effects of temperature and external stress/strain were evaluated on the solvus boundary of Al3Se in Al-Sc alloy, and the interface energy of Al/θ" in Al-Cu alloys. Results show that applying tensile strain/stress during conventional aging can significantly decrease the solubility entropy, by red-shifting the phonon DOS at high states. The resulted solvus boundary would shift up on the phase diagram, suggesting a reduced solubility limit and an increased maximum possible precipitation volume of AlaSc in Al-Sc alloy. Moreover, the applied strain/stress has different impacts on the formation energies of different orientated Al/θ" interfaces in Al-Cu alloys, which can be further exaggerated by the Poisson effect, and eventually affect the preferential precipitation orientation in Al-Cu alloy. Both mechanisms are expected to play important roles during stress/strain aging.
文摘Crystal plasticity theory was used to simulate upsetting tests of different dimensions and grain size micro copper cylinders in this study on the fluctuant flow stress scale effect. Results showed that with the decrease of billet grain quantity, flow stress fluctuation is not always increased, but there is a maximum. Through this study, the fluctuant flow stress scale effect can be understood deeper, and relevant necessary information was obtained for further prediction and control of this scale effect and to design the microforming process and die.
基金Projects(51578164,51678547,51878634,51878185,41807262)supported by the National Natural Science Foundation of China。
文摘Considering both the compaction effect of pile surrounding soil and the stress diffusion effect of pile end soil,this paper theoretically investigates the torsional vibration characteristics of tapered pile.Utilizing the complex stiffness transfer model to simulate compaction effect and tapered fictitious soil pile model to simulate stress diffusion,the analytical solution for the torsional impedance at tapered pile top is obtained by virtue of Laplace transform technique and impedance transfer method.Based on the present solution,a parametric study is conducted to investigate the rationality of the present solution and the influence of soil and pile properties on the torsional vibration characteristics of tapered pile embedded in layered soil.The results show that,both the compaction effect and stress diffusion effect have significant influence on the torsional vibration characteristics of tapered pile,and these two factors should be considered during the dynamic design of pile foundation.
基金Project(50578038)supported by the National Natural Science Foundation of China
文摘Crack is found to be a major distress that affects the performance of the epoxy asphalt pavement.An extended finite element method was proposed for investigating the fracture properties of the epoxy asphalt mixture.Firstly,the single-edge notched beam test was used to analyze the temperature effect and calculate the material parameters.Then,the mechanical responses were studied using numerical analysis.It is concluded that 5℃ can be selected as the critical temperature that affects the fracture properties,and numerical simulations indicate that crack propagation is found to significantly affect the stress state of the epoxy asphalt mixture.The maximum principal stress at the crack surface exhibits different trends at various temperatures.Numerical solution of stress intensity factor can well meet the theoretical solution,especially when the temperature is lower than 5℃.
文摘The effect of temperature on the properties of boron adsorption-desorption in brown-red soil, yellowbrown soil and calcareous alluvial soil of Hubei Province was investigated with the mobile displacement technique. The experimental data of B adsorption-desorption amounts and reaction t line at 25 and 40℃ were fitted by the zero-order, first-order and parabolic diffusion kinetic equations. The adsorption process was in conformity with the parabolic diffusion law at both the temperatures, and the values of rate constant of the parabolic diffusion equation in B adsorption were 0.138, 0.124 and 0.105 mg kg-1 min-1/2 at 25℃, and 0.147, 0.146 and 0.135 mg kg-1 min-1/2 at 40℃ for the brown-red soil, yellow-brown soil, and calcareous alluvial soil, respectively. The relationship between amount of B desorption and reaction time could be well described by the first-order kinetic equation, and the corresponding values of rate constant were 0.0422, 0.0563 and 0.0384 min-1 at 25℃, and 0.0408, 0.042 3 and 0.0401 min-1 at 40℃ for the brown-red soil, the yellow-brown soil and the calcareous alluvial soil, respectively. Therefore, the desorption process of B might be related to the amount of B adsorbed in soil. The higher the temperature, the lower the amount of B adsorption for the same soil in the same reaction time. The values of the apparent activation energy of B adsorption in the three soils calculated with the rate constants of parabolic diffusion equation were 3.27, 8.44 and 12.99 kJ mol-1, respectively, based on the experimental data of B adsorption amounts and reaction time at 25 and 40℃.
基金financially supported by the National Natural Science Foundation of China (No.42077244)the Open Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering,Institute of Rock and Soil Mechanics,Chinese Academy of Sciences (No.Z020005)the Fundamental Research Funds for the Central Universities of Southeast University,China (No.2242021R10080)。
文摘This study aimed to elucidate the strength weakening effect of high static pre-stressed rocks subjected to low-frequency disturbances under uniaxial compression.Based on the uniaxial compressive strength(UCS)of granite under static loading,70%,80%,and 90%of UCS were selected as the initial high static pre-stress(σ_(p)),and then the pre-stressed rock specimens were disturbed by sinusoidal stress with amplitudes of 30%,20%,and 10%of UCS under low-frequency frequencies(f)of 1,2,5,and 10 Hz,respectively.The results show that the rockburst failure of pre-stressed granite is caused by low-frequency disturbance,and the failure strength is much lower than UCS.When theσp or f is constant,the specimen strength gradually decreases as the f or σ_(p) increases.The experimental study illustrates the influence mechanism of the strength weakening effect of high static pre-stress rocks under low-frequency dynamic disturbance,that is,high static pre-stress is the premise and leading factor of rock strength weakening,while low-frequency dynamic disturbance induces rock failure and affects the strength weakening degree.
基金supported by the National Natural Science Foundation of China(No.91641205,No.51622605,No.91541201)the Shanghai Science and Technology Committee(No.17XD1402000)
文摘We report the investigation on the low-temperature oxidation of cyclohexane in a jet-stirred reactor over 500-742 K. Synchrotron vacuum ultraviolet photoionization mass spectrometry (SVUV-PIMS) was used for identifying and quantifying the oxidation species. Major products, cyclic olefins, and oxygenated products including reactive hydroperoxides and high oxygen compounds were detected. Compared with n-alkanes, a narrow low-temperature window (-80 K) was observed in the low-temperature oxidation of cyclohexane. Besides, a kinetic model for cyclohexane oxidation was developed based on the CNRS model [Combust. Flame 160, 2319 (2013)], which can better capture the experimental results than previous models. Based on the modeling analysis, the 1,5-H shift dominates the crucial isomerization steps of the first and second O2 addition products in the low-temperature chain branching process of cyclohexane. The negative temperature coefficient behavior of cyclohexane oxidation results from the reduced chain branching due to the competition from chain inhibition and propagation reactions, i.e. the reaction between cyclohexyl radical and O2 and the de- composition of cyclohexylperoxy radical, both producing cyclohexene and HO2 radical, as well as the decomposition of cyclohexylhydroperoxy radical producing hex-5-en-l-al and OH radical.
文摘Scale effect is one of the important aspects in the macro mechanical parame- ters’ research of rock mass, from a new point of view, by means of lab and field rock me- chanics test, establishment of E^Vp relation, classification of engineering rock mass, nu- merical simulation test and back analysis based on surrounding rock’s displacement monitoring results of Shuibuya Project’s underground power station, rock mass deforma- tion module’s size effect of surrounding rock of Shuibuya Project’s undegroud power sta- tion was studied. It’s shown that rock mass deformation module’s scale effect of sur- rounding rock of Shuibuya Project’s undeground power station is obvious, the rock mass deformation module to tranquilization is 20% of intact rock’s. Finally the relation between rock mass deformation modules and the scale of research was established.
文摘The semi-classical black hole tunneling radiation (Parikh-Wilczek tunneling proposal) is calculated undera minimal length uncertainty analysis.It is shown that,the generalized second law of thermodynamics may bound thetunneling probability radiation of a Reissner-Nordstrom black hole radiation.
基金The Science and Technology Support Program of Jiangsu Province(No.BE2014133)the Transformation Program of Scientific and Technological Achievements of Jiangsu Province(No.201701213).
文摘In order to study the stability of friction and contact of the rotating tribological pair system,considering the influence of the changeable factors on the stability,the system dynamics analysis model based on the Lagrange equation is firstly established.The surface contact stiffness model is determined on the basis of the fractal theory.The model of the friction torque with velocities is created by using the Stribeck friction effect.The Lyapunov indirect method is employed to explore the eigenvalue problem of the system state equation.The effects of the applied load,the fractal dimension,the fractal scaling coefficient and the Stribeck coefficient on the system stability are investigated in detail.The numerical simulation results demonstrate that the tribological pair system is prone to causing system instability at low speed,and the system instability boundary value decreases when the Stribeck coefficient decreases.The fractal dimension and the fractal scaling coefficient impact the system stability slightly when fractal dimensions are large,and the system instability can be reduced by properly increasing the surface smoothness.Moreover,the system instability evidently increases with the increase in the applied load and the Stribeck coefficient.These achievements can provide a reference and theoretical support for the analysis of the dynamic performance of the tribological pair system.
基金Projects(51538009,51674115,51804113) supported by the National Natural Science Foundation of China。
文摘The commonly used Mohr-Coulomb(M-C) failure condition has a limitation that it overestimates the tensile strength of cohesive soils. To overcome this limitation, the tensile strength cut-off was applied where the predicted tensile strength is reduced or eliminated. This work then presented a kinematical approach to evaluate the active earth pressure on subgrade retaining walls in cohesive backfills with saturated seepage effects. An effective rotational failure mechanism was constructed assuming an associative flow rule. The impact of seepage forces, whose distribution is described by a closed-form solution, was incorporated into the analysis. The thrust of active earth pressure was derived from the energy conservation equation, and an optimization program was then coded to obtain the most critical solution. Several sets of charts were produced to perform a parameter analysis. The results show that taking soil cohesion into account has a distinct beneficial influence on the stability of retaining walls, while seepage forces have an adverse effect. The active earth pressure increases when tensile strength cut-off is considered, and this increment is more noticeable under larger cohesion.