The development of non‐precious metal catalysts that facilitate the oxygen evolution reaction(OER)is important for the widespread application of hydrogen production by water splitting.Various perovskite oxides have b...The development of non‐precious metal catalysts that facilitate the oxygen evolution reaction(OER)is important for the widespread application of hydrogen production by water splitting.Various perovskite oxides have been employed as active OER catalysts,however,the underlying mechanism that occurs at the catalyst‐electrolyte interface is still not well understood,prohibiting the design and preparation of advanced OER catalysts.Here,we report a systematic investigation into the effect of proton dynamics on the catalyst‐electrolyte interfaces of four perovskite catalysts:La_(0.5)Sr_(0.5)CoO_(3‐δ)(LSCO),LaCoO_(3),LaFeO_(3),and LaNiO_(3).The pH‐dependent OER activities,H/D kinetic isotope effect,and surface functionalization with phosphate anion groups were investigated to elucidate the role of proton dynamics in the rate‐limiting steps of the OER.For oxides with small charge‐transfer energies,such as LSCO and LaNiO_(3),non‐concerted proton‐coupled electron transfer steps are involved in the OER,and the activity is strongly controlled by the proton dynamics on the catalyst surface.The results demonstrate the important role of interfacial proton transfer in the OER mechanism,and suggest that proton dynamics at the interface should carefully be considered in the design of future high‐performance catalysts.展开更多
This paper reports the piezoresistive effect of a resonant tunneling diode （RTD） in a microstructure. The fourbeam structure is analyzed and fabricated by positing RTDs at the stress sensitive regions. Stress along ...This paper reports the piezoresistive effect of a resonant tunneling diode （RTD） in a microstructure. The fourbeam structure is analyzed and fabricated by positing RTDs at the stress sensitive regions. Stress along the [110] orienta- tion and [110]ientation induces a change in the RTD＇s current-voltage （I-V） curves,i, e., the meso-piezoresistance variety,mainly in its negative different resistance （NDR） region. By different methods,the mechanic-electric coupling characteristic of RTD is studied and the consistent 10^9Pa^1 piezoresistive coefficients are discovered.展开更多
To analyze wind-induced response characteristics of a wind turbine tower more accurately, the blade-tower coupling effect was investigated. The mean wind velocity of the rotating blades and tower was simulated accordi...To analyze wind-induced response characteristics of a wind turbine tower more accurately, the blade-tower coupling effect was investigated. The mean wind velocity of the rotating blades and tower was simulated according to wind shear effects, and the fluctuating wind velocity time series of the wind turbine were simulated by a harmony superposition method. A dynamic finite element method (FEM) was used to calculate the wind-induced response of the blades and tower. Wind-induced responses of the tower were calculated in two cases (one included the blade-tower coupling effect, and the other only added the mass of blades and the hub at the top of the tower), and then the maximal displacements at the top of the tower of the tow cases were compared with each other. As a result of the influence of the blade-tower coupling effect and the total base shear of the blades, the maximal displacement of the first case increased nearly by 300% compared to the second case. To obtain more precise analysis, the blade-tower coupling effect and the total base shear of the blades should be considered simultaneously in the design of wind turbine towers.展开更多
文摘The development of non‐precious metal catalysts that facilitate the oxygen evolution reaction(OER)is important for the widespread application of hydrogen production by water splitting.Various perovskite oxides have been employed as active OER catalysts,however,the underlying mechanism that occurs at the catalyst‐electrolyte interface is still not well understood,prohibiting the design and preparation of advanced OER catalysts.Here,we report a systematic investigation into the effect of proton dynamics on the catalyst‐electrolyte interfaces of four perovskite catalysts:La_(0.5)Sr_(0.5)CoO_(3‐δ)(LSCO),LaCoO_(3),LaFeO_(3),and LaNiO_(3).The pH‐dependent OER activities,H/D kinetic isotope effect,and surface functionalization with phosphate anion groups were investigated to elucidate the role of proton dynamics in the rate‐limiting steps of the OER.For oxides with small charge‐transfer energies,such as LSCO and LaNiO_(3),non‐concerted proton‐coupled electron transfer steps are involved in the OER,and the activity is strongly controlled by the proton dynamics on the catalyst surface.The results demonstrate the important role of interfacial proton transfer in the OER mechanism,and suggest that proton dynamics at the interface should carefully be considered in the design of future high‐performance catalysts.
文摘This paper reports the piezoresistive effect of a resonant tunneling diode （RTD） in a microstructure. The fourbeam structure is analyzed and fabricated by positing RTDs at the stress sensitive regions. Stress along the [110] orienta- tion and [110]ientation induces a change in the RTD＇s current-voltage （I-V） curves,i, e., the meso-piezoresistance variety,mainly in its negative different resistance （NDR） region. By different methods,the mechanic-electric coupling characteristic of RTD is studied and the consistent 10^9Pa^1 piezoresistive coefficients are discovered.
基金supported by the National Natural Science Foundation of China (No. 50708015)the Program for New Century Excellent Talents in University (No. NCET-06-0270), China
文摘To analyze wind-induced response characteristics of a wind turbine tower more accurately, the blade-tower coupling effect was investigated. The mean wind velocity of the rotating blades and tower was simulated according to wind shear effects, and the fluctuating wind velocity time series of the wind turbine were simulated by a harmony superposition method. A dynamic finite element method (FEM) was used to calculate the wind-induced response of the blades and tower. Wind-induced responses of the tower were calculated in two cases (one included the blade-tower coupling effect, and the other only added the mass of blades and the hub at the top of the tower), and then the maximal displacements at the top of the tower of the tow cases were compared with each other. As a result of the influence of the blade-tower coupling effect and the total base shear of the blades, the maximal displacement of the first case increased nearly by 300% compared to the second case. To obtain more precise analysis, the blade-tower coupling effect and the total base shear of the blades should be considered simultaneously in the design of wind turbine towers.
