Fitness of node can denote its competing power and clustering denotes the transitivity of network. Because the fitness of node is uncertain or fuzzy in some social networks, an explicit form of the degree distribution...Fitness of node can denote its competing power and clustering denotes the transitivity of network. Because the fitness of node is uncertain or fuzzy in some social networks, an explicit form of the degree distribution on fuzzy fitness is derived within a mean field approach. It is a weighted sum of different fuzzy fitness. It can be found that the fuzzy fitness of nodes may lead to multiscaling. Moreover, the clustering coefficient of node decays as power law and clustering coefficient of network behavior not-decrease-but-increase’ phenomenon after some time. Some computer simulation results of these models illustrate these analytical results.展开更多
The surface morphology of Zn O films at different annealing temperatures and the performance of polymer solar cells(PSCs) with Zn O as the electron transport layer are studied.The low temperature sol-gel processed Zn ...The surface morphology of Zn O films at different annealing temperatures and the performance of polymer solar cells(PSCs) with Zn O as the electron transport layer are studied.The low temperature sol-gel processed Zn O film has smoother surface than that in higher temperature,which results in the best photovoltaic performance with a power conversion efficiency(PCE) of 3.66% for P3HT:PC61BM based solar cell.With increasing annealing temperature,the photovoltaic performance first deceases and then increases.It could be ascribed to the synergy effects of interface area,the conductivity and surface energy of Zn O film and series resistance of devices.展开更多
The coordination polymer poly(nickel-ethylenetetrathiolate) (poly(Ni-ett)), formed by nickel(Ⅱ) and 1,1,2,2-ethenetetrathiolate (ett), is the most promising N-type organic thermoelectric material ever repor...The coordination polymer poly(nickel-ethylenetetrathiolate) (poly(Ni-ett)), formed by nickel(Ⅱ) and 1,1,2,2-ethenetetrathiolate (ett), is the most promising N-type organic thermoelectric material ever reported; it is synthesized via potentiostatic deposition, and the effect of different applied potentials on the optimal performance of the polymers is investigated. The optimal thermoelectric property ofpoly(Ni-ett) synthesized at 0.6 V is remarkably greater than that of the polymers synthesized at 1 and 1.6 V, exhibiting a maximum power factor of up to 131.6μW/mK2 at 360 K. Furthermore, the structure-property correlation ofpoly(Ni-ett) is also extensively investigated. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analyses revealed that the larger size of crystalline domains and the higher oxidation state of poly(Ni-ett) synthesized at 0.6 V possibly results in the higher bulk mobility and carrier concentration in the polymer chains, respectively, accounting for the enhanced power factor.展开更多
Two stereomers of bisadduct analogues of [6, 6]-phenyl-C71-butyric acid methyl ester (bisPC71BM) were synthesized and their geometrical structures with cis- or trans-configuration were identified by X-ray crystallog...Two stereomers of bisadduct analogues of [6, 6]-phenyl-C71-butyric acid methyl ester (bisPC71BM) were synthesized and their geometrical structures with cis- or trans-configuration were identified by X-ray crystallogra- phy. Although both of the bisPC71BM have similar spec- trometric and electrochemical properties, the spatial orientation of the two addition groups on C7o has impact on crystal packing and molecular assembly of bisPC71BM isomers and, in turn, photovoltaic performance in polymer solar cell based on poly(3-hexylthiophene) (P3HT) (with power conversion efficiency of 1.72 % and 1.84 % for the solar cells involving cis- and trans-bisPC71BM, respec- tively). Although the power conversion efficiency remains to be improved, this work exemplifies that the photovoltaic properties of fullerene-based electron acceptors areinfluenced by aggregation of the stereomeric molecules and thus extends the guidelines for rational design of efficient fullerene acceptor.展开更多
A series of P3HT:PC71BM polymer solar cells (PSCs) with different PIDTDTQx doping concentrations were fabricated to in- vestigate the effect of the PIDTDTQx as a complementary electron donor on the performance of P...A series of P3HT:PC71BM polymer solar cells (PSCs) with different PIDTDTQx doping concentrations were fabricated to in- vestigate the effect of the PIDTDTQx as a complementary electron donor on the performance of PSCs. The power conversion efficiency (PCE) of the optimized ternary blend PSCs (with 2 wt% PIDTDTQx) reached 3.87%, which is 28% higher than that of the PSCs based on P3HT:PCvlBM (control cells). The short-circuit current density (J^c) was increased to 10.20 mA/cm2 compared with the control cells. The PCE improvement could be attributed to more photon harvest and charge carrier transport by appropriate doping PIDTDTQx. The energy transfer from P3HT to PIDTDTQx was demonstrated from the 650 nm emis- sion intensity decrease and the red-shifted emission peaks from 725 nm to 737 nm along with the increase of PIDTDTQx dop- ing concentrations.展开更多
基金This project was supported by"System management",the i mportant subject of shanghai (T0502)
文摘Fitness of node can denote its competing power and clustering denotes the transitivity of network. Because the fitness of node is uncertain or fuzzy in some social networks, an explicit form of the degree distribution on fuzzy fitness is derived within a mean field approach. It is a weighted sum of different fuzzy fitness. It can be found that the fuzzy fitness of nodes may lead to multiscaling. Moreover, the clustering coefficient of node decays as power law and clustering coefficient of network behavior not-decrease-but-increase’ phenomenon after some time. Some computer simulation results of these models illustrate these analytical results.
基金supported by the Independent Innovation Foundation of Shandong University(No.2014YQ015)
文摘The surface morphology of Zn O films at different annealing temperatures and the performance of polymer solar cells(PSCs) with Zn O as the electron transport layer are studied.The low temperature sol-gel processed Zn O film has smoother surface than that in higher temperature,which results in the best photovoltaic performance with a power conversion efficiency(PCE) of 3.66% for P3HT:PC61BM based solar cell.With increasing annealing temperature,the photovoltaic performance first deceases and then increases.It could be ascribed to the synergy effects of interface area,the conductivity and surface energy of Zn O film and series resistance of devices.
基金supported by the National Basic Research Program of China (2013CB632506)the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB12000000)+1 种基金Key Project of National Natural Science Foundation of China (51336009)National Natural Science Foundation of China (21290191, 21333011)
文摘The coordination polymer poly(nickel-ethylenetetrathiolate) (poly(Ni-ett)), formed by nickel(Ⅱ) and 1,1,2,2-ethenetetrathiolate (ett), is the most promising N-type organic thermoelectric material ever reported; it is synthesized via potentiostatic deposition, and the effect of different applied potentials on the optimal performance of the polymers is investigated. The optimal thermoelectric property ofpoly(Ni-ett) synthesized at 0.6 V is remarkably greater than that of the polymers synthesized at 1 and 1.6 V, exhibiting a maximum power factor of up to 131.6μW/mK2 at 360 K. Furthermore, the structure-property correlation ofpoly(Ni-ett) is also extensively investigated. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analyses revealed that the larger size of crystalline domains and the higher oxidation state of poly(Ni-ett) synthesized at 0.6 V possibly results in the higher bulk mobility and carrier concentration in the polymer chains, respectively, accounting for the enhanced power factor.
基金supported by the National Basic Research Program of China(2014CB845601)the National Natural Science Foundation of China(U1205111+3 种基金2139039051572231and51502252)the Fundamental Research Funds for the Central Universities(20720140512)
文摘Two stereomers of bisadduct analogues of [6, 6]-phenyl-C71-butyric acid methyl ester (bisPC71BM) were synthesized and their geometrical structures with cis- or trans-configuration were identified by X-ray crystallogra- phy. Although both of the bisPC71BM have similar spec- trometric and electrochemical properties, the spatial orientation of the two addition groups on C7o has impact on crystal packing and molecular assembly of bisPC71BM isomers and, in turn, photovoltaic performance in polymer solar cell based on poly(3-hexylthiophene) (P3HT) (with power conversion efficiency of 1.72 % and 1.84 % for the solar cells involving cis- and trans-bisPC71BM, respec- tively). Although the power conversion efficiency remains to be improved, this work exemplifies that the photovoltaic properties of fullerene-based electron acceptors areinfluenced by aggregation of the stereomeric molecules and thus extends the guidelines for rational design of efficient fullerene acceptor.
基金supported by the Fundamental Research Funds for the Central Universities(Grant No.2013JBZ004)the National Natural Science Foundation of China(Grant No.61377029)+1 种基金the Beijing Natural Science Foundation(Grant No.2122050)the State Key Laboratory of Catalysis,Chinese Academy of Sciences(Grant No.n-11-09)
文摘A series of P3HT:PC71BM polymer solar cells (PSCs) with different PIDTDTQx doping concentrations were fabricated to in- vestigate the effect of the PIDTDTQx as a complementary electron donor on the performance of PSCs. The power conversion efficiency (PCE) of the optimized ternary blend PSCs (with 2 wt% PIDTDTQx) reached 3.87%, which is 28% higher than that of the PSCs based on P3HT:PCvlBM (control cells). The short-circuit current density (J^c) was increased to 10.20 mA/cm2 compared with the control cells. The PCE improvement could be attributed to more photon harvest and charge carrier transport by appropriate doping PIDTDTQx. The energy transfer from P3HT to PIDTDTQx was demonstrated from the 650 nm emis- sion intensity decrease and the red-shifted emission peaks from 725 nm to 737 nm along with the increase of PIDTDTQx dop- ing concentrations.