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传统“孝道”文化简论 被引量:2
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作者 刘晓霞 《绥化学院学报》 2012年第6期44-47,共4页
孝道文化是儒家乃至整个中华民族伦理道德观念中最核心的基本元素,是我们每个人立身处世所必须遵循的第一行为准则。全面了解孝道文化的伦理内涵、宗法功用和教化传承对厘清和弘扬中华慈孝文化具有重要意义。
关键词 孝道文 伦理内涵 功用
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Study on the effect of four kinds of raw materials in hypertonic dehydration cell model
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作者 Yuanyuan Gao Qidan Tan +3 位作者 Chencan Cao Haifeng Chen Yuying Jia Lei Liu 《日用化学工业(中英文)》 CAS 北大核心 2024年第10期1218-1226,共9页
It aims to investigate the protective effects of sodium hyaluronate,panthenol,Portulaca oleracea L.and Calendula officinalis L.on hyperosmotic dehydration-induced injury of human immortalized keratinocytes(HaCaT).The ... It aims to investigate the protective effects of sodium hyaluronate,panthenol,Portulaca oleracea L.and Calendula officinalis L.on hyperosmotic dehydration-induced injury of human immortalized keratinocytes(HaCaT).The safety mass concentrations of four raw materials were screened by detecting cell viability,and the secretion of hyaluronic acid(HA)was determined using the ELISA method.The expression of HaCaT barrier function related genes(OVOL1,EREG,TGM1,TGM2,IVL,IRF6,THBS1,CASP14)was detected at the mRNA level to explore the regulatory effect of four raw materials on these genes.The results demonstrate that pretreatment with the four kinds of raw materials could increase the cell viability after hyperosmotic dehydration,promote the secretion of HA,and improve the expression of barrier function related genes after hyperosmotic dehydration,among which panthenol and Calendula officinalis L.are better.The results show that the four raw materials have a certain protective effect on the hyperosmotic dehydration cell model,which provides data support for its application in cosmetics. 展开更多
关键词 hypertonic dehydration cell model protective effect barrier repair efficacy evaluation of cosmetics soothing ingredients
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浅谈客家传统民居壁画的功用
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作者 徐建文 《客家文博》 2011年第2期50-54,共5页
客家传统民居壁画是在迁徙中形成和产生的,其根植于民族文化,深嵌于客家文化心理之中,并随历史的发展而与时俱进,它在装饰和美化客家人居环境的同时,还反映了客家的民俗文化特点,甚至还起到教化的作用。
关键词 客家民居壁画 装饰作用 审美要求 民俗特点 功用
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沈起凤的戏曲创作 被引量:1
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作者 陈方 《中山大学研究生学刊(社会科学版)》 2001年第1期66-72,共7页
沈起凤作为清代一个较有影响的戏曲家,一直少人重视,其实无论从思想和艺术上来看,其剧作都有一定的特色。他的戏曲注重的教化功用,对现实有许多不满和牢骚,但无反抗意识,将之归于天命,带有浓厚的宿命色彩。艺术上注重演出效果,曲辞通俗... 沈起凤作为清代一个较有影响的戏曲家,一直少人重视,其实无论从思想和艺术上来看,其剧作都有一定的特色。他的戏曲注重的教化功用,对现实有许多不满和牢骚,但无反抗意识,将之归于天命,带有浓厚的宿命色彩。艺术上注重演出效果,曲辞通俗易懂,形成平实的风格。 展开更多
关键词 清代 沈起凤 戏曲 戏曲创作 艺术特色 艺术风格 曲辞 功用
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杨万里诗学本质论
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作者 张玖青 《安庆师范学院学报(社会科学版)》 2006年第2期20-23,共4页
杨万里既强调诗为“矫天下之具”,又以“味”论诗。前者是理学家杨万里重功用教化思想的反映,后者则表明诗人杨万里对当时充斥诗坛的以史为诗、以理为诗的一种理性拒绝。二者相较,重情重性才是杨万里对诗歌本质的诠释。
关键词 诚斋体 功用 吟咏情性 消解
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Fifty Years of Botanical Gardens in China 被引量:10
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作者 贺善安 《Acta Botanica Sinica》 CSCD 2002年第9期1123-1133,共11页
The development, distribution and features of one hundred and forty botanical gardens (BGs) in China are reported and their functions on research, conservation, display and utilization of biodiversity are summarized i... The development, distribution and features of one hundred and forty botanical gardens (BGs) in China are reported and their functions on research, conservation, display and utilization of biodiversity are summarized in this paper. The contributions to the social and economic development in the early stage of Chinese BGs with the researches of economic plant (tobacco), medicinal plant (yam) and wild fruit tree resources are evaluated. The theoretical and applied achievements in recent years in seed science, plant conservation, economic plant introduction, acclimatization and breeding are also described. A general scope of living plant collections in Chinese BGs is presented and the outstanding ones, including Magnoliaceae, Zingiberaceae, Cycadaceae, medicinal plants, Actinidia and Rhododendron are particularly mentioned. With special reference to Chinese penjing art garden and silicified wood garden, the development of scientific popularization and tourism in BGs is reviewed. 展开更多
关键词 botanical garden BIODIVERSITY plant conservation medicinal plant plant introduction and acclimatization plant breeding plant collection
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Optimal Power Allocation for Heterogeneous Network Capacity Maximization 被引量:1
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作者 周文安 徐宇杰 +1 位作者 梁特 任晓涛 《China Communications》 SCIE CSCD 2013年第9期97-103,共7页
We investigate the optimal joint power allocation in Heterogeneous Networks (HetNets) to maximise its capacity. Consider- ing frequency reuse in the network, we study two power-constraint cases, i.e., per-cell po- w... We investigate the optimal joint power allocation in Heterogeneous Networks (HetNets) to maximise its capacity. Consider- ing frequency reuse in the network, we study two power-constraint cases, i.e., per-cell po- wer constraint case and per-tier power con- straint case. We formulate the capacity maxi- mization problem by allowing each subcarrier of Marco eNodeB (MeNB) to be shared by users from multiple Picos. We mathematically demonstrate that the optimal power allocation in the per-cell power constraint case has a re- markably simple nature: each Pico transmits to its user with maximum power, while MeNB either selects only one user to jointly transmit with maximum power or does not transmit to any user. In the per-tier power constraint case, the difference is that the power allocation be- tween two Picos takes the form of water-fill- ing. Numerical results verify that our proposed schemes outperform the conventional interfe- rence coordination schemes. 展开更多
关键词 HetNet PICO power allocation joint transmission
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Synthesis of Environmentally Friendly Multifunctional Metal (Calcium,Magnesium) Oleate Detergent with Antioxidation Property 被引量:4
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作者 Wang Yonglei Mamat Xamxikamar Eli Wumanjiang 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2011年第3期64-68,共5页
This article covers a method for synthesizing environmentally friendly multifunctional metal (calcium,magnesium) oleate detergents with antioxidation property.These multifunctional metal (calcium,magnesium) oleate det... This article covers a method for synthesizing environmentally friendly multifunctional metal (calcium,magnesium) oleate detergents with antioxidation property.These multifunctional metal (calcium,magnesium) oleate detergents with antioxidation property were synthesized using oil-soluble liquid antioxidants (PPIBP,PPIBTSTBP,and PPIBPDA) as reactive functional materials.These oil-soluble liquid antioxidants have the potential to be used as functional materials for application in synthesizing other kinds of substrate detergents. 展开更多
关键词 OIL-SOLUBLE liquid antioxidant calcium oleate magnesium oleate multifimctional detergent
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Efficacy and safety of Xiangsha Liujunzi granules for functional dyspepsia: A multi-center randomized double-blind placebo-controlled clinical study 被引量:34
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作者 Lin Lv Feng-Yun Wang +9 位作者 Xiang-Xue Ma Zhen-Hua Li Sui-Ping Huang Zhao-Hong Shi Hai-Jie Ji Li-Qun Bian Bei-Hua Zhang Ting Chen Xiao-Lan Yin Xu-Dong Tang 《World Journal of Gastroenterology》 SCIE CAS 2017年第30期5589-5601,共13页
AIM To assess the efficacy and safety of a Chinese herbal medicine (CHM), Xiangsha Liujunzi granules, in the treatment of patients with functional dyspepsia (FD). METHODS We performed a randomized, double-blind, place... AIM To assess the efficacy and safety of a Chinese herbal medicine (CHM), Xiangsha Liujunzi granules, in the treatment of patients with functional dyspepsia (FD). METHODS We performed a randomized, double-blind, placebo-controlled trial with patients from three centers. Two hundred and sixteen subjects diagnosed with FD according to ROME. criteria and confirmed by upper gastrointestinal endoscopy and spleen-deficiency and Qi-stagnation syndrome were selected to receive Xiangsha Liujunzi granules or placebo for 4 wk in a 2: 1 ratio by blocked randomization. The subjects also received follow-up after the 4-wk intervention. Herbal or placebo granules were dissolved in 300 mL of water. Participants in both groups were administered 130 mL (45 degrees C) three times a day. Participants were evaluated prior to and following 4 wk of the intervention in terms of changes in the postprandial discomfort severity scale (PDSS) score, clinical global impression (CGI) scale score, hospital anxiety and depression scale (HADS) score, traditional Chinese medicine symptoms score (SS), scores of various domains of the 36-item short form health survey (SF-36), gastric emptying (GE) and any observed adverse effects. RESULTS Compared with the placebo group, patients in the CHM group showed significant improvements in the scores of PDSS, HADS, SS, SF-36 and CGI scale (P < 0.05 or P < 0.01). They also showed the amelioration in the GE rates of the proximal stomach and distal stomach (P < 0.05 or P < 0.01). CONCLUSION Xiangsha Liujunzi granules offered significant symptomatic improvement in patients with FD. 展开更多
关键词 Functional dyspepsia Chinese herbal medicine Xiangsha Liujunzi Efficacy Randomized controlled trial
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中国古典文学与志士情怀养成
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作者 詹昌平 《福建工程学院学报》 CAS 2013年第5期447-452,共6页
中国古典文学的创作信条是"以诗言志""以文传道"。在数千年发展中,这种文学理论与实践促进了古代国民的知性发展,推动了中国社会的文明进步,也孕育了中华民族精英以"先天下之忧而忧,后天下之乐而乐""... 中国古典文学的创作信条是"以诗言志""以文传道"。在数千年发展中,这种文学理论与实践促进了古代国民的知性发展,推动了中国社会的文明进步,也孕育了中华民族精英以"先天下之忧而忧,后天下之乐而乐""苟利国家生死以,岂因祸福趋避之"等为内涵的志士情怀,从而架构起伟大民族的铮铮精神脊梁,其文学教化经验可资后人思想道德教育借鉴。 展开更多
关键词 中国古典文学 创作信条 志士情怀 功用
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Trifunctional strategy for the design and synthesis of a Ni-CeO_(2)@SiO_(2)catalyst with remarkable low-temperature sintering and coking resistance for methane dry reforming 被引量:5
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作者 Sixue Lin Jing Wang +5 位作者 Yangyang Mi Senyou Yang Zheng Wang Wenming Liu Daishe Wu Honggen Peng 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2021年第10期1808-1820,共13页
In this study,a trifunctional strategy was developed to prepare a confined Ni-based catalyst(Ni-CeO_(2)@SiO_(2))for dry reforming of methane(DRM)of two main greenhouse gases-CO_(2)and CH_(4).The Ni-CeO_(2)@SiO_(2)cata... In this study,a trifunctional strategy was developed to prepare a confined Ni-based catalyst(Ni-CeO_(2)@SiO_(2))for dry reforming of methane(DRM)of two main greenhouse gases-CO_(2)and CH_(4).The Ni-CeO_(2)@SiO_(2)catalyst was fabricated by utilizing the confinement effect of the SiO_(2)shell and the synergistic interaction between Ni-Ce and the decoking effect of CeO_(2).The catalysts were systematically characterized via X-ray diffraction,N_(2 )adsorption/desorption,transmission electron microscopy,energy dispersive X-ray spectroscopy,hydrogen temperature reduction and desorption set by program,oxygen temperature program desorption,Raman spectroscopy,thermogravimetric analysis,and in situ diffuse reflectance infrared Fourier transform spectroscopy measurements to reveal their physicochemical properties and reaction mechanism.The Ni-CeO_(2)@SiO_(2)catalyst exhibited higher activity and stability than the catalyst synthesized via the traditional impregnation method.In addition,no carbon deposition was detected over Ni-CeO_(2)@SiO_(2)after a 100 h durability test at 800℃,and the average particle size of Ni nanoparticles(NPs)in the catalyst increased from 5.01 to 5.77 nm.Remarkably,Ni-CeO_(2)@SiO_(2)also exhibited superior low-temperature stability;no coke deposition was observed when the catalyst was reacted at 600℃ for 20 h.The high coking and sintering resistance of this confined Ni-based DRM catalyst can be attributed to its trifunctional effect.The trifunctional strategy developed in this study could be used as a guideline to design other high-performance catalysts for CO_(2)and CH4 dry forming and accelerate their industrialization. 展开更多
关键词 Methane dry forming Low-temperature stability Coke resistance Tri functional strategy CO_(2)utilization
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Theoretical Studies on Interaction Between Methanol and Functionalized Single-Walled Carbon Nanotubes 被引量:1
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作者 M.D.Ganji M.Goodarzi +1 位作者 M.Nashtahosseini A.Mommadi-nejad 《Communications in Theoretical Physics》 SCIE CAS CSCD 2011年第2期365-370,共6页
We study the adsorption of a methanol molecule on single-walled carbon nanotubes (SWCNTs) with various diameters and chiral angles by using the density functional theory based calculations. We find that methanol pre... We study the adsorption of a methanol molecule on single-walled carbon nanotubes (SWCNTs) with various diameters and chiral angles by using the density functional theory based calculations. We find that methanol prefers to be adsorbed physically on the exterior surface of chiral nanotubes in comparison to the armchair and zigzag tubes with binding energy of about -2.76 kcal/mol, which is consistent with recent experimental and theoretical investigation results. We further consider the adsorption of methanol on the exterior surface and edge site of functionalized SWCNTs. The obtained results indicate that the binding energy of methanol is significantly increased for adsorption on the sidewall of functionalized nanotubes. It is also found that the adsorption of methanol at the edge site of both functionalized and pristine SWCNT is remarkably different (chemisoption process) in comparison to the exterior sidewall of the tubes. Furthermore, the electronic structures and Mulliken charge population of the considered complexes at their ground state are discussed within the context. 展开更多
关键词 Fuel cells METHANOL functionalized SWCNTs ADSORPTION ab initio calculations
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Purification and Characterization of a Versatile Peroxidase from Edible Mushroom Pleurotus eryngii 被引量:8
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作者 陈敏 姚善泾 +1 位作者 张虹 梁新乐 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2010年第5期824-829,共6页
A versatile peroxidase (VP-Peco60-7 ) was generated and purified from the liquid culture of Pleurotus eryngii. The purification procedure included ammonium sulfate precipitation, ion exchange chromatography, and gel c... A versatile peroxidase (VP-Peco60-7 ) was generated and purified from the liquid culture of Pleurotus eryngii. The purification procedure included ammonium sulfate precipitation, ion exchange chromatography, and gel chromatography. The molecular weight and isoelectric point (pI) of VP-Peco60-7 were determined to be approxi-mately 40 kDa and 4.1, respectively. By N-terminal sequence determination and peptide mapping analysis, VP-Peco60-7 was found to be similar to the versatile peroxidase isoenzyme VPL1, which was previously isolated from liquid cultures of the same species. However, the molecular weight and pI of VP-Peco60-7 were different from those of versatile peroxidases of liquid cultures, implying that the VP-Peco60-7 in this study is of a novel type. With 2,2′-azino-bis-(3-ethylbenzothiazoline-6-sulphonic acid) (ABTS) as a substrate, the maximal enzyme activity was obtained at 50 °C and pH 3.0. The catalysis of ABTS by VP-Peco60-7 was expressed by the Michaelis-Menten equa-tion. At 50 °C and pH 3.0, the maximum velocity (V max ) was 188.68 U·mg-1 and the michaelis constant (K m ) was 203.09 μmol·L-1 . 展开更多
关键词 Pleurotus eryngii versatile peroxidase PURIFICATION enzymatic properties
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谭元春《简远堂辑选名公四六金声》叙录
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作者 陈奕奕 《骈文研究》 2021年第1期245-249,共5页
《简远堂辑选名公四六金声》十卷、补遗一卷,由明代谭元春辑选,张溥阅次,马世奇评释,杨廷麟订正。选文凡328篇,以启类文体为主,按内容分为节序类、庆贺类、敦请类、候问类、上陈类、复答类、寿旦类、婚姻类、生育类、迎送类、拜谢类。... 《简远堂辑选名公四六金声》十卷、补遗一卷,由明代谭元春辑选,张溥阅次,马世奇评释,杨廷麟订正。选文凡328篇,以启类文体为主,按内容分为节序类、庆贺类、敦请类、候问类、上陈类、复答类、寿旦类、婚姻类、生育类、迎送类、拜谢类。谭元春选文标准有三:一是声律和谐,二是辞藻华丽,三是不录“陈篇饾饤”“沿袭旧吻者”。他以“金声”比骈文,揭示所选骈文价值水平之高。究《简远堂辑选名公四六金声》之旨,其约略有三:一是揭示骈文在句式、声律、辞藻三个方面的基本特征;二是强调骈文在教化、时用、实用三方面的功用性;三是注重骈文不“沿袭旧吻者”的创新性。 展开更多
关键词 四六金声 谭元春 声律 辞藻 功用
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Spatio-temporal Characteristics of Disturbance of Land Use Change on Major Ecosystem Function Zones in China 被引量:8
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作者 NING Jia LIU Jiyuan ZHAO Guosong 《Chinese Geographical Science》 SCIE CSCD 2015年第5期523-536,共14页
In recent years, because of increasing human activities, ecosystems have been substantially disturbed and their service functions have been greatly compromised. Based on the effect of land use changes on the major eco... In recent years, because of increasing human activities, ecosystems have been substantially disturbed and their service functions have been greatly compromised. Based on the effect of land use changes on the major ecosystem services, we estimated the ecosystem comprehensive anthropogenic disturbance index(ECADI) and analyzed the spatio-temporal characteristics of changes in the ECADI in China from 1990 to 2010. The average ECADI of the major ecosystem function zones in China in 2010 is approximately 0.382. The ECADI of Northeast China and North China is slightly higher than that of Northwest China and Southwest China. Most zones have slight changes in the ECADI. The average increases of ECADI in the major ecosystem function zones in China from 1990 to 2000 and from 2000 to 2010 are 0.0024 and 0.0002, respectively. The increase is mainly due to reclamation and urbanization, whereas the decrease is due to the implementation of ecosystem protection policies. During the last 20 years, the ECADI of water resources conservation zones increased first, and then stopped. The ECADI of soil conservation zones increased first, and then declined. The ECADI of sandstorm prevention zones, biodiversity conservation zones and flooding mitigation zones increased continuously. Our results may provide proposals to the government regarding land use planning and ecosystem protection plans in the major ecosystem zones. The major ecosystem function zones in the western part of China have been protected effectively. However, the major ecosystem function zones in the eastern part of China require more protection in the future. 展开更多
关键词 land use change major ecosystems services DISTURBANCE spatiotemporal patterns China
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Interfacial-interaction-induced fabrication of biomass-derived porous carbon with enhanced intrinsic active sites 被引量:2
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作者 Wenjuan Zhang Pei Jing +3 位作者 Juan Du Shujie Wu Wenfu Yan Gang Liu 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2022年第8期2231-2239,共9页
Carbon catalysis is an attractive metal-free catalytic transformation,and its performance is significantly dependent on the number of accessible active sites.However,owing to the inherent stability of the C-C linkage,... Carbon catalysis is an attractive metal-free catalytic transformation,and its performance is significantly dependent on the number of accessible active sites.However,owing to the inherent stability of the C-C linkage,only limited active sites at the edge defects of the basal plane can be obtained even after a harsh oxidation treatment.In this study,the concept of interfacial interactions was adopted to propose an efficient strategy to develop highly active carbon catalysts.The alumina/carbon interface formed in situ acted as a cradle for the generation of oxygen-containing functional groups.In the absence of oxidation treatment,the concentration of oxygen-containing functional groups and the specific surface area can reach 1.27 mmol·g^(-1) and 2340 m^(2)·g^(-1),respectively,which are significantly higher than those of carbon prepared by traditional hard template methods.This active carbon shows a significant enhancement in catalytic performance in the oxidative coupling of amine to imine,about 22-fold higher than that of a well-known graphite oxide catalyst.Such interfacial interaction strategies are based on sustainable carbon sources and can effectively tune the porous structure of carbon in the micro-and meso-ranges.This conceptual finding offers new opportunities for the development of high-performance carbon-based metal-free catalysts. 展开更多
关键词 Interfacial interaction Porous carbon Biomass Surface functionality IMINES
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Adsorbents for Expanded Bed Adsorption: Preparation and Functionalization 被引量:3
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作者 赵珺 姚善泾 林东强 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第4期678-687,共10页
Expanded bed adsorption(EBA),a promising and practical separation technique,has been widely studied in the past two decades.The development of adsorbents for EBA process is a challenging course,with the special design... Expanded bed adsorption(EBA),a promising and practical separation technique,has been widely studied in the past two decades.The development of adsorbents for EBA process is a challenging course,with the special design and preparation according to the target molecules and specific expanded bed systems.Many types of supporting matrices for expanded bed adsorbents have been developed,and their preparation methods are being consummated gradually.These matrices are activated and then coupled with ligands to form functionalized adsorbents,including ion-exchange adsorbents,affinity adsorbents,mixed mode adsorbents,hydrophobic charge induction chromatography adsorbents and others.In this review,the preparation of the matrices for EBA process is summa-rized,and the coupling of ligands to the matrices to prepare functionalized adsorbents is discussed as well. 展开更多
关键词 expanded bed adsorption MATRIX PREPARATION tunctionalized adsorbent CHROMATOGRAPHY SEPARATION
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Energy Efficiency Optimization for D2D Communications Based on SCA and GP Method 被引量:3
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作者 Xiaozheng Gao Hangcheng Han +1 位作者 Kai Yang Jianping An 《China Communications》 SCIE CSCD 2017年第3期66-74,共9页
In this paper, we propose an energy-efficient power control scheme for device-to-device(D2D) communications underlaying cellular networks, where multiple D2D pairs reuse the same resource blocks allocated to one cellu... In this paper, we propose an energy-efficient power control scheme for device-to-device(D2D) communications underlaying cellular networks, where multiple D2D pairs reuse the same resource blocks allocated to one cellular user. Taking the maximum allowed transmit power and the minimum data rate requirement into consideration, we formulate the energy efficiency maximization problem as a non-concave fractional programming(FP) problem and then develop a two-loop iterative algorithm to solve it. In the outer loop, we adopt Dinkelbach method to equivalently transform the FP problem into a series of parametric subtractive-form problems, and in the inner loop we solve the parametric subtractive problems based on successive convex approximation and geometric programming method to obtain the solutions satisfying the KarushKuhn-Tucker conditions. Simulation results demonstrate the validity and efficiency of the proposed scheme, and illustrate the impact of different parameters on system performance. 展开更多
关键词 device-to-device(D2D) communications power control energy efficiency(EE) successive convex approximation(SCA) geometric programming(GP)
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Outage Probability Minimization for Cognitive Relay Network Under Interference Power Constraints
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作者 岳文静 郑宝玉 +1 位作者 孟庆民 谢培中 《Transactions of Tianjin University》 EI CAS 2011年第3期208-214,共7页
A cognitive relay network model is proposed, which is defined by a source, a destination, a cognitive relay node and a primary user. The source is assisted by the cognitive relay node which is allowed to coexist with ... A cognitive relay network model is proposed, which is defined by a source, a destination, a cognitive relay node and a primary user. The source is assisted by the cognitive relay node which is allowed to coexist with the primary user by imposing severe constraints on the transmission power so that the quality of service of the primary user is not degraded by the interference caused by the secondary user. The effect of the cognitive relay node on the proposed cognitive relay network model is studied by evaluating the outage probability under interference power constraints for different fading environments. A relay transmission scheme, namely, decode-and-forward is considered. For both the peak and average interference power constraints, the closed-form outage expressions are derived over different channel fading models. Finally, the analytical outage probability expressions are validated through simulations. The results indicate that the proposed model has better outage probability than direct transmission. It is also found that the outage probability decreases with the increase of interference power constraints. Meanwhile, the outage probability under the average interference power constraint is much less than that under the peak interference power constraint when the average interference power constraint is equal to the peak interference power constraint. 展开更多
关键词 cognitive radio relay networks outage probability power control
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A thioether-functionalized pyrene-based covalent organic framework anchoring ultrafine Au nanoparticles for efficient photocatalytic hydrogen generation 被引量:1
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作者 Zhiming Zhou Chuanbiao Bie +2 位作者 Peize Li Bien Tan Yan Shen 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2022年第10期2699-2707,共9页
Covalent organic frameworks(COFs)have lately emerged as a blooming class of potential materials for photocatalytic water splitting because of their high crystallinity,huge surface areas,and structural versatility.Howe... Covalent organic frameworks(COFs)have lately emerged as a blooming class of potential materials for photocatalytic water splitting because of their high crystallinity,huge surface areas,and structural versatility.However,the photocatalytic performance for most pure COFs face some limitations factors,such as the significant recombination of photogenerated carriers and slow charge transfer.Herein,a novel thioether-functionalized pyrene-based COF(S_(4)-COF)was effectively produced and chosen as a support for the immobilization of ultrafine gold nanoparticles(Au NPs).S_(4)-COF photocatalyst with Au as cocatalyst demonstrates remarkable photocatalytic activity with a H_(2) generation rate of 1377μmol g^(−1) h^(−1) under visible light(>420 nm),which is ca.4.5-fold increase comparing to that of pure S_(4)-COF(302μmol g^(−1) h^(−1)).Au NPs anchored on S_(4)-COF possess an ultrafine size distribution ranging from 1.75 to 6.25 nm with an average size centered at 3.8 nm,which benefits from the coordination interaction between thioether groups and Au.Meanwhile,the produced Au@S_(4)-COF can generate a stable photocatalytic H_(2) generation during the four recycles and preserve its crystallinity structure after the stability testing.The Au NPs anchored on the S_(4)-COF photocatalyst can greatly accelerate the separation of photogenerated carriers and increase charge transfer because of the combined function of Au NPs and thioether groups.Such a method can not only prevent the aggregation of Au NPs onto thioether-containing COFs to achieve long-term photostability but also allow uniform dispersion for an ordered structure of photocatalysts.This work provides a rational strategy for designing and preparing COF-based photocatalysts for solar-driven H_(2) production. 展开更多
关键词 Photocatalysis Covalent organic framework Thioether functionalization Gold nanoparticle Coordination interaction Photogenerated carrier separation
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