The phase composition, phase transition and phase structure transformation of the wire-cut section of functionally graded WC-Co cemented carbide with dual phase structure were investigated by XRD phase analysis. It is...The phase composition, phase transition and phase structure transformation of the wire-cut section of functionally graded WC-Co cemented carbide with dual phase structure were investigated by XRD phase analysis. It is shown that the composition of η phase in the core zone is Co_3W_3C (M_6 C type). The structure of cobalt based solid solution binder phase is fcc type. At the cooling stage of the sintering process, the phase transition of η phase, i.e. M_6C→M_12C and the martensitic phase transition of the cobalt based solid solution binder phase, i.e. fcc→hcp are suppressed, which facilitates the strengthening of the alloy. Because the instantaneous temperature of the discharge channel is as high as 10 000 ℃ during the wire cutting process, the processed surface is oxidized. Nevertheless, the oxide layer thickness is in micro grade. In the oxide film, η phase is decomposed into W_2C and CoO, and cobalt based solid solution binder is selectively oxidized, while WC remains stable due to the existence of carbon containing liquid organic cutting medium.展开更多
By virtue of a complete set of two displacement potentials,an analytical derivation of the elastostatic Green’s functions of an exponentially graded transversely isotropic substrate–coating system is presented.Three...By virtue of a complete set of two displacement potentials,an analytical derivation of the elastostatic Green’s functions of an exponentially graded transversely isotropic substrate–coating system is presented.Three-dimensional point–load and patch–load Green’s functions for stresses and displacements are given in line-integral representations.The formulation includes a complete set of transformed stress–potential and displacement–potential relations,with utilizing Fourier series and Hankel transforms.As illustrations,the present Green’s functions are degenerated to the special cases such as an exponentially graded half-space and a homogeneous two-layered half-space Green’s functions.Because of complicated integrand functions,the integrals are evaluated numerically and for numerical computation of the integrals,a robust and effective methodology is laid out which gives the necessary account of the presence of singularities of integration.Comparisons of the existing numerical solutions for homogeneous two-layered isotropic and transversely isotropic half-spaces are made to confirm the accuracy of the present solutions.Some typical numerical examples are also given to show the general features of the exponentially graded two-layered half-space Green’s functions that the effect of degree of variation of material properties will be recognized.展开更多
基金Projects(50323008, 50574104) supported by the National Natural Science Foundation of ChinaProject (04JJ3084) supported by the Natural Science Foundation of Hunan Province, China
文摘The phase composition, phase transition and phase structure transformation of the wire-cut section of functionally graded WC-Co cemented carbide with dual phase structure were investigated by XRD phase analysis. It is shown that the composition of η phase in the core zone is Co_3W_3C (M_6 C type). The structure of cobalt based solid solution binder phase is fcc type. At the cooling stage of the sintering process, the phase transition of η phase, i.e. M_6C→M_12C and the martensitic phase transition of the cobalt based solid solution binder phase, i.e. fcc→hcp are suppressed, which facilitates the strengthening of the alloy. Because the instantaneous temperature of the discharge channel is as high as 10 000 ℃ during the wire cutting process, the processed surface is oxidized. Nevertheless, the oxide layer thickness is in micro grade. In the oxide film, η phase is decomposed into W_2C and CoO, and cobalt based solid solution binder is selectively oxidized, while WC remains stable due to the existence of carbon containing liquid organic cutting medium.
文摘By virtue of a complete set of two displacement potentials,an analytical derivation of the elastostatic Green’s functions of an exponentially graded transversely isotropic substrate–coating system is presented.Three-dimensional point–load and patch–load Green’s functions for stresses and displacements are given in line-integral representations.The formulation includes a complete set of transformed stress–potential and displacement–potential relations,with utilizing Fourier series and Hankel transforms.As illustrations,the present Green’s functions are degenerated to the special cases such as an exponentially graded half-space and a homogeneous two-layered half-space Green’s functions.Because of complicated integrand functions,the integrals are evaluated numerically and for numerical computation of the integrals,a robust and effective methodology is laid out which gives the necessary account of the presence of singularities of integration.Comparisons of the existing numerical solutions for homogeneous two-layered isotropic and transversely isotropic half-spaces are made to confirm the accuracy of the present solutions.Some typical numerical examples are also given to show the general features of the exponentially graded two-layered half-space Green’s functions that the effect of degree of variation of material properties will be recognized.