A complex optical model potential modified by the concept of bonded atom, which takes into consideration the overlapping effect of electron clouds between two atoms in a molecule, is employed to calculate the total cr...A complex optical model potential modified by the concept of bonded atom, which takes into consideration the overlapping effect of electron clouds between two atoms in a molecule, is employed to calculate the total cross sections （TCS5） for electrons scattering from several molecules （CF4, CCl4, CFCl3, CF2 Cl2, and CF3 Cl） over an incident energy range 30 - 5000 eV using the additivity rule model at Hartre-Fock level. The quantitative TCS5 are compared with those obtained by experiments and other theories wherever available, and good agreement is obtained above 100 eV. It is shown that the modified potential can successfully calculate the TCS5 of electron-molecule scattering over a wide energy range, especially at lower energies.展开更多
基金The project supported by National Natural Science Foundation of China under Grant Nos. 10174019 and 10574039
文摘A complex optical model potential modified by the concept of bonded atom, which takes into consideration the overlapping effect of electron clouds between two atoms in a molecule, is employed to calculate the total cross sections （TCS5） for electrons scattering from several molecules （CF4, CCl4, CFCl3, CF2 Cl2, and CF3 Cl） over an incident energy range 30 - 5000 eV using the additivity rule model at Hartre-Fock level. The quantitative TCS5 are compared with those obtained by experiments and other theories wherever available, and good agreement is obtained above 100 eV. It is shown that the modified potential can successfully calculate the TCS5 of electron-molecule scattering over a wide energy range, especially at lower energies.
