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不同养护条件下NH_(4)H_(2)PO_(4)对钢渣微粉胶凝性能的影响
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作者 李悦 龙世儒 林辉 《北京工业大学学报》 CAS CSCD 北大核心 2023年第7期769-775,共7页
为了消除钢渣微粉(steel slag,SS)中的游离氧化钙和氧化铁,激发SS的胶凝性能,以NH_(4)H_(2)PO_(4)为激发剂对SS进行活性激发,研究了不同养护条件下,NH_(4)H_(2)PO_(4)掺量对其激发SS浆体工作性能、体积稳定性、力学性能的影响规律,结合... 为了消除钢渣微粉(steel slag,SS)中的游离氧化钙和氧化铁,激发SS的胶凝性能,以NH_(4)H_(2)PO_(4)为激发剂对SS进行活性激发,研究了不同养护条件下,NH_(4)H_(2)PO_(4)掺量对其激发SS浆体工作性能、体积稳定性、力学性能的影响规律,结合X射线衍射(X-ray diffraction,XRD)和扫描电子显微镜(scanning electron microscope,SEM)分析探讨了NH_(4)H_(2)PO_(4)激发SS反应产物的种类及微观结构。结果表明:随m(NH_(4)H_(2)PO_(4))/m(SS)的增加,浆体的凝结时间延长;室温养护条件下,m(NH_(4)H_(2)PO_(4))/m(SS)>0.2时,浆体会发生膨胀,当m(NH_(4)H_(2)PO_(4))/m(SS)=0.6时,膨胀率约40%。加压养护可以有效避免浆体的膨胀,在室温环境下,试样28 d的抗压强度可达5.5 MPa,快速养护对硬化浆体的抗压强度影响不大。XRD和SEM分析结果显示:SS经NH_(4)H_(2)PO_(4)激发后,所得反应产物主要为Ca(NH_(4))_(2)(HPO_(4))_(2)·H_(2)O、Ca_(3)(PO_(4))_(2)和FePO_(4);加压养护使反应产物填充于狭小微观空间里,增加基体密实度。 展开更多
关键词 钢渣 NH_(4)H_(2)PO_(4) 膨胀 加压养护 抗压强度 反应产物
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Effects of curing under step-by-step load on mechanical and deformation properties of cemented gangue backfill column 被引量:9
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作者 GUO Yu-xia RAN Hong-yu +3 位作者 FENG Guo-rui DU Xian-jie QI Ting-ye WANG Ze-hua 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第11期3417-3435,共19页
A step-by-step load was utilized to mimic the load history of the backfill column in the in-situ curing process.The inner damage of the specimen during curing and uniaxial compressive testing was monitored by electric... A step-by-step load was utilized to mimic the load history of the backfill column in the in-situ curing process.The inner damage of the specimen during curing and uniaxial compressive testing was monitored by electrical resistivity and ultrasonic equipment.Results show that:1)Uniaxial compressive strength(UCS)and elastic modulus(EM)of the samples curing under pressure are higher than those of the control samples without pressure,ranging in ratio from 0.5%to 20.2%and 7.1%to 52.3%,respectively,and are influenced by the initial loading age(ILA)and stress strength ratio(SSR).The SSR during curing should not exceed 80%.2)The earlier the ILA is,the higher the total strain becomes.The higher the SSR applies,the larger the total strain gets.The creep strain increases with the increase of SSR and can be described by Burger’s viscoelastic creep model.When SSR is less than 80%,the earlier the ILA is,the smaller the creep strain becomes after the last step-loading.3)The stability of the early age backfill column under pressure can be monitored based on the change of ultrasonic pulse velocity(UPV)and electrical resistivity. 展开更多
关键词 cemented gangue backfill column curing under step-by-step load compressive strength elastic modulus deformation electrical resistivity
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