Several MoS2 catalysts of different structure, prepared by in situ decomposition of ammonium heptamolybdate (AHM) and molybdenum naphthenate (MoNaph), and by MoS2 exfoliation (TDM), were characterized by BET, X-...Several MoS2 catalysts of different structure, prepared by in situ decomposition of ammonium heptamolybdate (AHM) and molybdenum naphthenate (MoNaph), and by MoS2 exfoliation (TDM), were characterized by BET, X-ray diffraction (XRD), Energy Dispersive X-ray (EDX) and transmission electron microscopy (TEM). The analysis showed that MoS2 structure was dependant upon the preparation procedure. The activity of the catalysts was determined by measuring the hydrodeoxygenation (HDO) of phenol, 4-methylphenol and 4-methoxyphenol using a batch autoclave reactor operated at 2.8 MPa of hydrogen and temperatures ranging from 320-370℃. By comparing the conversion, the reactivity order of the catalysts was: AHM〉TDM-D〉MoNaph〉thermal〉MoS2 powder〉 TDM-W. Also, the effect of reaction temperature on the HDO conversion was explained in terms of equilibrium of reversible reaction kinetics. The main products of the HDO for phenolic compounds were identified by gas chromatography/mass spectrometry (GC/MS). The results showed that the product distribution and the HDO selectivity were correlated with the reaction temperature. Two parallel reaction routes, direct hydrogenolysis and combined hydrogenation-hydrogenolysis, were confirmed by the analysis of the product distribution. High temperature favored hydrogenolysis over hydrogenation for HDO of phenol and 4-methoxyphenol, whereas for 4-methylphenol the reverse was true.展开更多
AIM: To investigate the effects of a novel Leukotriene B4 receptor antagonist and/or tacrolimus on ischemia-reperfusion in a rat liver model. METHODS: Male Lewis rats were pretreated with ONO-4057 (100 mg/kg) and/or t...AIM: To investigate the effects of a novel Leukotriene B4 receptor antagonist and/or tacrolimus on ischemia-reperfusion in a rat liver model. METHODS: Male Lewis rats were pretreated with ONO-4057 (100 mg/kg) and/or tacrolimus (1 mg/kg) orally, and divided into four experimental groups; group 1 (control), group 2 (ONO-4057), group 3 (tacrolimus), group 4 (ONO-4057 + tacrolimus). RESULTS: There was a tendency for long survival in the groups treated with tacrolimus alone and ONO-4057 plus tacrolimus. Post-reperfusion serum aspartate aminotransferase levels decreased more signif icantly in ONO-4057 plus tacrolimus group (P < 0.01), than in the tacrolimus alone group (P < 0.05), compared to controls. CONCLUSION: This study demonstrated that pretreat-ment with ONO-4057 in combination with tacrolimus produced additive effects in a rat model of liver isch-emia-reperfusion injury.展开更多
The effects of different contents(0.4%, 0.7%, and 1.0%, mass fraction) of Mn or Ti additions on the micro structure, shape memory effect and the corrosion behaviour of Cu-Al-Ni shape memory alloys were studied by fiel...The effects of different contents(0.4%, 0.7%, and 1.0%, mass fraction) of Mn or Ti additions on the micro structure, shape memory effect and the corrosion behaviour of Cu-Al-Ni shape memory alloys were studied by field emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, differential scanning calorimetry and electrochemical and immersion tests in NaCl solution. It was observed that the microstructure, shape memory effect and corrosion characteristics are highly sensitive to the composition variations. It was found that the highest strain recovery was with 0.7% addition of Mn or Ti. This may be attributed to the presence of precipitation with a high volume fraction and the grain refinement. The electrochemical test showed that the formation of oxide layers in both Cu-Al-Ni-Mn and Cu-Al-Ni-Ti shape memory alloys(SMAs) provided good passivation which enhanced the corrosion resistance of the alloys. Immersion test showed that in Cu-Al-Ni-Mn SMAs, pitting corrosion occurred through feebleness in the oxide layer. A corrosion product adjacent to the pits was rich in Al/Mn oxide and depleted in Cu while inside of the pit it was rich in Cu. In Cu-Al-Ni-Ti SMAs, localized corrosion occurred on the surface of the specimens and dealuminization attack was also observed in the matrix.展开更多
The elution of WO ions by NaOH. NaNO3 NaCl and NH4Cl on strong basicanion exchange resins in quaternary ammonium form I and the adsorption properties after elution were studied. In addition, the elution curse, the per...The elution of WO ions by NaOH. NaNO3 NaCl and NH4Cl on strong basicanion exchange resins in quaternary ammonium form I and the adsorption properties after elution were studied. In addition, the elution curse, the permeation curveand the exchange capacities of operation were presented. The eluate containingtungsten with high content and excessive eluant of low content were obtained by employing the process of eluting using mixed solution of NaCl and NaOH. It's possible to obtain Na2WO4. 2H2O with high purity by evaporating and crystallizing theeluate. The results of mixed elution showed that the diffusion coefficients of Cl-.OH- and WO ions in solution or exchange agent varied due to the coexistence ofcounter ions and then the exchange velocity of WO→Cl- and WOe→OH- wasaccelerated.展开更多
The coupled effect of viscosity enhancing admixtures(VEA)and superplasticizer(SP)on the rheological behavior of cement paste was investigated in this work.Two types of VEAs,including hydroxypropyl methylcellulose(HPMC...The coupled effect of viscosity enhancing admixtures(VEA)and superplasticizer(SP)on the rheological behavior of cement paste was investigated in this work.Two types of VEAs,including hydroxypropyl methylcellulose(HPMC)and Welan gum,and two types of SPs,i.e.polycarboxylate(PCA)and polynaphthalenesulfonate(PNS)were used as admixtures for cement paste.Rheological curves of cement paste and simulated pore solution containing VEA and SP were tested.Simulated pore solution test results show that molecules of different SPs may generate different effects on the viscosity of VEA solutions.Hershel-Bulkley(H-B)model was used to fit rheological curve of cement paste.Strong interaction between PNS and HPMC was observed in this work.展开更多
This study was conducted to evaluate four different parental oriental varieties with their F1 crosses to estimate inheritance of some morphological traits, such as plant hight, number of leaves, total dry weigh and ch...This study was conducted to evaluate four different parental oriental varieties with their F1 crosses to estimate inheritance of some morphological traits, such as plant hight, number of leaves, total dry weigh and chemical compounds, especially nicotine and sugars during sun-curing period. The oriental varieties Kozarsko 541, Plovdiv 50 and Krumovgrad 17 from Bulgaria and Basma Xanthi 101 from Greece and their respective crosses with Basma Xanthi 101 were studied. The study was set up in 2014 and 2015 in experimental field of the Tobacco and Tobacco Products Institute, Plovdiv, using randomized block design with four replications. Common agricultural practices were applied during the growing season. The result indicated that in hybrid combination with parental varieties Kozarsko 541 and Plovdiv 50, except total dry weight, additive gene effects are important for traits height of plant and number of leaves. Height of plant and number of leaves are inherited partially dominant to parent with higher value and total dry weight inheritance was over dominant. In hybrid combination Krumovgrad 17 x Basma Xanthi 101, inheritance of the plant height and leaves number were over dominant type. Total dry weight is inherited partially dominant. In a word, prevailing mode for inheritance of plant hight and total dry weight was the over dominance and for number of leaves it was partial dominance. In sun-curing with yellowing stage, nicotine decreased and sugars increased in all tested varieties with a highest percentage in variety Kozarsko 541 (nicotine) and Krumovgrad 17 (sugars).展开更多
Aims The conifer litter is fairly recalcitrant and nutrient poor,and broadleaved litter promotes coniferous litter decomposition by increasing degradable nutrients and promoting microbial metabolism.Mixing Pinus masso...Aims The conifer litter is fairly recalcitrant and nutrient poor,and broadleaved litter promotes coniferous litter decomposition by increasing degradable nutrients and promoting microbial metabolism.Mixing Pinus massoniana litter and three broadleaved litters may increase the diversity and abundance of fungal decomposers compared with those in P.massoniana litter and vary depending on the number and proportion of broadleaved species included.Methods We analysed the composition and diversity of fungal communities during mixed litter decomposition in southwestern China with 35 treatments(P.massoniana,Toona sinensis,Cinnamomum camphora and Sassafras tzumu litter)using Illumina high-throughput sequencing.Important Findings The mixed litters increased fungal diversity and richness compared with those in the single-species litter,except in the following treatments:P.massoniana litter accounting for 70%-80%in the P.massoniana+T.sinensis,P.massoniana+S.tzumu+T.sinensis and P.massoniana+S.tzumu+C.camphora combinations,and P.massoniana+S.tzumu+C.camphora+T.sinensis combination with small proportion of T.sinensis litter.The diversity and richness of the 7:1:2 combination of P.massoniana+C.camphora+T.sinensis were significantly higher than those in the other treatments.Ascomycota and Basidiomycota were the dominant phyla,and Aspergillus was the most abundant genus.The decomposition of litters from one needleleaf and one broadleaved species(6:4)and one needleleaf species and two broadleaved species(broadleaved litter accounting for 30%-40%)exhibited synergistic interactions throughout the decomposition process,and the relative abundance of fungi that decompose refractory substances increased.The P.massoniana+C.camphora+T.sinensis combination and a 30%-40%broadleaf litter proportion increased fungal diversity and accelerated the decomposition of recalcitrant coniferous litter.Therefore,C.camphora and T.sinensis are a potential candidate species for mixed planting with P.massoniana.展开更多
The superimposed influences of the blade rows in a multistage compressor are important because different matches of upstream and downstream blades can result in significant differences in the stator wake oscillation. ...The superimposed influences of the blade rows in a multistage compressor are important because different matches of upstream and downstream blades can result in significant differences in the stator wake oscillation. Numerical investigation of the axial stator wake oscillation, which is affected upstream by the axial rotor and downstream by the radial rotor, was performed in an axial-radial combined compressor. Many configurations with different blade numbers and locations, which influence axial stator wake oscillation were investigated. When rotors have equal blade numbers, the axial stator wake oscillates periodically versus time within time T(moving blade passing 1/3 revolution). In contrast, stator wake oscillates irregularly within T when rotors have different blade numbers. A model-split subtraction method is presented in order to separate the influences of the individual blade rows on the wake oscillation of the axial stator. Analysis from the rotor-stator configuration showed that the unsteady flow angle fluctuation response is caused by the upstream rotor. For the rotor-stator-rotor configuration, the unsteady flow angle fluctuations are influenced by upand downstream blade rows. With the model-split subtraction method, the upand downstream influences on the flow angle fluctuation could be clearly separated and quantified. Low amplitudes could be observed when the influences from upand downstream moving rows were superimposed with the "positive peaknegative peak" type wave. Clocking investigations were carried out to change the relative superimposed phase of influences from the surrounding blade rows in order to modulate the amplitudes of the axial stator wake oscillation. However, the amplitudes did not reach the maximum when they were superimposed with "positive peak-positive peak" type wave due to the impact of the interaction between the two moving blade rows.展开更多
文摘Several MoS2 catalysts of different structure, prepared by in situ decomposition of ammonium heptamolybdate (AHM) and molybdenum naphthenate (MoNaph), and by MoS2 exfoliation (TDM), were characterized by BET, X-ray diffraction (XRD), Energy Dispersive X-ray (EDX) and transmission electron microscopy (TEM). The analysis showed that MoS2 structure was dependant upon the preparation procedure. The activity of the catalysts was determined by measuring the hydrodeoxygenation (HDO) of phenol, 4-methylphenol and 4-methoxyphenol using a batch autoclave reactor operated at 2.8 MPa of hydrogen and temperatures ranging from 320-370℃. By comparing the conversion, the reactivity order of the catalysts was: AHM〉TDM-D〉MoNaph〉thermal〉MoS2 powder〉 TDM-W. Also, the effect of reaction temperature on the HDO conversion was explained in terms of equilibrium of reversible reaction kinetics. The main products of the HDO for phenolic compounds were identified by gas chromatography/mass spectrometry (GC/MS). The results showed that the product distribution and the HDO selectivity were correlated with the reaction temperature. Two parallel reaction routes, direct hydrogenolysis and combined hydrogenation-hydrogenolysis, were confirmed by the analysis of the product distribution. High temperature favored hydrogenolysis over hydrogenation for HDO of phenol and 4-methoxyphenol, whereas for 4-methylphenol the reverse was true.
文摘AIM: To investigate the effects of a novel Leukotriene B4 receptor antagonist and/or tacrolimus on ischemia-reperfusion in a rat liver model. METHODS: Male Lewis rats were pretreated with ONO-4057 (100 mg/kg) and/or tacrolimus (1 mg/kg) orally, and divided into four experimental groups; group 1 (control), group 2 (ONO-4057), group 3 (tacrolimus), group 4 (ONO-4057 + tacrolimus). RESULTS: There was a tendency for long survival in the groups treated with tacrolimus alone and ONO-4057 plus tacrolimus. Post-reperfusion serum aspartate aminotransferase levels decreased more signif icantly in ONO-4057 plus tacrolimus group (P < 0.01), than in the tacrolimus alone group (P < 0.05), compared to controls. CONCLUSION: This study demonstrated that pretreat-ment with ONO-4057 in combination with tacrolimus produced additive effects in a rat model of liver isch-emia-reperfusion injury.
基金the Malaysian Ministry of Higher Education (MOHE) and Universiti Teknologi Malaysia for providing the financial support and facilities for this research, under Grant No. R.J130000.7824.4F150
文摘The effects of different contents(0.4%, 0.7%, and 1.0%, mass fraction) of Mn or Ti additions on the micro structure, shape memory effect and the corrosion behaviour of Cu-Al-Ni shape memory alloys were studied by field emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, differential scanning calorimetry and electrochemical and immersion tests in NaCl solution. It was observed that the microstructure, shape memory effect and corrosion characteristics are highly sensitive to the composition variations. It was found that the highest strain recovery was with 0.7% addition of Mn or Ti. This may be attributed to the presence of precipitation with a high volume fraction and the grain refinement. The electrochemical test showed that the formation of oxide layers in both Cu-Al-Ni-Mn and Cu-Al-Ni-Ti shape memory alloys(SMAs) provided good passivation which enhanced the corrosion resistance of the alloys. Immersion test showed that in Cu-Al-Ni-Mn SMAs, pitting corrosion occurred through feebleness in the oxide layer. A corrosion product adjacent to the pits was rich in Al/Mn oxide and depleted in Cu while inside of the pit it was rich in Cu. In Cu-Al-Ni-Ti SMAs, localized corrosion occurred on the surface of the specimens and dealuminization attack was also observed in the matrix.
文摘The elution of WO ions by NaOH. NaNO3 NaCl and NH4Cl on strong basicanion exchange resins in quaternary ammonium form I and the adsorption properties after elution were studied. In addition, the elution curse, the permeation curveand the exchange capacities of operation were presented. The eluate containingtungsten with high content and excessive eluant of low content were obtained by employing the process of eluting using mixed solution of NaCl and NaOH. It's possible to obtain Na2WO4. 2H2O with high purity by evaporating and crystallizing theeluate. The results of mixed elution showed that the diffusion coefficients of Cl-.OH- and WO ions in solution or exchange agent varied due to the coexistence ofcounter ions and then the exchange velocity of WO→Cl- and WOe→OH- wasaccelerated.
基金Project(2017YFB0310101)supported by National High Technology Research and Development Program of ChinaProject(51778269)supported by the National Natural Science Foundation of China
文摘The coupled effect of viscosity enhancing admixtures(VEA)and superplasticizer(SP)on the rheological behavior of cement paste was investigated in this work.Two types of VEAs,including hydroxypropyl methylcellulose(HPMC)and Welan gum,and two types of SPs,i.e.polycarboxylate(PCA)and polynaphthalenesulfonate(PNS)were used as admixtures for cement paste.Rheological curves of cement paste and simulated pore solution containing VEA and SP were tested.Simulated pore solution test results show that molecules of different SPs may generate different effects on the viscosity of VEA solutions.Hershel-Bulkley(H-B)model was used to fit rheological curve of cement paste.Strong interaction between PNS and HPMC was observed in this work.
文摘This study was conducted to evaluate four different parental oriental varieties with their F1 crosses to estimate inheritance of some morphological traits, such as plant hight, number of leaves, total dry weigh and chemical compounds, especially nicotine and sugars during sun-curing period. The oriental varieties Kozarsko 541, Plovdiv 50 and Krumovgrad 17 from Bulgaria and Basma Xanthi 101 from Greece and their respective crosses with Basma Xanthi 101 were studied. The study was set up in 2014 and 2015 in experimental field of the Tobacco and Tobacco Products Institute, Plovdiv, using randomized block design with four replications. Common agricultural practices were applied during the growing season. The result indicated that in hybrid combination with parental varieties Kozarsko 541 and Plovdiv 50, except total dry weight, additive gene effects are important for traits height of plant and number of leaves. Height of plant and number of leaves are inherited partially dominant to parent with higher value and total dry weight inheritance was over dominant. In hybrid combination Krumovgrad 17 x Basma Xanthi 101, inheritance of the plant height and leaves number were over dominant type. Total dry weight is inherited partially dominant. In a word, prevailing mode for inheritance of plant hight and total dry weight was the over dominance and for number of leaves it was partial dominance. In sun-curing with yellowing stage, nicotine decreased and sugars increased in all tested varieties with a highest percentage in variety Kozarsko 541 (nicotine) and Krumovgrad 17 (sugars).
基金supported by an innovation research project of the National Natural Science Foundation of China(no.31370628)the National Science and Technology Support Project of China(no.2011BAC09B05).
文摘Aims The conifer litter is fairly recalcitrant and nutrient poor,and broadleaved litter promotes coniferous litter decomposition by increasing degradable nutrients and promoting microbial metabolism.Mixing Pinus massoniana litter and three broadleaved litters may increase the diversity and abundance of fungal decomposers compared with those in P.massoniana litter and vary depending on the number and proportion of broadleaved species included.Methods We analysed the composition and diversity of fungal communities during mixed litter decomposition in southwestern China with 35 treatments(P.massoniana,Toona sinensis,Cinnamomum camphora and Sassafras tzumu litter)using Illumina high-throughput sequencing.Important Findings The mixed litters increased fungal diversity and richness compared with those in the single-species litter,except in the following treatments:P.massoniana litter accounting for 70%-80%in the P.massoniana+T.sinensis,P.massoniana+S.tzumu+T.sinensis and P.massoniana+S.tzumu+C.camphora combinations,and P.massoniana+S.tzumu+C.camphora+T.sinensis combination with small proportion of T.sinensis litter.The diversity and richness of the 7:1:2 combination of P.massoniana+C.camphora+T.sinensis were significantly higher than those in the other treatments.Ascomycota and Basidiomycota were the dominant phyla,and Aspergillus was the most abundant genus.The decomposition of litters from one needleleaf and one broadleaved species(6:4)and one needleleaf species and two broadleaved species(broadleaved litter accounting for 30%-40%)exhibited synergistic interactions throughout the decomposition process,and the relative abundance of fungi that decompose refractory substances increased.The P.massoniana+C.camphora+T.sinensis combination and a 30%-40%broadleaf litter proportion increased fungal diversity and accelerated the decomposition of recalcitrant coniferous litter.Therefore,C.camphora and T.sinensis are a potential candidate species for mixed planting with P.massoniana.
基金Financially supported by National Natural Science Foundation of China(No.51176013)Chinese Specialized Research Fund for the Doctoral Program of Higher Education(No.20091101110014)
文摘The superimposed influences of the blade rows in a multistage compressor are important because different matches of upstream and downstream blades can result in significant differences in the stator wake oscillation. Numerical investigation of the axial stator wake oscillation, which is affected upstream by the axial rotor and downstream by the radial rotor, was performed in an axial-radial combined compressor. Many configurations with different blade numbers and locations, which influence axial stator wake oscillation were investigated. When rotors have equal blade numbers, the axial stator wake oscillates periodically versus time within time T(moving blade passing 1/3 revolution). In contrast, stator wake oscillates irregularly within T when rotors have different blade numbers. A model-split subtraction method is presented in order to separate the influences of the individual blade rows on the wake oscillation of the axial stator. Analysis from the rotor-stator configuration showed that the unsteady flow angle fluctuation response is caused by the upstream rotor. For the rotor-stator-rotor configuration, the unsteady flow angle fluctuations are influenced by upand downstream blade rows. With the model-split subtraction method, the upand downstream influences on the flow angle fluctuation could be clearly separated and quantified. Low amplitudes could be observed when the influences from upand downstream moving rows were superimposed with the "positive peaknegative peak" type wave. Clocking investigations were carried out to change the relative superimposed phase of influences from the surrounding blade rows in order to modulate the amplitudes of the axial stator wake oscillation. However, the amplitudes did not reach the maximum when they were superimposed with "positive peak-positive peak" type wave due to the impact of the interaction between the two moving blade rows.