In order to build a ceramic component by inkjet printing, the object must be fabricated through the interaction and solidification of drops, typically in the range of 10–100 p L. In order to achieve this goal, stable...In order to build a ceramic component by inkjet printing, the object must be fabricated through the interaction and solidification of drops, typically in the range of 10–100 p L. In order to achieve this goal, stable ceramic inks must be developed. These inks should satisfy specific rheological conditions that can be illustrated within a parameter space defined by the Reynolds and Weber numbers. Printed drops initially deform on impact with a surface by dynamic dissipative processes, but then spread to an equilibrium shape defined by capillarity. We can identify the processes by which these drops interact to form linear features during printing, but there is a poorer level of understanding as to how 2D and 3D structures form. The stability of 2D sheets of ink appears to be possible over a more limited range of process conditions that is seen with the formation of lines. In most cases, the ink solidifies through evaporation and there is a need to control the drying process to eliminate the "coffee ring" defect. Despite these uncertainties, there have been a large number of reports on the successful use of inkjet printing for the manufacture of small ceramic components from a number of different ceramics. This technique offers good prospects as a future manufacturing technique. This review identifies potential areas for future research to improve our understanding of this manufacturing method.展开更多
Direct writing of graphene patterns and devices may significantly facilitate the application of graphene-based flexible electronics. In terms of scalability and cost efficiency, inkjet printing is very competitive ove...Direct writing of graphene patterns and devices may significantly facilitate the application of graphene-based flexible electronics. In terms of scalability and cost efficiency, inkjet printing is very competitive over other existing direct- writing methods. However, it has been challenging to obtain highly stable and clog-free graphene-based ink. Here, we report an alternative and highly efficient technique to directly print a reducing reagent on graphene oxide film to form conductive graphene patterns. By this "inkjet reduction" method, without using any other microfabrication technique, conductive graphene patterns and devices for various applications are obtained. The ionic nature of the reductant ink makes it clog-free and stable for continuous and large-area printing. The method shows self-limited reduction feature, which enables electrical conductivity of graphene patterns to be tuned within 5 orders of magnitude, reaching as high as 8,000 S.m-1. Furthermore, this method can be extended to produce noble metal/graphene composite patterns. The devices, including transistors, biosensors, and surface- enhanced Raman scattering substrates, demonstrate excellent functionalities. This work provides a new strategy to prepare large-area graphene-based devices that is low-cost and highly efficient, promising to advance research on graphene- based flexible electronics.展开更多
文摘In order to build a ceramic component by inkjet printing, the object must be fabricated through the interaction and solidification of drops, typically in the range of 10–100 p L. In order to achieve this goal, stable ceramic inks must be developed. These inks should satisfy specific rheological conditions that can be illustrated within a parameter space defined by the Reynolds and Weber numbers. Printed drops initially deform on impact with a surface by dynamic dissipative processes, but then spread to an equilibrium shape defined by capillarity. We can identify the processes by which these drops interact to form linear features during printing, but there is a poorer level of understanding as to how 2D and 3D structures form. The stability of 2D sheets of ink appears to be possible over a more limited range of process conditions that is seen with the formation of lines. In most cases, the ink solidifies through evaporation and there is a need to control the drying process to eliminate the "coffee ring" defect. Despite these uncertainties, there have been a large number of reports on the successful use of inkjet printing for the manufacture of small ceramic components from a number of different ceramics. This technique offers good prospects as a future manufacturing technique. This review identifies potential areas for future research to improve our understanding of this manufacturing method.
文摘Direct writing of graphene patterns and devices may significantly facilitate the application of graphene-based flexible electronics. In terms of scalability and cost efficiency, inkjet printing is very competitive over other existing direct- writing methods. However, it has been challenging to obtain highly stable and clog-free graphene-based ink. Here, we report an alternative and highly efficient technique to directly print a reducing reagent on graphene oxide film to form conductive graphene patterns. By this "inkjet reduction" method, without using any other microfabrication technique, conductive graphene patterns and devices for various applications are obtained. The ionic nature of the reductant ink makes it clog-free and stable for continuous and large-area printing. The method shows self-limited reduction feature, which enables electrical conductivity of graphene patterns to be tuned within 5 orders of magnitude, reaching as high as 8,000 S.m-1. Furthermore, this method can be extended to produce noble metal/graphene composite patterns. The devices, including transistors, biosensors, and surface- enhanced Raman scattering substrates, demonstrate excellent functionalities. This work provides a new strategy to prepare large-area graphene-based devices that is low-cost and highly efficient, promising to advance research on graphene- based flexible electronics.