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不同抗氧剂体系在聚碳酸酯中的应用对比
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作者 袁冬梅 薛鉴鹏 +2 位作者 李志 张璐 钱富娟 《工程塑料应用》 CAS CSCD 北大核心 2024年第7期167-172,共6页
聚碳酸酯(PC)在加工和使用过程中会发生老化现象从而影响其使用性能,通常加入抗氧剂可以抑制或延缓其老化。为了选择适用于PC的抗氧剂体系,选用三种主抗氧剂分别与辅助抗氧剂168复配使用于PC中,并采用多次挤出老化和热氧老化对其进行老... 聚碳酸酯(PC)在加工和使用过程中会发生老化现象从而影响其使用性能,通常加入抗氧剂可以抑制或延缓其老化。为了选择适用于PC的抗氧剂体系,选用三种主抗氧剂分别与辅助抗氧剂168复配使用于PC中,并采用多次挤出老化和热氧老化对其进行老化处理,分析了抗氧剂对PC性能的影响,研究了在加工老化和热氧老化过程中抗氧剂体系对PC老化的抑制效果和抗氧剂体系与色粉的配伍性,从而筛选出适用于PC的抗氧剂体系。结果表明,1790抗氧剂体系使PC初始颜色黄化,严重影响了产品的外观色泽;245抗氧剂体系对PC的初始颜色、光学性能和力学性能影响较小,但在加工老化和热氧老化过程中黄化速度较快,这会对产品的外观颜色产生不利影响;1076抗氧剂体系对PC的初始颜色、光学性能和力学性能影响较小,并且在加工老化和热氧老化过程中对PC有较好的保护作用;辅助抗氧剂168对PC初始性能影响较小,但过多的用量在加工老化和热氧老化过程中会使熔体流动速率升高,拉伸性能下降,应严格控制其用量;245抗氧剂体系和1076抗氧剂体系与色剂复配均具有较好的协同效应。抗氧剂1076体系较适用于PC。 展开更多
关键词 聚碳酸酯 抗氧剂 加工老化 热氧老化 黄色指数
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Influence of the Main Technological Variables of Cyclical Mechanic-Thermal Processing on the Strain Hardening of Steel Parts
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作者 Eleno Alfonso Brindis Sanjeevkoemar Bissesar +1 位作者 Faizel Abdoel Wahid Francisco Tchiquendja Eleno 《Journal of Mechanics Engineering and Automation》 2016年第1期1-8,共8页
The main objective of the present work was to determine the influence of the most important technological variables of CMTP (cyclical mechanic-thermal processing) on the strain hardening in the surface layers of ste... The main objective of the present work was to determine the influence of the most important technological variables of CMTP (cyclical mechanic-thermal processing) on the strain hardening in the surface layers of steel parts. For this, it was designed a full factorial plan at two levels of five independent variables that include the whole processing in two and three cycles, the cold-forming degree and force during the plastic deformation (burnishing), and the temperature and time at the given temperature during the aging. Each cycle is composed of plastic deformation at room temperature plus aging. As dependent variables, the degree and penetration depth of strain hardening were evaluated. Based on the appropriately used set of experimental data, it had been fitted an exponential model for each dependent variables and also a two-degree polynomial fitting of in-depth evolution of microhardness profile was obtained. The amount of cycles and the cold-forming degree are the technological variables of CMTP that influence the most on strain hardening, although other variables also are significant. The microhardness profile highlights that during the CMTP, the strain hardening decreases from the outer bound to the transition zone of the surface layers, where it disappears. 展开更多
关键词 Mechanic-thermal processing strain hardening surface layers microhardness.
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