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高压釜对加水模拟实验中氢产物的影响 被引量:10
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作者 马素萍 贺建桥 +1 位作者 汤渭 夏燕青 《沉积学报》 CAS CSCD 北大核心 2003年第4期713-716,共4页
在对有机质进行加水高温高压热解实验时 ,经常会发现气体产物中的氢气含量非常高。通过大量的实验我们发现除了通常人们所认为的有机来源之外 ,还有很大一部分为无机成因 ,即不锈钢高压釜在高温高压条件下与水反应释放的氢气。在我们的... 在对有机质进行加水高温高压热解实验时 ,经常会发现气体产物中的氢气含量非常高。通过大量的实验我们发现除了通常人们所认为的有机来源之外 ,还有很大一部分为无机成因 ,即不锈钢高压釜在高温高压条件下与水反应释放的氢气。在我们的实验中 ,无论是含有机质的还是仅含无机物的 ,产物中均有较大比例的氢气 ,其中在只有去离子水的模拟实验中也产生了一定量的氢气。这就证明不锈钢的高压釜确实参与了反应。 展开更多
关键词 氢气 不锈钢高压釜 模拟实验 生油岩 热解模拟实验 油气生成
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典型有机硫化合物热演化的加水热解实验研究 被引量:7
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作者 宋之光 王茂春 刘祖发 《地球化学》 CAS CSCD 北大核心 2007年第3期247-252,共6页
14种典型含硫化合物在200~330℃温度区间、在有低硫褐煤和硫抑制剂存在条件下的加水热模拟实验结果表明,大多数结构类型的含硫化合物是结构不稳定的化合物,它们的热稳定性差异很大,不同结构类型的含硫化合物所对应的热解温度不同,它们... 14种典型含硫化合物在200~330℃温度区间、在有低硫褐煤和硫抑制剂存在条件下的加水热模拟实验结果表明,大多数结构类型的含硫化合物是结构不稳定的化合物,它们的热稳定性差异很大,不同结构类型的含硫化合物所对应的热解温度不同,它们在不同温度段产物的分布也不尽相同,这表明单个硫化合物的地球化学行为差异很大,而单个有机硫化合物在有机质热成熟过程中的转换特征基本上可以依据其生成硫化氢、二次含硫化合物以及大分子含硫化合物的量来描述。另一方面,硫化氢作为主要热解产物表明硫化合物分解生成硫化氢是有机硫化合物成熟转化的主要机理性过程。在所调查的化合物中,苯并噻吩、二苯并噻吩、二苯硫和噻蒽等在最高热解温度下也不发生任何化学反应,表明这些化合物代表了稳定型结构的硫化合物,这与这些化合物广泛存在于成熟原油和沉积有机质中的状况是一致的。上述结果还显示含硫化合物的种类和结构类型是受有机质的成熟度或演化阶段控制的。 展开更多
关键词 有机硫化合物 热模拟实验 热解产物 硫化氢
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煤成烃生成及排驱加水热模拟实验 被引量:8
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作者 李荣西 金奎励 《沉积学报》 CAS CSCD 北大核心 1998年第1期98-102,共5页
用加水热模拟实验对采于我国胜利油田附近的石炭系太原组亮褐煤(R0=0.56%)生烃潜力进行研究。煤样富含镜质组(74.5%),壳质组少(8.8%),惰性组占16.7%,其中镜质组以富氢的基质镜质体为主。煤样裂隙发育,形成于滨海沼... 用加水热模拟实验对采于我国胜利油田附近的石炭系太原组亮褐煤(R0=0.56%)生烃潜力进行研究。煤样富含镜质组(74.5%),壳质组少(8.8%),惰性组占16.7%,其中镜质组以富氢的基质镜质体为主。煤样裂隙发育,形成于滨海沼泽相沉积环境。实验设200℃、230℃、260℃、290℃、320℃和350℃六个温度点,每个温度点加热72小时。实验结果表明该煤具有较高的生烃潜力和排油效率。其液态烃大量生成和排出始于R0=0.76%(290℃),在R0=1.18%(320℃)时达高峰。气态产物从R0=1.18%大量形成,直到R0=1.53%(350℃)继续增大。实验分析认为煤的生烃能力除了与其有机质类型、有机质丰度等有关外,还与其形成的沉积环境有关,缺氧的还原环境是煤作为烃源岩形成和保存的有利沉积环境。裂隙的发育有助于煤成油的排驱和运移。 展开更多
关键词 生烃潜力 排驱效率 热模拟实验 沉积环境
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不同烃源岩实验评价方法的对比 被引量:18
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作者 刘全有 刘文汇 +1 位作者 王晓锋 王万春 《石油实验地质》 CAS CSCD 北大核心 2007年第1期88-94,共7页
在Rock-Eval热解法、H/C比及加水热模拟实验3种烃源岩生烃潜力评价方法对比的基础上,对塔里木盆地满加尔坳陷低成熟侏罗系煤岩进行了生烃评价。对比结果表明,H/C比值与加水热解实验法评价结果较接近,生烃量分别为9.62和9.72 mg/g,而Rock... 在Rock-Eval热解法、H/C比及加水热模拟实验3种烃源岩生烃潜力评价方法对比的基础上,对塔里木盆地满加尔坳陷低成熟侏罗系煤岩进行了生烃评价。对比结果表明,H/C比值与加水热解实验法评价结果较接近,生烃量分别为9.62和9.72 mg/g,而Rock-Eval热解法得到的生烃潜力为32.75 mg/g,远高于其他两种评价结果。Rock-Eval热解法得到的是烃源岩的最大排烃量,而H/C比与加水热模拟实验法获得的是烃源岩的有效排烃量。因此,在对烃源岩的生烃评价中要根据实际需求选择不同的评价方法。 展开更多
关键词 Rock-Eval热解法 H/C比值 热模拟实验 生烃评价 塔里木盆地
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旱地深层土壤厌氧氨氧化菌及全细菌群落结构对加水培养的响应变化
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作者 王成 庄林杰 +1 位作者 赵思研 祝贵兵 《环境科学学报》 CAS CSCD 北大核心 2018年第10期4124-4132,共9页
为研究旱地深层土壤中厌氧氨氧化菌及相伴随的全细菌的群落结构对水分增加的响应变化,选取西澳大陆Kalgoorlie地区60 m深的典型旱地土壤,采集淀积层和母质层土壤样品,加入纯水或3.5%的盐水进行密闭培养.针对厌氧氨氧化功能基因hzsB基因... 为研究旱地深层土壤中厌氧氨氧化菌及相伴随的全细菌的群落结构对水分增加的响应变化,选取西澳大陆Kalgoorlie地区60 m深的典型旱地土壤,采集淀积层和母质层土壤样品,加入纯水或3.5%的盐水进行密闭培养.针对厌氧氨氧化功能基因hzsB基因及细菌16S rRNA基因进行高通量测序.结果显示:初始土壤并未有厌氧氨氧化菌的检出,加水培养3个月之后,开始有厌氧氨氧化菌的检出,此时盐水培养中厌氧氨氧化菌群多样性要高于纯水培养的结果.且纯水培养中,厌氧氨氧化菌群落结构在淀积层和母质层中类似,均以Candidatus ‘Brocadia anammoxidans'为主(92.09%和91.94%),另有一定量的Candidatus ‘Jettenia sp.'(7.43%和7.89%).盐水培养中,淀积层主导种属为Candidatus ‘Brocadia anammoxidans'(50.03%)和Candidatus ‘Jettenia sp.'(40.25%),母质层主导种属为Candidatus ‘Jettenia sp.'(71.20%);继续培养一个月后,盐水培养和纯水培养中厌氧氨氧化菌群多样性均有增加,且盐水培养中厌氧氨氧化菌群多样性依旧要高于纯水培养的结果.此时纯水培养中,淀积层依旧以Candidatus ‘Brocadia anammoxidans'(87.88%)为主导,母质层中Candidatus ‘Jettenia sp.'增长明显,达到50.90%,取代Candidatus ‘Brocadia anammoxidans'(39. 92%)成为主导种属.盐水培养中,Candidatus‘Brocadia fulgida'(45. 19%)与Candidatus ‘Brocadia anammoxidans'(47.99%)共同主导淀积层厌氧氨氧化菌群,母质层中Candidatus ‘Brocadia fulgida'增至73. 14%,取代Candidatus ‘Jettenia sp.'(13.65%)成为主导种属.另外,相伴随的母质层土壤全细菌群落结构在培养过程中相对比较稳定,以厌氧或兼性厌氧的变形菌门(Proteobacteria)占绝对主导(81.84%~95.45%),其中大部分为海洋营生的盐单胞菌科(Halomonadaceae)和希瓦氏菌科(Shewanellaceae).同时厚壁菌门(Firmicutes)在培养过程中出现较明显增长.培养过程中,Candidatus ‘Jettenia sp.'与放线菌门(Actinobacteria)的相对丰度变化显著正相关(r=0.991,p=0.009),与海洋营生的希瓦氏菌科(Shewanellaceae)的相对丰度变化显著负相关(r=-0.971,p=0.029).综上,本文在一定程度上揭示了水分及盐度的变化对厌氧氨氧化的发生及菌群组成分布的重要影响,进一步拓展了对不同生境中厌氧氨氧化菌生理特性的认识. 展开更多
关键词 厌氧氨氧化菌 全细菌 旱地深层土壤 加水实验 群落结构
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咸化湖相富含层状藻与结构藻烃源岩的成烃特征新探与意义 被引量:4
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作者 刘诗局 高岗 +5 位作者 靳军 张莉莉 刚文哲 向宝力 王静 王明 《地质学报》 EI CAS CSCD 北大核心 2023年第3期879-887,共9页
咸化湖相沉积条件下形成的细粒沉积岩是我国页岩油勘探的热点层系。本文依据有机岩石学、扫描电镜、生烃动力学和高温高压加水热模拟实验,对准噶尔盆地吉木萨尔凹陷芦草沟组咸化湖相含有典型层状藻和结构藻的烃源岩的成烃特征进行对比... 咸化湖相沉积条件下形成的细粒沉积岩是我国页岩油勘探的热点层系。本文依据有机岩石学、扫描电镜、生烃动力学和高温高压加水热模拟实验,对准噶尔盆地吉木萨尔凹陷芦草沟组咸化湖相含有典型层状藻和结构藻的烃源岩的成烃特征进行对比研究。有机岩石学及扫描电镜观察表明两种藻类的赋存形式差异明显,结构藻的赋存形式主要为孤立分布特征,长度约为20~50μm;层状藻垂向上呈书页状叠置,水平延伸长。生烃动力学及高温高压热模拟实验结果指示了两种有机质的成烃过程具有明显的差异性,其中结构藻为主的烃源岩在较低成熟度就可以生成一定量烃类,随着演化程度的增加,生油速率缓慢,生油范围宽;层状藻为主烃源岩的生烃特征表现为集中生烃,生油窗范围窄且主要生烃活化能较高。该认识对于有效烃源岩评价和页岩油勘探层段与甜点区的选择均具有重要的启示和指导意义。 展开更多
关键词 咸化湖相 层状藻 结构藻 生烃动力学 热模拟实验
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Experimental Studies on Critical Heat Flux in a Uniformly Heated Vertical Tube at Low Pressure and Flowrates
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作者 Husham M. Ahmed 《Journal of Energy and Power Engineering》 2012年第1期60-69,共10页
Investigations into critical beat flux at low flow and pressure conditions are of particular interest when predicting the nuclear reactor core behavior during Loss of Coolant accident (LOCA). Therefore, critical hea... Investigations into critical beat flux at low flow and pressure conditions are of particular interest when predicting the nuclear reactor core behavior during Loss of Coolant accident (LOCA). Therefore, critical heat flux (CHF) has been investigated in a uniformly heated vertical round tube at two low system pressures and six low water flowrates. The results have been compared with two correlations which have different approaches and CHF look-up table. Good agreements have been obtained for the three comparisons at the lower sets of mass fluxes. The Bowring correlation was found to be the best to correlate the experimental results with Root Mean Square Error RMSE of 0.54% and 0.56% for the 5 bar and 15 bar system pressure respectively. A comparisons with the Shim and Lee correlation yielded RMSE of 0.23% and 5.74% for the two system pressure respectively. When the look-up table of Groeneveld et al. was used, RMES of 0.55% and 25.2% was obtained for the two system pressure respectively. 展开更多
关键词 Critical heat flux DRYOUT BURNOUT subcooled boiling LOCA.
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Thermal Analysis of Composite Cements
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作者 Bentaieb Noureddine Touil Djamel +3 位作者 Lachemet Aziz Zirour Fatiha Ralida Belaadi Salah Frances Christine 《Journal of Chemistry and Chemical Engineering》 2011年第11期1002-1005,共4页
The hydration of cement compounds gives hydrated compounds, which allow linking together, the different particles and aggregate of cement, and gives the concrete the required qualities. The dynamics of hydration react... The hydration of cement compounds gives hydrated compounds, which allow linking together, the different particles and aggregate of cement, and gives the concrete the required qualities. The dynamics of hydration reactions will depend on many factors, such as the fineness of cement, the ratio w/c during hydration, temperature, mixing technique, and the presence of additives in blended cement, as pozzolan, tuff and slag from blast furnaces. We studied the thermal and kinetic reactions of Portland cement hydration, and its variants with different additions using a differential scanning calorimetric analysis. The parameters from these models of curves allow us to evaluate the enthalpies, and the degree of progression of this blended cement, and finally determine their activation energies. We can say that the hydration of Portland cement is due to a series of reactions as ( C3S,C2S,C3A and C4AF reactions with water) and each of them, has its own kinetic, the experimental measurement of the heat of hydration, allows us to represent the overall kinetics of these reactions values of activation energy, they are therefore apparent and global energy. In our experiments, significant differences in these physicochemical parameters were observed, depending on the additive used. 展开更多
关键词 Hydration of Portland cement kinetics of hydration cement thermal analysis.
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Numerical and Experimental Study on Dynamic Performance of Heat Pump Water Heater with Electronic Expansion Valve
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作者 Liang Zhang Xianmin Guo Weiguo Li Weihua Wang 《Journal of Energy and Power Engineering》 2012年第10期1582-1588,共7页
A series of experiments on the dynamic performance of the HPWH (heat pump water heater) unit with EXV (electronic expansion valve) under different environmental conditions were conducted. The dynamic heating capac... A series of experiments on the dynamic performance of the HPWH (heat pump water heater) unit with EXV (electronic expansion valve) under different environmental conditions were conducted. The dynamic heating capacity and COP (coefficient of performance) of the HPWH unit under different EXV openings were measured. The effects of the EXV opening on the performance of the HPWH unit were analyzed. Meanwhile, the dynamic performance of the HPWH with EXV was simulated and the results were compared with the experimental one. The experimental results indicate that during heating process, the COP increases firstly and then decreases for a fixed EXV opening, which is in good agreement with the numerical result. For different EXV openings, the COP and heating capacity of the system using larger EXV opening are superior to those using the smaller one in the initial heating stage. While in the late stage, the performance of system using smaller EXV opening is better. It is found that the system performance is improved significantly by changing the EXV opening in the different heating period and the average COP of the HPWH system is increased by 7.6%. 展开更多
关键词 Heat pump water heater electronic expansion valve experimental investigation simulation.
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Fire Extinct Experiments with Water Mist by Adding Additives 被引量:3
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作者 Lijun Yang Jianbo Zhao 《Journal of Thermal Science》 SCIE EI CAS CSCD 2011年第6期563-569,共7页
The effects of fire extinguishment with water mist by adding different additives were studied.Tens of chemical substances (including alkali metal salt,dilution agent and surface active agent) were selected as additive... The effects of fire extinguishment with water mist by adding different additives were studied.Tens of chemical substances (including alkali metal salt,dilution agent and surface active agent) were selected as additives due to their different extinct mechanisms.At first the performance of fire extinguishment with single additive was studied,then the effects of the same kinds of chemical substances under the same mass fraction were compared to study their influences on the fire extinguishment factors,including extinct time,fire temperature and oxygen concentration from which the fire extinct mechanism with additives could be concluded.Based on this the experiments were conducted to study the cooperate effect of the complexity of different additives.It indicated the relations between different firefighting mechanisms and different additives were competitive.From a large number of experiments the extinct mechanism with water mist by adding additives was concluded and an optimal compounding additive was selected. 展开更多
关键词 fire extinguishment ADDITIVES water mist
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