In this paper, pyrolysis of Indonesian oil sands (lOS) was investigated by two different heating methods to develop a better understanding of the microwave-assisted pyrolysis. Thermogravimetric analysis was conducte...In this paper, pyrolysis of Indonesian oil sands (lOS) was investigated by two different heating methods to develop a better understanding of the microwave-assisted pyrolysis. Thermogravimetric analysis was conducted to study the thermal decomposition behaviors of lOS, showing that 550 ℃ might be the pyrolysis final temperature. A explanation of the heat-mass transfer process was presented to demonstrate the influence of mi- crowave-assisted pyrolysis on the liquid product distribution. The heat-mass transfer model was also useful to explain the increase of liquid product yield and heavy component content at the same heating rate by two differ- ent heating methods. Experiments were carried out using a fixed bed reactor with and without the microwave irradiation. The results showed that liquid product yield was increased during microwave induced pyrolysis, while the formation of gas and solid residue was reduced in comparison with the conventional pyrolysis. Moreover, the liquid product characterization by elemental analysis and GC-MS indicated the significant effect on the liquid chemical composition by microwave irradiation. High polarity substances (ε 〉 10 at 25 ℃), such as oxy- organics were increased, while relatively low polarity substances (ε 〈 2 at 25℃), such as aliphatic hydrocarbons were decreased, suggesting that microwave enhanced the relative volatility of high polarity substances. The yield improvement and compositional variations in the liquid product promoted by the microwave-assisted pyrolysis deserve the further exploitation in the future,展开更多
In order to solve the current experimental controversy on the existence of the tensor glueball ξ(2230), we examine whether the conclusion from Seth's experimental measurement, which rejects existence of ξ(2230),...In order to solve the current experimental controversy on the existence of the tensor glueball ξ(2230), we examine whether the conclusion from Seth's experimental measurement, which rejects existence of ξ(2230), is reliable.We claim that the non-observation of the resonance structure by Seth is not a sound ground for rejecting the existence of ξ(2230) but it may just indicate that ξ(2230) has a broad width. We also study the tensor glueball properties: the mass, spin, and decay width. Our theoretical predictions of the mass and the spin of the ξ(2230) using QCD sum rule are about 2.23 GeV and J = 2, respectively. Our theoretical results also evidently show that the ξ(2230) must have a total decay width of about 100 MeV, which is much broader than the reported 20 MeV but a small partial decay width of 2 MeV into pp decay channel.展开更多
In this paper, we show that the coupled modified Kd V equations possess rich mathematical structures and some remarkable properties. The connections between the system and skew orthogonal polynomials,convergence accel...In this paper, we show that the coupled modified Kd V equations possess rich mathematical structures and some remarkable properties. The connections between the system and skew orthogonal polynomials,convergence acceleration algorithms and Laurent property are discussed in detail.展开更多
A novel approach is designed to optimize the synthesis of sulfonic-functionalized silica material. Results from 29Si and 27AI NMR suggest that the AI acts as the bridging atom connecting the methanesulfonate and silic...A novel approach is designed to optimize the synthesis of sulfonic-functionalized silica material. Results from 29Si and 27AI NMR suggest that the AI acts as the bridging atom connecting the methanesulfonate and silica matrix. Further pyridine-FTIR spectra followed by catalytic activity tests demonstrate that compared with previous methods, our new approach results in higher Lewis acid site concentration, higher thermal stability and superior catalytic activity. Moreover, the whole catalysis preparation procedure is environmentally friendly. Specifically, the silica matrix is synthesized through hydrolysis of tetrae- thylorthosilicate employing formic acid as hydro-catalyst, in which no surfactant species or precursors were involved.展开更多
基金Supported by the National Key Research and Development Program of China(2016YFB0301800)the partial support by The Royal Society International Exchange Award(IE161344)the State Scholarship Fund of China Scholarship Council(CSC)(201706255020)
文摘In this paper, pyrolysis of Indonesian oil sands (lOS) was investigated by two different heating methods to develop a better understanding of the microwave-assisted pyrolysis. Thermogravimetric analysis was conducted to study the thermal decomposition behaviors of lOS, showing that 550 ℃ might be the pyrolysis final temperature. A explanation of the heat-mass transfer process was presented to demonstrate the influence of mi- crowave-assisted pyrolysis on the liquid product distribution. The heat-mass transfer model was also useful to explain the increase of liquid product yield and heavy component content at the same heating rate by two differ- ent heating methods. Experiments were carried out using a fixed bed reactor with and without the microwave irradiation. The results showed that liquid product yield was increased during microwave induced pyrolysis, while the formation of gas and solid residue was reduced in comparison with the conventional pyrolysis. Moreover, the liquid product characterization by elemental analysis and GC-MS indicated the significant effect on the liquid chemical composition by microwave irradiation. High polarity substances (ε 〉 10 at 25 ℃), such as oxy- organics were increased, while relatively low polarity substances (ε 〈 2 at 25℃), such as aliphatic hydrocarbons were decreased, suggesting that microwave enhanced the relative volatility of high polarity substances. The yield improvement and compositional variations in the liquid product promoted by the microwave-assisted pyrolysis deserve the further exploitation in the future,
文摘In order to solve the current experimental controversy on the existence of the tensor glueball ξ(2230), we examine whether the conclusion from Seth's experimental measurement, which rejects existence of ξ(2230), is reliable.We claim that the non-observation of the resonance structure by Seth is not a sound ground for rejecting the existence of ξ(2230) but it may just indicate that ξ(2230) has a broad width. We also study the tensor glueball properties: the mass, spin, and decay width. Our theoretical predictions of the mass and the spin of the ξ(2230) using QCD sum rule are about 2.23 GeV and J = 2, respectively. Our theoretical results also evidently show that the ξ(2230) must have a total decay width of about 100 MeV, which is much broader than the reported 20 MeV but a small partial decay width of 2 MeV into pp decay channel.
基金supported by National Natural Science Foundation of China(Grant Nos.11331008,11201469,11571358 and 11601237)the China Postdoctoral Science Foundation Funded Project(Grant Nos.2012M510186 and 2013T60761)the Hong Kong Research Grant Council(Grant No.GRF HKBU202512)
文摘In this paper, we show that the coupled modified Kd V equations possess rich mathematical structures and some remarkable properties. The connections between the system and skew orthogonal polynomials,convergence acceleration algorithms and Laurent property are discussed in detail.
文摘A novel approach is designed to optimize the synthesis of sulfonic-functionalized silica material. Results from 29Si and 27AI NMR suggest that the AI acts as the bridging atom connecting the methanesulfonate and silica matrix. Further pyridine-FTIR spectra followed by catalytic activity tests demonstrate that compared with previous methods, our new approach results in higher Lewis acid site concentration, higher thermal stability and superior catalytic activity. Moreover, the whole catalysis preparation procedure is environmentally friendly. Specifically, the silica matrix is synthesized through hydrolysis of tetrae- thylorthosilicate employing formic acid as hydro-catalyst, in which no surfactant species or precursors were involved.