Neodymium(Nd)-based catalyst in butadiene(Bd)polymerization has drawn interests due to its availability in affording higher cis-1,4-unit selectivity than transition metal(Ti,Co,Ni,etc.)-based catalysts[1-2].Such outst...Neodymium(Nd)-based catalyst in butadiene(Bd)polymerization has drawn interests due to its availability in affording higher cis-1,4-unit selectivity than transition metal(Ti,Co,Ni,etc.)-based catalysts[1-2].Such outstanding high cis-1,4-unit selecti-vity is hypothetically originated from the presence of 4 f orbitals,that can participate in monomer coordination and thereby govern subsequent enchainment manners.This unique characteristic also renders the active species highly susceptible to Lewis bases,and may impact the overall selectivity as well as polyme-rization behavior after coordination.Nevertheless,it is still a virgin area in such a field,and the influence of Lewis bases on Nd-based diene polymerizations is still a black box.Based on this consideration,how nitrogen-containing donors(D)impacts the overall behaviors of Nd-mediated Bd polymerizations is disclosed.展开更多
In this paper, a new forming model of the feed direction burr for drilling process is presented. The feed direction burr formation is experimented and studied. The related theories are analyzed, and the influential ...In this paper, a new forming model of the feed direction burr for drilling process is presented. The feed direction burr formation is experimented and studied. The related theories are analyzed, and the influential factors of the feed direction burrs are pointed out. Furthermore, a certain number of new measures to prevent and decrease the burr in drilling process are advanced.展开更多
For laser assisted machining,shape of preheating laser heat source is changed irregularly because of complexity of material shape.So,the preheating temperature should be controlled by adjusting the feed rate or the la...For laser assisted machining,shape of preheating laser heat source is changed irregularly because of complexity of material shape.So,the preheating temperature should be controlled by adjusting the feed rate or the laser power.Thermal analyses of the laser assisted machining process for inclination planes were performed.By analyzing the obtained temperature profile,a proper feed rate control method was proposed according to the inclination angles.In addition,the temperature distribution of the cross section after feed rate control was predicted.The correlation equation between inclination angles and adjusted proper feed rate was proposed.The results of this analysis can be used to predict the preheating effect on workpiece and can be applied as a preheating temperature control method in laser assisted machining processes.展开更多
To investigate the effect of alternating magnetic field on austenite transformation process in the case of rapid heating,the austenite kinetics model of AISI 1045 steel was built for spot continual induction hardening...To investigate the effect of alternating magnetic field on austenite transformation process in the case of rapid heating,the austenite kinetics model of AISI 1045 steel was built for spot continual induction hardening(SCIH)process.The results shows that the effect of alternating magnetic field on austenite transformation fraction reaches the maximum(about 3%)when heating rate is the lowest.Relatively low magnetic flux density still has a certain effect on the austenite transformation process during the SCIH process.Concave surface structure can reduce the influence scope of alternating magnetic field on surface in all cases and the minimum influence scope appears when the feed path of inductor is longitudinal.Convex surface structure can minimize the influence scope of alternating magnetic field in depth when the feed path of inductor is longitudinal.The austenite distribution of transitional region on surface for horizontal movement is more uniform than that for longitudinal movement.The austenite distribution of transitional region in depth for longitudinal movement is more uniform than that for horizontal movement.The simulated results are consistent with the experimental results and the austenite transformation kinetics model developed for SCIH process is valid.展开更多
In tube hydroforming with axial feeding,under the effect of coupled internal pressure and axial stress,wrinkles often occur and affect the forming results.Wrinkling behavior of an AZ31B magnesium alloy tube was experi...In tube hydroforming with axial feeding,under the effect of coupled internal pressure and axial stress,wrinkles often occur and affect the forming results.Wrinkling behavior of an AZ31B magnesium alloy tube was experimentally investigated with different loading paths at different temperatures.Features of wrinkles,including shape,radius and width,were acquired from the experiments,as well as the thickness distribution.Numerical simulations were carried out to reveal the stress state during warm hydroforming,and then the strain history of material at the top and bottom of the wrinkles were analyzed according to the stress tracks and yielding ellipse.Finally,effects of loading paths on expansion ratio limit of warm hydroforming were analyzed.It is verified that at a certain temperature,expansion ratio limit can be increased obviously by applying a proper loading path and realizing enough axial feeding.展开更多
The purpose of this study is to develop a twin wheel creep-feed grinding machine using continuous dressing to machine precise axisymmetric turbine blades that have been difficult to machine using a conventional creep-...The purpose of this study is to develop a twin wheel creep-feed grinding machine using continuous dressing to machine precise axisymmetric turbine blades that have been difficult to machine using a conventional creep-feed machine.In order to develop such a machine,3D-modeling and machine simulations were performed and a twin wheel creep-feed grinding machine was manufactured.Furthermore,the axisymmetric precision of the machined workpieces through practical machining was evaluated and the quality of the continuous dressing effect of the developed machine was established.In addition,experimental considerations for a proper dresser-to-wheel speed ratio and proper feed rate of the dresser were carried out.As a result,a twin wheel creep-feed grinding machine with continuous dressing is developed through machine simulation,manufacturing and performance evaluation.Optimum condition for the dresser feed rate is 0.3μm/rev.In cases of large dressor-to-wheel speed ratio,grinding efficiency can be enhanced,but the surface roughness shows a conflicting trend.Developed twin wheel creep-feed grinding machine has satisfactory appraisal with regard to surface roughness,flatness,and parallelism.Satisfactory surface roughness below 0.1μm can be obtained for the blade of aircraft.However,in order to perform precise machining,it is necessary to improve the structure of the twin wheel creep-feed grinding machine.展开更多
Honing is a machining process which can economically produce exact bores regarding form, geometry and surface quality. During the honing process, the tool, equipped with one or several abrasive honing stones, combines...Honing is a machining process which can economically produce exact bores regarding form, geometry and surface quality. During the honing process, the tool, equipped with one or several abrasive honing stones, combines three movement components： rotation, oscillation in axial direction and radial feed movement of the honing stone. The feed movement is a decisive factor for the results of the honing process and can be controlled either by a gradual lining in fixed time intervals or by the regulation of the occurring forces. The presented studies show different approaches for the regulation of force controlled honing and their effects on the measured forces, the torque and the quality parameters of the process.展开更多
This paper provides an overview of the degradation in CANDU^a （Canadian Deuterium Uranium） feeders in operating plants observed from the mid 1990s onward. The degradation has been dominated by feeder wall thinning, ...This paper provides an overview of the degradation in CANDU^a （Canadian Deuterium Uranium） feeders in operating plants observed from the mid 1990s onward. The degradation has been dominated by feeder wall thinning, caused by FAC （flow accelerated corrosion） and feeder cracking. This paper summarizes the industry＇s response to the discovery of these two degradation mechanisms and the methodologies, tools and technologies developed to monitor the degradation and assess the continued fitness for service to manage the plant life. This paper identifies some of the lessons gained from more than a decade of industry effort, and discusses how these lessons are being implemented in the refurbished and new CANDU plants. CANDU^a is a registered trademark of Atomic Energy of Canada Limited.展开更多
CNC machining plays an important role in mechanical manufacturing.A key issue is to improve the machining feedrate while keeping the machining precision and satisfying the acceleration constraints of the CNC machine.F...CNC machining plays an important role in mechanical manufacturing.A key issue is to improve the machining feedrate while keeping the machining precision and satisfying the acceleration constraints of the CNC machine.For the consecutive micro-line segments interpolation,the velocities at the junction of two segments are the bottlenecks for the machining efficiency.This paper proposes a multi-period turning method to improve the feedrate at the junctions using the linear acceleration and deceleration mode,which utilizes the maximal acceleration capabilities of the NC machine while satisfying the machining precision.A new and more efficient look-ahead method and a feedrate override method are also proposed to boast the global machining speed.The proposed algorithm has been implemented on Blue Sky NC System,and experimented in real material manufacturing.Compared with several existing algorithms,the current algorithm can improve the manufacturing time ranging from 50% to 180%,depending on the machining parameters,and also results in better machining quality.In addition,the algorithm also satisfies the need of real-time interpolation.展开更多
Variable feedrate interpolation algorithms for five-axis parametric toolpath are very promising but still rather limited currently.In this paper,an off-line feedrate scheduling method of dual NURBS curve is presented ...Variable feedrate interpolation algorithms for five-axis parametric toolpath are very promising but still rather limited currently.In this paper,an off-line feedrate scheduling method of dual NURBS curve is presented with geometric and kinematical constraints.For a given dual parametric curve,the feedrates of sampling points are first scheduled sequent with confined feedrate of cutter tip and machine pivot,chord error,normal acceleration and angular feedrate.Then,the feedrate profiles of angular feed acceleration sensitive regions of the path are adjusted using a bi-directional scanning algorithm.After that,a linear programming method is used to adjust the feedrate profiles of linear feed acceleration sensitive regions and control the linear feed acceleration of both cutter tip and machine pivot within preset values.Further,a NURBS curve is used to fit the feedrates of sampling points.Finally,illustrative examples are carried out to validate the feasibility of the proposed feedrate scheduling method.The results show that the proposed method has the ability of effectively controlling the angular feed characters of cutter axis as well as the chord error and linear feed characters of cutter tip and machine pivot,and it has potential to be used in high accuracy and high quality five-axis machining.展开更多
基金Supported by PetroChina Company Limited Project (2020 B-2711)。
文摘Neodymium(Nd)-based catalyst in butadiene(Bd)polymerization has drawn interests due to its availability in affording higher cis-1,4-unit selectivity than transition metal(Ti,Co,Ni,etc.)-based catalysts[1-2].Such outstanding high cis-1,4-unit selecti-vity is hypothetically originated from the presence of 4 f orbitals,that can participate in monomer coordination and thereby govern subsequent enchainment manners.This unique characteristic also renders the active species highly susceptible to Lewis bases,and may impact the overall selectivity as well as polyme-rization behavior after coordination.Nevertheless,it is still a virgin area in such a field,and the influence of Lewis bases on Nd-based diene polymerizations is still a black box.Based on this consideration,how nitrogen-containing donors(D)impacts the overall behaviors of Nd-mediated Bd polymerizations is disclosed.
文摘In this paper, a new forming model of the feed direction burr for drilling process is presented. The feed direction burr formation is experimented and studied. The related theories are analyzed, and the influential factors of the feed direction burrs are pointed out. Furthermore, a certain number of new measures to prevent and decrease the burr in drilling process are advanced.
基金Project(2011-0017407)supported by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MEST)
文摘For laser assisted machining,shape of preheating laser heat source is changed irregularly because of complexity of material shape.So,the preheating temperature should be controlled by adjusting the feed rate or the laser power.Thermal analyses of the laser assisted machining process for inclination planes were performed.By analyzing the obtained temperature profile,a proper feed rate control method was proposed according to the inclination angles.In addition,the temperature distribution of the cross section after feed rate control was predicted.The correlation equation between inclination angles and adjusted proper feed rate was proposed.The results of this analysis can be used to predict the preheating effect on workpiece and can be applied as a preheating temperature control method in laser assisted machining processes.
基金Projects(51905390,51575415)supported by the National Natural Science Foundation of China。
文摘To investigate the effect of alternating magnetic field on austenite transformation process in the case of rapid heating,the austenite kinetics model of AISI 1045 steel was built for spot continual induction hardening(SCIH)process.The results shows that the effect of alternating magnetic field on austenite transformation fraction reaches the maximum(about 3%)when heating rate is the lowest.Relatively low magnetic flux density still has a certain effect on the austenite transformation process during the SCIH process.Concave surface structure can reduce the influence scope of alternating magnetic field on surface in all cases and the minimum influence scope appears when the feed path of inductor is longitudinal.Convex surface structure can minimize the influence scope of alternating magnetic field in depth when the feed path of inductor is longitudinal.The austenite distribution of transitional region on surface for horizontal movement is more uniform than that for longitudinal movement.The austenite distribution of transitional region in depth for longitudinal movement is more uniform than that for horizontal movement.The simulated results are consistent with the experimental results and the austenite transformation kinetics model developed for SCIH process is valid.
基金Project(NCET-07-0237)supported by the Program for New Century Excellent Talents in University,China
文摘In tube hydroforming with axial feeding,under the effect of coupled internal pressure and axial stress,wrinkles often occur and affect the forming results.Wrinkling behavior of an AZ31B magnesium alloy tube was experimentally investigated with different loading paths at different temperatures.Features of wrinkles,including shape,radius and width,were acquired from the experiments,as well as the thickness distribution.Numerical simulations were carried out to reveal the stress state during warm hydroforming,and then the strain history of material at the top and bottom of the wrinkles were analyzed according to the stress tracks and yielding ellipse.Finally,effects of loading paths on expansion ratio limit of warm hydroforming were analyzed.It is verified that at a certain temperature,expansion ratio limit can be increased obviously by applying a proper loading path and realizing enough axial feeding.
基金Work supported by the Second Stage of Brain Korea 21 Project
文摘The purpose of this study is to develop a twin wheel creep-feed grinding machine using continuous dressing to machine precise axisymmetric turbine blades that have been difficult to machine using a conventional creep-feed machine.In order to develop such a machine,3D-modeling and machine simulations were performed and a twin wheel creep-feed grinding machine was manufactured.Furthermore,the axisymmetric precision of the machined workpieces through practical machining was evaluated and the quality of the continuous dressing effect of the developed machine was established.In addition,experimental considerations for a proper dresser-to-wheel speed ratio and proper feed rate of the dresser were carried out.As a result,a twin wheel creep-feed grinding machine with continuous dressing is developed through machine simulation,manufacturing and performance evaluation.Optimum condition for the dresser feed rate is 0.3μm/rev.In cases of large dressor-to-wheel speed ratio,grinding efficiency can be enhanced,but the surface roughness shows a conflicting trend.Developed twin wheel creep-feed grinding machine has satisfactory appraisal with regard to surface roughness,flatness,and parallelism.Satisfactory surface roughness below 0.1μm can be obtained for the blade of aircraft.However,in order to perform precise machining,it is necessary to improve the structure of the twin wheel creep-feed grinding machine.
文摘Honing is a machining process which can economically produce exact bores regarding form, geometry and surface quality. During the honing process, the tool, equipped with one or several abrasive honing stones, combines three movement components： rotation, oscillation in axial direction and radial feed movement of the honing stone. The feed movement is a decisive factor for the results of the honing process and can be controlled either by a gradual lining in fixed time intervals or by the regulation of the occurring forces. The presented studies show different approaches for the regulation of force controlled honing and their effects on the measured forces, the torque and the quality parameters of the process.
文摘This paper provides an overview of the degradation in CANDU^a （Canadian Deuterium Uranium） feeders in operating plants observed from the mid 1990s onward. The degradation has been dominated by feeder wall thinning, caused by FAC （flow accelerated corrosion） and feeder cracking. This paper summarizes the industry＇s response to the discovery of these two degradation mechanisms and the methodologies, tools and technologies developed to monitor the degradation and assess the continued fitness for service to manage the plant life. This paper identifies some of the lessons gained from more than a decade of industry effort, and discusses how these lessons are being implemented in the refurbished and new CANDU plants. CANDU^a is a registered trademark of Atomic Energy of Canada Limited.
基金supported by the National Key Basic Research Project of China (Grant Nos 2011CB302400)the National Natural Science Foundation of China (Grant Nos 60821002, 10871195, 10925105)+1 种基金Major National S&T Project "Advanced CNC Systems"CAS Project "MM Methods for Advanced CNC Systems"
文摘CNC machining plays an important role in mechanical manufacturing.A key issue is to improve the machining feedrate while keeping the machining precision and satisfying the acceleration constraints of the CNC machine.For the consecutive micro-line segments interpolation,the velocities at the junction of two segments are the bottlenecks for the machining efficiency.This paper proposes a multi-period turning method to improve the feedrate at the junctions using the linear acceleration and deceleration mode,which utilizes the maximal acceleration capabilities of the NC machine while satisfying the machining precision.A new and more efficient look-ahead method and a feedrate override method are also proposed to boast the global machining speed.The proposed algorithm has been implemented on Blue Sky NC System,and experimented in real material manufacturing.Compared with several existing algorithms,the current algorithm can improve the manufacturing time ranging from 50% to 180%,depending on the machining parameters,and also results in better machining quality.In addition,the algorithm also satisfies the need of real-time interpolation.
基金supported by the National Natural Science Foundation of China under Grant Nos.51075054 and 11290143the National Basic Research Program of China under Grant No.2011CB716800
文摘Variable feedrate interpolation algorithms for five-axis parametric toolpath are very promising but still rather limited currently.In this paper,an off-line feedrate scheduling method of dual NURBS curve is presented with geometric and kinematical constraints.For a given dual parametric curve,the feedrates of sampling points are first scheduled sequent with confined feedrate of cutter tip and machine pivot,chord error,normal acceleration and angular feedrate.Then,the feedrate profiles of angular feed acceleration sensitive regions of the path are adjusted using a bi-directional scanning algorithm.After that,a linear programming method is used to adjust the feedrate profiles of linear feed acceleration sensitive regions and control the linear feed acceleration of both cutter tip and machine pivot within preset values.Further,a NURBS curve is used to fit the feedrates of sampling points.Finally,illustrative examples are carried out to validate the feasibility of the proposed feedrate scheduling method.The results show that the proposed method has the ability of effectively controlling the angular feed characters of cutter axis as well as the chord error and linear feed characters of cutter tip and machine pivot,and it has potential to be used in high accuracy and high quality five-axis machining.
