Nineβ‐cyclodextrin derivatives containing an amino group were synthesized via nucleophilic sub‐stitution from mono（6‐O‐p‐tolylsulfonyl）‐β‐cyclodextrin and used in asymmetric biomimetic Mi‐chael addition re...Nineβ‐cyclodextrin derivatives containing an amino group were synthesized via nucleophilic sub‐stitution from mono（6‐O‐p‐tolylsulfonyl）‐β‐cyclodextrin and used in asymmetric biomimetic Mi‐chael addition reactions in water at room temperature. The mechanism responsible for the moder‐ate activity and enantioselectivity of the β‐cyclodextrin derivatives was explored using nuclear magnetic resonance spectroscopy, namely 2D 1H rotating‐frame overhauser effect spectroscopy （ROESY）, ultraviolet absorption spectroscopy, and quantum chemical calculations, which provide a useful technique for investigating the formation of inclusion complexes. The effects of the pH of the reaction medium, theβ‐cyclodextrin derivative dosage, the structure of the modifying amino group, and various substrates on the yield and enantioselectivity were investigated. The results indicated that these factors had an important effect on the enantiomeric excess （ee） in the reaction system. Experiments using a competitor for inclusion complex formation showed that a hydrophobic cavity is necessary for enantioselective Michael addition. A comparison of the reactions using 4‐nitro‐β‐nitrostyrene and 2‐nitro‐β‐nitrostyrene showed that steric hindrance improved the enan‐tioselectivity. This was verified by the optimized geometries obtained from quantum chemical cal‐culations. An ee of 71%was obtained in the asymmetric Michael addition of cyclohexanone and 2‐nitro‐β‐nitrostyrene, using （S）‐2‐aminomethylpyrrolidine‐modified β‐CD as the catalyst, in an aqueous buffer solution, i.e., CH3COONa‐HCl （pH 7.5）.展开更多
[Objective] The effects of wheat based diet supplemented with xylanase on blood sugar and total protein in serum of geese were studied. [ Method ] By using the randomized design of single factor, the 1-day-old healthy...[Objective] The effects of wheat based diet supplemented with xylanase on blood sugar and total protein in serum of geese were studied. [ Method ] By using the randomized design of single factor, the 1-day-old healthy goslings were divided into 6 groups and fed with corn based diet, wheat based diet and wheat based diet supplemented with xylanase at different concentrations respectively, the contents of blood sugar and total protein in serum were determined. [ Result] The wheat based diet supplemented with xylanase could increase the blood sugar and total protein in serum of geese and wheat based diet supplemented with 0.2% xylanase generated the best effect, which was higher than those of corn based diet group. As for the concentration of protein in serum, wheat based diet supplemented with 0.2% xylanase was significantly different from corn based diet and wheat based diet. [ Conclusion] The wheat based diet supplemented with xylanase could enhance geese production.展开更多
Morphologic and cytological characteristics of hybrid F1 between E. canadensis and E. sibidcus were studied. The results showed that hybrid F1 were obviously exceeded parents in plant growth vigor, and spike type of F...Morphologic and cytological characteristics of hybrid F1 between E. canadensis and E. sibidcus were studied. The results showed that hybrid F1 were obviously exceeded parents in plant growth vigor, and spike type of F1 was between parents. The karyotype formula of hybrid F1 which was true hybrid was 2n =4x=16M ＋ 10m ＋2st. At meiotic anaphase, chromosome lagging behaviors were frequently observed. The frequency of lagging chromosomes of F1 was 87.37%. At meiotic metaphase, there were many univalents and multivalents, and the rod bivalent formed greatly.展开更多
The pollen grain morphology and leaf epiderm shape and microstructural of Rye（ Secale cereal ）, common wheat and Octoploid Trititrigia were observed with the scanning electron microscope（SEM）. The results revealed...The pollen grain morphology and leaf epiderm shape and microstructural of Rye（ Secale cereal ）, common wheat and Octoploid Trititrigia were observed with the scanning electron microscope（SEM）. The results revealed that there were great differences between pollen and leaf epiderm microcosmic morphology in three species. Such characteristics of Octoploid tnticalwere between those of common wheat and Rye. The morphology of pollen grain and leaf epiderm shape counld be used as an index for taxonomy for genera and species, and had somewhat scientif- ic references to identify new multiploid species created by chromosome engineering.展开更多
The economic losses and the health hazards of the mycotoxins produced by spoilage fungi are the main concerns of the food industry. The spoilage of bakery products by fungi is more common in countries with a high humi...The economic losses and the health hazards of the mycotoxins produced by spoilage fungi are the main concerns of the food industry. The spoilage of bakery products by fungi is more common in countries with a high humidity and temperature. About 5-10% of food production is spoiled by the growth of yeast and fungi in food materials. Similarly, in Western Europe, the growth of the spoilage fungi of bread is estimated to reach more than 200 million Euros per year. The history conditions of the food can be a major factor in determining any fungal spoilage--for example, stored and processed foods are more sensitive to spoilage when compared with fresh and prepared foods. Lactic acid bacteria isolated from Bulgarian wheat and rye flour were used in the present study to check their antifungal properties against pathogenic yeast and fungi imperfecta using standard disc diffusion method in vitro. A broad spectrum of antifungal activity of the six newly identified as L. plantarum strains e Tsl, Ts2, Ts3,Ts4 and Ts5, and L. helveticus Ts6 was estimated. Our in vitro studies were performed with wheat and rye sourdough, in order to simulate a real product and to assess the bio-protective potential of the tested lactobacilli. The used test-cultures are representatives of carcinogenic, toxigenic, deteriorative and allergenic fungi from the genera .4spergillus and Penicillium. The all tested strains completely suppress the growth of against C. glabrata 72. Strains L. plantarum Tsl and Ts3 completely suppress the growth against S. cerevisae. While, in the sample with L. plantarum strains e Tsl, Ts2, Ts3,Ts4 and Ts5, and L. helveticus Ts6, a retarded and weak growth of A. niger and P. claviforme was observed. However, the spore germination and the colony growth started only on the fifth day of the mould lactobacilli co-cultivation, which also should be considered as a good result. In this study six isolates Tsl,Ts2, Ts3, Ts4, Ts5 and Ts6, from the traditional Bulgarian wheat and rye flour have been identified as L. plantarum and L. helveticus and characterized as cultures with promising antifungal activity. Obtained results from the combined molecular identification （16S rRNA gene sequencing） approach contribute to give new data on the microbial biodiversity of this not well-studied niche. The antifungal activity of our new isolates, identified as L. plantarum and L. helveticus, seems to be a promising advantage of these six strains, suggesting their potential applications in different food technologies. However, more experiments have to be conducted to clarify the nature and the mechanisms of the reported antifungal activity and they are still in progress. The combination of dairy origin and strong inhibitory activity of the lactobacillus strains is a prerequisite for their possible application as starters and/or bioprotective antifungal adjuncts.展开更多
During the last thirty years the main interest in the medical consequences of milling of staple carbohydrate foods, particularly wheat and maize, has been in its effect on the fibre content as a result of the milling....During the last thirty years the main interest in the medical consequences of milling of staple carbohydrate foods, particularly wheat and maize, has been in its effect on the fibre content as a result of the milling. The late nineteenth and early twentieth centuries in the West saw great changes in milling processes, from stone milling using water or wind power, to increasingly sophisticated roller milling, with an展开更多
Severe solar events manifested by highly energetic X-Ray events accompanied by coronal mass ejections and proton flares caused flash floods in Makkah AI-Mukaramab, A1-Madinah AI-Munawarah and Jeddah. The responses can...Severe solar events manifested by highly energetic X-Ray events accompanied by coronal mass ejections and proton flares caused flash floods in Makkah AI-Mukaramab, A1-Madinah AI-Munawarah and Jeddah. The responses can be prompt, delayed or prompt-delayed, suggesting that the protons entered the troposphere either through the opening of a direct gate in the magnetosphere to the location concer.led due to magnetic reconnection, through the polar gates or through those two paths respectively. The authors suggest that there is a magnetic anomaly in Makkah AI-Mukaramah area which makes it liable to be subjected to flash floods. The width of the solar streams determines the width of the gate opened in the magnetosphere via magnetic reconnection and thus narrow streams affect only one location of the three cities while extended width streams can cause flash floods in all of Makkah AI-Mukaramah AI-Madinah AI Munawarah and Jeddah. In addition, the November 24-26 Jeddah flash flood could be attributed to a prompt event due to a moderately fast solar stream that arrived the earth on those days.展开更多
This study examines strategies in responding to thanks by CanE （Canadian English） and CamE （Cameroon English） speakers. Based on data collected by means of a DCT （Discourse Completion Task） questionnaire, the st...This study examines strategies in responding to thanks by CanE （Canadian English） and CamE （Cameroon English） speakers. Based on data collected by means of a DCT （Discourse Completion Task） questionnaire, the study addresses formal, functional, situational, and interactional similarities and differences in both varieties of English. With regard to speaker strategies （Aijmer, 1996） or conventions of means, it was found that the Canadian participants mostly prefer ＂minimizing the favor＂ when responding to thanks, while the Cameroonians most frequently ＂express appreciation＂. At the level of the realization types, the findings show that patterns with ＂no problem＂ are predominant in the Canadian corpus, whereas the Cameroonian respondents rather employ patterns with ＂welcome＂. Differences can also be found in the situational distribution of the speaker strategies and their linguistic realizations as well as in the use and the length of supportive moves.展开更多
This study aims to evaluate the potentialities of Pseudocytisus integrifolius （Salisb） Rehder （Brassicaceae） as a botanical insecticide for the protection of stored wheat against two pests of stored grain. The ess...This study aims to evaluate the potentialities of Pseudocytisus integrifolius （Salisb） Rehder （Brassicaceae） as a botanical insecticide for the protection of stored wheat against two pests of stored grain. The essential oil of Pseudoeytisus integrifolius was tested at different doses on adults of Rhyzopertha dominica Fab. （Bostrychidae） and Sitophilus granarius Linn. （Curculionidae）, at a temperature of 28 ~C and a relative humidity of 75%. This oil has insecticidal activity and gives, for the studied adults, a very significant reduction. The essential oil extracted from Pseudocytisus integrifolius is toxic on Rhyzopertha dominica with LDs0 = 2.61 ~tL/30g grain and LDs0 = 3.99 ~L/30g grain for Sitophilus granarius, the chemical composition analysis shows the richness of the essential oil compounds known for their insecticidal properties as dimethyl disulfide （DMDS） and dimethyl trisulfide explains the results.展开更多
Italian ray grass and oat are two grass species characterized by their ability to adjust tropical climate conditions. This study proposed to assess forage productivities to allow an appropriate mowing period determina...Italian ray grass and oat are two grass species characterized by their ability to adjust tropical climate conditions. This study proposed to assess forage productivities to allow an appropriate mowing period determination in their use as dairy female feed in Madagascar. A test on small plots has been set up in the southern part of the capital city Antananarivo during one dry period （4 months）. Live observations followed by laboratory proximate analyses have been performed for forage productivity and feeding value determination. Cultivated on tanety （hill）, irrigated in counter season, results show that： （I） oat higher height （H = 96.7 cm） than Italian ray grass （H= 69.4 cm） at 99 days of age; （2） similar biomass productivity; （3） dry matter yields significantly different （p = 0.05）; （4） certain similarity between dry matter yields and FMU （fodder milk unit） score evolution; （5） leafy stage of Italian ray grasses at 99 days of age; （6） mid-flowering stage for oats during the same period. Cell wall content, crude fiber and dry matter contents increased with age （p = 0.05）. Crude proteins and minerals evolved in opposite directions. Gross energy content did not present precise variation with age. This study allowed that for an acceptable quantitative and qualitative production during dry seasons, good mowing period for Italian ray grass could start at 76 days age, while oat could start being harvested at 68 days.展开更多
As important constitutes in many drugs, piperazine comprised compounds are of great interest for drug design. In this paper, two piperazine-based compounds were synthesized for the first time, with different strategie...As important constitutes in many drugs, piperazine comprised compounds are of great interest for drug design. In this paper, two piperazine-based compounds were synthesized for the first time, with different strategies exploited. For one compound, a highly reactive intermediate of isothiocyanate was constructed to get the desired piperazinecarbothioamide. The synthesis of the other compound was completed sequentially through Friedel-Crafts acylation, coupling reaction and Michael addition. Both synthetic routes have short steps and acceptable yields, and such strategies can be applied to the synthesis of similar oioerazine-containin~ comoounds.展开更多
We investigated 15N abundance （δ15N） of winter wheat （Triticum aestivum cv. Jinmai 1） plants and soil at different growth stages in a field with a 13-year fertilization history of urea and compost, to determine w...We investigated 15N abundance （δ15N） of winter wheat （Triticum aestivum cv. Jinmai 1） plants and soil at different growth stages in a field with a 13-year fertilization history of urea and compost, to determine whether or not the δ15N of plant parts can be used as an indicator of organic amendment with compost. Plant parts （roots, leaves, stems and grains） and soil were sampled at re-greening, jointing, grain filling and mature growth stages of winter wheat. There were significant differences between the urea and compost treatments in 815N of whole plants, plant parts and soil over the whole growing season. Determination of the δ15N of plant parts was more convenient than that of whole plant to distinguish between the application of organic amendment and synthetic N fertilizer.展开更多
基金supported by the National Natural Science Foundation of China (21425627,21376279)~~
文摘Nineβ‐cyclodextrin derivatives containing an amino group were synthesized via nucleophilic sub‐stitution from mono（6‐O‐p‐tolylsulfonyl）‐β‐cyclodextrin and used in asymmetric biomimetic Mi‐chael addition reactions in water at room temperature. The mechanism responsible for the moder‐ate activity and enantioselectivity of the β‐cyclodextrin derivatives was explored using nuclear magnetic resonance spectroscopy, namely 2D 1H rotating‐frame overhauser effect spectroscopy （ROESY）, ultraviolet absorption spectroscopy, and quantum chemical calculations, which provide a useful technique for investigating the formation of inclusion complexes. The effects of the pH of the reaction medium, theβ‐cyclodextrin derivative dosage, the structure of the modifying amino group, and various substrates on the yield and enantioselectivity were investigated. The results indicated that these factors had an important effect on the enantiomeric excess （ee） in the reaction system. Experiments using a competitor for inclusion complex formation showed that a hydrophobic cavity is necessary for enantioselective Michael addition. A comparison of the reactions using 4‐nitro‐β‐nitrostyrene and 2‐nitro‐β‐nitrostyrene showed that steric hindrance improved the enan‐tioselectivity. This was verified by the optimized geometries obtained from quantum chemical cal‐culations. An ee of 71%was obtained in the asymmetric Michael addition of cyclohexanone and 2‐nitro‐β‐nitrostyrene, using （S）‐2‐aminomethylpyrrolidine‐modified β‐CD as the catalyst, in an aqueous buffer solution, i.e., CH3COONa‐HCl （pH 7.5）.
基金the Science and Technology Key Projects of China (2004BA514A13-9)~~
文摘[Objective] The effects of wheat based diet supplemented with xylanase on blood sugar and total protein in serum of geese were studied. [ Method ] By using the randomized design of single factor, the 1-day-old healthy goslings were divided into 6 groups and fed with corn based diet, wheat based diet and wheat based diet supplemented with xylanase at different concentrations respectively, the contents of blood sugar and total protein in serum were determined. [ Result] The wheat based diet supplemented with xylanase could increase the blood sugar and total protein in serum of geese and wheat based diet supplemented with 0.2% xylanase generated the best effect, which was higher than those of corn based diet group. As for the concentration of protein in serum, wheat based diet supplemented with 0.2% xylanase was significantly different from corn based diet and wheat based diet. [ Conclusion] The wheat based diet supplemented with xylanase could enhance geese production.
基金Supported by Research on Distant Hybridization Breeding of Forage(2008BADB3B02)in the Eleventh Five-year Plan Periodthe Major Scientific and Technical Project of Inner Mongolia Autonomous Region,"Products Development of High Quality Adequet Grass"~~
文摘Morphologic and cytological characteristics of hybrid F1 between E. canadensis and E. sibidcus were studied. The results showed that hybrid F1 were obviously exceeded parents in plant growth vigor, and spike type of F1 was between parents. The karyotype formula of hybrid F1 which was true hybrid was 2n =4x=16M ＋ 10m ＋2st. At meiotic anaphase, chromosome lagging behaviors were frequently observed. The frequency of lagging chromosomes of F1 was 87.37%. At meiotic metaphase, there were many univalents and multivalents, and the rod bivalent formed greatly.
文摘The pollen grain morphology and leaf epiderm shape and microstructural of Rye（ Secale cereal ）, common wheat and Octoploid Trititrigia were observed with the scanning electron microscope（SEM）. The results revealed that there were great differences between pollen and leaf epiderm microcosmic morphology in three species. Such characteristics of Octoploid tnticalwere between those of common wheat and Rye. The morphology of pollen grain and leaf epiderm shape counld be used as an index for taxonomy for genera and species, and had somewhat scientif- ic references to identify new multiploid species created by chromosome engineering.
文摘The economic losses and the health hazards of the mycotoxins produced by spoilage fungi are the main concerns of the food industry. The spoilage of bakery products by fungi is more common in countries with a high humidity and temperature. About 5-10% of food production is spoiled by the growth of yeast and fungi in food materials. Similarly, in Western Europe, the growth of the spoilage fungi of bread is estimated to reach more than 200 million Euros per year. The history conditions of the food can be a major factor in determining any fungal spoilage--for example, stored and processed foods are more sensitive to spoilage when compared with fresh and prepared foods. Lactic acid bacteria isolated from Bulgarian wheat and rye flour were used in the present study to check their antifungal properties against pathogenic yeast and fungi imperfecta using standard disc diffusion method in vitro. A broad spectrum of antifungal activity of the six newly identified as L. plantarum strains e Tsl, Ts2, Ts3,Ts4 and Ts5, and L. helveticus Ts6 was estimated. Our in vitro studies were performed with wheat and rye sourdough, in order to simulate a real product and to assess the bio-protective potential of the tested lactobacilli. The used test-cultures are representatives of carcinogenic, toxigenic, deteriorative and allergenic fungi from the genera .4spergillus and Penicillium. The all tested strains completely suppress the growth of against C. glabrata 72. Strains L. plantarum Tsl and Ts3 completely suppress the growth against S. cerevisae. While, in the sample with L. plantarum strains e Tsl, Ts2, Ts3,Ts4 and Ts5, and L. helveticus Ts6, a retarded and weak growth of A. niger and P. claviforme was observed. However, the spore germination and the colony growth started only on the fifth day of the mould lactobacilli co-cultivation, which also should be considered as a good result. In this study six isolates Tsl,Ts2, Ts3, Ts4, Ts5 and Ts6, from the traditional Bulgarian wheat and rye flour have been identified as L. plantarum and L. helveticus and characterized as cultures with promising antifungal activity. Obtained results from the combined molecular identification （16S rRNA gene sequencing） approach contribute to give new data on the microbial biodiversity of this not well-studied niche. The antifungal activity of our new isolates, identified as L. plantarum and L. helveticus, seems to be a promising advantage of these six strains, suggesting their potential applications in different food technologies. However, more experiments have to be conducted to clarify the nature and the mechanisms of the reported antifungal activity and they are still in progress. The combination of dairy origin and strong inhibitory activity of the lactobacillus strains is a prerequisite for their possible application as starters and/or bioprotective antifungal adjuncts.
文摘During the last thirty years the main interest in the medical consequences of milling of staple carbohydrate foods, particularly wheat and maize, has been in its effect on the fibre content as a result of the milling. The late nineteenth and early twentieth centuries in the West saw great changes in milling processes, from stone milling using water or wind power, to increasingly sophisticated roller milling, with an
文摘Severe solar events manifested by highly energetic X-Ray events accompanied by coronal mass ejections and proton flares caused flash floods in Makkah AI-Mukaramab, A1-Madinah AI-Munawarah and Jeddah. The responses can be prompt, delayed or prompt-delayed, suggesting that the protons entered the troposphere either through the opening of a direct gate in the magnetosphere to the location concer.led due to magnetic reconnection, through the polar gates or through those two paths respectively. The authors suggest that there is a magnetic anomaly in Makkah AI-Mukaramah area which makes it liable to be subjected to flash floods. The width of the solar streams determines the width of the gate opened in the magnetosphere via magnetic reconnection and thus narrow streams affect only one location of the three cities while extended width streams can cause flash floods in all of Makkah AI-Mukaramah AI-Madinah AI Munawarah and Jeddah. In addition, the November 24-26 Jeddah flash flood could be attributed to a prompt event due to a moderately fast solar stream that arrived the earth on those days.
文摘This study examines strategies in responding to thanks by CanE （Canadian English） and CamE （Cameroon English） speakers. Based on data collected by means of a DCT （Discourse Completion Task） questionnaire, the study addresses formal, functional, situational, and interactional similarities and differences in both varieties of English. With regard to speaker strategies （Aijmer, 1996） or conventions of means, it was found that the Canadian participants mostly prefer ＂minimizing the favor＂ when responding to thanks, while the Cameroonians most frequently ＂express appreciation＂. At the level of the realization types, the findings show that patterns with ＂no problem＂ are predominant in the Canadian corpus, whereas the Cameroonian respondents rather employ patterns with ＂welcome＂. Differences can also be found in the situational distribution of the speaker strategies and their linguistic realizations as well as in the use and the length of supportive moves.
文摘This study aims to evaluate the potentialities of Pseudocytisus integrifolius （Salisb） Rehder （Brassicaceae） as a botanical insecticide for the protection of stored wheat against two pests of stored grain. The essential oil of Pseudoeytisus integrifolius was tested at different doses on adults of Rhyzopertha dominica Fab. （Bostrychidae） and Sitophilus granarius Linn. （Curculionidae）, at a temperature of 28 ~C and a relative humidity of 75%. This oil has insecticidal activity and gives, for the studied adults, a very significant reduction. The essential oil extracted from Pseudocytisus integrifolius is toxic on Rhyzopertha dominica with LDs0 = 2.61 ~tL/30g grain and LDs0 = 3.99 ~L/30g grain for Sitophilus granarius, the chemical composition analysis shows the richness of the essential oil compounds known for their insecticidal properties as dimethyl disulfide （DMDS） and dimethyl trisulfide explains the results.
文摘Italian ray grass and oat are two grass species characterized by their ability to adjust tropical climate conditions. This study proposed to assess forage productivities to allow an appropriate mowing period determination in their use as dairy female feed in Madagascar. A test on small plots has been set up in the southern part of the capital city Antananarivo during one dry period （4 months）. Live observations followed by laboratory proximate analyses have been performed for forage productivity and feeding value determination. Cultivated on tanety （hill）, irrigated in counter season, results show that： （I） oat higher height （H = 96.7 cm） than Italian ray grass （H= 69.4 cm） at 99 days of age; （2） similar biomass productivity; （3） dry matter yields significantly different （p = 0.05）; （4） certain similarity between dry matter yields and FMU （fodder milk unit） score evolution; （5） leafy stage of Italian ray grasses at 99 days of age; （6） mid-flowering stage for oats during the same period. Cell wall content, crude fiber and dry matter contents increased with age （p = 0.05）. Crude proteins and minerals evolved in opposite directions. Gross energy content did not present precise variation with age. This study allowed that for an acceptable quantitative and qualitative production during dry seasons, good mowing period for Italian ray grass could start at 76 days age, while oat could start being harvested at 68 days.
基金National Basic Research Program of China(Grant No.2012CB518000)the National Natural Science Foundation of China(Grant No.21172012)the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20120001110010)
文摘As important constitutes in many drugs, piperazine comprised compounds are of great interest for drug design. In this paper, two piperazine-based compounds were synthesized for the first time, with different strategies exploited. For one compound, a highly reactive intermediate of isothiocyanate was constructed to get the desired piperazinecarbothioamide. The synthesis of the other compound was completed sequentially through Friedel-Crafts acylation, coupling reaction and Michael addition. Both synthetic routes have short steps and acceptable yields, and such strategies can be applied to the synthesis of similar oioerazine-containin~ comoounds.
基金Supported by the National Natural Science Foundation of China(Nos.30870456 and 30911130503)
文摘We investigated 15N abundance （δ15N） of winter wheat （Triticum aestivum cv. Jinmai 1） plants and soil at different growth stages in a field with a 13-year fertilization history of urea and compost, to determine whether or not the δ15N of plant parts can be used as an indicator of organic amendment with compost. Plant parts （roots, leaves, stems and grains） and soil were sampled at re-greening, jointing, grain filling and mature growth stages of winter wheat. There were significant differences between the urea and compost treatments in 815N of whole plants, plant parts and soil over the whole growing season. Determination of the δ15N of plant parts was more convenient than that of whole plant to distinguish between the application of organic amendment and synthetic N fertilizer.
