[ Objective] The aim of this study was to discuss the effect of antioxidants and lipid peroxidation from pea crops of plateau. [ Method] SOD enzyme liquid from pea crops of plateau was extracted by means of protein co...[ Objective] The aim of this study was to discuss the effect of antioxidants and lipid peroxidation from pea crops of plateau. [ Method] SOD enzyme liquid from pea crops of plateau was extracted by means of protein concentration assay, enzyme activity assay and antioxidant activity determination by DPPH method, peroxide activity inhibition of in vitro tissues from mice by homogenate MDA colorimetry method and lipid peroxidation assay of in vitro tissues. [ Result ] IC50 of the crude enzyme liquid extracted from pea on DPPH was 55.16 mg/L, while the scavenging rate of the crude enzyme liquid was lower than that of ascorbic acid, tea polyphenol and citric acid with the same concentration. The synergistic effect was found in ascorbic acid and crude enzyme liquid, but the synergism of ascorbic acid was better than that of citric acid. IC50 of SOD enzyme liquid extracted from pea on DPPH was 11.1 mg/L, which was better than that of tea polyphenol and closely similar to that of ascorbic acid. SOD enzyme liquid extracted from pea had an inhibitory effect on MDA production from in vitro tissues such as liver, kidney and heart, especially for a significantly inhibitory effect on MDA from liver in vitro. When the concentration was 0.25 mg/ml, the inhibition rate reached 78.3%, and then the inhibition rate increased little with the concentration incresas, while its effect on heart and kidney were inferior. [ Conclusion] SOD crude enzyme liquid and SOD enzyme liquid extracted from pea all have certain DPPH scavenging capacity, while SOD enzyme liquid extracted from pea has an inhibitory effect on lipid peroxidation.展开更多
Magnéli phases TinO2n-1 have been demonstrated as promising environmentally friendly materials in advanced oxidation processes.In this study,Magnéli phases TinO2n-1 have been used as catalysts for the ozonat...Magnéli phases TinO2n-1 have been demonstrated as promising environmentally friendly materials in advanced oxidation processes.In this study,Magnéli phases TinO2n-1 have been used as catalysts for the ozonation of phenol in aqueous solution for the first time.The materials exhibited excellent catalytic ozonation activities both in phenol degradation and mineralization.When Ti4O7was added,the reaction rate was six-fold higher than that of with ozone alone,while the total organic carbon removal rate was substantially elevated from around 19.2%to 92%.By virtue of the good chemical stability of the materials,a low metal leaching of less than 0.15 mg·L^-1could effectively avoid the secondary pollution by metal ions.Radical quenching tests revealed·O2^-and ^1O2to be active oxygen species for phenol degradation at p H 5.As semiconductor catalysts,TinO2n-1 materials show electronic transfer capability.Ozone adsorbed at B-acid sites of the catalyst surface can capture an electron from the conversion of Ti(Ⅲ)to Ti(Ⅳ),and is thereby broken into the active oxygen species.It was interesting to observe that TinO2n-1 exhibit better catalytic activity for phenol degradation and mineralization with lower n value.The difference in electrical conductivity can be considered as a major factor for the catalytic performances.More highly conductive catalysts show a faster electron-transfer rate and better catalytic activity.Thus,significant evidences have been obtained for a single-electron-transfer mechanism of catalytic ozonation with Magnéli phases TinO2n-1.展开更多
In order to resolve grid distortions in finite element method(FEM), the meshless numerical method which is called general particle dynamics(GPD) was presented to simulate the large deformation and failure of geomateri...In order to resolve grid distortions in finite element method(FEM), the meshless numerical method which is called general particle dynamics(GPD) was presented to simulate the large deformation and failure of geomaterials. The Mohr-Coulomb strength criterion was implemented into the code to describe the elasto-brittle behaviours of geomaterials while the solid-structure(reinforcing pile) interaction was simulated as an elasto-brittle material. The Weibull statistical approach was applied to describing the heterogeneity of geomaterials. As an application of general particle dynamics to slopes, the interaction between the slopes and the reinforcing pile was modelled. The contact between the geomaterials and the reinforcing pile was modelled by using the coupling condition associated with a Lennard-Jones repulsive force. The safety factor, corresponding to the minimum shear strength reduction factor "R", was obtained, and the slip surface of the slope was determined. The numerical results are in good agreement with those obtained from limit equilibrium method and finite element method. It indicates that the proposed geomaterial-structure interaction algorithm works well in the GPD framework.展开更多
Most modern tall buildings using lighter construction materials are more flexible, which can lead to excessive wind-induced vibrations resulting in occupant discomfort and structural unsafety. It is necessary to predi...Most modern tall buildings using lighter construction materials are more flexible, which can lead to excessive wind-induced vibrations resulting in occupant discomfort and structural unsafety. It is necessary to predict and mitigate such wind-induced vibration at the preliminary design stage. Fluctuating across and along-wind loads acting on a tall building that could not be formulated theoretically were simulated numerically in the time domain using known across and along-wind load spectra. These simulated wind loads were used to estimate the across and along-wind responses of a tall building, which are less narrow-banded processes, based on the state space variable approach. The simulated across-wind response of root-mean-square value(0.0047) and that of KAREEM's(0.0040) and the simulated along-wind response of root-mean-square value(0.021) and that of SOLARI's(0.027) were compared. It is found that these are good approximations of closed form responses. Therefore, these numerically simulated across and along-wind loads can be used for across and along-wind responses estimation for the wind-resistant design of a tall building at the preliminary design stage.展开更多
Experimental study is performed to design and develop a cylindrical micro-pump driven by expansion and contraction of the heat deformation material, whose variation is caused with the aid of heating and cooling proper...Experimental study is performed to design and develop a cylindrical micro-pump driven by expansion and contraction of the heat deformation material, whose variation is caused with the aid of heating and cooling properties of Peltier devices. The pump consists of the diffuser valve unit, the heat deformation material unit, the nozzle valve unit, the Peltier devices and the cover. The input current of the Peltier devices is controlled by the bipolar power supply so that the Peltier devices are heated and cooled periodically. The working fluid flow in the micro-pump is caused by the periodical thermal deformation of material which is caused by the periodical heating and cooling of the Peltier devices. In order to measure the fluid flow in the micro-pump, micro air bubbles are employed as a tracer. The corresponding movement is recorded by X-ray apparatus and its velocity is measured by PIV (particle image velocimetry). It is found that, the micro-pump developed here can make the working fluid flow. The corresponding fluid flow in the micro pump is confirmed by the numerical method.展开更多
The present study proposes a novel refrigerator in theory, which uses 4He as working fluid to directly reach 2.3 K and uses a small amount of 3He to attain the temperature below 1.7 K. The compact and highly efficient...The present study proposes a novel refrigerator in theory, which uses 4He as working fluid to directly reach 2.3 K and uses a small amount of 3He to attain the temperature below 1.7 K. The compact and highly efficient new refrigerator works with the Vuilleumier cycle. The novel refrigerator is driven by a thermal compressor which creatively uses mix-refrigerants J-T refrigerator alternative to liquid nitrogen as the power source. Furthermore, the Vuilleumier cycle can be used to achieve temperature below liquid helium with the improvement of the ultra-low temperature regenerator material. A new method of reaching the temperature below 1.7 K is proposed on the regenerative refrigerator, which could be an important breakthrough for the cryogenic science and technology.展开更多
文摘[ Objective] The aim of this study was to discuss the effect of antioxidants and lipid peroxidation from pea crops of plateau. [ Method] SOD enzyme liquid from pea crops of plateau was extracted by means of protein concentration assay, enzyme activity assay and antioxidant activity determination by DPPH method, peroxide activity inhibition of in vitro tissues from mice by homogenate MDA colorimetry method and lipid peroxidation assay of in vitro tissues. [ Result ] IC50 of the crude enzyme liquid extracted from pea on DPPH was 55.16 mg/L, while the scavenging rate of the crude enzyme liquid was lower than that of ascorbic acid, tea polyphenol and citric acid with the same concentration. The synergistic effect was found in ascorbic acid and crude enzyme liquid, but the synergism of ascorbic acid was better than that of citric acid. IC50 of SOD enzyme liquid extracted from pea on DPPH was 11.1 mg/L, which was better than that of tea polyphenol and closely similar to that of ascorbic acid. SOD enzyme liquid extracted from pea had an inhibitory effect on MDA production from in vitro tissues such as liver, kidney and heart, especially for a significantly inhibitory effect on MDA from liver in vitro. When the concentration was 0.25 mg/ml, the inhibition rate reached 78.3%, and then the inhibition rate increased little with the concentration incresas, while its effect on heart and kidney were inferior. [ Conclusion] SOD crude enzyme liquid and SOD enzyme liquid extracted from pea all have certain DPPH scavenging capacity, while SOD enzyme liquid extracted from pea has an inhibitory effect on lipid peroxidation.
基金Supported by the National Natural Science Foundation of China(21676139)the Higher Education Natural Science Foundation of Jiangsu Province(15KJA530001)+1 种基金the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the Research Fund of State Key Laboratory of MaterialsOriented Chemical Engineering(ZK201604)
文摘Magnéli phases TinO2n-1 have been demonstrated as promising environmentally friendly materials in advanced oxidation processes.In this study,Magnéli phases TinO2n-1 have been used as catalysts for the ozonation of phenol in aqueous solution for the first time.The materials exhibited excellent catalytic ozonation activities both in phenol degradation and mineralization.When Ti4O7was added,the reaction rate was six-fold higher than that of with ozone alone,while the total organic carbon removal rate was substantially elevated from around 19.2%to 92%.By virtue of the good chemical stability of the materials,a low metal leaching of less than 0.15 mg·L^-1could effectively avoid the secondary pollution by metal ions.Radical quenching tests revealed·O2^-and ^1O2to be active oxygen species for phenol degradation at p H 5.As semiconductor catalysts,TinO2n-1 materials show electronic transfer capability.Ozone adsorbed at B-acid sites of the catalyst surface can capture an electron from the conversion of Ti(Ⅲ)to Ti(Ⅳ),and is thereby broken into the active oxygen species.It was interesting to observe that TinO2n-1 exhibit better catalytic activity for phenol degradation and mineralization with lower n value.The difference in electrical conductivity can be considered as a major factor for the catalytic performances.More highly conductive catalysts show a faster electron-transfer rate and better catalytic activity.Thus,significant evidences have been obtained for a single-electron-transfer mechanism of catalytic ozonation with Magnéli phases TinO2n-1.
基金Projects(51325903,51279218)supported by the National Natural Science Foundation of ChinaProject(cstc2013kjrcljrccj0001)supported by the Natural Science Foundation Project of CQ CSTC,ChinaProject(20130191110037)supported by Research fund by the Doctoral Program of Higher Education of China
文摘In order to resolve grid distortions in finite element method(FEM), the meshless numerical method which is called general particle dynamics(GPD) was presented to simulate the large deformation and failure of geomaterials. The Mohr-Coulomb strength criterion was implemented into the code to describe the elasto-brittle behaviours of geomaterials while the solid-structure(reinforcing pile) interaction was simulated as an elasto-brittle material. The Weibull statistical approach was applied to describing the heterogeneity of geomaterials. As an application of general particle dynamics to slopes, the interaction between the slopes and the reinforcing pile was modelled. The contact between the geomaterials and the reinforcing pile was modelled by using the coupling condition associated with a Lennard-Jones repulsive force. The safety factor, corresponding to the minimum shear strength reduction factor "R", was obtained, and the slip surface of the slope was determined. The numerical results are in good agreement with those obtained from limit equilibrium method and finite element method. It indicates that the proposed geomaterial-structure interaction algorithm works well in the GPD framework.
基金Project(2011-0028567)supported by the National Research Foundation of Korea
文摘Most modern tall buildings using lighter construction materials are more flexible, which can lead to excessive wind-induced vibrations resulting in occupant discomfort and structural unsafety. It is necessary to predict and mitigate such wind-induced vibration at the preliminary design stage. Fluctuating across and along-wind loads acting on a tall building that could not be formulated theoretically were simulated numerically in the time domain using known across and along-wind load spectra. These simulated wind loads were used to estimate the across and along-wind responses of a tall building, which are less narrow-banded processes, based on the state space variable approach. The simulated across-wind response of root-mean-square value(0.0047) and that of KAREEM's(0.0040) and the simulated along-wind response of root-mean-square value(0.021) and that of SOLARI's(0.027) were compared. It is found that these are good approximations of closed form responses. Therefore, these numerically simulated across and along-wind loads can be used for across and along-wind responses estimation for the wind-resistant design of a tall building at the preliminary design stage.
文摘Experimental study is performed to design and develop a cylindrical micro-pump driven by expansion and contraction of the heat deformation material, whose variation is caused with the aid of heating and cooling properties of Peltier devices. The pump consists of the diffuser valve unit, the heat deformation material unit, the nozzle valve unit, the Peltier devices and the cover. The input current of the Peltier devices is controlled by the bipolar power supply so that the Peltier devices are heated and cooled periodically. The working fluid flow in the micro-pump is caused by the periodical thermal deformation of material which is caused by the periodical heating and cooling of the Peltier devices. In order to measure the fluid flow in the micro-pump, micro air bubbles are employed as a tracer. The corresponding movement is recorded by X-ray apparatus and its velocity is measured by PIV (particle image velocimetry). It is found that, the micro-pump developed here can make the working fluid flow. The corresponding fluid flow in the micro pump is confirmed by the numerical method.
基金supported by the National Natural Science Foundation of China (Grant No. 50890181)
文摘The present study proposes a novel refrigerator in theory, which uses 4He as working fluid to directly reach 2.3 K and uses a small amount of 3He to attain the temperature below 1.7 K. The compact and highly efficient new refrigerator works with the Vuilleumier cycle. The novel refrigerator is driven by a thermal compressor which creatively uses mix-refrigerants J-T refrigerator alternative to liquid nitrogen as the power source. Furthermore, the Vuilleumier cycle can be used to achieve temperature below liquid helium with the improvement of the ultra-low temperature regenerator material. A new method of reaching the temperature below 1.7 K is proposed on the regenerative refrigerator, which could be an important breakthrough for the cryogenic science and technology.