锡烯作为新型的二维材料由于其预测的优异特性受到广泛关注,锡烯在生长过程中与衬底间的相互作用是该体系研究的重要课题。本文采用分子束外延法在平整有序的Au(111)表面沉积Sn元素制备锡烯,利用原位条件下的低能电子衍射(Low Energy El...锡烯作为新型的二维材料由于其预测的优异特性受到广泛关注,锡烯在生长过程中与衬底间的相互作用是该体系研究的重要课题。本文采用分子束外延法在平整有序的Au(111)表面沉积Sn元素制备锡烯,利用原位条件下的低能电子衍射(Low Energy Electron Diffraction,LEED)和同步辐射光电子能谱(Synchrotron Radiation Photoemission Spectroscopy,SR-PES)对不同覆盖度的样品表面进行分析,系统地研究了超高真空环境下锡烯在Au(111)表面的形成过程。结果表明:Sn原子先与Au(111)衬底发生强相互作用形成合金,随着生长厚度的增加,逐步形成锡烯并覆盖在合金表面。展开更多
Ordered epitaxial ZrO2 films were grown on Pt(111) and characterized by low energy electron diffraction (LEED), synchrotron radiation photoemission spectroscopy (SRPES) and X-ray photoelectron spectroscopy (XPS). The ...Ordered epitaxial ZrO2 films were grown on Pt(111) and characterized by low energy electron diffraction (LEED), synchrotron radiation photoemission spectroscopy (SRPES) and X-ray photoelectron spectroscopy (XPS). The films were prepared by vapor deposition of zirconium in an O2 atmosphere followed by annealing under ultra high vacuum. At low coverages, the films grew as discontinuous two-dimentional islands with ordered structures. The size and structure of these islands were dependent on the coverage of ZrO2 films. At coverage <0.5 monolayer (ML), ( 19^(1/2) × 19^(1/2)) R23.4° and (5×5) structures coexisted on the surface. As the coverage increased, the (19^(1/2) × 19^(1/2) ) R23.4° structure developed with increasing degree of long-range order, while the (5×5) structure gradually faded. When the coverage reached >6 ML, a continuous ZrO2(111) film was formed with a (1×1) surface LEED pattern coexisting with a (2×2) pattern. These ordered thin ZrO2 films provide good model surfaces of bulk ZrO2 and can be used for further fundamental studies of the surface chemistry of ZrO2 using modern surface science techniques.展开更多
文摘锡烯作为新型的二维材料由于其预测的优异特性受到广泛关注,锡烯在生长过程中与衬底间的相互作用是该体系研究的重要课题。本文采用分子束外延法在平整有序的Au(111)表面沉积Sn元素制备锡烯,利用原位条件下的低能电子衍射(Low Energy Electron Diffraction,LEED)和同步辐射光电子能谱(Synchrotron Radiation Photoemission Spectroscopy,SR-PES)对不同覆盖度的样品表面进行分析,系统地研究了超高真空环境下锡烯在Au(111)表面的形成过程。结果表明:Sn原子先与Au(111)衬底发生强相互作用形成合金,随着生长厚度的增加,逐步形成锡烯并覆盖在合金表面。
基金supported by the Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP, 200803580012)the National Natural Science Foundation of China (20873128)+2 种基金the Program for New Century Excellent Talents in University (NCET)the National Basic Research Program of China (2010CB923302)the Hundred Talents Program of the Chinese Academy of Sciences
文摘Ordered epitaxial ZrO2 films were grown on Pt(111) and characterized by low energy electron diffraction (LEED), synchrotron radiation photoemission spectroscopy (SRPES) and X-ray photoelectron spectroscopy (XPS). The films were prepared by vapor deposition of zirconium in an O2 atmosphere followed by annealing under ultra high vacuum. At low coverages, the films grew as discontinuous two-dimentional islands with ordered structures. The size and structure of these islands were dependent on the coverage of ZrO2 films. At coverage <0.5 monolayer (ML), ( 19^(1/2) × 19^(1/2)) R23.4° and (5×5) structures coexisted on the surface. As the coverage increased, the (19^(1/2) × 19^(1/2) ) R23.4° structure developed with increasing degree of long-range order, while the (5×5) structure gradually faded. When the coverage reached >6 ML, a continuous ZrO2(111) film was formed with a (1×1) surface LEED pattern coexisting with a (2×2) pattern. These ordered thin ZrO2 films provide good model surfaces of bulk ZrO2 and can be used for further fundamental studies of the surface chemistry of ZrO2 using modern surface science techniques.
