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一种新的热分析动力学处理方法 被引量:11
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作者 沈玉芳 陈栋华 袁誉洪 《华中师范大学学报(自然科学版)》 CAS CSCD 北大核心 2003年第1期75-79,共5页
用一种新的方法对一水草酸钙(CaC2O4·H2O)脱水反应的热分析动力学三因子,即活化能Ea、指前因子A和反应机理函数f(α)进行了求取.此方法可分为三步:(1)用迭代的方法求取Ea值;(2)用Popescu的方法求取反应的f(α);(3)由以上两步所得... 用一种新的方法对一水草酸钙(CaC2O4·H2O)脱水反应的热分析动力学三因子,即活化能Ea、指前因子A和反应机理函数f(α)进行了求取.此方法可分为三步:(1)用迭代的方法求取Ea值;(2)用Popescu的方法求取反应的f(α);(3)由以上两步所得的结果求取指前因子A.此方法有两大优点:对动力学参数Ea和f(α)分别进行求取,从而使f(α)求取的准确性不因Ea值求取是否存在误差而受影响;在f(α)的求取中没有引入任何积分误差,从而提高了计算结果的准确性. 展开更多
关键词 动力学处理方法 迭代法 Popescu法 非等温热分析 一水草酸钙 脱水反应 活化能 指前因子
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Aniline destruction by supercritical water oxidation and its reaction kinetics
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作者 WANG Jing-chang ZHAO Qi-cheng +1 位作者 LI Zhi-yi ZHANG Ping 《Journal of Environmental Science and Engineering》 2009年第7期14-17,共4页
Supercritical water oxidation (SCWO) is an effective method for wastewater treatment. In this study, a lot of experiments are carried out to study the influence of various factors on the aniline destruction rate in ... Supercritical water oxidation (SCWO) is an effective method for wastewater treatment. In this study, a lot of experiments are carried out to study the influence of various factors on the aniline destruction rate in the SCWO process with a novel experiment setup. The experimental results show that the aniline destruction rate rises with the increase of the residence time, the reaction temperature and the reaction pressure. A dynamics analysis of the aniline SCWO reaction is conducted and the dynamic equation is obtained. 展开更多
关键词 wastewater treatment supercritical water oxidation aniline destruction
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On the treatment of solid boundary in smoothed particle hydrodynamics 被引量:29
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作者 LIU MouBin SHAO JiaRu CHANG JianZhong 《Science China(Technological Sciences)》 SCIE EI CAS 2012年第1期244-254,共11页
As a popular meshfree particle method,the smoothed particle hydrodynamics(SPH) has suffered from not being able to di-rectly implement the solid boundary conditions.This influences the SPH approximation accuracy and h... As a popular meshfree particle method,the smoothed particle hydrodynamics(SPH) has suffered from not being able to di-rectly implement the solid boundary conditions.This influences the SPH approximation accuracy and hinders its further de-velopment and application to engineering and scientific problems.In this paper,a coupled dynamic solid boundary treatment(SBT) algorithm has been proposed,after investigating the features of existing SPH SBT algorithms.The novelty of the cou-pled dynamic SBT algorithm includes a new repulsive force between approaching fluid and solid particles,and a new numeri-cal approximation scheme for estimating field functions of virtual solid particles.The new SBT algorithm has been examined with three numerical examples including a typical dam-break flow,a dam-break flow with a sharp-edged obstacle,and a water entry problem.It is demonstrated that SPH with this coupled dynamic boundary algorithm can lead to accurate results with smooth pressure field,and that the new SBT algorithm is also suitable for complex and even moving solid boundaries. 展开更多
关键词 smoothed particle hydrodynamics (SPH) particle method solid boundary treatment (SBT) coupled dynamic SBT
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