酸岩反应动力学方式与酸溶蚀行为关系的理论判别

酸岩反应动力学方式与酸溶蚀行为之间关系的理论判别，对更好地实施油井酸化增产技术有重要意义。本文在前文工作基础上通过酸液在多孔介质毛细管内的层流传质与反应问题的求解，提出了受对流传质、扩散传质以及表面反应控制的动力学相互转化的一套临界判据，可在一定程度上对酸岩反应动力学方式与酸溶蚀行为之间的关系作出理论判别。

聚合物包膜尿素溶出动力学特征及其与包膜层通透性的关系

通过聚合物包膜尿素(PCU)在30℃纯水中的溶出试验,精确描述了PCU尿素溶出的动力学特征。将PCU尿素溶出过程分成4个阶段:滞后阶段、溶胀阶段、稳定阶段和衰退阶段。同时,基于Fick扩散第一定律,确立了PCU尿素溶出速率与包膜层通透性的关系方程,并根据此方程,推断出PCU尿素溶出过程中包膜层通透性的变化情况。结果表明,在溶胀阶段,溶出速率系数K(包膜层通透性的量度)逐渐变大;在稳定阶段,K为一稳定值;在衰退阶段,K随时间t变化可以用公式K=mt^(n-1)表示(式中m和n均为常数)。当n>1时,包膜层的通透性逐渐增大,肥心尿素溶出加快;当n=1时,包膜层通透性稳定,肥心尿素以一级动力学方式溶出;当n<1时,包膜层通透性逐渐减小,肥心尿素溶出变慢,导致明显的“尾留效应”。

UPWIND SCHEME FOR IDEAL 2-D MHD FLOWS BASED ON UNSTRUCTURED MESH

An upwind scheme based on the unstructured mesh is developed to solve ideal 2-D magnetohydrodynamics （MHD） equations. The inviscid fluxes are approximated by using the modified advection upstream splitting method （AUSM） scheme, and a 5-stage explicit Runge-Kutta scheme is adopted in the time integration. To avoid the influence of the magnetic field divergence created during the simulation, the hyperbolic divergence cleaning method is introduced. The shock-capturing properties of the method are verified by solving the MHD shock-tube problem. Then the 2-D nozzle flow with the magnetic field is numerically simulated on the unstructured mesh. Computational results demonstrate the effects of the magnetic field and agree well with those from references.

Release of Soil Nonexchangeable K by Organic Acids

The amounts of soil nonexchangeable K extracted with 0.01 mL/ L oxalic acid and citric acid solutions and that with boiling 1 mL/ L HNO3 for ten minutes were remarkably significantly correlated with each other, and the amount extracted with the oxalic acid solution was higher than that with the citric acid solution. The soil nonexchangeable K release was comprised of two first-order kinetic processes. The faster one was ascribed to the interlayer K in outer sphere, while the slower one to that in inner sphere. The rate constants of the soil nonexchageable K were significantly correlated with the amounts of nonexchangeable K extracted with boiling ImL/ L HNO3 for ten minutes. Study on the fitness of different kinetic equations indicated that the first-order, parabolic diffusion and zero-order equations could all describe the release of soil nonexchangeable K. well, but Elovich equation was not suitable to describe it.

Comparative Study on the Kinetic Equations of Potassium Release from Soils

Elovicb, two-constant, parabolic diffusion, exponential, second-order, first-order and zero-order equations were used to describe the kinetic characteristics of potassium desorption from six paddy soils df Zhejiang Province in a constant electric field (44.4 V/ cm) of EUF. Results showed that the second-order and Elovich equations could describe the potassium desorption kinetics best, as evidenced by the highest correlation coefficients (r) and the lowest standard errors (SE). The first-order, two-constant and parabolic diffusion equations also described the K desorption kinetics well, as showed by the relatively high correlation coefficients and relatively low standard errors. The zero-order equation did not describe the K desorption satisfactorily with a relatively low correlation coefficient and relatively high standard error. However, the exponential equation could not be used to describe the K desorption kinetics, due to the lowest correlation coefficient and the highest standard error.

Comparison of Seven Kinetic Equations for K Release and Application of Kinetic Parameters

Corn field experiments with two treatments, NP and NPK, where N in the form of urea, P in the form of calcium phosphate, and K in the form of KCl were applied at rates of 187.5, 33.3, and 125 kg ha^-1, respectively, on soils derived from Quaternary red clay were conducted in the hilly red soil region of Zhejiang Province, China. Plant grains and stalks were collected for determination of K content. Seven equations were used to describe the kinetics of K release from surface soil samples taken before the corn experiments under electric field strengths of 44.4 and 88.8 V cm^-1 by means of electro-ultrafiltration （EUF） and to determine if their parameters had a practical application. The second-order and Elovich equations excellently described K release; the first-order, power function, and parabolic diffusion equations also described K release well; but the zero-order and exponential equations were not so good at reflecting K release. Five reference standards from the field experiments, including relative grain yield （yield of the NP treatment/yield of the NPK treatment）, relative dry matter yield （dry matter of the NP treatment/dry matter of the NPK treatment）, quantity of K uptake in the NP treatment （no K application）, soil exchangeable K, and soil HNO3-soluble K, were used to test the effectiveness of equation parameters obtained from the slope or intercept of these equations. Correlations of the ymax （the maximum desorbable quantity of K） in the second-order equation and the constant b in the first-order and Elovich equations to all five reference standards were highly significant （P ≤ 0.01）. The constant a in the power function equation was highly significant （P 〈 0.01） for four of the five reference standards with the fifth being significant （P ≤ 0.05）. The constant b in the parabolic equation was also significantly correlated （P ≤ 0.05） to the relative grain yield and soil HNO3-soluble K. These suggested that all of these parameters could be used to estimate the soil K supplying capacity and the crop response to K fertilizer.

Design and dynamic analysis of the micro-suspended monorail

A 20 degree of the freedom model of the micro-suspended monorail is established to analyze a new type of the vehicle system named micro-suspended monorail.The formula of the tire is established by using the magic formula.Through the modal analysis of the vehicle,the modes of the vehicle are obtained,and resonance has little effect on the vehicle.When the vehicle moves in a right turn curve,it yaws in the clockwise direction.Under the action of the guidewheel(stable wheel)force,the front bogie yaws clockwise but the rear one yaws counterclockwise.Moreover,the two bogies and the car body roll during the curve passing process of the vehicle.When the vehicle speed is high enough,the left drive wheel will derail and the anti-overturning moments are provided by the stable wheels.Then,the car body yaws in the counterclockwise direction when it moves out of the curve.In the simulation of the vehicle passing the curve,the clearance between the guide wheel and rail surface will lead to a fatal impact on the bogie.At the same time,the dynamic response of the vehicle under the crosswind is tested.The vehicle will not overturn due to the crosswind.Finally,the collision of adjacent vehicles is analyzed.The results show that there is an intermittent collision force between two vehicles due to the vehicle's non synchronous pitch motion.

Form Invariant Sommerfeld Electrical Conductivity in Generalised d Dimensions

The Sommerfeld electrical conductivity is calculated in d dimensions following Boltzmann kinetic approach.At T = 0,the mathematical form of the electrical conductivity is found to remain invariant in any generalised spatial(d)dimensions.

A Multigrid Block LU-SGS Algorithm for Euler Equations on Unstructured Grids

We propose an efficient and robust algorithm to solve the steady Euler equa- tions on unstructured grids.The new algorithm is a Newton-iteration method in which each iteration step is a linear multigrid method using block lower-upper symmetric Gauss-Seidel(LU-SGS)iteration as its smoother To regularize the Jacobian matrix of Newton-iteration,we adopted a local residual dependent regularization as the replace- ment of the standard time-stepping relaxation technique based on the local CFL number The proposed method can be extended to high order approximations and three spatial dimensions in a nature way.The solver was tested on a sequence of benchmark prob- lems on both quasi-uniform and local adaptive meshes.The numerical results illustrated the efficiency and robustness of our algorithm.

Evaluation of Four Measurement Operation Modes of Streaming Potential for Microfiltration and Ultrafiltration Membranes

Surface charge characteristics of a membrane can be determined by the streaming potential. In order to obtain more accurate streaming potential value during the measurement, four measurement operation modes were investigated in this study, and among the four modes, the steady mode with pressure stepped downward was considered the best one. Experimental results showed that the effects of compaction on the streaming potential measurement for a microfiltration membrane was more obvious than that for a ultrafiltration membrane. Both feed pH and presoaking could affect the measurement of streaming potential.

Comparison of the spatio-temporal dynamics of vegetation between the Changbai Mountains of eastern Eurasia and the Appalachian Mountains of eastern North America

The Changbai Mountains and the Appalachian Mountains have similar spatial contexts.The elevation,latitude,and moisture gradients of both mountain ranges offer regional insight for investigating the vegetation dynamics in eastern Eurasia and eastern North America.We determined and compared the spatial patterns and temporal trends in the normalized difference vegetation index(NDVI)in the Changbai Mountains and the Appalachian Mountains using time series data from the Global Inventory Modeling and Mapping Studies 3^(rd) generation dataset from 1982 to 2013.The spatial pattern of NDVI in the Changbai Mountains exhibited fragmentation,whereas NDVI in the Appalachian Mountains decreased from south to north.The vegetation dynamics in the Changbai Mountains had an insignificant trend at the regional scale,whereas the dynamics in the Appalachian Mountains had a significant increasing trend.NDVI increased in 55% of the area of the Changbai Mountains and in 95% of the area of the Appalachian Mountains.The peak NDVI occurred one month later in the Changbai Mountains than in the Appalachian Mountains.The results revealed a significant increase in NDVI in autumn in both mountain ranges.The climatic trend in the Changbai Mountains included warming and decreased precipitation,and whereas that in the Appalachian Mountains included significant warming and increased precipitation.Positive and negative correlations existed between NDVI and temperature and precipitation,respectively,in both mountain ranges.Particularly,the spring temperature and NDVI exhibited a significant positive correlation in both mountain ranges.The results of this study suggest that human actives caused the differences in the spatial patterns of NDVI and that various characteristics of climate change and intensity of human actives dominated the differences in the NDVI trends between the Changbai Mountains and the Appalachian Mountains.Additionally,the vegetation dynamics of both mountain ranges were not identical to those in previous broader-scale studies.

Characterization on the hydrodynamics of a covering-plate Rushton impeller

A modified Rushton impeller with two circular covering-plates mounted on the upper and lower sides of the blades was designed.There are gaps between the plates and the blades.The turbulent hydrodynamics was analyzed by the computational fluid dynamics(CFD) method.Firstly,the reliability of the numerical model and simulation method was verified by comparing with the experimental results from literature.Subsequently,the power consumption,flow pattern,mean velocity and mixing time of the covering-plate Rushton impeller(RT-C) were studied and compared with the standard Rushton impeller(RT) operated under the same conditions.Results show that the power consumption can be decreased about 18%.Compared with the almost unchanged flow field in the lower stirred tank,the mean velocity was increased at the upper half of the stirred tank.And in the impeller region,the mean axial and radial velocities were increased,the mean tangential velocity was decreased.In addition,the average mixing time of RT-C was shortened about 4.14% than the counterpart of RT.The conclusions obtained here indicated that RT-C has a more effective mixing performance and it can be used as an alternative of RT in the process industries.

On the Geometrical Meaning of the Dynamic Equations in Analytical Mechanics

In this paper,the modern geometrical structure of analytical mechanics,the exterior differential forms and the geometrical meaning of dynamic equations are briefly discussed.

Anomalous Scaling of Surface Growth Equations with Spatially and Temporally Correlated Noise

Based on the scaling idea of local slopes by Lopez et al. [Phys. Rev. Lett. 94 （2005） 166103], we investigate anomalous dynamic scaling of （d ＋ 1）-dimensional surface growth equations with spatially and temporally correlated noise. The growth equations studied include the Kardar-Parisi-Zhang （KPZ）, Sun-Guo-Grant （SGG）, and Lai-Das Sarma-Villain （LDV） equations. The anomalous scaling exponents in both the weak- and strong-coupling regions are obtained, respectively.

A Framework for Non-Equilibrium Statistical Ensemble Theory

Since Gibbs synthesized a general equilibrium statistical ensemble theory, many theorists have attempted to generalized the Gibbsian theory to non-equilibrium phenomena domain, however the status of the theory of non-equilibrium phenomena can not be said as firm as well established as the Gibbsian ensemble theory. In this work, we present a framework for the non-equilibrium statistical ensemble formalism based on a subdynamic kinetic equation (SKE) rooted from the Brussels-Austin school and followed by some up-to-date works. The constructed key is to use a similarity transformation between Gibbsian ensembles formalism based on Liouville equation and the subdynamic ensemble formalism based on the SKE. Using this formalism, we study the spin-Boson system, as cases of weak coupling or strongly coupling, and obtain the reduced density operators for the Canonical ensembles easily.

Prediction of Aircraft＇s Longitudinal Motion Based on Aerodynamic Coefficients and Derivatives by Surrogate Model Approach

The accuracy of a flight simulation is highly dependent on the quality of the aerodynamic database and prediction accuracies of the aerodynamic coefficients and derivatives. A surrogate model is an approximation method that is used to predict unknown functions based on the sampling data obtained by the design of experiments. This model can also be used to predict aerodynamic coefficients/derivatives using several measured points. The objective of this paper is to develop an efficient digital flight simulation by solving the equation of motion to predict the aerodynamics data using a surrogate model. Accordingly, there is a need to construct and investigate aerodynamic databases and compare the accuracy of the surrogate model with the exact solution, and hence solve the equation of motion for the flight simulation analysis. In this study, sample datas for models are acquired from the USAF Stability and Control DATCOM, and a database is constructed for two input variables （the angle of attack and Mach number）, along with two derivatives of the X-force axis and three derivatives for the Z-force axis and pitching moment. Furthermore, a comparison of the value predicted by the Kriging model and the exact solution shows that its flight analysis prediction ability makes it possible to use the surrogate model in future analyses.

Mathematical Model for Takeoff Simulation of a Wing in Proximity to the Ground

Aircraft flying close to the ground benefit from enhanced efficiency owing to decreased induced drag and increased lift. In this study, a mathematical model is developed to simulate the takeoff of a wing near the ground using an Iterative Boundary Element Method （IBEM） and the finite difference scheme. Two stand-alone sub-codes and a mother code, which enables communication between the sub-codes, are developed to solve for the self-excitation of the Wing-In-Ground （WIG） effect. The aerodynamic force exerted on the wing is calculated by the first sub-code using the IBEM, and the vertical displacement of the wing is calculated by the second sub-code using the finite difference scheme. The mother code commands the two sub-codes and can solve for the aerodynamics of the wing and operating height within seconds. The developed code system is used to solve for the force, velocity, and displacement of an NACA6409 wing at a 4° Angle of Attack （AoA） which has various numerical and experimental studies in the literature. The effects of thickness and AoA are then investigated and conclusions were drawn with respect to generated results. The proposed model provides a practical method for understanding the flight dynamics and it is specifically beneficial at the pre-design stages of a WIG effect craft.

A Decay Result to an Elliptic Equation with Dynamical Boundary Condition

The decay estimations of the solution to an elliptic equation with dynamical boundary condition is considered.We proved that,for suitable initial datum,the energy of the solution decays "in time" exponentially if p=0,whereas the decay is polynomial order if p>0.

The Third Invariant Form of Hydrodynamic Equations and Application for Definition of Water Hammer Characteristics in Pipe

There were for a long time two invariant forms of hydrodynamic equations： one was related to coordinate system of references, and the other was versus to measure units of characteristics. These both invariant forms had important roles in the development of theoretical and practical applications of hydro-aerodynamics and related industries. The third invariant form of hydrodynamic equations is one for the dimensions of spaces. For this goal, the hyper quantities （space and physics） are introduced. Then these are created we can easily cover all problems in arbitrary dimensions （3D, 2D, 1D, separate space for liquids or constituent matters）. In particularly, when they are applied to water hammer problem, which is an especially problem, we can receive immediately celerity and pressure of the event.

钻探勘察加-鄂霍茨克海基底:检验地幔柱假说的最终途径

有关地幔柱的激烈辩论已有15年了.这个辩论的核心问题是：地幔柱是否存在,是否真正是地球热演化的一种重要动力学方式,还是人们用来方便解释某些地质现象的需要近年来的研究发现之前不少所谓的地幔柱并非地幔柱,而是一些零散的地幔熔融异常.尽管如此,这个辩论进展缓慢,远未达到共识.究其原因,障碍在于缺乏实质性的交流,往往是人云亦云.