In order to understand the kinetic characteristics of coal gas desorption based on the pulsating injection (PI), the research experimentally studied the kinetic process of methane desorption in terms of the PI and h...In order to understand the kinetic characteristics of coal gas desorption based on the pulsating injection (PI), the research experimentally studied the kinetic process of methane desorption in terms of the PI and hydrostatic injection (HI). The results show that the kinetic curves of methane desorption based on PI and HI are consistent with each other, and the diffusion model can best describe the characteristics of meth- ane desorption. Initial velocity, diffusion capacity and ultimate desorption amount of methane desorption after P! are greater than those after HI, and the ultimate desorption amount increases by 16.7-39.7%. Methane decay rate over the time is less than that of the HI. The PI influences the diffusion model param- eters, and it makes the mass transfer Biot number B'_i decrease and the mass transfer Fourier series F'_0 increase. As a result, PI makes the methane diffusion resistance in the coal smaller, methane diffusion rate greater, mass transfer velocity faster and the disturbance range of methane concentration wider than HI. Therefore, the effect of methane desorption based on PI is better than that of HI.展开更多
A digital photographic study of pool boiling with binary mixture Rll(CC13)-Rll3(CCl3CF3) was performed on a horizontal transparent heater at pressure of 0.1MPa. A high speed digital camera was applied to record th...A digital photographic study of pool boiling with binary mixture Rll(CC13)-Rll3(CCl3CF3) was performed on a horizontal transparent heater at pressure of 0.1MPa. A high speed digital camera was applied to record the bubble behaviors in boiling process. Strong effects of composition on bubble departure diameter, deparatre time, nucleation density were observed, which was attributed to the nature of the activation of the boiling surface and mass diffusion effects. The bubble departure diameter, departure period and nucleation density as functions of composition for binary mixtures R 11-R 113 were presented respectively. From the video images, it can be concluded that evaporation of microlayer is very important to the growth of bubble. It is also observed that there is not any liquid recruited into the microlayer below the bubble.展开更多
The lattice parameters,bulk modulus,rst derivative of the bulk modulus,electronic band structures,phonon dispersion curves and phonon density of states calculations for Li_(2)AlGa and Li_(2)AlIn Heusler alloys are per...The lattice parameters,bulk modulus,rst derivative of the bulk modulus,electronic band structures,phonon dispersion curves and phonon density of states calculations for Li_(2)AlGa and Li_(2)AlIn Heusler alloys are performed and compared in this study using density functional theory within the generalized gradient approximation.Computed lattice parameters display a good agreement with the literature.Obtained electronic band structures of both Heusler alloys show that they are in semi-metallic structure.Phonon dispersion curves and the phonon density of states graphs are also obtained in order to study the lattice dynamics of these Heusler alloys.It is noticed that Li_(2)AlGa and Li_(2)AlIn Heusler alloys are dynamically stable in the ground state.展开更多
A series of experiments has been done in a moderate-velocity cavitation tunnel to investigate the effects of attack angle change on hydrodynamic characters of supercavitation. Hydrodynamic characters of the aft sectio...A series of experiments has been done in a moderate-velocity cavitation tunnel to investigate the effects of attack angle change on hydrodynamic characters of supercavitation. Hydrodynamic characters of the aft section at various attack angles were compared. The investigation shows that hydrodynamic forces of the aft section are dependent of supercavity shapes at different attack angles,and the magnitude of hydrodynamic forces of the aft section varies with the change of attack angle. When the aft section is in the fully wetted case,the drag coefficient changes little. Lift and moment coefficients both increase with the increased attack angle,and the increase magnitude is not large. When the aft body planing is on the cavity boundary,the drag coefficient of nonzero attack angle is larger than that of zero attack angle,and the maximal lift and moment coefficients both vary obviously with the increased attack angle. In the case that the body is fully enveloped by cavity,the drag coefficient,lift coefficient and moment coefficient are nearly constant with the change of attack angles.展开更多
In this paper,we used tectonic dynamics theories to study the tectonic evolution characteristics of the Pingdingshan mine area,and analyzed the impact of tectonic progressive control on gas occurrence.The study result...In this paper,we used tectonic dynamics theories to study the tectonic evolution characteristics of the Pingdingshan mine area,and analyzed the impact of tectonic progressive control on gas occurrence.The study results are as follows:the Pingdingshan mine area has been mainly controlled by multiple squeezing and shearing actions of the Qinling orogenic belt since early and middle Yanshan,forming the tectonic control characteristics of master control in two directions,namely NWW trending and NNE trending;the NWW trending structure is dominated by squeezing and shearing,while the NNE trending structure is dominated by tension.Progressively controlled by the structure,the gas occurrence presents partition and zonation,i.e.compared with the western structure,the eastern NWW-NW trending structure of the mine area is more highly developed,resulting in the mine area gas occurrence distribution characteristics are distinct in the east while indistinct in the west.Based on this,the mine area can be divided into the following two geological dynamic areas:the western half of mine area,namely the Guodishan fault control area,where the NW-SE trending synchronous tension action suffered by the northeast side(footwall) is relatively strong,and compared with the southwest side(hanging wall),its coal and gas outburst seriousness is weak;and the eastern half of mine area,namely the NWW-NW thrust nappe fracture fold control area,which is a serious area of coal and gas outburst,in particular the axial area of the Likou syncline is the intersection compound and combination position of the NW and NE trending structures,a tectonic concentrated area,and the gas pressure and content here are the largest.展开更多
Proteins adsorption at solid surfaces are of paramount important for many natural processes. However, the role of specific water in influencing the adsorption process has not been well understood. We used molecular dy...Proteins adsorption at solid surfaces are of paramount important for many natural processes. However, the role of specific water in influencing the adsorption process has not been well understood. We used molecular dynamics simulation to study the adsorption of BPTI on Au surface in three water environments (dielectric constant model, partial and full solvation models). The result shows that a fast and strong adsorption can occur in the dielectric environment, which leads to significant structure changes, as confirmed by great deviation from the crystal structure, largely spreading along the Au surface, rapid lose in all secondary structures and the great number of atoms in contact with the surface. Compared to the dielectric model, slower adsorption and fewer changes in the calculated properties above are observed in the partial solvation system since the specific water layer weakens the adsorption effects. However, in the partial solvation system, the adsorption of polar Au surface causes a significant decrease in the specific hydration around the protein, which still results in large structure changes similar to the dielectric system, but with much less adsorption extent. Enough water molecules in the full solvation system could allow the protein to rotate, and to large extent preserve the protein native structure, thus leading to the slowest and weakest adsorption. On the whole, the effects of non-specific and specific solvation on the protein structure and adsorption dynamics are significantly different, highlighting the importance of the specific water molecule in the protein adsorption.展开更多
The nonlinear dynamics of permanent-magnet synchronous motor(PMSM) with v/f control signals is investigated intensively.First,the equilibria and steady-state characteristics of the system are formulated by analytical ...The nonlinear dynamics of permanent-magnet synchronous motor(PMSM) with v/f control signals is investigated intensively.First,the equilibria and steady-state characteristics of the system are formulated by analytical analysis.Then,some of its basic dynamical properties,such as characteristic eigenvalues,Lyapunov exponents and phase trajectories are studied by varying the values of system parameters.It is found that when the values of the system parameters are smaller,the PMSM operates in stable domains,no matter what the values of control gains are.With the values of parameters increasing,the unstability appears and PMSM falls into chaotic operation.Furthermore,the complex dynamic behaviors are verified by means of simulation.展开更多
We compare the direct free energy interpolation(DFEI) method and the quasi-harmonic approximation(QHA) in calculating of the equation of states and thermodynamic properties of prototype Al. The Gibbs free energy of Al...We compare the direct free energy interpolation(DFEI) method and the quasi-harmonic approximation(QHA) in calculating of the equation of states and thermodynamic properties of prototype Al. The Gibbs free energy of Al is calculated using the DFEI method based on the high-temperature phonon density of states reduced from classical molecular dynamics simulations. Then, we reproduce the thermal expansion coefficients, the specific heat, the isothermal bulk modulus of Al accurately. By comparing the results from the DFEI method and the QHA, we find that the DFEI method is indeed more accurate in calculating anharmonic properties than the QHA.展开更多
基金financially supported by the National Basic Research Program of China (No. 2011CB201205)the National Natural Science Foundation of China (No. 51274195)+2 种基金the Natural Science Foundation of Jiangsu Province of China (No. BK2012571)the National Major Scientific Instrument and Equipment Development Project of China (No. 2013YQ17046309)the Education Department Science and Technology Key Project of Henan Province of China (14B440007)
文摘In order to understand the kinetic characteristics of coal gas desorption based on the pulsating injection (PI), the research experimentally studied the kinetic process of methane desorption in terms of the PI and hydrostatic injection (HI). The results show that the kinetic curves of methane desorption based on PI and HI are consistent with each other, and the diffusion model can best describe the characteristics of meth- ane desorption. Initial velocity, diffusion capacity and ultimate desorption amount of methane desorption after P! are greater than those after HI, and the ultimate desorption amount increases by 16.7-39.7%. Methane decay rate over the time is less than that of the HI. The PI influences the diffusion model param- eters, and it makes the mass transfer Biot number B'_i decrease and the mass transfer Fourier series F'_0 increase. As a result, PI makes the methane diffusion resistance in the coal smaller, methane diffusion rate greater, mass transfer velocity faster and the disturbance range of methane concentration wider than HI. Therefore, the effect of methane desorption based on PI is better than that of HI.
基金Supported by the National Natural Science Foundation of China (No.10355001) and the Century Programme of ChineseAcademy of Sciences.
文摘A digital photographic study of pool boiling with binary mixture Rll(CC13)-Rll3(CCl3CF3) was performed on a horizontal transparent heater at pressure of 0.1MPa. A high speed digital camera was applied to record the bubble behaviors in boiling process. Strong effects of composition on bubble departure diameter, deparatre time, nucleation density were observed, which was attributed to the nature of the activation of the boiling surface and mass diffusion effects. The bubble departure diameter, departure period and nucleation density as functions of composition for binary mixtures R 11-R 113 were presented respectively. From the video images, it can be concluded that evaporation of microlayer is very important to the growth of bubble. It is also observed that there is not any liquid recruited into the microlayer below the bubble.
文摘The lattice parameters,bulk modulus,rst derivative of the bulk modulus,electronic band structures,phonon dispersion curves and phonon density of states calculations for Li_(2)AlGa and Li_(2)AlIn Heusler alloys are performed and compared in this study using density functional theory within the generalized gradient approximation.Computed lattice parameters display a good agreement with the literature.Obtained electronic band structures of both Heusler alloys show that they are in semi-metallic structure.Phonon dispersion curves and the phonon density of states graphs are also obtained in order to study the lattice dynamics of these Heusler alloys.It is noticed that Li_(2)AlGa and Li_(2)AlIn Heusler alloys are dynamically stable in the ground state.
基金Sponsoed by the National Natural Science Foundation of China(Grant No.10832007)
文摘A series of experiments has been done in a moderate-velocity cavitation tunnel to investigate the effects of attack angle change on hydrodynamic characters of supercavitation. Hydrodynamic characters of the aft section at various attack angles were compared. The investigation shows that hydrodynamic forces of the aft section are dependent of supercavity shapes at different attack angles,and the magnitude of hydrodynamic forces of the aft section varies with the change of attack angle. When the aft section is in the fully wetted case,the drag coefficient changes little. Lift and moment coefficients both increase with the increased attack angle,and the increase magnitude is not large. When the aft body planing is on the cavity boundary,the drag coefficient of nonzero attack angle is larger than that of zero attack angle,and the maximal lift and moment coefficients both vary obviously with the increased attack angle. In the case that the body is fully enveloped by cavity,the drag coefficient,lift coefficient and moment coefficient are nearly constant with the change of attack angles.
基金funded by Twelfth Five Year Plan Special Science and Technology of China(No.2011ZX05040-005)open fund of State Key Laboratory Cultivation Base for Gas Geology and Gas Control of China(No.WS2013A11)+1 种基金the Fundamental Research Funds for the Universities of Henan Province of China(No. NSFRF140104)the Open Project of the State Key Laboratory of Coal Resources and Safe Mining of China(No.SKLCRSM14KFB11)
文摘In this paper,we used tectonic dynamics theories to study the tectonic evolution characteristics of the Pingdingshan mine area,and analyzed the impact of tectonic progressive control on gas occurrence.The study results are as follows:the Pingdingshan mine area has been mainly controlled by multiple squeezing and shearing actions of the Qinling orogenic belt since early and middle Yanshan,forming the tectonic control characteristics of master control in two directions,namely NWW trending and NNE trending;the NWW trending structure is dominated by squeezing and shearing,while the NNE trending structure is dominated by tension.Progressively controlled by the structure,the gas occurrence presents partition and zonation,i.e.compared with the western structure,the eastern NWW-NW trending structure of the mine area is more highly developed,resulting in the mine area gas occurrence distribution characteristics are distinct in the east while indistinct in the west.Based on this,the mine area can be divided into the following two geological dynamic areas:the western half of mine area,namely the Guodishan fault control area,where the NW-SE trending synchronous tension action suffered by the northeast side(footwall) is relatively strong,and compared with the southwest side(hanging wall),its coal and gas outburst seriousness is weak;and the eastern half of mine area,namely the NWW-NW thrust nappe fracture fold control area,which is a serious area of coal and gas outburst,in particular the axial area of the Likou syncline is the intersection compound and combination position of the NW and NE trending structures,a tectonic concentrated area,and the gas pressure and content here are the largest.
文摘Proteins adsorption at solid surfaces are of paramount important for many natural processes. However, the role of specific water in influencing the adsorption process has not been well understood. We used molecular dynamics simulation to study the adsorption of BPTI on Au surface in three water environments (dielectric constant model, partial and full solvation models). The result shows that a fast and strong adsorption can occur in the dielectric environment, which leads to significant structure changes, as confirmed by great deviation from the crystal structure, largely spreading along the Au surface, rapid lose in all secondary structures and the great number of atoms in contact with the surface. Compared to the dielectric model, slower adsorption and fewer changes in the calculated properties above are observed in the partial solvation system since the specific water layer weakens the adsorption effects. However, in the partial solvation system, the adsorption of polar Au surface causes a significant decrease in the specific hydration around the protein, which still results in large structure changes similar to the dielectric system, but with much less adsorption extent. Enough water molecules in the full solvation system could allow the protein to rotate, and to large extent preserve the protein native structure, thus leading to the slowest and weakest adsorption. On the whole, the effects of non-specific and specific solvation on the protein structure and adsorption dynamics are significantly different, highlighting the importance of the specific water molecule in the protein adsorption.
基金Supported by the Key Program of National Natural Science Foundation of China under Grant No. 50937001the National Natural Science Foundation of China under Grant Nos. 10947011,11262004,61263021,and 50877028
文摘The nonlinear dynamics of permanent-magnet synchronous motor(PMSM) with v/f control signals is investigated intensively.First,the equilibria and steady-state characteristics of the system are formulated by analytical analysis.Then,some of its basic dynamical properties,such as characteristic eigenvalues,Lyapunov exponents and phase trajectories are studied by varying the values of system parameters.It is found that when the values of the system parameters are smaller,the PMSM operates in stable domains,no matter what the values of control gains are.With the values of parameters increasing,the unstability appears and PMSM falls into chaotic operation.Furthermore,the complex dynamic behaviors are verified by means of simulation.
基金Supported by the National Natural Science Foundation of China under Grant No.41574076the Young Core Teacher Scheme of Henan Province under Grant No.2014GGJS-108the Fundamental and Cutting-edge Technology Research Program of Henan Province under Grant No.152300410218
文摘We compare the direct free energy interpolation(DFEI) method and the quasi-harmonic approximation(QHA) in calculating of the equation of states and thermodynamic properties of prototype Al. The Gibbs free energy of Al is calculated using the DFEI method based on the high-temperature phonon density of states reduced from classical molecular dynamics simulations. Then, we reproduce the thermal expansion coefficients, the specific heat, the isothermal bulk modulus of Al accurately. By comparing the results from the DFEI method and the QHA, we find that the DFEI method is indeed more accurate in calculating anharmonic properties than the QHA.