酚醛-有机硅氧烷接枝体的相容性及表面性质

对合成有机硅改性酚醛树脂的相容性和表面性质进行了研究。用动态力学方法测定玻璃化转变温度 Tg 研究改性树脂的相容性。根据接触角测定值 。

Stress initialization methods for dynamic numerical simulation of rock mass with high in-situ stress

In the context of deep rock engineering,the in-situ stress state is of major importance as it plays an important role in rock dynamic response behavior.Thus,stress initialization becomes crucial and is the first step for the dynamic response simulation of rock mass in a high in-situ stress field.In this paper,stress initialization methods,including their principles and operating procedures for reproducing steady in-situ stress state in LS-DYNA,are first introduced.Then the most popular four methods,i.e.,explicit dynamic relaxation(DR)method,implicit-explicit sequence method,Dynain file method and quasi-static method,are exemplified through a case analysis by using the RHT and plastic hardening rock material models to simulate rock blasting under in-situ stress condition.Based on the simulations,it is concluded that the stress initialization results obtained by implicit-explicit sequence method and dynain file method are closely related to the rock material model,and the explicit DR method has an obvious advantage in solution time when compared to other methods.Besides that,it is recommended to adopt two separate analyses for the whole numerical simulation of rock mass under the combined action of in-situ stress and dynamic disturbance.

Solubility of red palm oil in supercritical carbon dioxide： Measurement and modelling

The solubility of red palm oil （RPO） in supercritical carbon dioxide （scCO2） was determined using a dynamic method at 8.5-25 MPa and, 313.15-333.15 K and at a fixed scCO2 flow rate of 2.9 g. mn -1 using a full factorial design. The solubility was determined under low pressures and temperatures as a preliminary study for RPO par- ticle formation using scCO2. The solubility of RPO was 0.5-11.3 mg. （g CO2） -1 and was significantly affected by the pressure and temperature. RPO solubility increased with pressure and decreased with temperature. The Adachi-Lu model showed the best-fit for RPO solubility data with an average relative deviation of 14% with a high coefficient of determination, R2 of 0.9667, whereas the Peng-Robinson equation of state thermodynamic model recorded deviations of 17%-30%.

Online dynamic measurement of saturation-capillary pressure relation in sandy medium under water level fluctuation

An online dynamic method based on electrical conductivity probe, tensiometer and datataker was presented to measure saturation-capillary pressure （S-p） relation in water-light nonaqueous phase liquid （LNAPL） two-phase sandy medium under water level fluctuation. Three-electrode electrical conductivity probe （ECP） was used to measure water saturation. Hydrophobic tensiometer was obtained by spraying waterproof material to the ceramic cup of commercially available hydrophilic tensiometer. A couple of hydrophilic tensiometer and hydrophobic tensiometer were used to measure pore water pressure and pore LNAPL pressure of the sandy medium, respectively. All the signals from ECP and tensiometer were collected by a data taker connected with a computer. The results show that this method can finish the measurement of S-R relation of a complete drainage or imbibition process in less than 60 min. It is much more timesaving compared with 10-40 d of traditional methods. Two cycles of water level fluctuation were produced, and four saturation-capillary pressure relations including two stable residual LNAPL saturations of the sandy medium were obtained during in 350 h. The results show that this method has a good durable performance and feasibility in the porous medium with complicated multiphase flow. Although further studies are needed on the signal stability and accuracy drift of the ECP, this online dynamic method can be used successfully in the rapid characterization of a LNAPL migration in porous media.

Seismic stability of reinforced soil walls under bearing capacity failure by pseudo-dynamic method

In order to evaluate the seismic stability of reinforced soil walls against bearing capacity failure,the seismic safety factor of reinforced soil walls was determined by using pseudo-dynamic method,and calculated by considering different parameters,such as horizontal and vertical seismic acceleration coefficients,ratio of reinforcement length to wall height,back fill friction angle,foundation soil friction angle,soil reinforcement interface friction angle and surcharge.The parametric study shows that the seismic safety factor increases by 24-fold when the foundation soil friction angle varies from 25°to 45°,and increases by 2-fold when the soil reinforcement interface friction angle varies from 0 to 30°.That is to say,the bigger values the foundation soil and/or soil reinforcement interface friction angles have,the safer the reinforced soil walls become in the seismic design.The results were also compared with those obtained from pseudo-static method.It is found that there is a higher value of the safety factor by the present work.

Dynamical Properties of Two Coupled Dissipative QED Cavities Driven by Coherent Fields

When two identical QED cavities driven by the coherent fields are located in a uniform environment, in addition to dissipation, there appears an indirect coupling between the two cavities induced by the background fields. We investigate the effects of the coherent fields, the dissipation as well as the incoherent coupling on the following dynamical properties of the system： photon transfer, reversible decoherence, and quantum state transfer, etc. We find that the photons in the cavities do not leak completely into the environment due to the collective coupling between the cavities and the enviroment, and the photons are transferred irreversibly from the cavity with more photons to the cavity with less ones due to the incoherent coupling so that they are equally distributed among the two cavities. The coherent field pumping on the two cavities increases the mean photons, complements the revived magnitude of the reversible decoherence, but hinders the quantum state transfer between the two cavities. The above phenomena may find applications in quantum communication and other basic fields.

Encouraging Active Viewing, Rather Than Passive Watching in the Audio-visual English Class

The present article deals with the effective use of film clips in the classroom to encourage active viewing. It argues that viewing material and activities should meet the needs and interest of learners and lead towards a product that can benefit their language-learning capabilities. The selection of right film clips and the designing of appropriate tasks are discussed in detail.

Atomistic Model of Uranium

The electronic state and potential data of U2 molecules are performed by first principle calculations with B3LYP hybrid exchange-correlation functional, the valence electrons of U atom are treated with the （5s4p3d4f）/[3s3p2d2f] contraction basis sets, and the cores are approximated with the relativistic effective core potential. The results show that the ground electronic state is x^9∑g＋. The pair potential data are fitted with a Murrell-Sorbie analytical potential function. The U-U embedded atom method （EAM） interatomic potential is determined based on the generalized gradient approximation calculation within the framework of the density functional theory using Perdew-Burke-Ernzerhof exchange-correlation functional at the spin-polarized level. The physical properties, such as the cohesive energy, the lattice constant, the bulk modulus, the shear modulus, the sc/fec relative energy, the hep/fce rela- tive energy, the shear modulus and the monovacaney formation energy are used to evaluate the EAM potential parameters. The U-U pair potential determined by the first principle calculations is in agreement with that defined by the EAM potential parameters. The EAM calculated formation energy of the monovacancy in the fee structure is also found to be in close agreement with DFT calculation.

Static and Dynamic Indicators in the Analysis of Internal Sources of Companies＇ Investments Financing

The Republic of Serbia is characterized by an unsatisfactory macroeconomic environment. Under the conditions of an evident shortage of liquid assets, the financial capital has moved from real to the financial sector, which led companies to over-indebtedness and shutdown of their own capacities. Therefore, capital investments largely depend on internal financing sources and the ability of companies to internally generate funds for investments. In this regard, an emphasis is placed on the difference in the assessment of the company＇s investment capacity based on internal financing sources, which are measured using static and dynamic indicators in order to prove the necessity of applying dynamic coefficients, which are unfortunately not present in our domestic practice. The paper examines and proves the advantages of the use of the dynamic approach for such analyses using the example of energy sector, which is one of the most important branches in Serbian economy.

Diffusion-Controlled Adsorption Kinetics of Triton X-100 at Air/Solution Interface

In this paper, the equilibrium surface tension and the dynamic surface tension of aqueous Triton X-100 solution at temperature 25 ℃ were measured by means of Wilhelmy plate method and maximal bubble pressure method respectively. The determined critical micellar concentration（cmc） of Triton X-100 at 25 ℃ is (2.2×10-4) mol/dm3. The adsorption mechanics of Triton X-100 at air/solution was determined. For the submicellar concentrations it is diffusion-controlled. The diffusion coefficient was calculated from the experimental data in the range of short limit. In the range of long time adsorption, the subsurface concentration is fitted from the measured dynamic surface tensions.

Development of Vibrating Monitoring for Hydro Power Turbines under Operating Condition

Units and components of the powerful power equipment are exposed to the big static and dynamic load. An example of such equipments is turbines hydraulic power plant and, especially, hydroelectric pumped storage power plant. Existing techniques of control of a vibrating condition do not consider： very wide frequency range of vibrating processes, difficult character of such processes in the form of the sum multiharmonic, random and close to shock processes. Such techniques usually do not consider intervals of start-up and stop, and also work on transitive modes when loadings on a construction are maximum. Available techniques of an estimation of admissible level of vibrating influence and tests for vibration durability are not harmonized enough among themselves. Various known interpretations of communication of vibrating characteristics and durability estimations on mechanical pressure at broadband vibrating influence yield ambiguous result. On the basis of the analysis of the published information, we attempt to formulate the requirement to system of vibrating monitoring of the hydraulic turbine and power motor pumps. System should provide data acquisition and the analysis of the data on a vibrating condition taking into account accumulation of vibrating influences and long term of operation on the basis of estimation methods as low-cycle, and high-cycle （gigacycle） fatigue is made.

A Research on Particle-Based Parallel Methods for Fluid Animation

In this paper, we present an acceleration strategy for Smoothed Particle Hydrodynamics （SPH） on multi-GPU platform. For single-GPU, we first use a neighborhood search algorithm of compacting cell index combined with spatial domain characteristics For multi-GPU, we focus on the changing patterns of SPH＇s computational time. Simple dynamic load balancing algorithm works well because the computational time of each time step changes slowly compared to previous time step. By further optimizing dynamic load balancing algorithm and the communication strategy among GPUs, a nearly linear speedup is achieved in different scenarios with a scale of millions particles. The quality and efficiency of our methods are demonstrated using multiple scenes with different particle numbers.

Dynamic simulation based on Jacobian-free Newton-GMRES methods with adaptive preconditioner for power systems

Dynamic simulation is one of the most complex and important computations for power systems researches.Traditional solutions based on normal Newton iterations almost all depend on evaluations of Jacobian matrixes,which increases the programming complexity of and limits the parallelizability of the whole simulation.In this paper,a new adaptive preconditioned Jacobian-free Newton-GMRES(m)method is proposed to be applied to dynamic simulations of power systems.This new method has totally Jacobian-free characteristics,which saves calculations and storages of Jacobian matrixes and features strong parallelizability.Moreover,several speedup strategies are introduced to enhance efficiency and parallelizability of overall computations.Numerical tests are carried out on IEEE standard test systems and results show that in series computing environment,simulations based on the proposed method have comparable speed to those based on classical Newton-Raphson methods.

An efficient time-integration method for nonlinear dynamic analysis of solids and structures

This paper presents an efficient time-integration method for obtaining reliable solutions to the second-order nonlinear dynamic problems in structural engineering. This method employs both the backward-acceleration differentiation formula and the trapezoidal rule, resulting in a self-starting, single step, second-order accurate algorithm. With the same computational effort as the trapezoidal rule, the proposed method remains stable in large deformation and long time range solutions even when the trapezoidal rule fails. Meanwhile, the proposed method has the following characteristics: (1) it is applicable to linear as well as general nonlinear analyses; (2) it does not involve additional variables (e.g. Lagrange multipliers) and artificial parameters; (3) it is a single-solver algorithm at the discrete time points with symmetric effective stiffness matrix and effective load vectors; and (4) it is easy to implement in an existing computational software. Some numerical results indicate that the proposed method is a powerful tool with some notable features for practical nonlinear dynamic analyses.

Performance of DDA time integration

Discontinuous deformation analysis(DDA) is a numerical method for analyzing the deformation of block system. It employs unified dynamic formulation for both static and dynamic analysis, in which the so-called kinetic damping is adopted for absorbing dynamic energy. The DDA dynamic equations are integrated directly by the constant acceleration algorithm of Newmark family integrators. In order to have an insight into the DDA time integration scheme, the performance of Newmark time integration scheme for dynamic equations with kinetic damping is systematically investigated, formulae of stability, bifurcation, spectral radius, critical kinetic damping and algorithmic damping are presented. Combining with numerical examples, recognition and suggestions of Newmark integration scheme application in the DDA static and dynamic analysis are proposed.

Theoretical methods for excited state dynamics of molecules and molecular aggregates

This contribution provides a summary of proposed theoretical and computational studies on excited state dynamics in molecular aggregates, as an important part of the National Natural Science Foundation (NNSF) Major Project entitled "Theoretical study of the low-lying electronic excited state for molecular aggregates". This study will focus on developments of novel methods to simulate excited state dynamics of molecular aggregates, with the aim of understanding several important chemical physics processes, and providing a solid foundation for predicting the opto-electronic properties of organic functional materials and devices. The contents of this study include: (1) The quantum chemical methods for electronic excited state and electronic couplings targeted for dynamics in molecular aggregates; (2) Methods to construct effective Hamiltonian models, and to solve their dynamics using system-bath approaches; (3) Non-adiabatic mixed quantum-classic methods targeted for molecular aggregates; (4) Theoretical studies of charge and energy transfer, and related spectroscopic phenomena in molecular aggregates.

A Review of Empirical Studies in L2 Dynamic Assessment

The present paper reviews 25 studies conducted in the domain of L2 （second/foreign language） dynamic assessment （DA） in recent years. It begins with a survey of relevant research, then discusses some of the major findings and problems, and finishes with some suggestions for further research. The main findings of the review are as follows： （a） DA has the potential to promote L2 competence development; （b） both the interactionist approach and interventionist approach have attracted the interest of L2 researchers; （c） most studies have focused on small samples; （d） reading and grammatical knowledge have drawn the most attention; （e） group DA may be a potential method to advance L2 competence development in both the focused individual and the other members of the group; （f） computers might play a complementary role to humans acting as mediators; and （g） case study methodology has been the overwhelming choice for experimental design. Based on the available research, we suggest that additional studies are called for on the following issues： （a） L2 DA as an approach to measurement, （b） potential mediators, （c） validity issues of L2 DA, （d） the interface between DA and second language acquisition, and （e） the development of L2 classroom teachers.

Simulation of construction shape-forming process of cable domes

A cable dome has no stiffness or load carrying capacity unless it has been prestressed.Analyses of cable domes are based on successful prestressing designs,making force finding analysis very important.A new force finding method named the imbal-ance force iterative method is proposed,which can overcome some limitations of the integrity feasible prestressing method.For instance,even if groups are assigned by mistake,the pretension distribution that satisfies the known geometry form can also be found.This method possess good stability and calculation efficiency,and a case study indicates that it is applicable to the force finding of large and complicated cable domes.On the other hand,form finding analysis of cable domes is also a key engineering problem.However,rigid displacement occurs in this process,which makes the analysis more complex.In this pa-per,the dynamic relaxation method was selected,and the problem of rigid displacement was therefore effectively solved.The method includes two steps:first,the stretching cables are released,and secondly,an axial force is imposed on the two ends of each released cable.This method is convenient in its calculation and clear in its conception.A case study indicates that the method is suitable for the simulation of the construction process of various cable domes and cable-strut tension structures.Moreover,a form finding experiment was conducted on a model of a cable dome with a diameter of 4.8 m by tensing diagonal cables.The behavior of the model in the form finding process was investigated.The experimental results indicate that the ini-tial lengths of members and prestress loss are key issues in cable domes design.The results also prove that the methods of form finding and force finding proposed in this paper are reliable and effective.