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动态单滴法研究乳状液液膜的稳定性 被引量:3
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作者 张河哲 白光月 +1 位作者 王玉洁 严忠 《物理化学学报》 SCIE CAS CSCD 北大核心 1993年第2期233-237,共5页
乳状液液膜作为化学分离的一种手段,自七十年代发现以来已有了许多进展,但是如何将其工业化还有许多课题有待于进一步研究.目前,除了乳状液液膜的水静态渗透性质以外,对乳状液液膜的稳定性和溶胀性质的研究主要采用搅拌法.虽然得到较好... 乳状液液膜作为化学分离的一种手段,自七十年代发现以来已有了许多进展,但是如何将其工业化还有许多课题有待于进一步研究.目前,除了乳状液液膜的水静态渗透性质以外,对乳状液液膜的稳定性和溶胀性质的研究主要采用搅拌法.虽然得到较好的规律性,但是搅拌法具有乳状液滴粒径分布广的弱点,对于不同的搅拌方式及条件,乳状液液膜的有效面积不同,对液膜作用的机械强度不同,因此结果会有很大差别.我们自行设计的动态单滴法实验装置,可定量地研究乳状液液膜的溶胀、稳定性及水渗透性质. 展开更多
关键词 动态单滴 乳状液液膜 分离膜
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Unsteady Motion of a Single Droplet in Surfactant Solutions 被引量:2
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作者 李晓锦 毛在砂 费维扬 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2003年第6期715-725,共11页
A numerical investigation of the unsteady motion of a deformed drop released freely in another quiescent liquid contaminated by surfactant is presented in this paper. The finite difference method was used to solve num... A numerical investigation of the unsteady motion of a deformed drop released freely in another quiescent liquid contaminated by surfactant is presented in this paper. The finite difference method was used to solve numerically the coupled time-dependent Navier-Stokes and convective-diffusion equations in a body-fitted orthogonal coordinate system. Numerical simulation was conducted on the experimental cases, in which MIBK drops with the size ranging from 1.24 mm to 1.97 mm rose and accelerated freely in pure water and in dilute sodium dodecyl sulphate (SDS) aqueous solution. The applicability of the numerical scheme was validated by the agreement between the simulation results and the experimental data. Both the numerical and experimental results showed that the velocitytime profile exhibited a maximum rising velocity for drops in SDS solutions, which was close to the terminal velocity in pure water, before it dropped down to a steady-state value. The effect of the sorption kinetics of surfactant on the accelerating motion was also evaluated. It is also suggested that introduction of virtual mass force into the formulation improved obviously the precision of numerical simulation of transient drop motion. 展开更多
关键词 SURFACTANT single drop unsteady motion sorption kinetics numerical simulation
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