具有回跳特征的电磁继电器动态反力计算模型

电磁继电器触点的碰撞接触及所引起的回跳是影响继电器可靠性与电寿命的重要因素。传统的动态特性计算中,大多对此回避或仅作简化处理。本文提出了具有回跳特征的继电器动态反力计算模型。它通过分别建立衔铁与各触簧的动力学方程,将簧片结构等效为弹簧?振子模型,采用弹簧?阻尼模型计算连续接触力等方法得到动态反力特性。得到的动态反力特性包括触点间接触力、推杆接触力和各部件的运动速度及位移。经仿真与实验验证,使用该计算模型得到的结果是正确的。计算结果还表明,控制触点闭合速度、减小簧片刚度可以减小触点回跳、控制衔铁速度、增大动合超程及空程可以避免触点二次回跳。

工程机械铰接系统铰点动态约束反力的研究

通过整车系统动力学分析,对铰接式工程机械铰接系统铰点动态约束反力进行了研究。在作业工况下,铰接系统铰点受到三个力及二个力矩的作用,这些力和力矩的大小依赖于作业阻力、机械自重、惯性力、车轮滚动阻力和车轮驱动力矩,得到了其解析表达式。

Full Quantum State Resolved Scattering Dynamics of the F+H_(2)→HF+H Reaction at 5.02 kJ/mol

A crossed molecular beams, state-to-state scattering study was carried out on the F＋H2→HF＋H reaction at the collision energy of 5.02 kJ/mol, using the highly sensitive H atom Rydberg tagging time-of-flight method. All the peaks in the TOF spectra can be clearly assigned to the ro-vibrational structures of the HF product. The forward scattering of the HF product at v′=3 has been observed. The small forward scattering of the HF product at v′=2 has also been detected. Detailed theoretical analysis is required in order to fully understand the dynamical origin of these forward scattering products at this high collision energy.

Role of Fe/S ratios in the enhancement of uranium bioleaching from a complex uranium ore by Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans consortium

The role of Fe/S ratios(ω, g/g) in the uranium bioleaching from a complex uranium ore by Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans consortium was investigated. The results showed good uranium extraction with over 90% at the Fe/S ratio of 5:0.5, 5:1 and 5:5, while poor extraction(<46%) at the Fe/S ratio of 5:0 and 5:10.Furthermore, the bacterial community analysis based on species-specific gyrB numbers indicated that, absent sulfur or excessive sulfur would be not conducive to the synergistic growth for A. ferrooxidans and A. thiooxidans, and then not conducive to the uranium dissolution. Meanwhile, the sulfur-oxidizers could play an important role in the process of uranium synergistic bioleaching by mixed bacterial consortia. Additionally, the characteristics of mineral residue was detected by SEM-EDS. The results showed appropriate sulfur dosage would change the structure and improve the porosity of passivation substance. Lastly, the uranium dissolution kinetics and biochemical reaction mechanism was analyzed. It indicated that the biochemical reaction coupling iron and sulfur had a pleiotropic effect on the uranium dissolution from the ore particles, appropriate Fe/S ratio is the key factor for uranium bioleaching by chemoautotrophic acidophiles.

State Feedback Predictive Control for Hybrid System via Parametric Optimization

In this article, state feedback predictive controller for hybrid system via parametric programming is proposed. First, mixed logic dynamic （MLD） modeling mechanism for hybrid system is analyzed, which has a distinguished advantage to deal with the logic rules and constraints of a plant. Model predictive control algorithm with moving horizon state estimator （MHE） is presented. The estimator is adopted to estimate the current state of the plant with process disturbance and measurement noise, and the state estimated are utilized in the predictive controller for both regulation and tracking problems of the hybrid system based on MLD model. Off-line parametric programming is adopted and then on-line mixed integer programming problem can be treated as the parameter programming with estimated state as the parameters. A three tank system is used for computer simulation, results show that the proposed MHE based predictive control via parametric programming is effective for hybrid system with model/olant mismatch, and has a potential for the engineering applications.

Kinetics of Non-catalyzed Decomposition of Glucose in High-temperature Liquid Water

The decomposition kinetics of glucose was studied in high-temperature liquid water （HTLW） from 180 to 220℃ under a pressure of 10 MPa. It was found the main products from glucose decomposition were 5-hydroxymethylfurfural （5-HMF） and levulinic acid （LA）. The decomposition kinetics of 5-HMF and stability of LA in HTLW were further investigated. A kinetic model for glucose decomposition was proposed accordingly. In the model, a series of first-order reactions with the consideration of parallel by-reactions were used to illustrate the decomposition of glucose. The decomposition activation energies of glucose, 5-HMF, and LA were evaluated as 118.85, 95.40, and 31.29 kJ·mol^-1, respectively.

Release of Soil Nonexchangeable K by Organic Acids

The amounts of soil nonexchangeable K extracted with 0.01 mL/ L oxalic acid and citric acid solutions and that with boiling 1 mL/ L HNO3 for ten minutes were remarkably significantly correlated with each other, and the amount extracted with the oxalic acid solution was higher than that with the citric acid solution. The soil nonexchangeable K release was comprised of two first-order kinetic processes. The faster one was ascribed to the interlayer K in outer sphere, while the slower one to that in inner sphere. The rate constants of the soil nonexchageable K were significantly correlated with the amounts of nonexchangeable K extracted with boiling ImL/ L HNO3 for ten minutes. Study on the fitness of different kinetic equations indicated that the first-order, parabolic diffusion and zero-order equations could all describe the release of soil nonexchangeable K. well, but Elovich equation was not suitable to describe it.

Metastable State of Clindamycin Phosphate in Cooling Crystallization

The metastable state and nucleation kinetics of clindamycin phosphate (CP) in cooling crystallization were studied by metastable zone width (MZW) method and induction time method. By correlating the MZW experimental results with temperature, agitation rate and cooling rate, it is found that the correlation result shows good agreement with the change trend of MZW. The critical nucleation parameters were evaluated based on the classical theory of nucleation; both the interfacial tension and the radius of critical nucleus increased with the decrease of relative supersaturation. The effect of supersaturation on the nucleation rate was analyzed. It is indicated that the new phase formation of CP is governed by mononuclear mechanism.

Preparation and Dynamic Tensile Behavior of C200 Green Reactive Powder Concrete

A new type of green reactive powder concrete (GRPC) with compressive strength of 200 MPa is prepared by utilizing composite mineral admixtures, natural fine aggregates, and short and fine steel fibers. The quasi-static mechanical properties (mechanical strength, toughness, fracture energy and interfacial bonding strength) of GRPC specimens, cured in three different types of regimes, are investigated. The experimental results show that the mechanical properties of the C200 GRPC made with the powder binders that is composed of 40% of Portland cement, 25% of ultra fine slag, 25% of ultra fine fly ash and 10% of silica fume are better than the others'. The corresponding compressive strength, flexural strength and fracture energy are more than 200 MPa, and 30 000 J/ m2 respectively. The dynamic tensile behavior of the C200 GRPC is also investigated through the split Hopkinson pressure bar (SHPB) according to the spalling phenomenon. The dynamic testing results demonstrate that strain rate has an important effect on the dynamic tensile behavior of GRPC. With the increase of strain rate, its peak stress and relevant strain increase. The GRPC exhibits an excellent strain ratio stiffening effect under the dynamic tensile load with high strain ratio, resulting in a significant change of the fracture pattern.

Dynamic fracture behavior of rock under impact load using the caustics method

We studied the dynamic fracture mechanical behavior of rock under different impact rates. The fracture experiment was a three-point bending beam subjected to different impact loads monitored using the reflected caustics method. The mechanical parameters for fracture of the three-poim bending beam specimen under impact load are analyzed. The mechanism of crack propagation is discussed. Experimental results show that the dynamic stress intensity factor increases before crack initiation. When the dynamic stress intensity factor reaches its maximum value the crack starts to develop. After crack initiation the dynamic stress intensity factor decreases rapidly and oscillates. As the impact rate increases the cracks initiate earlier, the maximum value of crack growth velocity becomes smaller and the values of dynamic stress intensity factor also vary less during crack propagation. The results provide a theoretical basis for the study of rock dynamic fracture.

Dynamic Kinetics of Methanol Synthesis over a Commercial Copper-Based Catalyst

Adsorption, surface reaction and process dynamics on the surface of a commercial copper-based catalyst for methanol synthesis from CO/CO2/H2 were systematically studied by means of temperature programmed desorption (TPD), temperature programmed surface reaction (TPSR), in-situ Fourier transform-inferred spec-troscopy(FTIR) and stimulus-response techniques. As a part of results, an elementary step sequence was suggested and a group of ordinary differential equations (ODEs) for describing transient conversations relevant to all species on the catalyst surface and in the gas phase in a micro-fixed-bed reactor was derived. The values of the parameters referred to dynamic kinetics were estimated by fitting the solution of the ODEs with the transient response data obtained by the stimulus-response technique with a FTIR analyzer as an on-line detector.

Adaptive variable structure control based on backstepping for spacecraft with reaction wheels during attitude maneuver

An adaptive variable structure control method based on backstepping is proposed for the attitude maneuver problem of rigid spacecraft with reaction wheel dynamics in the presence of uncertain inertia matrix and external disturbances. The proposed control approach is a combination of the backstepping and the adaptive variable structure control. The cascaded structure of the attitude maneuver control system with reaction wheel dynamics gives the advantage for applying the backstepping method to construct Lyapunov functions. The robust stability to external disturbances and parametric uncertainty is guaranteed by the adaptive variable structure control. To validate the proposed control algorithm, numerical simulations using the proposed approach are performed for the attitude maneuver mission of rigid spacecraft with a configuration consisting of four reaction wheels for actuator and three magnetorquers for momentum unloading. Simulation results verify the effectiveness of the proposed control algorithm.

Sigma Meson Production in Nuclear Reactions

The sigma meson production in p ＋ ^12C and p A- ^40Ca reactions at the incident energy Ep = 1.5 GeV is investigated within the Quantum Molecular Dynamics model. The simulation results indicate a distinctive A dependence of the sigma production, that is, the increase of A is followed by an increase of the production cross sections. We find that the σ meson production in proton-induced reactions is strongly medium-dependent, and the produced σ mesons decaying in a denser medium experience a stronger mass shift towards lower masses. This mass shift is an experimentally accessible observable in the final state pion pairs, which do not suffer from reabsorption by the surrounding nucleons. It is pointed out that the ratio of measured sigma cross sections as a function of the sigma invariant-mass from various reactions is a good probe to explore the existence of the σ meson in a dense nuclear environment.

Centrifuge modeling of dynamic behavior of pile-reinforced slopes during earthquakes

A series of centrifuge model tests of sandy slopes were conducted to study the dynamic behavior of pile-reinforced slopes subjected to various motions.Time histories of accelerations,bending moments and pile earth pressures were obtained during excitation of the adjusted El Centro earthquake and a cyclic motion.Under a realistic earthquake,the overall response of the pile-reinforced slope is lower than that of the non-reinforced slope.The histories of bending moments and dynamic earth pressures reach their maximums soon after shaking started and then remain roughly stable until the end of shaking.Maximum moments occur at the height of 3.5 m,which is the deeper section of the pile,indicating the interface between the active loading and passive resistance regions.The dynamic earth pressures above the slope base steadily increase with the increase of height of pile.For the model under cyclic input motion,response amplitudes at different locations in the slope are almost the same,indicating no significant response amplification.Both the bending moment and earth pressure increase gradually over a long period.

跳远起跳技术生物力学剖析

本文从生物力学角度对跳远的起跳技术进行分析,从而了解起跳技术全过程的力学原理及身体各部分的运动特点。

Optimal state feedback control of brushless direct-current motor drive systems based on Lyapunov stability criterion

This paper develops a unified methodology for a real-time speed control of brushless direct-current motor drive systems in the presence of measurement noise and load torque disturbance. First, the mathematical model and hardware structure of system is established. Next, an optimal state feed back controller using the Kalman filter state estimation technique is derived. This is followed by an adaptive control algorithm to compensate for the effects of noise and disturbance. Those two algorithms working together can provide a very-high-speed regulation and dynamic response over a wide range of operating conditions. Simulated responses are presented to highlight the effectiveness of the proposed control strategy.

Analyzing Nonstationary Random Response of a SDOF System under the Evolutionary Random Excitation by Wavelet Transform

For evolutionary random excitations, a general method of analyzing nonstationary random responses of systems was presented in this paper. Firstly, for the evolutionary random excitation model, the evolutionary power spectrum density function （EPSD） of a random excitation was given by wavelet transform. Based on the EPSD, the nonstationary responses of a SDOF system subjected to evolutionary random excitations were studied. The application and validity of presented method were illustrated by numerical examples. In numerical examples, the recently developed stochastic models for El Centro （1934） and Mexico City （1985） earthquakes which preserve the nonstationary evolutions of amplitude and frequency content of ground accelerations were used as excitations. The nonstationary random mean-square responses of a SDOF system under these two excitations were evaluated and compared with simulated results.

The Design and Control of Distillation Column with Side Reactors for Chlorobenzene Production

The distillation column with side reactors (SRC) can overcome the temperature/pressure mismatch in the traditional reactive distillation, the column operates at temperature/pressure favorable for vapor-liquid separation, while the reactors operate at temperatures/pressures favorable for reaction kinetics. According to the smooth operation and automatic control problem of the distillation column with side reactors (SRC), the design, simulation calculation and dynamic control of the SCR process for chlorobenzene production are discussed in the paper. Firstly, the mechanism models, the integrated structure optimal design and process simulation systems are established, respectively. And then multivariable control schemes are designed, the controllability of SRC process based on the optimal steady-state integrated structure is explored. The dynamic response performances of closed-loop system against several disturbances are discussed to verify the effectiveness of control schemes for the SRC process. The simulating results show that the control structure using conventional control strategies can effectively overcome feeding disturbances in a specific range.

Quasi-Classical Trajectory Investigation of H+SO_(2)→OH+SO Reaction on Full-Dimensional Accurate Potential Energy Surface

The reaction H+SO_(2)→OH+SO is important in the combustion and atmospheric chemistry,as well as the interstellar medium.It also represents a typical complex-forming reaction with deep complexes,serving as an ideal candidate for testing various kinetics theories and providing interesting reaction dynamical phenomena.In this work,we reported a quasiclassical trajectory study of this reaction on our previously developed accurate full-dimensional potential energy surface.The experimental thermal rate coefficients over the temperature range 1400 K≤T≤2200 K were well reproduced.For the reactant SO_(2)being sampled at the ground ro-vibrational state,the calculated integral cross sections increased slightly along the collision energy ranging from 31.0 kcal/mol to 40.0 kcal/mol,and then became essentially flat at the collision energy within 40.0−55.0 kcal/mol.The product angular distributions are almost symmetric with nearly identical backward-forward double peak structure.The products OH and SO vibrational state distributions were also analyzed.

Ab initio Molecular Dynamics Study of Adsorption of Hydroxyl Groups on Graphene Surface

Reduced graphene oxide is the precursor to produce graphene in a large scale;however,to date,there has been no consensus on the electronic structure of reduced graphene oxide.In this study,we carried out an ab initio molecular dynamics simulation to investigate the adsorption process of hydroxyl groups on graphene surface.During the adsorption process,the OH group needs to firstly pass through a physical adsorption complex with the OH above the bridge site of two carbon atoms,next to surmount a transition state,then to be adsorbed at the atop site of a carbon atom.With a 5×5 graphene surface,up to 6 hydroxyl groups can be adsorbed on the graphene surface,indicating the concentration coverage of the hydroxyl groups on graphene surface is about 12%.The simulation results show that the negative adsorption energy increases linearly as the number of adsorbed hydroxyl groups increases,and the band gap also increases linearly with the number of adsorbed hydroxyl groups.