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我国住房市场的动态学分析
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作者 张文玺 《长江论坛》 2008年第5期53-57,共5页
本文从住房模型出发,运用动态学方法,分别对住房资本已存市场和新增住房市场的均衡进行分析,得到了住房市场的鞍点路径和处于鞍点上的均衡住房存量和真实住房价格。
关键词 住房市场 动态学分析
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存量与增量:商业银行不良贷款的动态学分析 被引量:26
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作者 毛瑞宁 《金融研究》 CSSCI 北大核心 2002年第6期131-134,F003,共5页
本文以商业银行不良贷款的动态学 (历史继承关系 )为考察对象 ,重点分析新增不良贷款的主要特点及其化解方法。研究发现 :由于不良贷款存在动态相关性 ,简单划分不良贷款“存量”和“增量” ,并分别提出化解措施是一种现实偏差。在政策... 本文以商业银行不良贷款的动态学 (历史继承关系 )为考察对象 ,重点分析新增不良贷款的主要特点及其化解方法。研究发现 :由于不良贷款存在动态相关性 ,简单划分不良贷款“存量”和“增量” ,并分别提出化解措施是一种现实偏差。在政策意义上 ,虽然不良贷款存量化解不一定能遏制新增不良贷款扩张 ,但是增量化解必须结合存量问题通盘解决。 展开更多
关键词 商业银行 不良贷款 动态学分析 存量 增量 中国 信贷管理 监管制度 信用环境
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周围型肺癌的X线诊断与影像学动态分析 被引量:2
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作者 陈协辉 郭欣睿 +2 位作者 李刚 梁俊生 李秋雨 《现代医用影像学》 2019年第7期1519-1521,共3页
目的:通过对周围型肺癌患者实施X线检查和影像动态分析,探究其诊断效果。方法:从来我院诊治的2016年1月-2018年12月的周围型肺癌患者中随机抽取48例,进行X线检查和CT检查,观察其临床诊断效果和影像学动态结果。结果:动态学结果发现有42... 目的:通过对周围型肺癌患者实施X线检查和影像动态分析,探究其诊断效果。方法:从来我院诊治的2016年1月-2018年12月的周围型肺癌患者中随机抽取48例,进行X线检查和CT检查,观察其临床诊断效果和影像学动态结果。结果:动态学结果发现有42例患者病程长短不一,病灶呈不同程度增大,出现不规则性或者圆形、椭圆形肿块,最小直径为2.5mm,最长直径为9.0mm,平均直径为(6.1±1.02)mm。其中有30例分叶征,空洞征有14例,16例毛刺征,9例斑点化钙化,14例胸膜萎缩征;所有病灶都为结节状,20例分叶征,13例细毛刺征,16例胸膜萎缩征;肺内的单发结节病灶直径在9~20mm范围内,平均直径为14.3±1.23mm。在48例患者中,有36例出现结节状,没有钙化,密度较为均匀,其中有14例患者病灶有小透光区。有18例病灶轮廓不清的患者,其中有13例出现细小毛刺征,16例胸膜萎缩征,6例表现斑片影,病灶边缘较为模糊,形态不规则,6例出现空洞征。结论:患者病灶直径在15mm以内,边缘有分叶征、胸膜萎缩征、毛刺等表现,内有空泡征,不伴随临床症状,提示为早期周围型肺癌。 展开更多
关键词 周围型肺癌 X线 影像动态分析
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Rate controlling mechanisms in hot deformation of 7A55 aluminum alloy 被引量:4
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作者 冯迪 张新明 +2 位作者 刘胜胆 吴泽政 谈琦 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第1期28-35,共8页
The hot deformation behavior of 7A55 aluminum alloy was investigated at the temperature ranging from 300 ℃ to 450 ℃ and strain rate ranging from 0.01 s-1 to 1 s-1 on a Gleeble-3500 simulator. Processing maps were es... The hot deformation behavior of 7A55 aluminum alloy was investigated at the temperature ranging from 300 ℃ to 450 ℃ and strain rate ranging from 0.01 s-1 to 1 s-1 on a Gleeble-3500 simulator. Processing maps were established in order to apprehend the kinetics of hot deformation and the rate controlling mechanism was interpreted by the kinetic rate analysis obeying power-law relation. The results indicated that one significant domain representing dynamic recrystallization (DRX) existed on the processing maps and lying in 410-450 &#176;C and 0.05-1 s-1. The conclusions of kinetic analysis correlated well with those obtained from processing maps. The apparent activation energy values calculated in the dynamic recrystallization (DRX) domain and the stability regions except dynamic recrystallization (DRX) domain were 91.2 kJ/mol and 128.8 kJ/mol, respectively, which suggested that grain boundary self-diffusion and cross-slip were the rate controlling mechanisms. 展开更多
关键词 7A55 aluminum alloy processing maps hot deformation kinetic analysis dynamic recrystallization
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Comparative study on bioleaching of two different types of low-grade copper tailings by mixed moderate thermophiles 被引量:9
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作者 Xiao-dong HAO Xue-duan LIU +4 位作者 Qin YANG Hong-wei LIU Hua-qun YIN Guan-zhou QIU Yi-li LIANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第9期1847-1853,共7页
The bioleaching of two different types of low-grade copper tailings,acid-leaching tailings(ALT)and copper flotation tailings(CFT)by mixed moderate thermophiles,and the variation of mineralogical and microbiological ch... The bioleaching of two different types of low-grade copper tailings,acid-leaching tailings(ALT)and copper flotation tailings(CFT)by mixed moderate thermophiles,and the variation of mineralogical and microbiological characteristics during their dissolution processes were comparatively investigated.Results showed that bioleaching behaviors of the two types of tailings were significantly different.In ALT bioleaching,lower redox potential,higher[Fe3+]/[Fe2+]ratio and higher cell density in solution were obtained.These resulted in higher total copper,primary copper sulfide and secondary copper sulfide extractions,compared with CFT bioleaching.X-ray diffraction analysis suggested that gypsum and some metal organic complexes were detected in CFT bioleaching,which could cause the sluggish oxidation of sulphide minerals.The shifts of microbial community in the leachates and leaching residues varied greatly between ALT and CFT bioleaching.The percentage of iron-oxidizing bacteria in ALT bioleaching was higher than that of CFT,but the sulfur-oxidizing bacteria percentage was the opposite.The archaeon F.thermophilum L1 was detected in ALT but not in CFT. 展开更多
关键词 BIOLEACHING TAILINGS microbial community dynamics mineralogical analysis
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Synthesis and properties of UV curable polyurethane acrylates based on two different hydroxyethyl acrylates 被引量:10
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作者 廖峰 曾幸荣 +2 位作者 李红强 赖学军 赵富春 《Journal of Central South University》 SCIE EI CAS 2012年第4期911-917,共7页
Two kinds of UV curable polyurethane acrylate oligomers (PUPA and PUCA) were synthesized via the addition reaction between isophorone diisocyanate (IPDI) and polyethylene glycol monoacrylate (PEA6) or polycaprol... Two kinds of UV curable polyurethane acrylate oligomers (PUPA and PUCA) were synthesized via the addition reaction between isophorone diisocyanate (IPDI) and polyethylene glycol monoacrylate (PEA6) or polycaprolactone modified hydroxyethyl acrylate (PCLA2). The structures of PUPA and PUCA were characterized by Fourier transform infrared spectroscopy (FT-IR), IH nuclear magnetic resonance (^H NMR), gel permeation chromatography (GPC) and differential scanning calorimeter (DSC), and the thermal stability and dynamic mechanical thermal properties of their cured films were measured by thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA), respectively. The viscosity of the oligomers and mechanical properties of the cured films were also studied. The results show that both oligomers have narrow molecular weight distribution. The viscosity of PUPA is 2.310 Pa.s at 25 ℃, while that of PUCA is: up to 3.980 Pa-s. The UV cured PUPA and PUCA films have homogeneous phase structure, and the PUCA film shows higher glass transition temperature and storage modulus. Furthermore, the PUCA film possesses better mechanical properties than PUPA, while the latter shows better alkali resistance. 展开更多
关键词 UV curable oligomer isophorone diisocyanate polyurethane acrylate hydroxyethyl acrylate
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Effect of small tensile deformation on damping capacities of Mg-1%Al alloy 被引量:2
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作者 胡小石 赫晓东 +1 位作者 郑明毅 吴昆 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第B07期444-447,共4页
Tensile tests with small deformation amounts of 0.5%,1%,3%and 5%were performed at room temperature on as cast Mg-1%Al alloy.Microstructures of the Mg-1%Al alloys before and after deformation were observed by optical m... Tensile tests with small deformation amounts of 0.5%,1%,3%and 5%were performed at room temperature on as cast Mg-1%Al alloy.Microstructures of the Mg-1%Al alloys before and after deformation were observed by optical microscopy(OM) and transmission electron microscopy(TEM).The strain amplitude dependent and temperature dependent damping capacities of the as-cast and deformed Mg-1%Al alloys were investigated by dynamic mechanical analysis(DMA).The mechanism of deformation on damping capacity of Mg-1%Al alloy was discussed.The results show that the as-cast Mg-1%Al alloy has high damping value at high strain.When the tensile elongation is higher than 3%,the damping values of this alloy in high strain region are significantly decreased at room temperature.But the large amount of dislocations produced by tensile deformation are activated by heat,and then increase the damping value at high temperature. 展开更多
关键词 Mg-1%Al alloy tensile deformation damping capacity dislocations TEMPERATURE
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Theoretical analysis of thermoviscoelastic contact between friction lining and wire rope in mine friction hoists 被引量:2
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作者 PENG Yu-xing ZHU Zhen-cai CHEN Guo-an 《Mining Science and Technology》 EI CAS 2009年第4期518-521,共4页
Serious accidents of mine hoists caused by high-speed sliding between friction lining and wire rope are often seen in coal mines.In order to solve this problem,we analyzed the contact characteristics between friction ... Serious accidents of mine hoists caused by high-speed sliding between friction lining and wire rope are often seen in coal mines.In order to solve this problem,we analyzed the contact characteristics between friction lining and wire rope.Then we carried out a dynamic mechanical analysis(DMA) to explain the change in mechanical properties of the friction lining as function of temperature and load frequency and found that temperature has a stronger effect on the mechanical properties than the frequency.We used multiple regression analysis to obtain the thermoviscoelastic constitutive relations of the friction lining.As well we derived the analytic solution for the thermoviscoelastic contact radius and pressure by combining the theory of viscoelastic contact mechanics with thermoviscoelastic constitutive relations. 展开更多
关键词 contact mechanics THERMOVISCOELASTICITY friction lining dynamic mechanical analysis mine hoist
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Effect of precipitation on internal friction of AZ91 magnesium alloy 被引量:1
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作者 刘树伟 姜海昌 +1 位作者 李秀艳 戎利建 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第B07期453-457,共5页
The effect of precipitation on the internal friction(IF)of AZ91 magnesium alloy was investigated by using X-ray diffraction(XRD)analysis,scanning electron microscope(SEM)observation,and dynamic mechanical analysis(DMA... The effect of precipitation on the internal friction(IF)of AZ91 magnesium alloy was investigated by using X-ray diffraction(XRD)analysis,scanning electron microscope(SEM)observation,and dynamic mechanical analysis(DMA).Six different states of alloy were prepared by applying different heat treatment processes:as-cast,in-complete solid solution,complete solid solution,micro-precipitation,continuous precipitation and continuous-discontinuous precipitation.It was found that the internal friction of in-completely solid-solutionized,completely solid-solutionized and micro-precipitated specimens showed a similar characteristic,and the grain boundary relaxation is completed depressed due to the Al atoms supersaturated in theα-Mg solution.However,a thermal relaxation internal friction peak was observed for continuously precipitated and continuously-discontinuously precipitated specimens at around 438 K and frequency of about 1 Hz,which was attributed to the grain boundaries relaxation.Furthermore,it was found that the relaxation of theβ-Mg17Al12/α-Mg phase interfaces should give its contribution to the background internal friction in the as-cast,continuously precipitated and continuously-discontinuously precipitated specimens. 展开更多
关键词 PRECIPITATION solutionization isothermal treatment AGING internal friction
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Magnesium composites with hybrid nano-reinforcements:3D simulation of dynamic tensile response at elevated temperatures 被引量:5
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作者 Xia ZHOU Zi-fan LIU +1 位作者 Feng SU Ya-fu FAN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第3期636-647,共12页
3D numerical simulations of dynamical tensile response of hybrid carbon nanotube(CNT)and SiC nanoparticle reinforced AZ91D magnesium(Mg)based composites considering interface cohesion over a temperature range from 25 ... 3D numerical simulations of dynamical tensile response of hybrid carbon nanotube(CNT)and SiC nanoparticle reinforced AZ91D magnesium(Mg)based composites considering interface cohesion over a temperature range from 25 to 300℃ were carried out using a 3D representative volume element(RVE)approach.The simulation predictions were compared with the experimental results.It is clearly shown that the overall dynamic tensile properties of the nanocomposites at different temperatures are improved when the total volume fraction and volume fraction ratio of hybrid CNTs to SiC nanoparticles increase.The overall maximum hybrid effect is achieved when the hybrid volume fraction ratio of CNTs to SiC nanoparticles is in the range from 7:3 to 8:2 under the condition of total volume fraction of 1.0%.The composites present positive strain rate hardening and temperature softening effects under dynamic loading at high temperatures.The simulation results are in good agreement with the experimental data. 展开更多
关键词 magnesium matrix composites hybrid nanosized reinforcements dynamic mechanical properties numerical analysis
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Damping of Magnetorheological Elastomers 被引量:2
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作者 Lin Chen Xing-long Gong Wei-hua Li 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2008年第6期581-585,共5页
The damping property of magnetorheological (MR) elastomers is characterized by a modified dynamic mechanical-magnetic coupled analyzer. The influences of the external magnetic flux density, damping of the matrix, co... The damping property of magnetorheological (MR) elastomers is characterized by a modified dynamic mechanical-magnetic coupled analyzer. The influences of the external magnetic flux density, damping of the matrix, content of iron particles, dynamic strain, and driving frequency on the damping properties of MR elastomers were investigated experimentally. The experimental results indicate that the damping properties of MR elastomers greatly depend on the interfacial slipping between the inner particles and the matrix. Different from general composite materials, the interracial slipping in MR elastomers is affected by the external applied magnetic field. 展开更多
关键词 Magnetorheological elastomers Damping property Interfacial slipping
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Static and Dynamic Analyses of Long-Span Spatial Steel-Cable-Membrane Hybrid Structures
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作者 丁阳 彭翼 李忠献 《Transactions of Tianjin University》 EI CAS 2003年第4期302-306,共5页
With the increment of the complexity of structural systems and the span of spatial structures, the interactions between parts of the structures, especially between some flexible substructures, become too complex to be... With the increment of the complexity of structural systems and the span of spatial structures, the interactions between parts of the structures, especially between some flexible substructures, become too complex to be analyzed clearly. In this paper, taking an actual gymnasium of a long-span spatial steel-cable-membrane hybrid structure as the calculation model, the static and dynamic analyses of the hybrid structures are performed by employing the global analysis of the whole hybrid structure and the substructural analysis of the truss arch substructure, the cable-membrane substructure, etc. In addition, the comparison of stresses and displacements of structural members in the global and substructural analyses is made. The numerical results show that serious errors exist in the substructural analysis of the hybrid structure, and the global analysis is necessary for the hybrid structure under the excitation of static loads and seismic loads. 展开更多
关键词 long-span spatial structure steel-cable-membrane hybrid structure static and dynamic analyses global analysis substructural analysis SUBSTRUCTURE
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Effect of Ultraviolet Aging on Asphalt Rheological Properties
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作者 Wang Jiani Xue Zhongjun +1 位作者 Tan Yiqiu Zhang Lei 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2013年第4期26-32,共7页
This paper simulated the ultraviolet aging process of asphalt and used dynamic mechanic analysis (DMA) method to evaluate the effect of ultraviolet aging on the asphalt theological properties. After having experienc... This paper simulated the ultraviolet aging process of asphalt and used dynamic mechanic analysis (DMA) method to evaluate the effect of ultraviolet aging on the asphalt theological properties. After having experienced ultravio- let aging, the low temperature performance of asphalt binder decreased significantly, with its complex modulus increased and phase angle decreased along with changing rheological properties as compared to the performance of original asphalt binder. The ultraviolet aging process would make asphalt binder more sensitive to brittle and fatigue failure. On the basis of the time-temperature superposition principle (TTSP), the viscoelastic transition frequency (coT) is proposed to evaluate the effect of ultraviolet aging. It is found that with the increase in ultraviolet aging time, the cox moves to the lower frequency range gradually. Since the viscoelastic transition frequency is sensitive to the effect of aging, it can be used as an indicator of ultraviolet aging. 展开更多
关键词 ASPHALT ultraviolet aging rheological properties viscoelastic transition frequency
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Effects of static aeroelasticity on composite wing characteristics under different flight attitudes
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作者 霍世慧 袁喆 +1 位作者 王富生 岳珠峰 《Journal of Central South University》 SCIE EI CAS 2013年第2期312-317,共6页
Composite wing static aeroelasticity was analyzed through a loosely coupled method and the effects on composite wing characteristics under different flight attitudes were presented. Structural analysis and aerodynamic... Composite wing static aeroelasticity was analyzed through a loosely coupled method and the effects on composite wing characteristics under different flight attitudes were presented. Structural analysis and aerodynamic analysis were carried out through finite element method (FEM) software NASTRAN and computational fluid dynamics (CFD) software FLUENT, respectively. Correlative data transfer and mesh regenerate procedure were applied to couple the results of computational structure dynamics (CSD) and CFD. After static aeroelasticity analysis under different flight attitudes, it can be seen that lift increases with the increase of flight speed and the incremental value enlarges gradually in both rigid and elastic wings. Lift presents a linear increment relationship with the increase of attack angle when the flight speed is 0.4Ma or 0.6Ma, but nonlinear increment in elastic wing when flight speed is 0.8Ma. On the effect of aeroelasticity, the maximum of deformation increases with the increase of flight speed and attack angle, and the incremental value decreases with the increase of flight speed while uniform with different attack angles. The results provide a reference for engineering applications. 展开更多
关键词 static aeroelasticity elastic deformation aerodynamic characteristics structural characteristics flight attitudes
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Agent-Based Simulation for Analyzing Network Formation with Learning Dynamics
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作者 Michiharu Masui Mikio Ogawa 《Journal of Mathematics and System Science》 2012年第9期576-585,共10页
In game theoretic context, it is assumed that the decision maker has the extraordinary skills of reasoning and calculation. This assumption is called "perfect rationality". A player with perfect rationality can solv... In game theoretic context, it is assumed that the decision maker has the extraordinary skills of reasoning and calculation. This assumption is called "perfect rationality". A player with perfect rationality can solve complex problems without making mistakes. However, recently, many studies have restricted this rationality or the structure of game. These restrictions are called "bounded rationality." The authors also focus on bounded rationality, but with learning dynamics and complex networks. A complex network covers a wide area. Currently, a wide range of studies have not only investigated network formation and the characteristics of a formed network, but also analyzed situations where a network is already provided. In addition, in an analysis using game theory, a prisoners' dilemma type game was used to investigate how a change in the network structure would affect the players' relationships Therefore, our model employs decision makers with learning dynamics and describes the interaction of decision makers as a network. The purpose of this study is to examine the behavior of the decision maker with learning dynamics and the formation of networks by the interaction of decision makers through an agent-based simulation. 展开更多
关键词 Game theory complex network simple dynamics best-response dynamics agent-based simulation.
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Comparison of the morphometric dynamics of fast-growing and slow-growing strains of turbot Scophthalmus maximus
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作者 王新安 马爱军 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2015年第4期890-894,共5页
The dynamics of changes in body shape of fast-growing and slow-growing strains of turbot Scophthalmus maximus, and of the differences in body shape between the two strains, were evaluated from 3 to 27 months of age. T... The dynamics of changes in body shape of fast-growing and slow-growing strains of turbot Scophthalmus maximus, and of the differences in body shape between the two strains, were evaluated from 3 to 27 months of age. The ratios of total length/body length, body width/body length and total length/body width were used as morphometric indices. The two strains exhibited different temporal trends in total length/body length but similar trends in body width/body length and total length/body width. Generally, body width/body length of the two strains increased with time and total length/body width decreased. Thus, the bodies of both fast-growing and slow-growing strains of turbot changed from a narrow to a more rounded shape. However, the ratio total length/body length was generally lower, body width/body length was mostly higher and total length/body width was consistently lower in the fast-growing strain than in the slowgrowing strain. Correlation analysis of the three shape ratios with body weight showed that total length/body length and total length/body width were unsuitable, and that width/body length was suitable, for use as a phenotypic marker for selective breeding of turbot for growth in weight. 展开更多
关键词 Scophthalmus maximus slow-growing strain fast-growing strain morphometric comparison
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Dynamic Alignment of D2 Enhanced by Two Few-cycle Pulses
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作者 Zeng-qiang Yang Zhi-rong Guo +1 位作者 Bao-xiang Yin Mao-zhu Sun 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2008年第5期421-426,共6页
Dynamic alignment of D2 induced by two few-cycle pulses was investigated by solving the time-dependent Schr6dinger equation numerically based on a rigid rotor model. The results show that alignment of D2 can be enhanc... Dynamic alignment of D2 induced by two few-cycle pulses was investigated by solving the time-dependent Schr6dinger equation numerically based on a rigid rotor model. The results show that alignment of D2 can be enhanced by two few-cycle pulses compared with the level achievable by a single few-cycle pulse as long as the time delay between two pulses is chosen properly, and the pulse duration of two lasers plays an important role in the aligning process of D2 molecules. 展开更多
关键词 Dynamic alignment Few-cycle pulses Pulse duration
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Dynamic responses research of offshore wind turbine tripod foundation and upper structure
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作者 Ruojie Peng 《International English Education Research》 2015年第4期73-75,共3页
In order to obtain the performance of the offshore wind turbine tripod foundation, a tripod foundation model was built by ANSYS. The static analysis, modal analysis and the transient dynamic analysis were run. Differe... In order to obtain the performance of the offshore wind turbine tripod foundation, a tripod foundation model was built by ANSYS. The static analysis, modal analysis and the transient dynamic analysis were run. Different parameters such as displacement, velocity, acceleration, stress were obtained and by analyzing these data, it is reasonable to draw a conclusion that the tripod foundation has a good performance used on the offshore wind turbine. 展开更多
关键词 Offshore wind turbine Tripod foundation Dynamic responses.
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Study on Microblog Dissemination Law in View ol Forwarding
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作者 CHEN Xia JIA Yuan GUO Longfei 《China Communications》 SCIE CSCD 2014年第2期128-137,共10页
Forwarding is a major means of information dissemination on the Microblog platform.The article,combining static analysis and dynamic analysis,takes Microblog forwarding as the object of study,and studies the network t... Forwarding is a major means of information dissemination on the Microblog platform.The article,combining static analysis and dynamic analysis,takes Microblog forwarding as the object of study,and studies the network topology of grass-roots Microblog forwarding users.It also studies the correlation between characteristic quantity and forwarding times of Microblog network topology.Furthermore,it conducts modification on virus transmission model,builds and verifies the Microblog forwarding dynamical model.The study finds out that Microblog postings present qute strong dissemination capacity on the initial stage,and some Microblog postings with many forwarding times and long duration of forwarding process due to the dynamic growth of the forwarding user network and the joining of strong nodes make network infection density decrease in some phases. 展开更多
关键词 Microblog dissemination law social network dissemination dynamics Microblog forwarding
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π-Conjugated Unit-Dependent Optical Properties of Linear Conjugated Oligomers
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作者 Ning Sui Lu Zou +7 位作者 Yun-fei Song Qiu-lin Zhong Ying-hui Wang Xiao-gang Wei Zeng-bin Wang Yu-guang Ma Yan-qiang Yang Han-zhuang Zhang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2014年第3期315-320,共6页
The optical properties of three linear conjugated oligomers (F-P, F-P-F, and P-F-P-F-P), where phenothiazine (P) and fluorene (F) groups arrange alternately, are investigated. With the enhancement of the π-conj... The optical properties of three linear conjugated oligomers (F-P, F-P-F, and P-F-P-F-P), where phenothiazine (P) and fluorene (F) groups arrange alternately, are investigated. With the enhancement of the π-conjugated system, their absorption and emission bands both gradually red shift, and their two-photon properties are also improved. Meanwhile, their fluorescence dynamic traces are analyzed with continuous rate distribution model, exhibiting that their decay rates gradually accelerate and the rate distribution width become narrower. The quantum chemical calculation offers their molecular structures and transition mechanism, showing that the enhancement of π-conjugated system should be responsible for tile improvement of two-photon properties. 展开更多
关键词 OLIGOMER Z-SCAN Fluorescence dynamics
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