The nanometer cobalt blue pigments were prepared by microemulsion method. Using dynamic light scattering(DLS) test method, the influences of water content on the size of liquid drop of microemulsion and the liquid dro...The nanometer cobalt blue pigments were prepared by microemulsion method. Using dynamic light scattering(DLS) test method, the influences of water content on the size of liquid drop of microemulsion and the liquid drop of microemulsion on the final diameter of nanometer particle were studied in the course of preparation. Accordingly, the method to control the diameter of nanometer particle by changing water content was established. The nanometer cobalt blue particles were confirmed by XRD and TEM. Color parameters of pigments were determined. The quantum size effect of the pigments was discussed.展开更多
A modified seeded growth process of silica particles with a continuous addition of tetraethyl orthosilicate (TEOS) was presented to control the diameter of silica particles. The diameter of particles was monitored b...A modified seeded growth process of silica particles with a continuous addition of tetraethyl orthosilicate (TEOS) was presented to control the diameter of silica particles. The diameter of particles was monitored by dynamic light scattering to control the addition of TEOS. The increase in the diameter of the silica particles with time and the addition of TEOS was investigated. The diameter of silica seeds increased from 193 nm to 446 nm in 4 h. The final diameter of silica particles was tailored within the range of ±5 nm to the target diameter. Silica particles with diameter of 446 nm were synthesized and assembled into photonic crystals with a pseudo band gap centered at just 1000 nm. The feasibility and practicability of this modified seeded growth process was verified.展开更多
According to theory of photoautotrophic micro-propagation, and principle and technology of environmental engineering, an automatic control and regulation under photoautotrophic micro-propagation by plants was designed...According to theory of photoautotrophic micro-propagation, and principle and technology of environmental engineering, an automatic control and regulation under photoautotrophic micro-propagation by plants was designed, which can be used for planting condition optimization of photoautotrophic micro-propagation and qualified industrialized production of seedlings.展开更多
Reversible assembly and disassembly of rodlike large complex micelles have been achieved by applying photoswitching of supramolecular inclusion and exclusion of azobenzene-functionalized hyperbranched polyglycerol and...Reversible assembly and disassembly of rodlike large complex micelles have been achieved by applying photoswitching of supramolecular inclusion and exclusion of azobenzene-functionalized hyperbranched polyglycerol and acyclodextrin as driv ing force, promising a versatile system for selfassembly switched by light. Hydrogennuclear magnetic resonance (H NMR) and Fourier transform infrared (FTIR) spectroscopy were applied to characterize the azobenzenefunctionalized hyperbranched polyglycerol. Atomic force microscopy (AFM), transmission electron microscopy (TEM) and dynamic laser light scattering (DLS) were employed to investigate and track the morphology of the rodlike large complex micelles before and after irradiation of UV light.展开更多
A microwave photonic link (MPL) with high spurious-free dynamic range (SFDR) is proposed and analyzed. The optical carrier is divided equally into two paths. The path I is modulated by radio frequency (RF) signa...A microwave photonic link (MPL) with high spurious-free dynamic range (SFDR) is proposed and analyzed. The optical carrier is divided equally into two paths. The path I is modulated by radio frequency (RF) signals in a Mach-Zehnder modulator (MZM), and the phase of path 2 is controlled before the combination with path 1. By properly adjusting the phase difference of the two paths with the optical phase shifter, the third-order intermodulation distortion (IMD3) can be significantly suppressed. A proof-of-concept simulation is carried out. The results show that a reduction of 40 dB in the IMD3 and an improvement of 21.1 dB in the SFDR are achieved as compared with the conventional MZM-based MPL. The proposed MPL shows the advantages of simple structure, low cost and high efficiency.展开更多
Supramolecular binary vesicles were constructed by host-guest complex formation between p-sulfonatocalix[4]arene and three cationic gemini surfactants, which were identified by UV-vis, dynamic laser scattering, transm...Supramolecular binary vesicles were constructed by host-guest complex formation between p-sulfonatocalix[4]arene and three cationic gemini surfactants, which were identified by UV-vis, dynamic laser scattering, transmission electron microscopy, scanning electron microscopy, atomic force microscopy, and surface tension experiments. The critical aggregation concentration of gemini surfactants decreased pronouncedly by a factor of ca. 1000 owing to the complexation of p-sulfonato-calix[4]arene.展开更多
Sulfonatocalix[4]arene lowers the critical aggregation concentration of fluorocarbon surfactant pronouncedly by a factor of ca.100 to form binary amphiphilic aggregates on the basis of host-guest complexation,which wa...Sulfonatocalix[4]arene lowers the critical aggregation concentration of fluorocarbon surfactant pronouncedly by a factor of ca.100 to form binary amphiphilic aggregates on the basis of host-guest complexation,which was identified by1H NMR spectroscopy,fluorescence spectroscopy,optical transmittance spectroscopy,dynamic laser scattering,high-resolution transmission electron microscopy,scanning electron microscopy,and surface tension experiments.Moreover,the resulting aggregates can respond to external stimuli,including temperature and inclusion of competitor guest.Therefore,the present system may have potential applications in drug delivery systems.展开更多
文摘The nanometer cobalt blue pigments were prepared by microemulsion method. Using dynamic light scattering(DLS) test method, the influences of water content on the size of liquid drop of microemulsion and the liquid drop of microemulsion on the final diameter of nanometer particle were studied in the course of preparation. Accordingly, the method to control the diameter of nanometer particle by changing water content was established. The nanometer cobalt blue particles were confirmed by XRD and TEM. Color parameters of pigments were determined. The quantum size effect of the pigments was discussed.
文摘A modified seeded growth process of silica particles with a continuous addition of tetraethyl orthosilicate (TEOS) was presented to control the diameter of silica particles. The diameter of particles was monitored by dynamic light scattering to control the addition of TEOS. The increase in the diameter of the silica particles with time and the addition of TEOS was investigated. The diameter of silica seeds increased from 193 nm to 446 nm in 4 h. The final diameter of silica particles was tailored within the range of ±5 nm to the target diameter. Silica particles with diameter of 446 nm were synthesized and assembled into photonic crystals with a pseudo band gap centered at just 1000 nm. The feasibility and practicability of this modified seeded growth process was verified.
基金Supported by Agriculture Development Program for Science and Technology in Guangdong Province(2009B020405003)~~
文摘According to theory of photoautotrophic micro-propagation, and principle and technology of environmental engineering, an automatic control and regulation under photoautotrophic micro-propagation by plants was designed, which can be used for planting condition optimization of photoautotrophic micro-propagation and qualified industrialized production of seedlings.
基金supported by the National Natural Science Foundation of China (20974093)the National Basic Research Program of China (973 Program, 2007CB936004)+3 种基金Qianjiang Talent Foundation of Zhejiang Province (2010R10021)the Fundamental Research Funds for the Central Universities (2009QNA4040)Zhejiang Provincial Natural Science Foundation of China (R4110175)Research Fund for the Doctoral Program of Higher Education of China ( 20100101110049)
文摘Reversible assembly and disassembly of rodlike large complex micelles have been achieved by applying photoswitching of supramolecular inclusion and exclusion of azobenzene-functionalized hyperbranched polyglycerol and acyclodextrin as driv ing force, promising a versatile system for selfassembly switched by light. Hydrogennuclear magnetic resonance (H NMR) and Fourier transform infrared (FTIR) spectroscopy were applied to characterize the azobenzenefunctionalized hyperbranched polyglycerol. Atomic force microscopy (AFM), transmission electron microscopy (TEM) and dynamic laser light scattering (DLS) were employed to investigate and track the morphology of the rodlike large complex micelles before and after irradiation of UV light.
基金supported by the Fundamental Research Funds for the Central Universities(No.JB142001-9)the Programme of Introducing Talents of Discipline to Universities China 111 Project(No.B08038)
文摘A microwave photonic link (MPL) with high spurious-free dynamic range (SFDR) is proposed and analyzed. The optical carrier is divided equally into two paths. The path I is modulated by radio frequency (RF) signals in a Mach-Zehnder modulator (MZM), and the phase of path 2 is controlled before the combination with path 1. By properly adjusting the phase difference of the two paths with the optical phase shifter, the third-order intermodulation distortion (IMD3) can be significantly suppressed. A proof-of-concept simulation is carried out. The results show that a reduction of 40 dB in the IMD3 and an improvement of 21.1 dB in the SFDR are achieved as compared with the conventional MZM-based MPL. The proposed MPL shows the advantages of simple structure, low cost and high efficiency.
基金supported by the National Natural Science Foundation of China (20932004)the Prospective Basic Research Subject of China Petroleum (P07009)
文摘Supramolecular binary vesicles were constructed by host-guest complex formation between p-sulfonatocalix[4]arene and three cationic gemini surfactants, which were identified by UV-vis, dynamic laser scattering, transmission electron microscopy, scanning electron microscopy, atomic force microscopy, and surface tension experiments. The critical aggregation concentration of gemini surfactants decreased pronouncedly by a factor of ca. 1000 owing to the complexation of p-sulfonato-calix[4]arene.
基金supported by the National Basic Research Program of China(2011CB932502)the National Natural Science Foundation of China(91227107 and 21172119)
文摘Sulfonatocalix[4]arene lowers the critical aggregation concentration of fluorocarbon surfactant pronouncedly by a factor of ca.100 to form binary amphiphilic aggregates on the basis of host-guest complexation,which was identified by1H NMR spectroscopy,fluorescence spectroscopy,optical transmittance spectroscopy,dynamic laser scattering,high-resolution transmission electron microscopy,scanning electron microscopy,and surface tension experiments.Moreover,the resulting aggregates can respond to external stimuli,including temperature and inclusion of competitor guest.Therefore,the present system may have potential applications in drug delivery systems.