Pyoverdine is one of the siderphores excreted by Pseudomonas aeruginosa that can help microbe to uptake iron in vitro. To determine the effect of pyoverdine chelating with iron, we purified the free pyoverdine and app...Pyoverdine is one of the siderphores excreted by Pseudomonas aeruginosa that can help microbe to uptake iron in vitro. To determine the effect of pyoverdine chelating with iron, we purified the free pyoverdine and applied the dynamic laser light scattering （DLS） to detect the interaction between the pyoverdine and ferric hydroxide. The real-time DLS data analysis indicated that pyoverdine can directly combine with Fe（OH）3 to form complexes and these substances are gradually degraded by themselves then completely disappeared. In our experiment, we have demonstrated that pyoverdine may not only chelate ferric ion but also availably dissolve ferric hydroxide which assists bacteria to survive in iron-deficient environments.展开更多
The concentration of acetaldehyde(AA) is the main quality index of poly(ethylene terephthalate)(PET) used in food and drink packaging.A new method for AA removal has been developed by using supercritical carbon dioxid...The concentration of acetaldehyde(AA) is the main quality index of poly(ethylene terephthalate)(PET) used in food and drink packaging.A new method for AA removal has been developed by using supercritical carbon dioxide(sc CO2) during the solid-state polycondensation of PET.The influence factors of AA removal including the temperature,pressure,reaction time and the size of pre-polymer particles are systematically studied in this work.The results indicate that it is a highly efficient way to obtain high molecular weight PET with relative low concentration of AA.Correspondingly,the polymerization degree of PET could increase from 27.9 to 85.6 while the concentration of AA reduces from 0.229 × 10^(-6) to 0.055 × 10^(-6) under the optimal operation conditions of 230 °C,8 MPa and size of 0.30–0.45 mm.Thermodynamic performance tests show the increasing extent of PET crystallinity due to the fact that the plasticization of sc CO_2 is not obvious with extended reaction time,therefore the increasing crystallinity has no significant influence on AA removal.SEM observations reveal that the effects of sc CO_(2-) induced plasticization and swelling on PET increase significantly with the decrease of prepolymer size,and the surface of PET becomes more loose and porous in favor of the AA removal.展开更多
It is critical to study how different forest management practices affect forest carbon sequestration under global climate change regime. Previous researches focused on the stand-level forest carbon sequestration with ...It is critical to study how different forest management practices affect forest carbon sequestration under global climate change regime. Previous researches focused on the stand-level forest carbon sequestration with rare investigation of forest carbon stocks influ- enced by forest management practices and climate change at regional scale. In this study, a general integrative approach was used to simulate spatial and temporal variations of woody biomass and harvested biomass of forest in China during the 21st century under dif- ferent scenarios of climate and CO2 concentration changes and management tasks by coupling Integrated Terrestrial Ecosystem Carbon budget （InTEC） model with Global Forest Model （G4M）. The results showed that forest management practices have more predominant effects on forest stem stocking biomass than climate and CO2 concentration change. Meanwhile, the concurrent future changes in cli- mate and CO2 concentration will enhance the amounts of stem stocking biomass in forests of China by 12%-23% during 2001-2100 relative to that with climate change only. The task for maximizing stem stocking biomass will dramatically enhance the stem stocking biomass from 2001~100, while the task for maximum average increment will result in an increment of stem stocking biomass before 2050 then decline. The difference of woody biomass responding to forest management tasks was owing to the current age structure of forests in China. Meanwhile, the sensitivity of long-term woody biomass to management practices for different forest types （coniferous forest, mixed forest and deciduous forest） under changing climate and CO2 concentration was also analyzed. In addition, longer rotation length under future climate change and rising CO2 concentration scenario will dramatically increase the woody biomass of China during 2001~100. Therefore, our estimation indicated that taking the role of forest management in the carbon cycle into the consideration at regional or national level is very important to project the forest carbon sequestration under future climate change and rising atmospheric CO2 concentration.展开更多
The vibration states of transition molecule S<SUB>2</SUB>O, including both bending and stretching vibrations, are studied in the framework of dynamical symmetry groups . We get all the vibration spectra of...The vibration states of transition molecule S<SUB>2</SUB>O, including both bending and stretching vibrations, are studied in the framework of dynamical symmetry groups . We get all the vibration spectra of S<SUB>2</SUB>O by fitting 22 spectra data with 10 parameters. The fitting rms of the Hamiltonian is 2.12 cm<SUP>-1</SUP>. With the parameters and Lie algebraic theory, we give the analytical expression of the potential energy surface, which helps us to calculate the dissociation energy and force constants of S<SUB>2</SUB>O in the electronic ground state.展开更多
基金We thank professor Fan Jin of University of Science and Technology of China provided idea and designed the experiments. This work was supported by the National Program on Key Basic Research Project （No.2012CB933802） and the National Natural Science Foundation of China （No.21274141, No.21104071）.
文摘Pyoverdine is one of the siderphores excreted by Pseudomonas aeruginosa that can help microbe to uptake iron in vitro. To determine the effect of pyoverdine chelating with iron, we purified the free pyoverdine and applied the dynamic laser light scattering （DLS） to detect the interaction between the pyoverdine and ferric hydroxide. The real-time DLS data analysis indicated that pyoverdine can directly combine with Fe（OH）3 to form complexes and these substances are gradually degraded by themselves then completely disappeared. In our experiment, we have demonstrated that pyoverdine may not only chelate ferric ion but also availably dissolve ferric hydroxide which assists bacteria to survive in iron-deficient environments.
基金Supported by the National Key Research and Development Program of China(2016YFB0302702)the National Natural Science Foundation of China(21676083)+1 种基金the Shanghai Rising-Star Program(16QB140130)the 111 Project(B08021)
文摘The concentration of acetaldehyde(AA) is the main quality index of poly(ethylene terephthalate)(PET) used in food and drink packaging.A new method for AA removal has been developed by using supercritical carbon dioxide(sc CO2) during the solid-state polycondensation of PET.The influence factors of AA removal including the temperature,pressure,reaction time and the size of pre-polymer particles are systematically studied in this work.The results indicate that it is a highly efficient way to obtain high molecular weight PET with relative low concentration of AA.Correspondingly,the polymerization degree of PET could increase from 27.9 to 85.6 while the concentration of AA reduces from 0.229 × 10^(-6) to 0.055 × 10^(-6) under the optimal operation conditions of 230 °C,8 MPa and size of 0.30–0.45 mm.Thermodynamic performance tests show the increasing extent of PET crystallinity due to the fact that the plasticization of sc CO_2 is not obvious with extended reaction time,therefore the increasing crystallinity has no significant influence on AA removal.SEM observations reveal that the effects of sc CO_(2-) induced plasticization and swelling on PET increase significantly with the decrease of prepolymer size,and the surface of PET becomes more loose and porous in favor of the AA removal.
基金Under the auspices of International Science and Technology Cooperation Project(No.2010DFA22480)Major State Basic Research Development Program of China(No.2010CB833503)
文摘It is critical to study how different forest management practices affect forest carbon sequestration under global climate change regime. Previous researches focused on the stand-level forest carbon sequestration with rare investigation of forest carbon stocks influ- enced by forest management practices and climate change at regional scale. In this study, a general integrative approach was used to simulate spatial and temporal variations of woody biomass and harvested biomass of forest in China during the 21st century under dif- ferent scenarios of climate and CO2 concentration changes and management tasks by coupling Integrated Terrestrial Ecosystem Carbon budget （InTEC） model with Global Forest Model （G4M）. The results showed that forest management practices have more predominant effects on forest stem stocking biomass than climate and CO2 concentration change. Meanwhile, the concurrent future changes in cli- mate and CO2 concentration will enhance the amounts of stem stocking biomass in forests of China by 12%-23% during 2001-2100 relative to that with climate change only. The task for maximizing stem stocking biomass will dramatically enhance the stem stocking biomass from 2001~100, while the task for maximum average increment will result in an increment of stem stocking biomass before 2050 then decline. The difference of woody biomass responding to forest management tasks was owing to the current age structure of forests in China. Meanwhile, the sensitivity of long-term woody biomass to management practices for different forest types （coniferous forest, mixed forest and deciduous forest） under changing climate and CO2 concentration was also analyzed. In addition, longer rotation length under future climate change and rising CO2 concentration scenario will dramatically increase the woody biomass of China during 2001~100. Therefore, our estimation indicated that taking the role of forest management in the carbon cycle into the consideration at regional or national level is very important to project the forest carbon sequestration under future climate change and rising atmospheric CO2 concentration.
基金The project supported by National Natural Science Foundation of China and partly by the Science Foundation of Shandong Province of China
文摘The vibration states of transition molecule S<SUB>2</SUB>O, including both bending and stretching vibrations, are studied in the framework of dynamical symmetry groups . We get all the vibration spectra of S<SUB>2</SUB>O by fitting 22 spectra data with 10 parameters. The fitting rms of the Hamiltonian is 2.12 cm<SUP>-1</SUP>. With the parameters and Lie algebraic theory, we give the analytical expression of the potential energy surface, which helps us to calculate the dissociation energy and force constants of S<SUB>2</SUB>O in the electronic ground state.
