The intra- and inter-band relaxation dynamics of CdSe/CdS/ZnS core/shell/shell quantum dots are investigated with the aid of time-resolved nonlinear transmission spectra which are obtained using femtosecond pump-probe...The intra- and inter-band relaxation dynamics of CdSe/CdS/ZnS core/shell/shell quantum dots are investigated with the aid of time-resolved nonlinear transmission spectra which are obtained using femtosecond pump-probe technique. By selectively exciting the core and shell carrier, the dynamics are studied in detail. Carrier relaxation is found faster in the conduction band of the CdS shell (about 130 fs) than that in the conduction band of the CdSe core (about 400 fs). From the experiments it is distinctly demonstrated the existence of the defect states in the interface between the CdSe core and the CdS shell, indicating that ultrafast spectroscopy might be a suitable tool in studying interface and surface morphology properties in nanosystems.展开更多
Defect-mediated processes in two-dimensional transition metal dichalcogenides have a significant influence on their carrier dynamics and transport properties,however,the detailed mechanisms remain poorly understood.He...Defect-mediated processes in two-dimensional transition metal dichalcogenides have a significant influence on their carrier dynamics and transport properties,however,the detailed mechanisms remain poorly understood.Here,we present a comprehensive ultrafast study on defect-mediated carrier dynamics in ion exchange prepared few-layer MoS2 by femtosecond time-resolved Vis-NIR-MIR spectroscopy.The broadband photobleaching feature observed in the near-infrared transient spectrum discloses that the mid-gap defect states are widely distributed in few-layer MoS2 nanosheets.The processes of fast trapping of carriers by defect states and the following nonradiative recombination of trapped carriers are clearly revealed,demonstrating the mid-gap defect states play a significant role in the photoinduced carrier dynamics.The positive to negative crossover of the signal observed in the mid-infrared transient spectrum further uncovers some occupied shallow defect states distributed at less than0.24 e V below the conduction band minimum.These defect states can act as effective carrier trap centers to assist the nonradiative recombination of photo-induced carriers in few-layer MoS2 on the picosecond time scale.展开更多
Debris flow is one of the major secondary mountain hazards following the earthquake. This study explores the dynamic initiation mechanism of debris flows based on the strength reduction of soils through static and dyn...Debris flow is one of the major secondary mountain hazards following the earthquake. This study explores the dynamic initiation mechanism of debris flows based on the strength reduction of soils through static and dynamic triaxial tests. A series of static and dynamic triaxial tests were conducted on samples in the lab. The samples were prepared according to different grain size distribution, degree of saturation and earthquake magnitudes. The relations of dynamic shear strength, degree of saturation, and number of cycles are summarized through analyzing experimental results. The findings show that the gravelly soil with a wide and continuous gradation has a critical degree of saturation of approximately 87%, above which debris flows will be triggered by rainfall, while the debris flow will be triggered at a critical degree of saturation of about 73% under the effect of rainfall and earthquake(M>6.5). Debris flow initiation is developed in the humidification process, and the earthquake provides energy for triggering debris flows. Debris flows are more likely to be triggered at the relatively low saturation under dynamic loading than under static loading. The resistance of debris flow triggering relies more on internal frication angle than soil cohesion under the effect of rainfall and earthquake. The conclusions provide an experimental analysis method for dynamic initiation mechanism of debris flows.展开更多
In Greece extended cracking of twin-block concrete sleepers (ties) and fouling of the ballast-bed were observed with implied problems of gauge widening and deterioration of track's geometry. This led to a ten-year ...In Greece extended cracking of twin-block concrete sleepers (ties) and fouling of the ballast-bed were observed with implied problems of gauge widening and deterioration of track's geometry. This led to a ten-year investigation program, during which a new method was developed for the estimation of actions on track panel as well as of the pressures / stresses that develop under the seating surface of the sleeper on the ballast-bed. Results from the tests performed on the ballast used in the Greek network are also presented, conducted in laboratories in France, Austria, and Greece. The influence of the actions -static and mainly dynamic- on the track response and the stress and strain of the ballast-bed are also discussed as derived from the tests and theoretical analysis.展开更多
This study presents a decoupling control scheme of fluid catalytic cracking unit to account for the high interaction between two temperature control loops. The feed flow rate load disturbance is introduced to test the...This study presents a decoupling control scheme of fluid catalytic cracking unit to account for the high interaction between two temperature control loops. The feed flow rate load disturbance is introduced to test the proposed decoupling control scheme. Through simulation study shown that the decoupling is effective, stable and it presents advantage over controller without decoupler. Also, this scheme is able to offer good dynamic performance for most disturbances.展开更多
基金This work was supported by the National Natural Science Foundation of China (No.11074003) and the Key Program of Educational Commission of Anhui Province of China (No.KJ2010AI32). For the help of Prof. J. L. Zhao at Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences in sample preparation is greatly appreciated.
文摘The intra- and inter-band relaxation dynamics of CdSe/CdS/ZnS core/shell/shell quantum dots are investigated with the aid of time-resolved nonlinear transmission spectra which are obtained using femtosecond pump-probe technique. By selectively exciting the core and shell carrier, the dynamics are studied in detail. Carrier relaxation is found faster in the conduction band of the CdS shell (about 130 fs) than that in the conduction band of the CdSe core (about 400 fs). From the experiments it is distinctly demonstrated the existence of the defect states in the interface between the CdSe core and the CdS shell, indicating that ultrafast spectroscopy might be a suitable tool in studying interface and surface morphology properties in nanosystems.
基金supported by the National Key Research and Development Program of China(No.2018YFA0208700)the National Natural Science Foundation of China(No.21603270 and No.21773302)the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB30000000)。
文摘Defect-mediated processes in two-dimensional transition metal dichalcogenides have a significant influence on their carrier dynamics and transport properties,however,the detailed mechanisms remain poorly understood.Here,we present a comprehensive ultrafast study on defect-mediated carrier dynamics in ion exchange prepared few-layer MoS2 by femtosecond time-resolved Vis-NIR-MIR spectroscopy.The broadband photobleaching feature observed in the near-infrared transient spectrum discloses that the mid-gap defect states are widely distributed in few-layer MoS2 nanosheets.The processes of fast trapping of carriers by defect states and the following nonradiative recombination of trapped carriers are clearly revealed,demonstrating the mid-gap defect states play a significant role in the photoinduced carrier dynamics.The positive to negative crossover of the signal observed in the mid-infrared transient spectrum further uncovers some occupied shallow defect states distributed at less than0.24 e V below the conduction band minimum.These defect states can act as effective carrier trap centers to assist the nonradiative recombination of photo-induced carriers in few-layer MoS2 on the picosecond time scale.
基金sponsored by Natural Science Foundation of China (Grant No. 51269012)Major Projects of Natural Science Foundation of Inner Mongolia Autonomous Region (Grant No. ZD0602)+2 种基金part of National Project 973 "Wenchuan Earthquake Mountain Hazards Formation Mechanism and Risk Control" (Grant No. 2008CB425800)funded by "New Century Excellent Talents" of University of Ministry of Education of China (Grant No. NCET-11-1016)China Scholarship Council
文摘Debris flow is one of the major secondary mountain hazards following the earthquake. This study explores the dynamic initiation mechanism of debris flows based on the strength reduction of soils through static and dynamic triaxial tests. A series of static and dynamic triaxial tests were conducted on samples in the lab. The samples were prepared according to different grain size distribution, degree of saturation and earthquake magnitudes. The relations of dynamic shear strength, degree of saturation, and number of cycles are summarized through analyzing experimental results. The findings show that the gravelly soil with a wide and continuous gradation has a critical degree of saturation of approximately 87%, above which debris flows will be triggered by rainfall, while the debris flow will be triggered at a critical degree of saturation of about 73% under the effect of rainfall and earthquake(M>6.5). Debris flow initiation is developed in the humidification process, and the earthquake provides energy for triggering debris flows. Debris flows are more likely to be triggered at the relatively low saturation under dynamic loading than under static loading. The resistance of debris flow triggering relies more on internal frication angle than soil cohesion under the effect of rainfall and earthquake. The conclusions provide an experimental analysis method for dynamic initiation mechanism of debris flows.
文摘In Greece extended cracking of twin-block concrete sleepers (ties) and fouling of the ballast-bed were observed with implied problems of gauge widening and deterioration of track's geometry. This led to a ten-year investigation program, during which a new method was developed for the estimation of actions on track panel as well as of the pressures / stresses that develop under the seating surface of the sleeper on the ballast-bed. Results from the tests performed on the ballast used in the Greek network are also presented, conducted in laboratories in France, Austria, and Greece. The influence of the actions -static and mainly dynamic- on the track response and the stress and strain of the ballast-bed are also discussed as derived from the tests and theoretical analysis.
文摘This study presents a decoupling control scheme of fluid catalytic cracking unit to account for the high interaction between two temperature control loops. The feed flow rate load disturbance is introduced to test the proposed decoupling control scheme. Through simulation study shown that the decoupling is effective, stable and it presents advantage over controller without decoupler. Also, this scheme is able to offer good dynamic performance for most disturbances.