A spiral fluidity test model of superalloys with 10 mm in height and 3 mm in thickness was designed to evaluate the fluidity of two distinct Ni-based superalloys IN718 and IN939.The factors influencing fluidity are as...A spiral fluidity test model of superalloys with 10 mm in height and 3 mm in thickness was designed to evaluate the fluidity of two distinct Ni-based superalloys IN718 and IN939.The factors influencing fluidity are ascertained through comparative analysis utilizing methodologies such as JMat Pro,differential scanning calorimetry and high-temperature confocal laser scanning microscopy.The results show that under identical testing conditions,the fluidity of the IN939 superalloy surpasses that of the IN718 superalloy.When subjected to the same temperature,the melt viscosity and surface tension of IN939 superalloy are considerably reduced relative to those of IN718 superalloy,which is beneficial to improving the melt fluidity.Furthermore,the liquidus temperature and solidification range for the IN939 superalloy are both smaller compared with those of the IN718 superalloy.This condition proves advantageous in delaying dendrite coherency,thereby improving fluidity.展开更多
A computational fluid dynamics (CFD) simulation was carried out with CFX4,3 to investigate the melt flow and temperature distributions in the settler of a flash furnace. Sixteen cases of one slag tap hole adopted wi...A computational fluid dynamics (CFD) simulation was carried out with CFX4,3 to investigate the melt flow and temperature distributions in the settler of a flash furnace. Sixteen cases of one slag tap hole adopted with one matte tap hole (1-to-l) and one slag tap hole adopted with two matte tap holes (1-to-2) operation modes were modelled. The simulation results show that the melt flows are similar in both two operation modes, but evident circulations can be found in the case of the 1-to-2 operation mode. The combination modes of the slag and matte tap holes are found to have a significant effect on the temperature distributions of the melt. The melt temperature is more uniform in the case of the 1-to-2 mode. Selection of a matte tap hole farther away from the inlet is more conducive to achieve a uniform distribution of the melt temperature in the settler in nractical tannine oneration展开更多
The rheological properties including the complex modulus G* and the phase angle δof matrix and warm mix asphalt (WMA)binders were measured by using the dynamic shear rheometer (DSR ) test at the medium temperatu...The rheological properties including the complex modulus G* and the phase angle δof matrix and warm mix asphalt (WMA)binders were measured by using the dynamic shear rheometer (DSR ) test at the medium temperature ranging from 16 to 40 ℃,and the relationships between the fatigue factor G* sinδand the matrix binder property,WMA additive and test temperature were established.It is found that G* decreases with the increasing temperature while δincreases inversely,and G* of the asphalt binder with high WMA additive dosage is large,and δis small.G*sinδexponentially decreases with the increasing temperature and linearly increases with the increase in additive dosage,and the amplitudes of variation are large at low temperatures and high additive dosages.The effect of WMA additive on the rheological property is more remarkable for the matrix asphalt binder with low G*.Besides,aging has a great effect on the property of matrix asphalt binder,and a slight effect on the interaction between asphalt and additive.The high additive dosage can increase the fatigue cracking potential of the asphalt binder.展开更多
The single phase La2(CO3)3·3.4H2 O was synthesized by hydrothermal method. The thermal decomposition and intermediates and final solid products of La2(CO3)3·3.4H2O from 30 to 1000 °C were characteri...The single phase La2(CO3)3·3.4H2 O was synthesized by hydrothermal method. The thermal decomposition and intermediates and final solid products of La2(CO3)3·3.4H2O from 30 to 1000 °C were characterized by XRD, FTIR and DTA-TG. The kinetics of dehydration of La2(CO3)3·3.4H2O in the temperature range of 30-366 °C was investigated under non-isothermal conditions. Flynn-Wall-Ozawa and Friedman isoconversion methods were used to calculate the activation energy and analyze the reaction steps; multivariate non-linear regression program was applied to determine the most probable mechanism and the kinetic parameters. The results show that the thermal dehydration of La2(CO3)3·3.4H2O is a kind of three-step competitive reaction, and controlled by an n-order initial reaction followed by n-order competitive reaction(FnFnFn model). The activation energy matching with the most probable model is close to value obtained by Friedman method. The fitting curves match the original TG-DTG curves very well.展开更多
Warm tensile tests for aluminum alloy 7022 sheet are held at different temperatures and strain rates. The range of temperature is 293-773 K and that of the strain rate is 0. 001-0.1 s^-1. The warm tensile properties,r...Warm tensile tests for aluminum alloy 7022 sheet are held at different temperatures and strain rates. The range of temperature is 293-773 K and that of the strain rate is 0. 001-0.1 s^-1. The warm tensile properties,relations among temperature,strain rate,and the flow stress are discussed. Constitutive equations under the warm tension are obtained based on revised Hooke law and Grosman equation. It is concluded that flow stress declines with the increase of the temperature and the decrease of the strain rates. The elongation percentage increases with the increase of the temperature and the decrease of strain rate.展开更多
The retrogression kinetics for grain boundary precipitate (GBP) of 7A55 aluminum alloy was investigated by transmission electron microscopy (TEM) observation. The results reveal that the coarsening behavior of GBP...The retrogression kinetics for grain boundary precipitate (GBP) of 7A55 aluminum alloy was investigated by transmission electron microscopy (TEM) observation. The results reveal that the coarsening behavior of GBP obeys “LSW” theory, namely, the cube of GBP average size has a linear dependence relation to retrogression time, and the coarsening rate accelerates at the elevated retrogression temperature. The GBP coarsening activation energy Qo of (115.2±1.3) kJ/mol is obtained subsequently. Taking the retrogression treatment schedule of 190℃, 45 min derived from AA7055 thin plate as reference, the non-isothermal retrogression model for GBP coarsening behavior is established based on “LSW”theory and “iso-kinetics” solution, which includes an Arrhenius form equation. After that, the average size of GBP r(t) is predicted successfully at any non-isothermal process T(t) when the initial size of GBP r0 is given. Finally, the universal characterization method for the microstructure homogeneity along the thickness direction of TA55 aluminum alloy thick plate is also set up.展开更多
A new method was proposed, in which a high-power CO2 laser modulated by high frequency was used as the driv- ing source to heat up a surface-temperature sensor. The continual beam and the pulsed beam sent out by the s...A new method was proposed, in which a high-power CO2 laser modulated by high frequency was used as the driv- ing source to heat up a surface-temperature sensor. The continual beam and the pulsed beam sent out by the same laser could be used in the same system to carry on the static calibration of the radiation thermometer and the dynamic calibration of the temperature sensor to be checked. The frequency-response characteristics of high-speed radiation thermometer surpassed that of the temperature sensor, therefore it could be used as the reference value to calibrate the latter and let system error be cor- rected. Differences in the environment of the sensor installing and the error caused by the change of thermo-physical proper- ty could be avoided. Thus, the difficult problem of traceable dynamic calibration of temperature was solved. In experiment, to obtain the frequency characteristics of the thermocouple and the dynamic performance of the K type thermocouple, which could compensate the dynamic characteristics of the sensor, the sensor was dynamically corrected by using the method, and then the mathematical model was established.展开更多
We propose a novel thermal-conscious power model for integrated circuits that can accurately predict power and temperature under voltage scaling. Experimental results show that the leakage power consumption is underes...We propose a novel thermal-conscious power model for integrated circuits that can accurately predict power and temperature under voltage scaling. Experimental results show that the leakage power consumption is underestimated by 52 % if thermal effects are omitted. Furthermore, an inconsistency arises when energy and temperature are simultaneously optimized by dynamic voltage scaling. Temperature is a limiting factor for future integrated circuits,and the thermal optimization approach can attain a temperature reduction of up to 12℃ with less than 1.8% energy penalty compared with the energy optimization one.展开更多
The elementary reactions of propylene polymerization catalyzed by conventional Ziegler-Natta catalysts was proposed according to the comprehensive view and without considering the effect of any impurity in the materia...The elementary reactions of propylene polymerization catalyzed by conventional Ziegler-Natta catalysts was proposed according to the comprehensive view and without considering the effect of any impurity in the material on propylene polymerization. The Monte Carlo simulation technique was employed to investigate the kinetics of propylene polymerization in order to determine the validity of the stationary state assumption and the effects of the polymerization temperature on the polymerization. The simulated total amount of active species, which only increases quickly at the beginning of the polymerization, indicates that the stationary state assumption in the studied system is valid. Moreover, significant effects of polymerization temperature on the polymerization conversion, and the molecular weight and its distribution were also analyzed. The simulated results show that the consumption rate of propylene increases with the increase of polymerization temperature; the maximum values of the number-average degree of polymerization are constant at different polymerization temperatures, however, the peak appears earlier with the higher temperature; as the polymerization temperature increases, the average molecular weight decreases and the molecular weight distribution changes greatly.展开更多
The Mg-Ni hydride was prepared by hydriding combustion synthesis under a high magnetic field. The dehydriding kinetics of the hydrides was measured under the isothermal and non-isothermal conditions. A model was appli...The Mg-Ni hydride was prepared by hydriding combustion synthesis under a high magnetic field. The dehydriding kinetics of the hydrides was measured under the isothermal and non-isothermal conditions. A model was applied to analyzing the kinetics behavior of Mg-Ni hydride. The calculation results show that the theoretical value and the experimental data can reach a good agreement, especially in the case of non-isothermal dehydriding. The rate-controlling step is the diffusion of hydrogen atoms in the solid solution. The sample prepared under magnetic field of 6 T under the isothermal condition can reach the best performance. The similar tendency was observed under the non-isothermal condition and the reason was discussed.展开更多
Based on LabVlEW platform, a distributed dynamic storage testing system is designed for measuring transient high temperature signals of explosion field. Using a highpower semiconductor laser as heat source, a traceabl...Based on LabVlEW platform, a distributed dynamic storage testing system is designed for measuring transient high temperature signals of explosion field. Using a highpower semiconductor laser as heat source, a traceable dynamic calibration system is established to perform dynamic calibration of thermocouples. With quantumbehaved particle swam optimization (QP-SO) algorithm on MATLAB platform, a model of dynamic compensation filter is established. It is used by LabVIEW that calls MATLAB Script nodes or COM components to accomplish the mixed programming of LabVIEW and MATLAB, further to compensate the temperature values of the thermocouples dynamically. The experimental results show that the technique that combines temperature measurement system with LabVIEW platform is applied well in testing the explosion temperature of ther mobaric weaponry and makes the compensation values closer to the actual signals.展开更多
Viscose activated carbon fibers (ACFs) were characterized using specific surface area, scanning electron modified with chemical vapor deposition (CVD). The samples were microscopy (SEM), pore size distribution a...Viscose activated carbon fibers (ACFs) were characterized using specific surface area, scanning electron modified with chemical vapor deposition (CVD). The samples were microscopy (SEM), pore size distribution and Fourier transform infrared spectroscopy (FTIR). Batch adsorption experiments were carried out to investigate the adsorption behavior of modified ACFs for methyl orange(MO) from its aqueous solutions. The results show that the adsorption isotherms of MO onto modified ACFs well follows the Langmuir isotherm equation. The adsorption kinetics of MO can be well described by the pseudo second-order kinetic model. The adsorption process involves the intra-particle diffusion, but is not the only rate-controlling step. Thermodynamic parameters including AG, AH and AS were calculated, suggesting that the adsorption of MO onto modified ACFs is a spontaneous, exothermic and physisorption process. FTIR result indicates that the major adsorption mechanism of modified ACFs for MO is hydrogen bond.展开更多
α-Bi2O3 powders were prepared from nanometer Bi powders through low-temperature oxidation at less than 873.15 K. XRD, SEM, TEM and HRTEM were used to characterize the structure and morphology of Bi powders and Bi2O3 ...α-Bi2O3 powders were prepared from nanometer Bi powders through low-temperature oxidation at less than 873.15 K. XRD, SEM, TEM and HRTEM were used to characterize the structure and morphology of Bi powders and Bi2O3 particles. Kinetic studies on the bismuth oxidation at low-temperatures were carried out by TGA method. The results show that bismuth beads should be reunited and oxidized to become irregular Bi2O3 powders. The bismuth oxidation follows shrinking core model, and its controlling mechanism varies at different reaction time. Within 0-10 min, the kinetics is controlled by chemical reaction, after that it is controlled by O2 diffusion in the solid α-Bi2O3 layer. The apparent activation energy is determined as 55.19 kJ/mol in liquid-phase oxidation.展开更多
基金support from the National Natural Science Foundation of China(Nos.52031012,51904218)。
文摘A spiral fluidity test model of superalloys with 10 mm in height and 3 mm in thickness was designed to evaluate the fluidity of two distinct Ni-based superalloys IN718 and IN939.The factors influencing fluidity are ascertained through comparative analysis utilizing methodologies such as JMat Pro,differential scanning calorimetry and high-temperature confocal laser scanning microscopy.The results show that under identical testing conditions,the fluidity of the IN939 superalloy surpasses that of the IN718 superalloy.When subjected to the same temperature,the melt viscosity and surface tension of IN939 superalloy are considerably reduced relative to those of IN718 superalloy,which is beneficial to improving the melt fluidity.Furthermore,the liquidus temperature and solidification range for the IN939 superalloy are both smaller compared with those of the IN718 superalloy.This condition proves advantageous in delaying dendrite coherency,thereby improving fluidity.
基金Project (2002AA00104) supported by the National High-tech Research and Development Program of China
文摘A computational fluid dynamics (CFD) simulation was carried out with CFX4,3 to investigate the melt flow and temperature distributions in the settler of a flash furnace. Sixteen cases of one slag tap hole adopted with one matte tap hole (1-to-l) and one slag tap hole adopted with two matte tap holes (1-to-2) operation modes were modelled. The simulation results show that the melt flows are similar in both two operation modes, but evident circulations can be found in the case of the 1-to-2 operation mode. The combination modes of the slag and matte tap holes are found to have a significant effect on the temperature distributions of the melt. The melt temperature is more uniform in the case of the 1-to-2 mode. Selection of a matte tap hole farther away from the inlet is more conducive to achieve a uniform distribution of the melt temperature in the settler in nractical tannine oneration
基金The National Natural Science Foundation of China(No.51408043)the Natural Science Foundation of Shaanxi Province(No.2014JQ7278)
文摘The rheological properties including the complex modulus G* and the phase angle δof matrix and warm mix asphalt (WMA)binders were measured by using the dynamic shear rheometer (DSR ) test at the medium temperature ranging from 16 to 40 ℃,and the relationships between the fatigue factor G* sinδand the matrix binder property,WMA additive and test temperature were established.It is found that G* decreases with the increasing temperature while δincreases inversely,and G* of the asphalt binder with high WMA additive dosage is large,and δis small.G*sinδexponentially decreases with the increasing temperature and linearly increases with the increase in additive dosage,and the amplitudes of variation are large at low temperatures and high additive dosages.The effect of WMA additive on the rheological property is more remarkable for the matrix asphalt binder with low G*.Besides,aging has a great effect on the property of matrix asphalt binder,and a slight effect on the interaction between asphalt and additive.The high additive dosage can increase the fatigue cracking potential of the asphalt binder.
基金Project(201011005-5)supported by the National Land and Resources Public Welfare Scientific Research Project of ChinaProject(41030426)supported by the National Natural Science Foundation of China+1 种基金Project(20095122110015)supported by Specialized Research Fund for the Doctoral Program of Higher Education of ChinaProject(2010-32)supported by Scientific Research Foundation of the Education Ministry for Returned Chinese Scholars,China
文摘The single phase La2(CO3)3·3.4H2 O was synthesized by hydrothermal method. The thermal decomposition and intermediates and final solid products of La2(CO3)3·3.4H2O from 30 to 1000 °C were characterized by XRD, FTIR and DTA-TG. The kinetics of dehydration of La2(CO3)3·3.4H2O in the temperature range of 30-366 °C was investigated under non-isothermal conditions. Flynn-Wall-Ozawa and Friedman isoconversion methods were used to calculate the activation energy and analyze the reaction steps; multivariate non-linear regression program was applied to determine the most probable mechanism and the kinetic parameters. The results show that the thermal dehydration of La2(CO3)3·3.4H2O is a kind of three-step competitive reaction, and controlled by an n-order initial reaction followed by n-order competitive reaction(FnFnFn model). The activation energy matching with the most probable model is close to value obtained by Friedman method. The fitting curves match the original TG-DTG curves very well.
基金Supported by the National Natural Science Foundation of China (50772095)the Graduate Innovation Foundation of Jiangsu Province (CX09B-073Z)~~
文摘Warm tensile tests for aluminum alloy 7022 sheet are held at different temperatures and strain rates. The range of temperature is 293-773 K and that of the strain rate is 0. 001-0.1 s^-1. The warm tensile properties,relations among temperature,strain rate,and the flow stress are discussed. Constitutive equations under the warm tension are obtained based on revised Hooke law and Grosman equation. It is concluded that flow stress declines with the increase of the temperature and the decrease of the strain rates. The elongation percentage increases with the increase of the temperature and the decrease of strain rate.
基金Project(2012CB619505)supported by the National Basic Research Program of China
文摘The retrogression kinetics for grain boundary precipitate (GBP) of 7A55 aluminum alloy was investigated by transmission electron microscopy (TEM) observation. The results reveal that the coarsening behavior of GBP obeys “LSW” theory, namely, the cube of GBP average size has a linear dependence relation to retrogression time, and the coarsening rate accelerates at the elevated retrogression temperature. The GBP coarsening activation energy Qo of (115.2±1.3) kJ/mol is obtained subsequently. Taking the retrogression treatment schedule of 190℃, 45 min derived from AA7055 thin plate as reference, the non-isothermal retrogression model for GBP coarsening behavior is established based on “LSW”theory and “iso-kinetics” solution, which includes an Arrhenius form equation. After that, the average size of GBP r(t) is predicted successfully at any non-isothermal process T(t) when the initial size of GBP r0 is given. Finally, the universal characterization method for the microstructure homogeneity along the thickness direction of TA55 aluminum alloy thick plate is also set up.
基金Research Project Supported by Shanxi Scholarship Council of China(No.2012-068)Taiyuan Science and Technology Agency(No.120247-20)Surface-temperature Sensor Dynamic Measurement and Calibration Technology Research of National Defense Fundamental Scientific Research
文摘A new method was proposed, in which a high-power CO2 laser modulated by high frequency was used as the driv- ing source to heat up a surface-temperature sensor. The continual beam and the pulsed beam sent out by the same laser could be used in the same system to carry on the static calibration of the radiation thermometer and the dynamic calibration of the temperature sensor to be checked. The frequency-response characteristics of high-speed radiation thermometer surpassed that of the temperature sensor, therefore it could be used as the reference value to calibrate the latter and let system error be cor- rected. Differences in the environment of the sensor installing and the error caused by the change of thermo-physical proper- ty could be avoided. Thus, the difficult problem of traceable dynamic calibration of temperature was solved. In experiment, to obtain the frequency characteristics of the thermocouple and the dynamic performance of the K type thermocouple, which could compensate the dynamic characteristics of the sensor, the sensor was dynamically corrected by using the method, and then the mathematical model was established.
文摘We propose a novel thermal-conscious power model for integrated circuits that can accurately predict power and temperature under voltage scaling. Experimental results show that the leakage power consumption is underestimated by 52 % if thermal effects are omitted. Furthermore, an inconsistency arises when energy and temperature are simultaneously optimized by dynamic voltage scaling. Temperature is a limiting factor for future integrated circuits,and the thermal optimization approach can attain a temperature reduction of up to 12℃ with less than 1.8% energy penalty compared with the energy optimization one.
基金The National Natural Science Foundation of China(No.20406016)the Project of Fujian Petrochemical Company of SIN-OPEC (No.MS/FJ-08-JS-15-2005-01).
文摘The elementary reactions of propylene polymerization catalyzed by conventional Ziegler-Natta catalysts was proposed according to the comprehensive view and without considering the effect of any impurity in the material on propylene polymerization. The Monte Carlo simulation technique was employed to investigate the kinetics of propylene polymerization in order to determine the validity of the stationary state assumption and the effects of the polymerization temperature on the polymerization. The simulated total amount of active species, which only increases quickly at the beginning of the polymerization, indicates that the stationary state assumption in the studied system is valid. Moreover, significant effects of polymerization temperature on the polymerization conversion, and the molecular weight and its distribution were also analyzed. The simulated results show that the consumption rate of propylene increases with the increase of polymerization temperature; the maximum values of the number-average degree of polymerization are constant at different polymerization temperatures, however, the peak appears earlier with the higher temperature; as the polymerization temperature increases, the average molecular weight decreases and the molecular weight distribution changes greatly.
基金Project(51464008) supported by the National Natural Science Foundation of ChinaProject(KY[2012]004) supported by the Key Laboratory Item of Education Office in Guizhou Province,China
文摘The Mg-Ni hydride was prepared by hydriding combustion synthesis under a high magnetic field. The dehydriding kinetics of the hydrides was measured under the isothermal and non-isothermal conditions. A model was applied to analyzing the kinetics behavior of Mg-Ni hydride. The calculation results show that the theoretical value and the experimental data can reach a good agreement, especially in the case of non-isothermal dehydriding. The rate-controlling step is the diffusion of hydrogen atoms in the solid solution. The sample prepared under magnetic field of 6 T under the isothermal condition can reach the best performance. The similar tendency was observed under the non-isothermal condition and the reason was discussed.
基金The 11th Postgraduate Technology Innovation Project of North University of China(No.20141147)
文摘Based on LabVlEW platform, a distributed dynamic storage testing system is designed for measuring transient high temperature signals of explosion field. Using a highpower semiconductor laser as heat source, a traceable dynamic calibration system is established to perform dynamic calibration of thermocouples. With quantumbehaved particle swam optimization (QP-SO) algorithm on MATLAB platform, a model of dynamic compensation filter is established. It is used by LabVIEW that calls MATLAB Script nodes or COM components to accomplish the mixed programming of LabVIEW and MATLAB, further to compensate the temperature values of the thermocouples dynamically. The experimental results show that the technique that combines temperature measurement system with LabVIEW platform is applied well in testing the explosion temperature of ther mobaric weaponry and makes the compensation values closer to the actual signals.
基金Project (50802115) supported by the National Natural Science Foundation of ChinaProject (2010FJ4075) supported by Science and Technology Planning Project of Hunan Province, China+1 种基金Project (CDJJ-10010205) supported by the Science Foundation of Changsha University, ChinaProject supported by the Construct Program of the Key Discipline in Hunan Province, China
文摘Viscose activated carbon fibers (ACFs) were characterized using specific surface area, scanning electron modified with chemical vapor deposition (CVD). The samples were microscopy (SEM), pore size distribution and Fourier transform infrared spectroscopy (FTIR). Batch adsorption experiments were carried out to investigate the adsorption behavior of modified ACFs for methyl orange(MO) from its aqueous solutions. The results show that the adsorption isotherms of MO onto modified ACFs well follows the Langmuir isotherm equation. The adsorption kinetics of MO can be well described by the pseudo second-order kinetic model. The adsorption process involves the intra-particle diffusion, but is not the only rate-controlling step. Thermodynamic parameters including AG, AH and AS were calculated, suggesting that the adsorption of MO onto modified ACFs is a spontaneous, exothermic and physisorption process. FTIR result indicates that the major adsorption mechanism of modified ACFs for MO is hydrogen bond.
基金Project (2006BAB02B05-04- 01/02) supported by the National Key Technologies R&D Program of China
文摘α-Bi2O3 powders were prepared from nanometer Bi powders through low-temperature oxidation at less than 873.15 K. XRD, SEM, TEM and HRTEM were used to characterize the structure and morphology of Bi powders and Bi2O3 particles. Kinetic studies on the bismuth oxidation at low-temperatures were carried out by TGA method. The results show that bismuth beads should be reunited and oxidized to become irregular Bi2O3 powders. The bismuth oxidation follows shrinking core model, and its controlling mechanism varies at different reaction time. Within 0-10 min, the kinetics is controlled by chemical reaction, after that it is controlled by O2 diffusion in the solid α-Bi2O3 layer. The apparent activation energy is determined as 55.19 kJ/mol in liquid-phase oxidation.